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Reactivity and Microstructure of Calcined Marl as Supplementary Cementitious Material

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Calcined Clays for Sustainable Concrete

Part of the book series: RILEM Bookseries ((RILEM,volume 10))

Abstract

The reactivity and microstructure of cement paste and mortar where cement is replaced by up to 65 vol.% calcined marl are discussed. It was found that the compressive strength evolution of mortar is following the same linear relation with amount of hydrate water at early ages for different cement replacements (35-65 vol.%), but that this deviates and give higher strength than predicted by the bound water at higher ages. Strength increases on a long term in spite of depleted calcium hydroxide at earlier ages and are discussed in terms of changes in CSH and CAH. XRD does not reveal any unusual crystalline products, but ettringite and hemi-/mono-carboaluminate hydrate. SEM with WDS in a 2 year old mortar found pure CAH in a pore with atomic Ca/Al = 1.6 and some Si that might be a hydrogarnet.

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References

  1. Justnes, H., Østnor, T., Danner, T.: Calcined marl as effective pozzolana. In: Proceedings of the International RILEM Conference on Advances in Construction Materials through Science and Engineering, RILEM PRO 79, Hong Kong, China, 8 p. 5–7 September 2011

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  2. Justnes, H., Østnor, T.A.: Durability and microstructure of mortar with calcined marl as supplementary cementing material. In: Proceedings of the XIII conference on Durability of Building Materials and Components (DBMC), Sao Paulo, Brazil, pp. 771–780, 3–5 September 2014

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  3. De Weerdt, K., Sellevold, E., Kjellsen, K.O., Justnes, H.: Fly ash—limestone ternary cements—effect of component fineness. Adv. Cem. Res. 23(4), 203–214 (2011)

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Acknowledgments

The paper is based on the work performed in COIN, see www.coinweb.no for information.

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Correspondence to Tone Østnor .

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© 2015 RILEM

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Østnor, T., Justnes, H., Danner, T. (2015). Reactivity and Microstructure of Calcined Marl as Supplementary Cementitious Material. In: Scrivener, K., Favier, A. (eds) Calcined Clays for Sustainable Concrete. RILEM Bookseries, vol 10. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-9939-3_29

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  • DOI: https://doi.org/10.1007/978-94-017-9939-3_29

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  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-017-9938-6

  • Online ISBN: 978-94-017-9939-3

  • eBook Packages: EngineeringEngineering (R0)

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