Summary
The reactions of [Fe(bipyz)3]2+ (bipyz = 2,2′-bipyrazine) and [Fe(box)3]2+ [box = 2,2′-bis-(5,6-dihydro-4-H-1,3-oxazine] with H2O and HO− in aqueous solution have been followed. The [Fe(bipyz)3]2+ ion is attacked at the ligand with both nucleophiles and the ligand is cleaved. A similar reaction between HO− and [Fe(box)3]2+ is observed. Detailed kinetics for all reactions are reported.
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- phen:
-
1,10-phenanthroline
- bipy:
-
2,2′-bipyridyl
- bipym:
-
2,2′-bipyrimidine
References
R. D. Gillard, W. S. Walters and P. A. Williams,J. Chem. Soc. Dalton Trans., in press, and refs. therein.
R. D. Gillard, R. J. Lancashire and P. A. Williams,Transition Met. Chem., 78/118.
M. J. Blandamer, J. Burgess, P. Cookson, D. L. Roberts, P. Wellings, F. M. Mekhail and P. Askalani,J. Chem. Soc. Dalton Trans., 996 (1978).
M. J. Blandamer, J. Burgess, R. I. Haines, F. M. Mekhail and P. Askalani,J. Chem. Soc. Dalton Trans., 1001 (1978).
J. Burgess and R. I. Haines,J. Chem. Soc. Dalton Trans., 1447 (1978).
J. J. Lafferty and F. H. Case,J. Org. Chem., 32, 1591 (1967).
H. Appel, German Patent No. 1411640 (1973);Chem. Abstr., 79, P53340y (1900)
R. D. Gillard, L. A. P. Kane-Maguire and P. A. Williams,J. Chem. Soc. Dalton Trans., 1039 (1977).
W. S. Walters, R. D. Gillard and P. A. Williams,Aust. J. Chem., 31, 1959 (1978).
A. Albert,Angew. Chem., 79, 913 (1967).
R. S. Sagitullin, A. N. Kost and G. G. Danagulyan,Tetrahedron Lett., 4135 (1978).
H. C. van der Plas and H. Jongejen,Tetrahedron Lett., 4385 (1967).
E. A. Oostveen and H. C. van der Plas,Rec. trav. Chim., 93, 233 (1974).
M. E. C. Biffin, D. J. Brown and T. C. Lee,J. Chem. Soc. C, 573 (1967).
A. R. Katritzky and J. M. Lagowski,Heterocyclic Chemistry, Methuen, London, 1960.
A. B. P. Lever, J. Lewis and R. S. Nyholm,J. Chem. Soc., 1187 (1964).
R. D. Gillard and P. A. Williams,Transition Met. Chem., 2, 109 (1977).
R. D. Gillard,Coord. Chem. Rev., 16, 67 (1975).
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Part XXV: R. D. Gillard, W. S. Walters and P. A. Williams,J. Chem. Soc. Dalton Trans., in press.
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Gillard, R.D., Knight, D.W. & Williams, P.A. Equilibria in complexes ofn-heterocyclic molecules, part XXVI. Reactions of hydroxide and water with the tris-(2,2′-bipyrazine)iron(II) and tris-[2,2′-bis-(5,6-dihydro-4-H-1,3-oxazine)]iron(II) ions. Transition Met Chem 4, 375–378 (1979). https://doi.org/10.1007/BF00623981
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DOI: https://doi.org/10.1007/BF00623981