Japan encounters an urgent issue of “Carbon Neutrality” as a member of the international world and is required to make the action plans to accomplish this issue, i.e., the zero emission of CO₂ by 2050. Our world must change the industries to adapt to the electrification based on the renewable powers. Microwave chemistry is a candidate of electrification of industries for the carbon neutrality on the conditions of usage of renewable energy power generation. This invited paper shows an example of “Microwave Pidgeon process” for smelting magnesium in which heating with burning fossil coals can be replaced with microwave energy for discussing how microwave technology should be developed for that purpose from both the academic and industrial sides.