Abstract
Intrusion of synthetic textile dyes in the ecosystem has been recognized as a serious issue worldwide. The effluents generated from textiles contain large amount of recalcitrant unfixed dyes which are regarded as emerging contaminants in the field of waste water study. Removal of various toxic dyes often includes diverse and complex set of physico-chemical, biological and advanced oxidation processes adopted for treatment. Adsorption in itself is a well-known technique utilized for treatment of textile effluents using a variety of adsorbents. In addition, ozonation deals with effective removal of dyes using high oxidising power of ozone. The review summarizes dye removal study by a combination of ozonation and adsorption methods. Also, to acquire an effective interpretation of this combined approach of treating wastewater, a thorough study has been made which is deliberated here. Results assert that, with the combined ability of ozone and a catalyst/adsorbent, there is high possibility of total elimination of dyes from waste water. Several synthetically prepared materials have been used along with few natural materials during the combined treatment. However, considering practical applicability, some areas were identified during the study where work needs to be done for effective implementation of the combined treatment.
Similar content being viewed by others
References
Cooper P. Removing colour from dyehouse waste waters: a critical review of technology available. Journal of the Society of Dyers and Colourists, 1993, 109(3): 97–100
Rajkumar D, Song B J, Kim J G. Electrochemical degradation of Reactive Blue 19 in chloride medium for the treatment of textile dyeing wastewater with identification of intermediate compounds. Dyes and Pigments, 2007, 72(1): 1–7
Mittal A, Kaur D, Mittal J. Batch and bulk removal of a triarylmethane dye, Fast Green FCF, from wastewater by adsorption over waste materials. Journal of Hazardous Materials, 2009, 163(2-3): 568–577
Robinson T, Mc Mullan G, Marchant R, Nigam P. Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. Bioresource Technology, 2001, 77(3): 247–255
Mittal A, Kaur D, Mittal J. Applicability of waste materials–bottom ash and deoiled soya–as adsorbents for the removal and recovery of a hazardous dye, brilliant green. Journal of Colloid and Interface Science, 2008, 326(1): 8–17
Bapat S A, Jaspal D K. Parthenium hysterophorus: novel adsorbent for the removal of heavy metals and dyes. Global Journal of Environmental Science and Management, 2016, 2(2): 135–144
Gupta V K, Khamparia S, Tyagi I, Jaspal D, Malviya A. Decolorization of mixture of dyes: a critical review. Global Journal of Environmental Science and Management, 2015, 1(1): 71–94
Pearce C I, Lloyd J R, Guthrie J T. The removal of colour from textile wastewater using whole bacterial cells: a review. Dyes and Pigments, 2003, 58(3): 179–196
Khamparia S, Jaspal D. Investigation of adsorption of Rhodamine B onto a natural adsorbent Argemone mexicana. Journal of Environmental Management, 2016, 183(P3): 786–793
Joshi M, Bansal R, Purwar R. Colour removal from textile effluents. Indian Journal of Fibre and Textile Research, 2004, 29(2): 239–259
Anjaneyulu Y, Chary N S, Raj D S. Decolourization of industrial effluents–available methods and emerging technologies: a review. Reviews in Environmental Science and Biotechnology, 2005, 4(4): 245–273
Adegoke K A, Bello O S. Dye sequestration using agricultural wastes as adsorbents. Water Resources and Industry, 2015, 12: 8–24
Guo Y, Yang L, Cheng X, Wang X. The application and reaction mechanism of catalytic ozonation in water treatment. Journal of Environmental and Analytical Toxicology, 2012, 2(7): 1–6
Gogate P R, Pandit A B. A review of imperative technologies for wastewater treatment II: hybrid methods. Advances in Environmental Research, 2004, 8(3): 553–597
Oller I, Malato S, Sánchez-Pérez J A. Combination of Advanced Oxidation Processes and biological treatments for wastewater decontamination: a review. Science of the Total Environment, 2011, 409(20): 4141–4166
van der Zee F P, Villaverde S. Combined anaerobic-aerobic treatment of azo dyes: a short review of bioreactor studies. Water Research, 2005, 39(8): 1425–1440
Beltran F J, Rivas F J, Gimeno O. Comparison between photocatalytic ozonation and other oxidation processes for the removal of phenols from water. Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire), 2005, 80(9): 973–984
de Moraes S G, Freire R S, Durán N. Degradation and toxicity reduction of textile effluent by combined photocatalytic and ozonation processes. Chemosphere, 2000, 40(4): 369–373
Anandan S, Lee G J, Chen P K, Fan C, Wu J J. Removal of orange II dye in water by visible light assisted photocatalytic ozonation using Bi2O3 and Au/Bi2O3 nanorods. Industrial & Engineering Chemistry Research, 2010, 49(20): 9729–9737
Agustina T E, Ang H M, Vareek V K. A review of synergistic effect of photocatalysis and ozonation on wastewater treatment. Journal of Photochemistry and Photobiology C, Photochemistry Reviews, 2005, 6(4): 264–273
Ghoreishi S M, Haghighi R. Chemical catalytic reaction and biological oxidation for treatment of non-biodegradable textile effluent. Chemical Engineering Journal, 2003, 95(1): 163–169
Lee L Y, Ng H Y, Ong S L, Hu J Y, Tao G, Kekre K, Viswanath B, Lay W, Seah H. Ozone-biological activated carbon as a pretreatment process for reverse osmosis brine treatment and recovery. Water Research, 2009, 43(16): 3948–3955
García-Montaño J, Domènech X, García-Hortal J A, Torrades F, Peral J. The testing of several biological and chemical coupled treatments for Cibacron Red FN-R azo dye removal. Journal of Hazardous Materials, 2008, 154(1-3): 484–490
Libra J A, Sosath F. Combination of biological and chemical processes for the treatment of textile wastewater containing reactive dyes. Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire), 2003, 78(11): 1149–1156
Stock N L, Peller J, Vinodgopal K, Kamat P V. Combinative sonolysis and photocatalysis for textile dye degradation. Environmental Science & Technology, 2000, 34(9): 1747–1750
Tezcanli-Güyer G, Ince N H. Individual and combined effects of ultrasound, ozone and UV irradiation: a case study with textile dyes. Ultrasonics, 2004, 42(1-9): 603–609
Chakraborty S, De S, Basu J K, Das Gupta S. Treatment of a textile effluent: application of a combination method involving adsorption and nanofiltration. Desalination, 2005, 174(1): 73–85
Mittal A, Malviya A, Kaur D, Mittal J, Kurup L. Studies on the adsorption kinetics and isotherms for the removal and recovery of Methyl Orange from wastewaters using waste materials. Journal of Hazardous Materials, 2007, 148(1-2): 229–240
Prieto O, Fermoso J, Nunez Y, Del Valle J L, Irusta R. Decolouration of textile dyes in wastewaters by photocatalysis with TiO2. Solar Energy, 2005, 79(4): 376–383
Khamparia S, Jaspal D. Adsorptive removal of Direct Red 81 dye from aqueous solution onto Argemone mexicana. Sustainable Environment Research, 2016, 26(3): 117–123
Orge C A, Sousa J P, Gonçalves F, Freire C, Órfao J J, Pereira M F. Development of novel mesoporous carbon materials for the catalytic ozonation of organic pollutants. Catalysis Letters, 2009, 132(1-2): 1–9
Crini G. Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment. Progress in Polymer Science, 2005, 30(1): 38–70
de Souza S M, Bonilla K A, de Souza A A. Removal of COD and color from hydrolyzed textile azo dye by combined ozonation and biological treatment. Journal of Hazardous Materials, 2010, 179(1-3): 35–42
Valdes H, Sanchez-Polo M, Rivera-Utrilla J, Zaror C A. Effect of ozone treatment on surface properties of activated carbon. Langmuir, 2002, 18(6): 2111–2116
Faria P C, Orfao J J, Pereira M F. Ozone decomposition in water catalyzed by activated carbon: influence of chemical and textural properties. Industrial & Engineering Chemistry Research, 2006, 45 (8): 2715–2721
Arslan-Alaton I, Seremet O. Advanced treatment of biotreated textile industry wastewater with ozone, virgin/ozonated granular activated carbon and their combination. Journal of Environmental Science and Health. Part A, 2004, 39(7): 1681–1694
Chiang H L, Huang C P, Chiang P C. The surface characteristics of activated carbon as affected by ozone and alkaline treatment. Chemosphere, 2002, 47(3): 257–265
Pereira MF, Goncalves A G, Orfao J J. Carbon materials as catalysts for the ozonation of organic pollutants in water. Boletin del Grupo Espanol del Carbon, 2014, (31): 18–24
Avramescu SM, Mihalache N, Bradu C, Neata M, Udrea I. Catalytic ozonation of acid red 88 from aqueous solutions. Catalysis Letters, 2009, 129(3–4): 273–280
Jans U, Hoigne J. Activated carbon and carbon black catalyzed transformation of aqueous ozone into OH radicals. Ozone Science and Engineering, 1998, 20(1): 67–90
Beltran F J, Masa F J, Pocostales J P. A comparison between catalytic ozonation and activated carbon adsorption/ozone-regeneration processes for wastewater treatment. Applied Catalysis B: Environmental, 2009, 92(3): 393–400
Faria P C, Orfão J J, Pereira M F. Mineralisation of coloured aqueous solutions by ozonation in the presence of activated carbon. Water Research, 2005, 39(8): 1461–1470
Arslan-Alaton I. Pretreatment of textile dye carriers with ozonation and enhanced ozonation. Environmental Engineering Science, 2004, 21(4): 507–514
Liu S S, He J X. Research on Reuse of Low Concentration Dyeing Effluent Decolorized Continuously On-line by Ozone Combined with Active Carbon. Journal of Donghua University, 2006, 2: 3 (Natural Science)
Soares O S, Faria P C, Orfao J J, Pereira M F. Ozonation of textile effluents and dye solutions in the presence of activated carbon under continuous operation. Separation Science and Technology, 2007, 42 (7): 1477–1492
Lei L, Gu L, Zhang X, Su Y. Catalytic oxidation of highly concentrated real industrial wastewater by integrated ozone and activated carbon. Applied Catalysis A, General, 2007, 327(2): 287–294
Gao L, Zhai Y, Ma H, Wang B. Degradation of cationic dye methylene blue by ozonation assisted with kaolin. Applied Clay Science, 2009, 46(2): 226–229
Beak M H, Ijagbemi C O, Kim D S. Azo dye Acid Red 27 decomposition kinetics during ozone oxidation and adsorption processes. Journal of Environmental Science and Health. Part A, 2009, 44(6): 623–629
Konsowa A H, Ossman M E, Chen Y, Crittenden J C. Decolorization of industrial wastewater by ozonation followed by adsorption on activated carbon. Journal of Hazardous Materials, 2010, 176(1-3): 181–185
Huang F, Luo M, Cui L, Wu G. Catalytic ozonation of methylene blue in aqueous solution by loading transition metal (Co/Cu/Fe/Mn) on carbon. Korean Journal of Chemical Engineering, 2015, 32(2): 268–273
He H, Wu D, Lv Y, Ma L. Enhanced mineralization of aqueous Reactive Black 5 by catalytic ozonation in the presence of modified GAC. Desalination and Water Treatment, 2016, 57(32): 14997–15006
Oguz E, Keskinler B. Removal of colour and COD from synthetic textile wastewaters using O3, PAC, H2O2 and HCO3-. Journal of Hazardous Materials, 2008, 151(2-3): 753–760
Sun B, Gao M, Arowo M, Wang J, Chen J, Meng H, Shao L. Ozonation of Acid Red 14 in the presence of inorganic salts in a microporous tube-in-tube microchannel reactor. Industrial & Engineering Chemistry Research, 2014, 53(49): 19071–19076
Perez A A, Poznyak T I, Chairez J I. Effect of the interaction between dye and acetic acid on the decomposition of Basic Green 4 with additive by ozone. Journal of Environmental Science and Health. Part A, 2014, 49(1): 18–26
Lin S H. Adsorption of disperse dye by powdered activated carbon. Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire), 1993, 57(4): 387–391
Papic S, Koprivanac N, Bozic A L, Metes A. Removal of some reactive dyes from synthetic wastewater by combined Al (III) coagulation/carbon adsorption process. Dyes and Pigments, 2004, 62(3): 291–298
Harrelkas F, Azizi A, Yaacoubi A, Benhammou A, Pons M N. Treatment of textile dye effluents using coagulation–flocculation coupled with membrane processes or adsorption on powdered activated carbon. Desalination, 2009, 235(1): 330–339
Rivera-Utrilla J, Méndez-Díaz J, Sánchez-Polo M, Ferro-García M A, Bautista-Toledo I. Removal of the surfactant sodium dodecylbenzenesulphonate from water by simultaneous use of ozone and powdered activated carbon: comparison with systems based on O3 and O3/H2O2. Water Research, 2006, 40(8): 1717–1725
Beltrán F J, Pocostales J P, Alvarez P M, Jaramillo J. Mechanism and kinetic considerations of TOC removal from the powdered activated carbon ozonation of diclofenac aqueous solutions. Journal of Hazardous Materials, 2009, 169(1-3): 532–538
Kovalova L, Siegrist H, von Gunten U, Eugster J, Hagenbuch M, Wittmer A, Moser R, Mc Ardell C S. Elimination of micropollutants during post-treatment of hospital wastewater with powdered activated carbon, ozone, and UV. Environmental Science & Technology, 2013, 47(14): 7899–7908
Zhang J C, Wang Y H, Song L F, Hu J Y, Ong S L, NgWJ, Lee L Y. Feasibility investigation of refinery wastewater treatment by combination of PACs and coagulant with ultrafiltration. Desalination, 2005, 174(3): 247–256
Feng Y, Shi W J, Tan D J, Chen Q Y, Zhang H H, Du S. Tertiary purification of biologically–treated effluent of dye-making wastewater by activated carbon catalytic ozonation. Acta Scientiae Circumstantiae, 2013, 10: 12
Wu G, Wei W, Cui L. Adsorption and catalytic ozonation performance of activated carbon and cobalt-supported activated carbon derived from brewing yeast. Canadian Journal of Chemical Engineering, 2014, 92(1): 36–40
Gul S, Ozcan O, Erbatur O. Ozonation of CI Reactive Red 194 and CI Reactive Yellow 145 in aqueous solution in the presence of granular activated carbon. Dyes and Pigments, 2007, 75(2): 426–431
Gholami-Borujeni F, Naddafi K, Nejatzade-Barandozi F. Application of catalytic ozonation in treatment of dye from aquatic solutions. Desalination and Water Treatment, 2013, 51(34-36): 6545–6551
Pachhade K, Sandhya S, Swaminathan K. Ozonation of reactive dye, Procion Red MX-5B catalyzed by metal ions. Journal of Hazardous Materials, 2009, 167(1-3): 313–318
Wu C H, Kuo C Y, Chang C L. Decolorization of azo dyes using catalytic ozonation. Reaction Kinetics and Catalysis Letters, 2007, 91(1): 161–168
Li Z, Zhao J, Zhong W, Duan E, Li G, Liu Y, Gao X. Efficiency and kinetics of catalytic ozonation of Acid Red B over Cu-Mn/g-Al2O3 catalysts. Ozone Science and Engineering, 2015, 37(3): 287–293
Khuntia S, Majumder S K, Ghosh P. Catalytic ozonation of dye in a microbubble system: hydroxyl radical contribution and effect of salt. Journal of Environmental Chemical Engineering, 2016, 4(2): 2250–2258
Mehta B, Chokshi N, Ruparelia J P. A Cerium oxide supported on Activated Carbon for Catalytic Ozonation of Reactive Black-5. CHEMCON-2014 IICHE, 2014 https://www.researchgate.net/profile/Nikita_Chokshi/publication/273125248_A_CERIUM_OXIDE_SUPPORTED_ON_ACTIVATED_CARBON_FOR_CATALYTIC_OZONATION_OF_REACTIVE_BLACK-5/links/54f7fcdd0cf210398e93be96.pdf
Wu J, Gao H, Yao S, Chen L, Gao Y, Zhang H. Degradation of crystal violet by catalytic ozonation using Fe/activated carbon catalyst. Separation and Purification Technology, 2015, 147: 179–185
Polat D, Balci I, Ozbelge T A. Catalytic ozonation of an industrial textile wastewater in a heterogeneous continuous reactor. Journal of Environmental Chemical Engineering, 2015, 3(3): 1860–1871
Sun H, Sun M, Zhang Y, Quan X. Catalytic ozonation of reactive red X-3B in aqueous solution under low pressure: decolorization and OH$ generation. Frontiers of Environmental Science & Engineering, 2015, 9(4): 591–595
Asgari G, Hoseinzadeh E, Taghavi M, Jafari J, Sidmohammadi A. Removal of Reactive Black 5 from Aqueous solution using catalytic. Jundishapur Journal of Health Sciences, 2012, 4(2): 21–30
Liu X, Zhou Z, Jing G, Fang J. Catalytic ozonation of Acid Red B in aqueous solution over a Fe–Cu–O catalyst. Separation and Purification Technology, 2013, 115: 129–135
Orge C A, Orfao J J, Pereira M F, Barbero B P, Cadus L E. Lanthanum-based perovskites as catalysts for the ozonation of selected organic compounds. Applied Catalysis B: Environmental, 2013, 140: 426–432
Hassan M, Hawkyard C J. Decolourisation of dyes and dye house effluent in a bubble-column reactor by heterogeneous catalytic ozonation. Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire), 2006, 81(2): 201–207
Faria P C, Orfao J J, Pereira M F. Activated carbon and ceria catalysts applied to the catalytic ozonation of dyes and textile effluents. Applied Catalysis B: Environmental, 2009, 88(3): 341–350
Pirgalioglu S, Ozbelge T A. Comparison of non-catalytic and catalytic ozonation processes of three different aqueous single dye solutions with respect to powder copper sulfide catalyst. Applied Catalysis A, General, 2009, 363(1): 157–163
Chen H W, Kuo Y L, Chiou C S, You S W, Ma C M, Chang C T. Mineralization of reactive Black 5 in aqueous solution by ozone/H2O2 in the presence of a magnetic catalyst. Journal of Hazardous Materials, 2010, 174(1-3): 795–800
Zhu S N, Hui K N, Hong X, Hui K S. Catalytic ozonation of basic Yellow 87 with a reusable catalyst chip. Chemical Engineering Journal, 2014, 242: 180–186
Lu J, Wei X, Chang Y, Tian S, Xiong Y. Role of Mg in mesoporous MgFe2O4 for efficient catalytic ozonation of Acid Orange II. Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire), 2016, 91(4): 985–993
Moussavi G, Mahmoudi M. Degradation and biodegradability improvement of the reactive Red 198 azo dye using catalytic ozonation with MgO nanocrystals. Chemical Engineering Journal, 2009, 152(1): 1–7
Pugazhenthiran N, Sathishkumar P, Murugesan S, Anandan S. Effective degradation of Acid Orange 10 by catalytic ozonation in the presence of Au-Bi2O3 nanoparticles. Chemical Engineering Journal, 2011, 168(3): 1227–1233
Zhang S, Wang D, Quan X, Zhou L, Zhang X. Multi-walled carbon nanotubes immobilized on zero-valent iron plates (Fe0-CNTs) for catalytic ozonation of methylene blue as model compound in a bubbling reactor. Separation and Purification Technology, 2013, 116: 351–359
Qu R, Xu B, Meng L, Wang L, Wang Z. Ozonation of indigo enhanced by carboxylated carbon nanotubes: performance optimization, degradation products, reaction mechanism and toxicity evaluation. Water Research, 2015, 68: 316–327
Hu E, Wu X, Shang S, Tao X M, Jiang S X, Gan L. Catalytic ozonation of simulated textile dyeing wastewater using mesoporous carbon aerogel supported copper oxide catalyst. Journal of Cleaner Production, 2016, 112: 4710–4718
Valdés H, Tardón R F, Zaror C A. Methylene blue removal from contaminated waters using heterogeneous catalytic ozonation promoted by natural zeolite: mechanism and kinetic approach. Environmental Technology, 2012, 33(16-18): 1895–1903
Wang Y H, Zhang J C, Song L F, Hu J Y, Ong S L, Ng W J. Adsorption removal of phenol in water and simultaneous regeneration by catalytic oxidation. Environmental Engineering Science, 2005, 22(5): 608–614
Dong Y, He K, Zhao B, Yin Y, Yin L, Zhang A. Catalytic ozonation of azo dye active brilliant red X-3B in water with natural mineral brucite. Catalysis Communications, 2007, 8(11): 1599–1603
Valdés H, Godoy H P, Zaror C A. Heterogeneous catalytic ozonation of cationic dyes using volcanic sand. Water Science and Technology, 2010, 61(12): 2973–2978
Gül S, Eren O, Kir S, Onal Y. A comparison of different activated carbon performances on catalytic ozonation of a model azo reactive dye. Water Science and Technology, 2012, 66(1): 179–184
Valdés H, Tardón R F, Zaror C A. Methylene blue removal from contaminated waters using O3, natural zeolite, and O3/zeolite. Water Science and Technology, 2009, 60(6): 1419–1424
Valdes H, Tardon R F, Zaror C A. Role of surface hydroxyl groups of acid-treated natural zeolite on the heterogeneous catalytic ozonation of methylene blue contaminated waters. Chemical Engineering Journal, 2012, 211: 388–395
Taseidifar M, Khataee A, Vahid B, Khorram S, Joo SW. Production of nanocatalyst from natural magnetite by glow discharge plasma for enhanced catalytic ozonation of an oxazine dye in aqueous solution. Journal of Molecular Catalysis A Chemical, 2015, 404: 218–226
Moussavi G, Khosravi R. Preparation and characterization of a biochar from pistachio hull biomass and its catalytic potential for ozonation of water recalcitrant contaminants. Bioresource Technology, 2012, 119: 66–71
Reddy P M, Krushnamurty K, Mahammadunnisa S K, Dayamani A, Subrahmanyam C. Preparation of activated carbons from bio-waste: effect of surface functional groups on methylene blue adsorption. International Journal of Environmental Science and Technology, 2015, 12(4): 1363–1372
Torres-Blancas T, Roa-Morales G, Barrera-Diaz C, Urena-Nunez F, Cruz-Olivares J, Balderas-Hernandez P, Natividad R. Ozonation of Indigo Carmine Enhanced by Fe/Pimenta dioica L. Merrill Particles. International Journal of Photoenergy, 2015, 2015: 1–9
Zhang S, Wang D, Zhang S, Zhang X, Fan P. Ozonation and carbonassisted ozonation of methylene blue as model compound: effect of solution pH. Procedia Environmental Sciences, 2013, 18: 493–502
Acknowledgements
One of the authors (SK) is thankful to the financial support provided by Symbiosis International University to carry out this research under Junior Research Fellowship program.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Khamparia, S., Jaspal, D.K. Adsorption in combination with ozonation for the treatment of textile waste water: a critical review. Front. Environ. Sci. Eng. 11, 8 (2017). https://doi.org/10.1007/s11783-017-0899-5
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11783-017-0899-5