Complexation of tungsten carbonyl moieties with C- and C,C-methylthio-derivatives of charge-compe... more Complexation of tungsten carbonyl moieties with C- and C,C-methylthio-derivatives of charge-compensated nido-carborane.
Five glycoconjugates were obtained from ortho-carboranylacetic acid and β-actosylamine or β-d-gal... more Five glycoconjugates were obtained from ortho-carboranylacetic acid and β-actosylamine or β-d-galactopyranosylamine derivatives with the terminal amino group in the spacer. The glycoconjugates have different lengths of the spacer (9 to 15 atoms) and contain two or three βlactosylamine residues or one, two, or three β-d-galactopyranosylamine residues.
Reactions of an amino derivative of the closo-decaborate anion [1-B10H9NH3]- with aromatic aldehy... more Reactions of an amino derivative of the closo-decaborate anion [1-B10H9NH3]- with aromatic aldehydes afforded Schiff bases [1-B10H9NH=CHAr]- (Ar=Ph, C6H4-2-OMe, or C6H4-4-NHCOMe). The reduction of the latter with sodium borohydride gave the corresponding benzylamino derivatives [1-B10H9NH2CH2Ar]-.
p-Carborane has been arylated on the 2-B-atom in high yields, using the Suzuki–Miyaura reaction. ... more p-Carborane has been arylated on the 2-B-atom in high yields, using the Suzuki–Miyaura reaction. Thus the reaction between 2-I-p-carborane and various arylboronic acids [1-naphthyl-, phenyl-, 4-MeOC6H4, 3-CH3CONHC6H4, 4-NCC6H4, 3-NO2C6H4], gave the corresponding 2-aryl-p-carboranes in DME solution when reacted in the presence of cesium fluoride and the catalytic Pd2(dba)3–dppb system.
... Vladimir V. Nesterov, † Mikhail Yu. Antipin, † Vladimir I. Bregadze, † and Stefan Sjöberg ‡. ... more ... Vladimir V. Nesterov, † Mikhail Yu. Antipin, † Vladimir I. Bregadze, † and Stefan Sjöberg ‡. AN Nesmeyanov Institute of Organo-Element Compounds, Russian Academy of Sciences, Vavilov Str. 28, 117813, Moscow, Russia, Department ...
Complexation of tungsten carbonyl moieties with C- and C,C-methylthio-derivatives of charge-compe... more Complexation of tungsten carbonyl moieties with C- and C,C-methylthio-derivatives of charge-compensated nido-carborane.
Five glycoconjugates were obtained from ortho-carboranylacetic acid and β-actosylamine or β-d-gal... more Five glycoconjugates were obtained from ortho-carboranylacetic acid and β-actosylamine or β-d-galactopyranosylamine derivatives with the terminal amino group in the spacer. The glycoconjugates have different lengths of the spacer (9 to 15 atoms) and contain two or three βlactosylamine residues or one, two, or three β-d-galactopyranosylamine residues.
Reactions of an amino derivative of the closo-decaborate anion [1-B10H9NH3]- with aromatic aldehy... more Reactions of an amino derivative of the closo-decaborate anion [1-B10H9NH3]- with aromatic aldehydes afforded Schiff bases [1-B10H9NH=CHAr]- (Ar=Ph, C6H4-2-OMe, or C6H4-4-NHCOMe). The reduction of the latter with sodium borohydride gave the corresponding benzylamino derivatives [1-B10H9NH2CH2Ar]-.
p-Carborane has been arylated on the 2-B-atom in high yields, using the Suzuki–Miyaura reaction. ... more p-Carborane has been arylated on the 2-B-atom in high yields, using the Suzuki–Miyaura reaction. Thus the reaction between 2-I-p-carborane and various arylboronic acids [1-naphthyl-, phenyl-, 4-MeOC6H4, 3-CH3CONHC6H4, 4-NCC6H4, 3-NO2C6H4], gave the corresponding 2-aryl-p-carboranes in DME solution when reacted in the presence of cesium fluoride and the catalytic Pd2(dba)3–dppb system.
... Vladimir V. Nesterov, † Mikhail Yu. Antipin, † Vladimir I. Bregadze, † and Stefan Sjöberg ‡. ... more ... Vladimir V. Nesterov, † Mikhail Yu. Antipin, † Vladimir I. Bregadze, † and Stefan Sjöberg ‡. AN Nesmeyanov Institute of Organo-Element Compounds, Russian Academy of Sciences, Vavilov Str. 28, 117813, Moscow, Russia, Department ...
Uploads
Papers by Igor Sivaev