Abstract
An overview is presented on catalytic kinetic methods for heavy metal determination by photometry or fluorometry reported in recent years. The article summarizes the analytical procedures, the kinetics and reaction mechanisms of some typical methods, and their applications to real sample determination.
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References
Ahamad I, Hayat S, Pichtel J (2005) Heavy metal contamination of soil: problems and remedies. Science Publishers, Inc. Enfield, NH, USA
Pérez-Bendito D, Silva M (1988) Kinetic methods in analytical chemistry. Wiley, New York
Mottola HA (1993) An account of kinetic determinations and other kinetic aspects of analytical chemistry: from Cordoba to Erlangen. Analyst 118:675
Crouch SR (1993) Trends in kinetic methods of analysis. Anal Chim Acta 283:453
Crouch SR, Cullen TF, Scheeline A, Kirkor ES (1998) Kinetic determinations and some kinetic aspects of analytical chemistry. Anal Chem 70:53R
Crouch SR, Scheeline A, Kirkor ES (2000) Kinetic determinations and some kinetic aspects of analytical chemistry. Anal Chem 72:53R
Muller H (1995) Catalytic methods of analysis: characterization, classification and methodology. Pure Appl Chem 67:601
Viguier RFH, Hulme AN (2006) A sensitized europium complex generated by micromolar concentrations of copper(I): toward the detection of copper(I) in biology. J Am Chem Soc 128:11370
Wolfbeis OS (2007) The click reaction in the luminescent probing of metal ions and its implications on biolabeling techniques. Angew Chem Int Ed 46:2
Ojeda CB, Rojas FS (2005) Determination of rhodium: since the origins until today spectrophotometric methods. Talanta 67:1
Kawashima T, Nakano S, Tabata M, Tanaka M (1997) Catalytic reactions as applied to trace analysis. Trends Anal Chem 16:132
Tomiyasu T, Teshima N, Nakano S, Kawashima T (1998) Kinetic-catalytic determination of traces of iron by the oxidative coupling reaction of 3-methyl-2-benzothiazolinone hydrazone with N,N-dimethylaniline. Talanta 47:1093
Fujimoto T, Teshima N, Kurihara M, Nakano S, Kawashima T (1999) Catalytic determination of cobalt at sub-nanogram levels using the oxidative coupling of 3-methyl-2-benzothiazolinone hydrazone with N-ethyl-N-(2-hydroxy-3-sulfopropyl)-3,5-dimethoxyaniline by manual and flow-injection methods. Talanta 49:1091
Hemantha Kumar MS, Nagaraja P, Yathirajan HS (2003) Copper(II)-catalysed oxidative coupling reaction of 3-hydroxyacetanilide with 3-methyl-2-benzothiazolinone hydrazone for the spectrophotometric determination of traces of copper(II). Anal Bioanal Chem 375:315
Ohno S, Teshima N, Watanabe T, Itabashi H, Nakano S, Kawashima T (1996) Determination of ultratrace amounts of copper(II) by its catalytic effect on the oxidative coupling reaction of 3-methyl-2-benzothiazolinone hydrazone with N-ethyl-N-(2-hydroxy-3-sulfopropyl)-3,5-dimethoxyaniline. Analyst 121:1515
Huang XY, Chen H (2002) Study on the oxidative coupling of p-amino-N,N-dimethylaniline with 1-amino-8-naphthol-3,6-disulfonic acid and its application. Spectrosc Spect Anal 22:627
Huang XY, Chen H (2003) Catalysis of trace iron on the coloring reaction of p-amino-N,N-dimethylaniline with 1-amino-8-naphthol-3,6-disulfonic acid. Chin J Anal Chem 31:175
Chen H, Huang XY (2003) Catalytic spectrophotometric determination of chromium(VI) by the oxidative coupling reaction of p-amino-N,N-dimethylaniline with N,N-dimethylaniline. Chin J Anal Chem 31:87
Mohamed AA, Fawy KF (2000) Catalytic determination of vanadium based on the bromate oxidative-coupling reaction of metol with phloroglucinol. Mikrochim Acta 134:229
Mohamed AA, Fawy KF (2000) Catalytic spectrophotometric determination of vanadium in seawaters based on the bromate oxidative-coupling reaction of metol with 2,3,4-trihydroxybenzoic acid. Anal Sci 17:769
Tang B, Liu Y, Wang HJ, Sun TL (1999) Catalytic spectrophotometric determination of trace iron with hydrogen peroxide-2,4-dichlorophenol-4-aminoantipyrine system. Chin J Anal Chem 27:1397
Krishna PB, Subrahmanyam P, Dilip KJ, Chiranjeevi P (2006) Simple sensitive spectrophotometric determination of vanadium in biological and environmental samples. E-J Chem 3:286
Suresh KK, Suvardhan K, Krishnaiah L, Rekha K, Kiran K, Janardhanam K, Jayaraj B, Chiranjeevi P (2007) Development of novel reactions for the simple and sensitive spectrophotometric determination of vanadium in various samples. Talanta 71:588
Safavi A, Maleki N, Farjami F (2001) Selective kinetic spectrophotometric determination of copper at nanograms per milliliter level. Talanta 54:397
Mohamed AA, Ahmed SA, El-Shahat MF (2001) Catalytic spectrophotometric determination of hexavalent chromium. J Trace Microprob Tech 19:297
Mubarak AT, Mohamed AA, Fawy KF, Al-Shihry AS (2007) Highly sensitive catalytic determination of molybdenum. Talanta 71:632
Roustoiu-Csavdar A, Baldea S, Mihai D (2002) Kinetic determination of trace amounts of Cu(II) in water based on its catalytic effect on the reaction of mercaptosuccinic acid and Cr(VI). Microchim Acta 140:1
Rustoiu-Csavdari A, Baldea S, Mihai D (2002) Catalytic determination of Pb(II) in the presence of Cu(II). Anal Bioanal Chem 374:17
Rustoiu-Csavdari A, Mihai D, Baldea I (2005) Kinetic catalytic determination of trace Cu(II) in water samples with the thioglycolic/thiolactic acid-chromate reaction. Anal Bioanal Chem 381:1373
Huang ZJ, Hu QF, Yang GY, Wang JQ, Jing C, Xu QH, Li ZB (2005) Catalytic spectrophotometric determination of osmium using diantipyrylphenylmethane derivatives. Chemia Analityczna 50:913
Huang ZJ, Hu QF, Yin JY, Xu QH (2001) Catalytic kinetic spectrophotometric determination of trace osmium. Chin J Anal Chem 29:1437
Kuang YY, Xu QH, Zhu LY (1999) Ir(IV)–KIO4–diantipyryl-(p-chloro)-phenylmethane system for catalytic spectrophotometric determination of trace iridium. Chin J Anal Chem 27:532
Huang ZJ, Yang GY, Yin JY, Xu QH (1999) Inhibition kinetic determination of platinium. Chin J Anal Chem 27:1040
Chen JS, Xu QH (2000) Spectrophotometric determination of trace ruthenium(III) based on its catalytic effect on the potassium periodate–diantipyryl-(p-iod)-phenylmethane reaction. Chin J Anal Chem 28:1144
Lin HS, Xu QH, Yin JY (1998) Inhibition of palladium (II) in color system of vanadium(V)–manganese(II)–Tween 20-diantipyryl-(m-hydroxy)-phenylmethane and its application. Chin J Anal Chem 26:1112
Angulo R, Lopez-Cueto G, Ubide C (1998) The hexacyanomanganate(IV)–hydrogen peroxide reaction. Kinetic determination of vanadium. Talanta 46:63
Prasad S (2005) Kinetic method for determination of nanogram amounts of copper(II) by its catalytic effect on hexacyanoferrate(III)–citric acid indicator reaction. Anal Chim Acta 540:173
Prasad S, Halafihi T (2003) Development and validation of catalytic kinetic spectrophotometric method for determination of copper(II). Microchim Acta 142:237
Wang HS, Zhang AM (1997) Microdetermination of vanadium(V) by its catalytic effect on the oxidation of 1-naphthyl red with potassium bromate. Microchem J 57:218
Safavi A, Nezhad MRH, Shams E (2000) Highly selective and sensitive kinetic spectrophotometric determination of vanadium(IV) in the presence of vanadium(V). Anal Chim Acta 409:283
Absalan G, Alipour Y (2003) Catalytic-kinetic determination of vanadium(IV) using methyl orange–bromate redox reaction. Anal Sci 19:635
Jiang TS, Zhai QZ, Hu WH, Fan Z (2003) Kinetic catalytic determination of vanadium by V(V)–(arsenzo-TB)–KBrO3 system. Chin J Anal Chem 31:895
Liu C (2000) Determination of trace vanadium by catalytic kinetic method. Chin J Anal Chem 28:1481
Sikalos TS, Arabatzis YM, Prodromidis MI, Veltsistas PG, karayannis MI (2004) Spectrophotometric determination of trace amounts of vanadium based on its catalytic effect on the reaction of diphenylamine and hydrogen peroxide. Microchim Acta 135:197
Milovanovic GA, Cakar MM, Vucic NB, and Jokanovic M (2000) Selective indicator reaction for kinetic determination of traces of manganese(II), ribavirin and tiazofurin. Mikrochim. Acta 135:173
Wu Y, Li JF, Garidi (2004) Determination of trace manganese in Mongolian medicine by methylthymol blue–Mn(II)–H2O2 catalytic system. Spectrosc Spect Anal 24:1652
Tomiyasu T, Yonehara N, Teshima N, Kawashima T (1999) Kinetic method for the determination of iron(II, III) by its catalytic effect on the oxidation of 3-methyl-2-benzothiazolinone hydrazone with hydrogen peroxide. Anal Chim Acta 394:55
Chen RZ, Wang XJ, Liu CM, Li JX, Yang YH (2001) Catalytic spectrophotometric determination of trace amounts of iron (III) based on the oxidation of bromothymol blue by hydrogen dioxide. Chin J Anal Chem 29:1233
Kawakubo S, Hagihara Y, Honda Y, Iwatsuki M (1999) Speciation of iron in river and tap waters by catalytic spectrophotometry using oxidation of o-phenylenediamine with hydrogen peroxide. Anal Chim Acta 388:35
Qi YJ, Wang XJ, Li HM, Gao HW (2002) Catalytic spectrophotometry for the determination of trace cobalt by the new indicating reaction. Spectrosc Spect Anal 22:449
Xia CB, Huang ND, Wang HJ, He XZ (2004) Catalytic kinetic spectrophotometric determination of nickel in alloys. Spectrosc Spect Anal 24:1484
Pourreza N, Behpour M (1998) Catalytic spectrophotometric determination of trace amounts of copper based on the oxidation of 2,4-dinitrophenylhydrazone-1,2-naphtoquinone-4-sulfonic acid by hydrogen peroxide. Anal Sci 14:997
Zheng HL, Long TR, Zhu Y (2004) Study on determination of trace copper(II) by catalytic kinetic discoloring spectrophotometry. Spectrosc Spect Anal 24:114
Khan MN, Sarwar A (2001) Determination of trace amounts of copper(II) by using catalytic redox reaction between methylene blue and ascorbic acid. Anal Sci 17:1195
Huiming Mao (1996) Determination of trace copper in serum by a new catalytic kinetic spectrophotometric method. Microchem J 53:303
Wang XJ, Chen RZ, Wang BX, Dong SQ (2000) Catalytic kinetic spectrophotometric determination of copper(II). Chin J Anal Chem 28:1444
Ding SF (2000) Catalytic spectrophotometric determination of trace amounts of copper with the system of ascorbic acid and ammonium molybdate. Spectrosc Spect Anal 20:250
Mitic SS, Miletic GZ, Obradovic MV (2004) Kinetic determination of traces of copper(II) by its catalytic effect on the oxidation of sodium pyrogallol-5-sulfonate by hydrogen peroxide. Spectrosc Lett 37:43
He RH, Wang JH (2001) A novel catalytic procedure for the determination of ultratrace zirconium. Microchim Acta 137:7
Sha R, Bao D, Wu D, Erdengsang (2004) A catalytic kinetic spectrophotometric method for determination of trace zinc(II) in Mongolian medicine and hair sample. Spectrosc Spect Anal 24:1646
Li SF, Lin X, Liu JM (2002) Spectrophotometric determination of trace zinc based on its catalytic fading reaction of red pigment for Myrica rubra CV. by hydrogen peroxide. Chin J Anal Chem 30:1337
Mousavi MF, Karami AR (2000) Catalytic-spectrophotometric determination of trace amounts of molybdenum (VI) ion. Microchem J 64:33
Bejan D (1999) Kinetic catalytic spectrophotometric determination of low concentrations of molybdenum in white wines. Anal Chim Acta 390:255
Zhu QR, Sun DM, Li HY (2002) Determination of trace molybdenum by extraction catalytic kinetic spectrophotometry. Spectrosc Spect Anal 22:107
Li JG, Cui HH, Shi LY (2003) Kinetic spectrophotometric determination of trace molybdenum by hydrogen peroxide–potassium iodide–tetrabase new system. Chin J Anal Chem 31:812
Liu Z (2000) Catalytic spectrophotometric determination of trace molybdenum using reduction of Lauth’s violet and hydrazine hydrochloride. Chin J Anal Chem 28:601
Lin ZF, Zheng ZS (2000) Catalytic spectrophotometric determination of trace Ag(I) using Triton X-100 as sensitizer. Chin J Anal Chem 28:326
Liu JM, Lin YL, Yang TL (2004) Catalytic spectrophotometric determination of trace mercury based on the oxidizing decoloration reaction of nickel-Eriochrome Red B complex by hydrogen peroxide. Chin J Anal Chem 32:759
Kompany-Zareh M, Tavallali H, Sajjadi M (2002) Application of generalized artificial neural networks coupled with an orthogonal design to optimization of a system for the kinetic spectrophotometric determination of Hg(II). Anal Chim Acta 469:303
Rezaei B, Majidia N (2007) A simple and high sensitive spectrophotometric method for ultra trace determination of ruthenium with its catalytic effect on the oxidation of pyronine B by periodate. Spectrochim Acta Part A 66:869
Afkhami A, Zarei AR (2003) Kinetic spectrophotometric determination of rhodium(III) based on its catalytic effect towards the oxidation of malachite green with periodate. Chemia Analityczna 48:859
Fedorina LI, Khomutova EG, Rysev AP (1997) Catalytic activity of rhodium solutions in oxidation reactions of azo dyes with sodium periodate. J Anal Chem 52:773
Li ZB, Cao QE, Xu QH, Li LX (1999) Kinetic spectrophotometric determination of rhodium based on its catalytic effect on the butylrhodamine B–potassium periodate reaction. Chin J Anal Chem 27:198
Mousavi MF, Barzegar M, Rahmani A, Jabbari A (2002) Catalytic kinetic determination of trace amounts of palladium with photometric detection. Microchim Acta 140:41
Ensafi AA, Keyvanfard M (2002) Kinetic-spectrophotometric determination of palladium in hydrogenation catalyst by its catalytic effect on the oxidation of pyrogallol red by hydrogen peroxide. Spectrochim Acta Part A 58:1567
Li JG, Qin XF, Wei YQ (2002) Determination of trace palladium based on kinetic-spectrophotometry with malachite green-sodium hypophosphite system. Spectrosc Spect Anal 22:110
Jabbari A, Barzegar M, Rahmani A, Mousavi MF (2002) Kinetic photometric determination of trace amounts of palladium(II) based on its catalytic effect on the reduction of safranin with hypophosphite. Indian J Chem 41A:2303
Manzoori JL, Sorouraddin MH, Amjadi M (2000) Spectrophotometric determination of osmium based on its catalytic effect on the oxidation of carminic acid by hydrogen peroxide. Talanta 53:61
Miao JG, Wu XH (2002) The catalysis of osmium(IV) in tribromo-arsenazo-ascorbic acid decolorizing reaction and determination of trace osmium(IV). Chin J Anal Chem 30:443
Li ZB, Cao QE, Wang JL, Xu QH (2000) Kinetic spectrophotometric determination of trace osmium by its catalytic effect on the oxidation of methylene blue. Chin J Anal Chem 28:361
Xu HP, Li J, Chen XG, Hu ZD (2001) Catalytic spectrophotometric determination of osmium(IV) using osmium(IV)–KIO4–chlorophosphonazo-mA system. Chin J Anal Chem 29:546
Li CN, Li ZB, Wang JL, Cao QE (2003) Kinetic catalytic spectrophotometric determination of trace iridium (IV) by iridium(IV)–methyl orange–potassium iodide system. Chin J Anal Chem 31:508
Li ZB, Li CN, Xu QH, Liu YJ (1999) Catalytic spectrophotometric determination of trace iridium with Nile blue and periodate. Chin J Anal Chem 27:778
Li X, Liu YY, Jing XB, Chen LR (2003) Catalytic spectrophotometric determination of platinum by Pt(IV)–chlorophosphonazo-pA–KIO4. Chin J Appl Chem 20:1000
Kou MZ, Kou FQ, Kou ZY (2004) Catalytic spectrophotometric determination of platinum(IV) by Pt(IV)–potassium bromate-2-(4-chloro-2-phosphonopheny)azo-7-(2,4,6-trichlorophenyl)azo-1,8-dihyaroxy-3,6-naphthalene disulfonie acid system. Chin J Anal Chem 32:1120
Rancic SM, Nikolic-Mandic SD, Mandic LM (2005) Kinetic spectrophotometric method for gold(III) determination. Anal Chim Acta 547:144
Li HZ, Zhou CL, Luo CN, Wang JG (2002) Catalytic kinetic spectrophotometric determination of trace gold after separation and enrichment by triazole chelating resin. Chin J Anal Chem 30:1077
Bontchev PR (1972) Catalytic reactions—II: activation. Talanta 19:675
Mutaftchiev KL (2001) Kinetic determination of nanogram levels of manganese(II) by Naphthol blue black–potassium periodate–1,10-phenanthroline system. Mikrochim Acta 136:79
Mutaftchiev K (2003) Catalytic spectrophotometric determination of manganese in some medicinal plants and their infusions. Turk J Chem 27:619
Mutaftchiev K, Tzachev K (2003) Determination of manganese(II) in some medicinal plants and their decoctions by a kinetic spectrophotometric method. Phytochem Anal 14:160
Mutaftchiev K (2001) Determination of free state manganese(II) in decoctions of some medicinal plants by a kinetic spectrophotometric method. Anal Lett 34:1401
Tabatabaee M, Nateghi MR, Mosavi SJ (2006) Kinetic-spectrophotometric determination of trace amounts of silver using the oxidation of thionine with peroxodisulfate. Anal Sci 22:1601
Safavi A, Mirzajani R (2002) Catalytic determination of traces of silver(I) using the oxidation of Janus green with peroxodisulfate. Anal Sci 18:329
Pouretedal HR (2003) Catalytic kinetic spectrophotometric determination of trace silver. Int J Chem 13:1
Pourreza N, Parham H, Hashemi F (2003) Kinetic-spectrophotometric determination of trace silver(I) using its catalytic effect on the oxidation reaction of Fuchsin by peroxodisulfate in the presence of 1,10-phenanthroline as an activator. J Anal Chem 58:333
Chen XG, Zou XY, Liang Q, Ouyang LQ, Chen GR, Li ZZ, Qian Y (2006) Catalytic kinetic spectrophotometric determination of trace iron(III) based on the decoloration reaction of hydrogen peroxide and Alizarin S. Chin J Anal Chem 34:371
Sulka GD, Jaskula M (1999) Kinetics based determination of trace amounts of silver at the excess of copper ions. Anal Chim Acta 394:185
Gao JZ, Zhang X, Yang W, Zhao BW, Hou JG, Kang JW (2000) Kinetic spectrophotometric determination of trace amounts of vanadium. Talanta 51:447
Guo LQ, Lin XC, Xie ZH, Fu YB (2005) Study on β-cyclodexdrin sensitizing catalytic kinetic spectrophotometric determination of Mn(II). Spectrosc Spect Anal 25:1662
Ma LL, Yang CY (1999) Catalytic kinetic spectrophotometric determination of trace chromium(VI) in a micellar system. Chin J Anal Chem 27:990
Shemirani F, Asghari AR, Hajimoosa MA (1999) Use of the triiodide hexadecylpyridinium chloride micellar system for the kinetic determination of tungsten(VI). Talanta 48:879
Yu P, Gao JJ, Song EJ (2005) Kinetic spectrophotometric determination of trace chromium(VI) with sensitized function of microemulsion. Spectrosc Spect Anal 25:1674
Wu HZ, Qiu CY, Zheng ZS (1999) Kinetic spectrophotometric determination of trace chromium(VI) with sensitized function of microemulsion. Chin J Anal Chem 27:668
Huang XD, Chen MZ (2004) Determination of trace silver by catalytic spectrophotometric method with anion surface active agent as a solubilizer. Chin J Anal Chem 32:268
Liu JM, Yang TL, Huang YH (2003) Catalytic spectrophotometric determination of trace zinc with sodium dodecylbenzene solfonate–potassium bromide-methylene. Chin J Anal Chem 31:256
Wei Q, Duan C, Wang J, Ma H, Du B (2006) Studies and application of catalytic kinetic spectrophotometric determination of trace chromium(VI) sensitized by microemulsion medium. Ann Chim 96:451
Wei Q, Yan LG, Chang GH, Ou QY (2003) Kinetic spectrophotometric determination of trace manganese(II) with dahlia violet in nonionic microemulsion medium. Talanta 59:253
Mohamed AA, Mubarak AT, Marstani ZMH, Fawy KF (2006) A novel kinetic determination of dissolved chromium species in natural and industrial waste water. Talanta 70:460
Gao F, Zhang DY, Ge ZQ, Wang L (2003) Nile blue–potassium periodate–cetyl pyridine bromide–nitrilotriacetic acid system for catalytic spectrophotometric determination of manganese. Chin J Anal Chem 31:1217
Xie ZH, Zheng ZS, Wang D, Fu YB (1999) Catalytic spectrophotometric method for the determination of trace manganese(II) with dodecyl dimethylamino acetic acid as sensitizer. Chin J Anal Chem 27:350
Bontchev PR (1970) Catalytic reaction—I. Talanta 17:499
Li X, Liu YY (2006) Spectrophotometric determination of trace chromium by catalytic kinetic spectrophotometry. Chin J Anal Lab 25:53
Tomiyasu T, Aikou S, Anazawa K, Sakamoto H (2005) A kinetic method for the determination of copper by its catalytic effect on the oxidation of 3-methyl-2-benzothiazolinone hydrazone with hydrogen peroxide: a mechanic study. Anal Sci 21:917
He RH, Wang JH (2001) Catalytic determination of cobalt by a concentration-jump chemical relaxation method. Talanta 432:151
Reis C, Andrade JC, Bruns RE, Moran RC (1998) Application of the split-spot experimental design for the optimization of a catalytic procedure for the determination of Cr (VI). Anal Chim Acta 369:269
Shiobara T, Teshima N, Kurihara M, Nakano S, Kawashima T (1999) Catalytic flow injection determination of vanadium by oxidation of N-(3-sulfopropyl)-3,3’,5,5’-tetramethyl-benzidine using bromate. Talanta 49:1083
Nakano S, Tanaka E, Mizutani Y (2003) Flow-injection spectrophotometry of vanadium by catalysis of the bromate oxidation of N,N’-bis(2-hydroxyl-3-sulfopropyl)tolidine. Talanta 61:203
Kaneko M, Kurihara M, Nakano S, Kawashima T (2002) Flow-injection determination of chromium(III) by its catalysis on the oxidative coupling of 3-methyl-2-benzothiazolinone hydrazone with N-ethyl-N-(2-hydroxy-3-sulfopropyl)-3-methoxyaniline. Anal Chim Acta 474:167
Su L, Li JG, Ma HB, Tao GH (2004) Determination of trace amounts of manganese in natural waters by flow injection stopped-flow catalytic kinetic spectrophotometry. Anal Chim Acta 522:281
Nakano S, Tanaka K, Oki R, Kawashima T (1999) Flow-injection spectrophotometry of manganese by catalysis of the periodate oxidation of 2,2’-azinobis(3-ethylbenzothiazoline-6-sulfonic acid). Talanta 49:1077
Nakano S, Matumoto Y, Yoshii M (2005) Flow-injection photometric determination of manganese (II) based on its catalysis of the periodate oxidation of N,N’-bis(2-hydroxy-3-sulfopropyl)tolidine. Talanta 68:312
Maniasso N, Zagatto EAG (1998) Flow-injection spectrophotometric catalytic determination of manganese in plants exploiting the aerial oxidation of diphenylcarbazone. Anal Chim Acta 366:87
Lunvongsa S, Oshima M, Motomizu S (2006) Determination of total and dissolved amount of iron in water samples using catalytic spectrophotometric flow injection analysis. Talanta 58:969
Kawakuba S, Okazaki Y, Iwatsuki M (2003) Catalytic flow-injection determination of reactive iron in non-acidified water samples. Anal Sci 19:373
Nogueira ARA, Souza GB, Batista LAR, Arruda MAZ, Miyazawa M (1998) Catalytic determination of cobalt by flow injection spectrophotometry: application in animal faeces analysis using hydrochloric acid as extracting solution. Anim Feed Sci Technol 74:79
Kawashima T, Itabashi H, Teshima N, Kurihara M, Nakano S (1999) Flow-injection determination of copper(II) based on its catalytic effect on the oxidative coupling of 3-methyl-2-benzothiazolinone hydrazone with N-ethly-N-(2-hydroxy-3-sulfopropyl)-3,5-dimethoxyaniline in a micellar medium. Anal Sci 15:835
Nakano S, Nakaso K, Noguchi K, Kawashima T (1997) Catalytic flow-injection determination of copper at nanogram levels by using color formation of N-phenyl-p-phenylenediamine with m-phenylenediamine in the presence of pyridine and ammonia as activators. Talanta 44:765
Wei J, Teshima N, Ohno S, Sakai T (2003) Catalytic flow-injection determination of sub-ppb copper(II) using the redox reaction of cysteine with iron(III) in the presence of 2,4,6-tris(2-pyridyl)-1,3,5-triazine. Anal Sci 19:731
Crespo GA, Andrade FJ, Inon FA, Tudino MB (2005) Kinetic method for the determination of trace amounts of copper(II) in water matrices by its catalytic effect on the oxidation of 1,5-diphenylcarbazide. Anal Chim Acta 539:317
Teshima N, Katsumata H, Kurihara M, Sakaib T, Kawashima T (1999) Flow-injection determination of copper(II) based on its catalysis on the redox reaction of cysteine with iron(III) in the presence of 1,10-phenanthroline. Talanta 50:41
Ensafi AA, Chamjanjgli MA, Mansour HR (2001) Catalytic spectrophotometric determination of ruthenium by flow injection method. Talanta 55:715
Shpigun LK, Kamilova PM, Shushenachev YV (2002) Flow-injection determination of gold(III) based on its catalytic effect on the peroxodisulfate oxidation of bromopyrogallol red. J Anal Chem 57:1049
Themelisa DG, Trellopoulosa AV, Tzanavarasb PD, Sofonioua M (2007) Highly selective flow injection spectrophotometric determination of gold based on its catalytic effect on the oxidation of variamine blue by potassium iodate in aqueous N,N-dimethylformamide medium. Talanta 72:277
Lunvongsa S, Takayanagi T, Oshima M, Motomizu S (2006) Novel catalytic oxidative coupling reaction of N,N-dimethyl-p-phenylenediamine with 1,3-phenylenediamine and its applications to the determination of copper and iron at trace levels by flow injection technique. Anal Chim Acta 576:261
Watanabe T, Teshima N, Nakano S, Kawashima T (1998) Flow-injection/standard subtraction method for the determination of iron(III) based on its catalytic effect and inhibition of EDTA. Anal Chim Acta 374:303
Lannuzel D, Jong J, Schoemann V, Trevena A, Tisonc JL, Chou L (2006) Development of a sampling and flow injection analysis technique for iron determination in the sea ice environment. Anal Chim Acta 556:476
Carneiro JMT, Dias ACB, Zagatto EAG, Honorato RS (2002) Spectrophotometric catalytic determination of Fe(III) in estuarine waters using a flow-batch system. Anal Chim Acta 455:327
Weeks DA, Bruland KW (2002) Improved method for shipboard determination of iron in seawater by flow injection analysis. Anal Chim Acta 453:21
Lohan MC, Aguilar-Islas AM, Bruland KW (2006) Direct determination of iron in acidified (pH 1.7) seawater samples by flow injection analysis with catalytic spectrophotometric detection: Application and intercomparison. Limnol Oceanogr: Methods 4:164
Wang HW, Zhou YY, Zhao YK, Li QF, Chen XG, Hu ZD (2001) Optimization of on-line microwave flow injection analysis system by artificial neural networks for the determination of ruthenium. Anal Chim Acta 429:207
Zeng YB, Xu HP, Liu HT, Wang KT, Chen XG, Hu ZD, Fan BT (2001) Application of artificial neural networks in multifactor optimization of an on-line microwave FIA system for catalytic kinetic determination of ruthenium(III). Talanta 54:603
Chen XG, Xu HP, Dong LJ, Liu HT, Zeng YB, Hu ZD (2002) Application of artificial neural networks in multivariable optimization of an on-line microwave FIA system for catalytic kinetic determination of iridium(III). Anal Bioanal Chem 373:883
Lunvongsa S, Tsuboi T, Motomizu S (2006) Sequential determination of trace amounts of iron and copper in water samples by flow injection analysis with catalytic spectrophotometric detection. Anal Sci 22:169
Ensafi AA, Chanjangali MA, Mansour HR (2004) Sequential determination of iron(II) and iron(III) in pharmaceutical by flow-injection analysis with spectrophotometric detection. Anal Sci 20:645
Gervasio APG, Fortes PRF, Meneses SRP, Miranda CES, Zagatto EAG (2006) An improved flow-injection system for spectrophotometric determination of molybdenum and tungsten in tool steels. Talanta 69:927
Ohno S, Teshima N, Zhang H, Sakai T (2003) Utilization of activating and masking effects by ligands for highly selective catalytic spectrophotometric determination of copper and iron in natural waters. Talanta 60:1177
Watanabe T, Teshima N, Kurihara M, Nakano S, Kawashima T (1999) Successive flow-injection determination of iron(III) and copper(II) by means of effect of activators. Chem Lett 28:521
Ohno S, Tanaka M, Teshima N, Sakai T (2004) Successive determination of copper and iron by a flow injection catalytic photometric method using a serial flow cell. Anal Sci 20:171
Ye Y, Mao H, Chen Y (1998) Catalytic kinetic simultaneous determination of iron, silver and manganese with the Kalman filter by using flow injection analysis stopped-flow spectrophotometry. Talanta 45:1123
Tomiyasu T (1999) Kinetic-mechanistic study of the chlorpromazine–hydrogen peroxide reaction catalyzed by molybdenum(V1) and tungsten(VI), and their differential determination. Anal Chim Acta 349:43
Tavallali H, Massoumi A (1998) Simultaneous kinetic spectrophotometric determination of vanadium(V) and iron(III). Talanta 47:479
Iturriaga H, Coello J, Maspoch S, Porcel M (2001) Multi-component kinetic-spectrophotometric analysis. Selection of wavelength and time ranges. Analyst 126:1135
Zhu ZL, Gu ZC, Chen RM, Han CQ, Lu BL (1994) Simultaneous determination of catalysts based on the differences in the characteristic rate spectra of catalytic kinetics. Anal Chim Acta 298:19
Foresa PR, Menesesa SRP, Zagatto EAG (2006) A novel flow-batched strategy for implementing differential kinetic analysis. Anal Chim Acta 572:316
Safavi A, Absalan G, Maesum S (2001) Simultaneous determination of V(IV) and Fe(II) as catalyst using “neural networks” through a single catalytic kinetic run. Anal Chim Acta 432:229
Huang XY, Zhang CF, Ji CT, Ji MD (2000) Simultaneous determination of copper and silver by catalytic kinetic spectrophotometry. Chin J Anal Chem 28:529
Magni DM, Olivieri AC, Bonivardi AL (2005) Artificial neural networks study of the catalytic reduction of resazurin: stopped-flow injection kinetic-spectrophotometric determination of Cu(II) and Ni(II). Anal Chim Acta 528:275
Khayamian T, Ensafi AA, Atabati M (2002) Simultaneous determination of Os(III) and Ru(IV) as catalysts through a single catalytic kinetic run using principal component artificial neural network. Anal Lett 35:2039
Zhou Y, Li YQ, Yang JG, Zheng B (2003) Simultaneous determination of copper and iron by flow-injection catalytic kinetic spectrophotometry with multi-channel detector. Spectrosc Spect Anal 22:374
He CY, Wu GH, Cheng Q, Chen YC (2004) Simultaneous determination of copper and iron by catalytic kinetic spectrophotometry. Spectrosc Spect Anal 24:730
Tang B, Han F, Ma L (2001) Application and development of catalytic fluorimetry. Chin J Anal Chem 29:347
Gao JZ, Zhang X, Yang W, Kang JW (2002) Highly sensitive spectrofluorimetric kinetic determination of ultratrace amounts of vanadium(V) based on the oxidation of 1,8-diaminonaphthalene by bromate. Anal Chim Acta 455:159
Szabo K, Marek N (2002) Investigation of catalytic reaction with spectrofluorimetric method. J Biochem Biophys Methods 53:189
Chen LH (1997) Determination of trace copper by kinetic fluorescence quenching. Chin J Anal Chem 25:937
Yu Y, Hong CH, Wang RQ, Huang JF (1998) Catalytic fluorimetric determination of trace manganese(II) based on its catalysis for furfural-7-amino-8-hydroxyquinoline-5-sulfonic acid. Chin J Anal Chem 26:414
Yu Y, Hong CH (2000) Catalytic kinetics-fluorescence analysis studies on Fe(III)–H2O2–furfural-7-amino-8-hydroxy-5-sulfoquinoline system. Spectrosc Spect Anal 20:110
Tang B, Han F (2001) Spectrofluorimetric determination of manganese at the nanogram level by catalytic oxidation of 2-hydroxy-1-naphthaldehyde salicyloylhydrazone by hydrogen peroxide. Anal Lett 34:1353
Tang B, Han F, Zhang GY, Liang FZ (2002) Kinetic-spectrofluorimetric determination of trace amounts of osmium. Anal Lett 35:517
Tang B, Zhang H, Wang Y (2004) Determination of trace palladium with salicyladehyde furfuralhydrazone (SAFH) by catalytic kinetic spectrofluorimetry. Anal Lett 37:1219
Tang B, Han F, Zhang GY (2002) Kinetic-spectrofluorimetric determination of trace amounts of iridium. Talanta 56:603
Tang B, Ma L, Wang HJ (2002) Recent advances in the application of new host compound to determine bioactive molecule. Chin J Anal Chem 30:482
Zhang N, Kong QC, Chen ZZ, Xu KH, Tang B (2006) Determination of trace rhodium by supramolecular catalytic kinetic spectrofluorimetry of β-CD–rhodium–KBrO3–vanillin salicylhydrazone. Microchim Acta 158:165
Zhang H, Tang B, Wang Y (2004) Determination of trace osmium by supramolecular catalytic kinetic spectrofluorimetry of β-CD–osmium–KBrO3–o-vanillin furfuralhydrazone. Talanta 63:825
Tang B, Zhang N, Chen ZZ, Kong QC (2006) Determination of trace platinum by supramolecular catalytic kinetic spectrofluorimetry of β-cyclodextrin–platinum–KBrO3–salicylaldehyde furfuralhydrazone. Anal Bioanal Chem 384:769
Chen LH, Ge HY (2003) Catalytic fluorimetric determination of trace vanadium with phenosafranine as indicator. Spectrosc Spect Anal 23:1154
Bao SY, Li SC, Meng FH, Wang GH, Shi SX (2002) Study on kinetic fluorimetric determination of trace vanadium. Spectrosc Spect Anal 22:284
Bao SY, Li SC, Shi SX (2001) Catalytic fluorimetric determination of trace vanadium using acridine orange. Chin J Anal Chem 29:1170
Liu SY, Gao WH, Liu XX, Chen YW (2007) Determination of trace chromium(VI) by catalytic spectrofluorimetry using Pyronine Y–H2O2–Cr(VI) System. Spectrosc Spect Anal 27:113
Feng SL, Wang RY, Fan J (2000) Catalytic spectrofluorimetric determination of trace chromium(VI). Chin J Anal Chem 28:61
Chen LH, Wang DS (1997) Catalytic spectrofluorimetric determination of trace chromium(VI) based on the oxidation of safranine T by hydrogen peroxide. Chin J Anal Chem 25:120
Zhang GE, Feng SL, Cheng DX (1996) Catalytic fluorimetric determination of trace cobalt in vitamin B12. Microchem J 53:308
Safavi A, Baezzat MR (1998) Fluorimetric kinetic-FIA determination of Ag(I) based on its catalytic effect on the reduction reaction of safranine with iodide. Microchem J 58:138
Tang B, Zhang H, Wang Y (2004) Flow injection kinetic spectrofluorimetric determination of trace amounts of palladium. Anal Chim Acta 511:17
Tang B, Zhang H, Wang Y (2005) Flow injection kinetic spectrofluorimetric determination of trace amounts of osmium. Spectrochim Acta Part A 61:2239
Wang KT, Chen XG, Hu ZD (1996) Kinetic flow-injection spectrofluorimetric determination of iridium. Chin J Anal Chem 24:914
Tang B, Zhang H, Wang Y (2004) On-line separation, preconcentration and determination of trace amounts of gold in mineral sample by flow injection catalytic kinetic spectrofluorimetry. Anal Chim Acta 525:305
Acknowledgement
This work was supported by National Basic Research Program of China (973 Program, 2007CB936000), National Natural Science Funds for Distinguished Young Scholar (No. 20725518), Major Program of National Natural Science Foundation of China (No. 90713019), National Natural Science Foundation of China (No. 20575036) and Important Project of Natural Science Foundation of Shandong Province in China (No. Z2006B09), the Research Foundation for the Doctoral Program of Ministry of Education (No. 20060445002)
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Chen, Z., Zhang, N., Zhuo, L. et al. Catalytic kinetic methods for photometric or fluorometric determination of heavy metal ions. Microchim Acta 164, 311–336 (2009). https://doi.org/10.1007/s00604-008-0048-8
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DOI: https://doi.org/10.1007/s00604-008-0048-8