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Bushnell et al., 1988 - Google Patents

Synthesis of the hexaamine ligand 1, 4, 7-tris (3-aminopropyl)-1, 4, 7-triazacyclononane: reactivity and x-ray crystal structures of the nickel (II) and cobalt (III) …

Bushnell et al., 1988

Document ID
1807497966964578384
Author
Bushnell G
Fortier D
McAuley A
Publication year
Publication venue
Inorganic Chemistry

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The synthesis of the ligand 1, 4, 7-tris (3-aminopropyl)-1, 4, 7-triazacyclononane (taptacn) may be achieved by the reaction of 1, 4, 7-triazacyclononane with an excess of acrylonitrile, followed by reduction of the nitrile with sodium metal in toluene. Halide salts of the cobalt …
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    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00Compounds containing elements of Groups 7 or 17 of the Periodic System
    • C07F13/005Compounds without a metal-carbon linkage
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    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073Rhodium compounds
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    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0046Ruthenium compounds
    • C07F15/0053Ruthenium compounds without a metal-carbon linkage
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    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/02Iron compounds
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    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
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    • C07F15/0086Platinum compounds
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    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/06Cobalt compounds
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    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
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    • C07F1/08Copper compounds
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    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic System
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