Petroleum hydrocarbons (PHs) in contaminated sites may threaten human health and ecological safety, while the environmental behaviors of PHs with varying carbon chains and critical influencing factors need to be elucidated, thus facilitating efficient risk management. This study explored the occurrence characteristics and spatial variations of different PHs at the depths of 0-10 m in an abandoned industrial site, as well as evaluated the effects of solid organic matter (SOM), dissolved organic matter (DOM), and soil texture on the migration potentials of PHs with varying carbon chains. Furthermore, the leaching potentials of different PHs were integrated into their risk assessment. The total concentrations of PHs in contaminated soils ranged from 22.7 to 397 mg/kg in contaminated soils, and the long-chained PHs (C22-C40) represented the major components with an average contribution of 46.9 %, followed by short-chained PHs (C10-C12, 32.0 % average) and medium-chained PHs (C13-C21, 21.1 % average). As soil depth increased, a declining trend was observed in the proportions of long-chain PHs, with an augmentation in the relative abundance of short-chain PHs. The random forest model coupling redundancy analysis showed that SOM was the major contributor to the occurrence and vertical attenuation of PHs with longer carbon chains in underground soils, with clay component exerting a greater additional effect than silt and sand components. While DOM in soils exhibited a relatively high contribution to the retention of PHs with short carbon chains. These results demonstrated the significant influence of SOM and clay on the behavior of long-chained PHs and DOM on that of short-chained ones. Besides direct human exposure, the leaching potentials of PHs, particularly short-chained ones, in soils should be considered for a more comprehensive risk assessment. The findings of this study may assist with the behavior modelling and prediction of different PHs as well as the corresponding risk control.