RoHS

Examples of product components containing restricted substances

RoHS restricted substances have been used in a broad array of consumer electronics products. Examples of components that have contained lead include:

• paints and pigments
• PVC (vinyl) cables as a stabiliser (e.g., power cords, USB cables)
• solders
• printed circuit board finishes, leads, internal and external interconnects
• glass in television and photographic products (e.g., CRT television screens and camera lenses)
• metal parts
• lamps and bulbs
• batteries
• integrated circuits or microchips

Cadmium is found in many of the components above; examples include plastic pigmentation, nickel–cadmium (NiCd) batteries and CdS photocells (used in night lights). Mercury is used in lighting applications and automotive switches; examples include fluorescent lamps and mercury tilt switches (these are rarely used nowadays). Hexavalent chromium is used for metal finishes to prevent corrosion. Polybrominated biphenyls and diphenyl ethers/oxides are used primarily as flame retardants.^[12]

Hazardous materials and the high-tech waste problem

RoHS and other efforts to reduce hazardous materials in electronics are motivated in part to address the global issue of consumer electronics waste. As newer technology arrives at an ever-increasing rate, consumers are discarding their obsolete products sooner than ever. This waste ends up in landfills and in countries like China to be "recycled".^[13]

In the fashion-conscious mobile market, 98 million U.S. cell phones took their last call in 2005. All told, the EPA estimates that in the U.S. that year, between 1.5 and 1.9 million tons of computers, TVs, VCRs, monitors, cell phones, and other equipment were discarded. If all sources of electronic waste are tallied, it could total 50 million tons a year worldwide, according to the UN Environment Programme.^[14]

American electronics sent offshore to countries like Ghana in West Africa under the guise of recycling may be doing more harm than good. Not only are adult and child workers in these jobs being poisoned by heavy metals, but these metals are returning to the U.S. "The U.S. right now is shipping large quantities of leaded materials to China, and China is the world's major manufacturing center," Dr. Jeffrey Weidenhamer says, a chemistry professor at Ashland University in Ohio. "It's not all that surprising things are coming full circle and now we're getting contaminated products back."^[13]

Changing toxicity perceptions

In addition to the high-tech waste problem, RoHS reflects contemporary research over the past 50 years in biological toxicology that acknowledges the long-term effects of low-level chemical exposure on populations. New testing is capable of detecting much smaller concentrations of environmental toxicants. Researchers are associating these exposures with neurological, developmental, and reproductive changes.

RoHS and other environmental laws are in contrast to historical and contemporary law that seek to address only acute toxicology, that is direct exposure to large amounts of toxic substances causing severe injury or death.^[15]

Life-cycle impact assessment of lead-free solder

The United States Environmental Protection Agency (EPA) has published a life-cycle assessment (LCA) of the environmental impacts of lead-free and tin–lead solder, as used in electronic products.^[16] For bar solders, when only lead-free solders were considered, the tin/copper alternative had the lowest (best) scores. For paste solders, bismuth/tin/silver had the lowest impact scores among the lead-free alternatives in every category except non-renewable resource consumption. For both paste and bar solders, all of the lead-free solder alternatives had a lower (better) LCA score in toxicity categories than tin/lead solder. This is primarily due to the toxicity of lead, and the amount of lead that leaches from printed wiring board assemblies, as determined by the leachability study conducted by the partnership. The study results are providing the industry with an objective analysis of the life-cycle environmental effects of leading candidate alternative lead-free solders, allowing industry to consider environmental concerns along with the traditionally evaluated parameters of cost and performance. This assessment is also allowing industry to redirect efforts toward products and processes that reduce solders' environmental footprint, including energy consumption, releases of toxic chemicals, and potential risks to human health and the environment. Another life-cycle assessment by IKP, University of Stuttgart, shows similar results to those of the EPA study.^[17]

Life-cycle impact assessment of BFR-free plastics

The ban on concentrations of brominated flame retardants (BFR) above 0.1% in plastics has affected plastics recycling. As more and more products include recycled plastics, it has become critical to know the BFR concentration in these plastics, either by tracing the origins of the recycled plastics to establish the BFR concentrations, or by measuring the BFR concentrations from samples. Plastics with high BFR concentrations are costly to handle or to discard, whereas plastics with levels below 0.1% have value as recyclable materials.

There are a number of analytical techniques for the rapid measurement of BFR concentrations. X-ray fluorescence spectroscopy can confirm the presence of bromine (Br), but it does not indicate the BFR concentration or specific molecule. Ion attachment mass spectrometry (IAMS) can be used to measure BFR concentrations in plastics. The BFR ban has significantly affected both upstream (plastic material selection) and downstream (plastic material recycling).^{[citation needed]}

2011/65/EU (RoHS 2)

The RoHS 2 directive (2011/65/EU) is an evolution of the original directive and became law on 21 July 2011 and took effect on 2 January 2013. It addresses the same substances as the original directive while improving regulatory conditions and legal clarity. It requires periodic re-evaluations that facilitate gradual broadening of its requirements to cover additional electronic and electrical equipment, cables and spare parts.^[18] The CE logo now indicates compliance and RoHS 2 declaration of conformity is now detailed (see below).^{[citation needed]}

In 2012, a final report from the European Commission revealed that some EU Member States considered all toys under the scope of the primary RoHS 1 Directive 2002/95/EC, irrespective of whether their primary or secondary functions were using electric currents or electromagnetic fields. From the implementation of RoHS 2 or RoHS Recast Directive 2011/65/EU on, all the concerned Member States will have to comply with the new regulation.

The key difference in the recast is that it is now necessary to demonstrate conformity in a similar way to the LVD and EMC directives. Not being able to show compliance in sufficiently detailed files, and not ensuring it is implemented in production is now a criminal offence. Like the other CE marking directives it mandates production control and traceability to the technical files. It describes two methods of achieving presumption of conformity (Directive 2011/65/EU Article 16.2), either technical files should include test data for all materials or a standard accepted in the official journal for the directive, is used. Currently the only standard is EN IEC 63000:2018 (based on IEC 63000:2016 superseded EN 50581:2012), a risk based method to reduce the amount of test data required (Harmonised Standards list for RoHS2, OJEU C363/6).

One of the consequences of the requirement to demonstrate conformity is the requirement to know the exemption use of each component, otherwise it is not possible to know compliance when the product is placed on the market, the only point in time the product must be 'compliant'. Many do not understand that 'compliance' varies depending on what exemptions are in force and it is quite possible to make a non-compliant product with 'compliant' components. Compliance must be calculated on the day of placing on the market. In reality this means knowing the exemption status of all components and using up stock of old status parts before the expire date of the exemptions (Directive 2011/65/EU Article 7.b referring to Decision 768/2008/EC Module A Internal production control). Not having a system to manage this could be seen as a lack of diligence and a criminal prosecution could occur (UK Instrument 2012 N. 3032 section 39 Penalties).

RoHS 2 also has a more dynamic approach to exemptions, creating an automatic expiration if exemptions are not renewed by requests from industry. Additionally new substances can be added to the controlled list, with 4 new substances expected to be controlled by 2019. All these mean greater information control and update systems are required. ^{[citation needed]}

Other differences include new responsibilities for importers and distributors and markings to improve traceability to the technical files. These are part of the NLF for directives and make the supply chain a more active part of the policing (Directive 2011/65/EU Articles 7, 9, 10).

There has been a recent additional amendment 2017/2102 to 2011/65

2015/863 (RoHS 2 amendment)

The RoHS 2 directive (2011/65/EU) contains allowance to add new materials and 4 materials are highlighted for this attention in the original version, the amendment 2015/863 adds four additional substances to Annex II of 2011/65/EU (3/4 of the new restrictions are recommended for investigation in the original directive, ref Para 10 of preamble). This is another reason that simple component RoHS compliance statements are not acceptable as compliance requirements vary depending on the date the product is placed on the market (ref IEC 63000:2016). The additional four substances restriction and evidence requirements shall be applied for products placed on the market on or after 22 July 2019 except where exemptions permit as stated in Annex III.,^[5] although at the time of writing no exemptions exist or have been applied for, for these materials. The four additional substances are

1. Bis(2-Ethylhexyl) phthalate (DEHP)
2. Benzyl butyl phthalate (BBP)
3. Dibutyl phthalate (DBP)
4. Diisobutyl phthalate (DIBP)

The maximum permitted concentrations in non-exempt products are 0.1%.

The new substances are also listed under the REACH Candidate list, and DEHP is not authorised for manufacturing (use as a substance) in the EU under Annex XIV of REACH.^[19]

How XRF Works

XRF uses X-rays to excite atoms in a sample. When atoms stabilize, they release energy as photons. The device measures this energy to identify elements in the sample. Each element emits a unique energy, allowing precise detection. XRF creates an energy spectrum showing what elements are present and how much of each exists. This data supports both qualitative and quantitative analysis.

XRF for RoHS Testing

XRF effectively detects key RoHS-restricted elements^[28] like lead, mercury, and cadmium. It can also find chromium but cannot tell if it’s hexavalent chromium. Additional tests are necessary for that. However, XRF^[29] cannot analyze organic compounds such as phthalates or PBBs. XRF can detect total bromine which works as a pre-screening method. However, these substances require other methods like gas chromatography-mass spectrometry (GC-MS) for precise detection.

XRF offers many advantages. It’s fast and non-destructive, meaning samples remain intact after analysis. It works well for solid materials with minimal preparation, saving time and reducing costs. Handheld XRF devices allow on-site testing, making them useful in industrial and environmental settings. These devices analyze samples in seconds, increasing efficiency.

Limits of XRF

XRF struggles to detect light elements like carbon or oxygen. It also cannot analyze molecules or organic substances. Despite these limits, XRF remains a top choice for detecting heavy metals and ensuring compliance with environmental regulations^[30] like RoHS.

History

RoHS did not require any specific product labelling, but many manufacturers have adopted their own compliance marks to reduce confusion. Visual indicators have included explicit "RoHS compliant" labels, green leaves, check marks, and "PB-Free" markings. Chinese RoHS labels, a lower case "e" within a circle with arrows, can also imply compliance.

RoHS 2 attempts to address this issue by requiring the aforementioned CE mark whose use is policed by the Trading Standards enforcement agency.^[32] It states that the only permitted indication of RoHS compliance is the CE mark.^[33] The closely related WEEE (Waste Electrical and Electronic Equipment Directive), which became law simultaneously with RoHS, depicts a waste-can logo with an "X" through it and often accompanies the CE mark.

Asia / Pacific

China Order No. 39

Final Measures for the Administration of the Control and Electronic Information Products (often referred to as China RoHS^[34]) has the stated intent to establish similar restrictions, but in fact takes a very different approach. Unlike EU RoHS, where products in specified categories are included unless specifically excluded, there will be a list of included products, known as the catalogue – see Article 18 of the regulation – which will be a subset of the total scope of Electronic Information Products, or EIPs, to which the regulations apply. Initially, products that fall under the covered scope must provide markings and disclosure as to the presence of certain substances, while the substances themselves are not (yet) prohibited. There are some products that are EIPs, which are not in scope for EU RoHS, e.g. radar systems, semiconductor-manufacturing equipment, photomasks, etc. The list of EIPs is available in Chinese and English.^[35] The marking and disclosure aspects of the regulation were intended to take effect on 1 July 2006, but were postponed twice to 1 March 2007. There is no timeline for the catalogue yet.

Japan

Japan does not have any direct legislation dealing with the RoHS substances, but its recycling laws have spurred Japanese manufacturers to move to a lead-free process in accordance with RoHS guidelines. A ministerial ordinance Japanese industrial standard for Marking of Specific Chemical Substances (J-MOSS), effective from 1 July 2006, directs that some electronic products exceeding a specified amount of the nominated toxic substances must carry a warning label.^[36]

South Korea

South Korea promulgated the Act for Resource Recycling of Electrical and Electronic Equipment and Vehicles on 2 April 2007. This regulation has aspects of RoHS, WEEE, and ELV.^[37]

United States

The Consumer Product Safety Act was enacted in 1972 followed by the Consumer Product Safety Improvement Act in 2008.

California has passed the Electronic Waste Recycling Act of 2003 (EWRA). This law prohibits the sale of electronic devices after 1 January 2007, that are prohibited from being sold under the EU RoHS directive, but across a much narrower scope that includes LCDs, CRTs, and the like and only covers the four heavy metals restricted by RoHS. EWRA also has a restricted material disclosure requirement.

Effective 1 January 2010, the California Lighting Efficiency and Toxics Reduction Act applies RoHS to general purpose lights, i.e. "lamps, bulbs, tubes, or other electric devices that provide functional illumination for indoor residential, indoor commercial, and outdoor use."^[38]

Other US states and cities are debating whether to adopt similar laws, and there are several states that have mercury and PBDE bans already.^{[citation needed]}

United Kingdom

On January 31, 2020, the United Kingdom completed its withdrawal from the European Union and subsequently entered a transition phase spanning from February 1 to December 31, 2020. This event is commonly referred to as Brexit. During this transitional period, the United Kingdom conducted a comprehensive assessment of various regulations, including RoHS. UK RoHS stays well aligned with EU RoHS, with similar scopes, restricted substances, thresholds, and exemptions.^[39][40]

Ireland

Worldwide standards and certification are available under the QC 080000 standard, governed by the National Standards Authority of Ireland, to ensure the control of hazardous substances in industrial applications.

Sweden

In 2012 Sweden's Chemicals Agency (Kemi) and Electrical Safety Authority tested 63 consumer electronics products and found that 12 were out of compliance. Kemi claims that this is similar to testing results from prior years. "Eleven products contained prohibited levels of lead, and one of polybrominated diphenyl ether flame retardants. Details of seven companies have been passed to Swedish prosecutors. Kemi says that levels of non-compliance with RoHS are similar to previous years, and remain too high."^[41]

Effect on reliability

Potential reliability concerns were addressed in Annex item #7 of the RoHS directive, granting some specific exemptions from regulation until 2010. These issues were raised when the directive was first implemented in 2003 and reliability effects were less known.^[53]

Another potential problem that some lead-free, high tin-based solders may face is the growth of tin whiskers. These thin strands of tin can grow and make contact with an adjacent trace, developing a short circuit. Lead in the solder suppresses the growth of tin whiskers. Historically tin whiskers have been associated with a handful of failures, including a nuclear power plant shutdown and pacemaker incident where pure tin plating was used. However, these failures pre-date RoHS. They also do not involve consumer electronics, and therefore may employ RoHS-restricted substances if desired. Manufacturers of electronic equipment for mission-critical aerospace applications have followed a policy of caution and therefore resisted the adoption of lead-free solders.

To help mitigate potential problems, lead-free manufacturers are using a variety of approaches such as tin-zinc formulations that produce non-conducting whiskers or formulations that reduce growth, although they do not halt growth completely in all circumstances.^[54] Fortunately, experience thus far suggests deployed instances of RoHS compliant products are not failing due to whisker growth. Dr. Ronald Lasky of Dartmouth College reports: "RoHS has been in force for more than 15 months now, and ~$400B RoHS-compliant products have been produced. With all of these products in the field, no significant numbers of tin whisker-related failures have been reported."^[55] Whisker growth occurs slowly over time, is unpredictable, and not fully understood, so time may be the only true test of these efforts. Whisker growth is even observable for lead-based solders, albeit on a much smaller scale.

Some countries have exempted medical and telecommunication infrastructure products from the legislation.^[56] However, this may be a moot point, since as electronic component manufacturers convert their production lines to producing only lead-free parts, conventional parts with eutectic tin-lead solder will simply not be available, even for military, aerospace and industrial users. To the extent that only solder is involved, this is at least partially mitigated by many lead-free components' compatibility with lead-containing solder processes. Leadframe-based components, such as Quad Flat Packages (QFP), Small Outline Integrated Circuits (SOIC), and Small outline packages (SOP) with gull wing leads, are generally compatible since the finish on the part leads contributes a small amount of material to the finished joint. However, components such as Ball grid arrays (BGA) which come with lead-free solder balls and leadless parts are often not compatible with lead-containing processes.^[57]

Economic effect

There are no de minimis exemptions, e.g., for micro-businesses. This economic effect was anticipated and at least some attempts at mitigating the effect were made.^[58]

Another form of economic effect is the cost of product failures during the switch to RoHS compliance. For example, tin whiskers were responsible for a 5% failure rate in certain components of Swiss Swatch watches in 2006, prior to the July implementation of RoHS, reportedly triggering a US$1 billion recall.^[59][60] Swatch responded to this by applying for an exemption to RoHS compliance, but this was denied.^[61][62]

Health benefits

RoHS helps reduce damage to people and the environment in third-world countries where much of today's "high-tech waste" ends up.^[14][63][64] The use of lead-free solders and components reduces risks to electronics industry workers in prototype and manufacturing operations. Contact with solder paste no longer represents the same health hazard as it used to.^[65]

Reliability concerns unfounded

Contrary to the predictions of widespread component failure and reduced reliability, RoHS's first anniversary (July 2007) passed with little fanfare.^[66] Most contemporary consumer electronics are RoHS compliant. As of 2013, millions of compliant products are in use worldwide.

Many electronics companies keep "RoHS status" pages on their corporate websites. For example, the AMD website states:

Although lead containing solder cannot be completely eliminated from all applications today, AMD engineers have developed effective technical solutions to reduce lead content in microprocessors and chipsets to ensure RoHS compliance while minimizing costs and maintaining product features. There is no change to fit, functional, electrical or performance specifications. Quality and reliability standards for RoHS compliant products are expected to be identical compared to current packages.^[67]

RoHS printed circuit board finishing technologies are surpassing traditional formulations in fabrication thermal shock, solder paste printability, contact resistance, and aluminium wire bonding performance and nearing their performance in other attributes.^[68]

The properties of lead-free solder, such as its high temperature resilience, has been used to prevent failures under harsh field conditions. These conditions include operating temperatures with test cycles in the range of −40 °C to +150 °C with severe vibration and shock requirements. Automobile manufacturers are turning to RoHS solutions now as electronics move into the engine bay.^[69]

Flow properties and assembly

One of the major differences between lead-containing and lead-free solder pastes is the "flow" of the solder in its liquid state. Lead-containing solder has a lower surface tension, and tends to move slightly to attach itself to exposed metal surfaces that touch any part of the liquid solder. Lead-free solder conversely tends to stay in place where it is in its liquid state, and attaches itself to exposed metal surfaces only where the liquid solder touches it.

This lack of "flow" – while typically seen as a disadvantage because it can lead to lower quality electrical connections – can be used to place components more tightly than they used to be placed due to the properties of lead-containing solders.

For example, Motorola reports that their new RoHS wireless device assembly techniques are "...enabling a smaller, thinner, lighter unit." Their Motorola Q phone would not have been possible without the new solder. The lead-free solder allows for tighter pad spacing.^[70]

Some exempt products achieve compliance

Research into new alloys and technologies is allowing companies to release RoHS products that are currently exempt from compliance, e.g. computer servers.^[71] IBM has announced a RoHS solution for high lead solder joints once thought to remain a permanent exemption. The lead-free packaging technology "...offers economical advantages in relation to traditional bumping processes, such as solder waste reduction, use of bulk alloys, quicker time-to-market for products and a much lower chemical usage rate."^[72][73]

Test and measurement vendors, such as National Instruments, have also started to produce RoHS-compliant products, despite devices in this category being exempt from the RoHS directive.^[74]