Mass number

Different types of radioactive decay are characterized by their changes in mass number as well as atomic number, according to the radioactive displacement law of Fajans and Soddy. For example, uranium-238 usually decays by alpha decay, where the nucleus loses two neutrons and two protons in the form of an alpha particle. Thus the atomic number and the number of neutrons each decrease by 2 (Z: 92 → 90, N: 146 → 144), so that the mass number decreases by 4 (A = 238 → 234); the result is an atom of thorium-234 and an alpha particle (⁴
₂He²⁺
):^[4]

238 92U

→

234 90Th

+

4 2He2+

On the other hand, carbon-14 decays by beta decay, whereby one neutron is transmuted into a proton with the emission of an electron and an antineutrino. Thus the atomic number increases by 1 (Z: 6 → 7) and the mass number remains the same (A = 14), while the number of neutrons decreases by 1 (N: 8 → 7).^[5] The resulting atom is nitrogen-14, with seven protons and seven neutrons:

14 6C

→

14 7N

+

e−

+

ν e

Beta decay is possible because different isobars^[6] have mass differences on the order of a few electron masses. If possible, a nuclide will undergo beta decay to an adjacent isobar with lower mass. In the absence of other decay modes, a cascade of beta decays terminates at the isobar with the lowest atomic mass.

Another type of radioactive decay without change in mass number is emission of a gamma ray from a nuclear isomer or metastable excited state of an atomic nucleus. Since all the protons and neutrons remain in the nucleus unchanged in this process, the mass number is also unchanged.

The mass number gives an estimate of the isotopic mass measured in atomic mass units (u). For ¹²C, the isotopic mass is exactly 12, since the atomic mass unit is defined as 1/12 of the mass of ¹²C. For other isotopes, the isotopic mass is usually within 0.1 u of the mass number. For example, ³⁵Cl (17 protons and 18 neutrons) has a mass number of 35 and an isotopic mass of 34.96885.^[7] The difference of the actual isotopic mass minus the mass number of an atom is known as the mass excess,^[8] which for ³⁵Cl is –0.03115. Mass excess should not be confused with mass defect which is the difference between the mass of an atom and its constituent particles (namely protons, neutrons and electrons).

There are two reasons for mass excess:

1. The neutron is slightly heavier than the proton. This increases the mass of nuclei with more neutrons than protons relative to the atomic mass unit scale based on ¹²C with equal numbers of protons and neutrons.
2. Nuclear binding energy varies between nuclei. A nucleus with greater binding energy has a lower total energy, and therefore a lower mass according to Einstein's mass–energy equivalence relation E = mc². For ³⁵Cl, the isotopic mass is less than 35, so this must be the dominant factor.

The mass number should also not be confused with the standard atomic weight (also called atomic weight) of an element, which is the ratio of the average atomic mass of the different isotopes of that element (weighted by abundance) to the atomic mass constant.^[9] The atomic weight is a mass ratio, while the mass number is a counted number (and so an integer).

This weighted average can be quite different from the near-integer values for individual isotopic masses. For instance, there are two main isotopes of chlorine: chlorine-35 and chlorine-37. In any given sample of chlorine that has not been subjected to mass separation there will be roughly 75% of chlorine atoms which are chlorine-35 and only 25% of chlorine atoms which are chlorine-37. This gives chlorine a relative atomic mass of 35.5 (actually 35.4527 g/mol).

Moreover, the weighted average mass can be near-integer, but at the same time not corresponding to the mass of any natural isotope. For example, bromine has only two stable isotopes, ⁷⁹Br and ⁸¹Br, naturally present in approximately equal fractions, which leads to the standard atomic mass of bromine close to 80 (79.904 g/mol),^[10] even though the isotope ⁸⁰Br with such mass is unstable.

• Bishop, Mark. "The Structure of Matter and Chemical Elements (ch. 3)". An Introduction to Chemistry. Chiral Publishing. p. 93. ISBN 978-0-9778105-4-3. Retrieved 2008-07-08.