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Synthesis of N- and S-Vinyl Derivatives of Heteroaromatic Compounds Using Phase-transfer Catalysis

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A method has been developed for the synthesis of N- and S-vinyl derivatives of heteroaromatic compounds from NH heterocycles or their thiols in the phase-transfer catalytic system ClCH2CH2Br-KOH (s)-18-crown-6-toluene. It is shown that it is possible to prepare N,S-divinyl derivatives of 3-mercaptoindole and 2-mercaptobenzimidazole.

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Authors and Affiliations

  1. Latvian Institute of Organic Synthesis, Riga, LV-1006

    E. Abele, O. Dzenitis, K. Rubina & E. Lukevics

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  1. E. Abele
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  2. O. Dzenitis
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  3. K. Rubina
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  4. E. Lukevics
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Abele, E., Dzenitis, O., Rubina, K. et al. Synthesis of N- and S-Vinyl Derivatives of Heteroaromatic Compounds Using Phase-transfer Catalysis. Chemistry of Heterocyclic Compounds 38, 682–685 (2002). https://doi.org/10.1023/A:1019913218413

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  • DOI: https://doi.org/10.1023/A:1019913218413

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