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Hart et al., 1974 - Google Patents

Possible photochemical (. pi. 4s+. pi. 2a) Diels-Alder reaction. Photodimerization of 6, 6-dimethyl-2, 3-benzo-2, 4-cycloheptadienone

Hart et al., 1974

Document ID
10102697242767084489
Author
Hart H
Miyashi T
Buchanan D
Sasson S
Publication year
Publication venue
Journal of the American Chemical Society

External Links

Snippet

Irradiation of the title compound 11 gave predominantly two stereoisomeric dimers, shown by chemical and X-ray crystal data to have the structures 16 and 17, together with a small amount of a cyclobutane dimer (19?). A mechanism which rationalizes the major products …
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