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16 pages, 8582 KiB  
Article
Electrospun Cellulose Acetate/Poly(Vinyl Alcohol) Nanofibers Loaded with Methyl Gallate and Gallic Acid for Anti-Staphylococcus aureus Applications
by Pimsumon Jiamboonsri, Weradesh Sangkhun and Sompit Wanwong
Polymers 2024, 16(21), 2971; https://doi.org/10.3390/polym16212971 - 23 Oct 2024
Viewed by 670
Abstract
Methyl gallate (MG) and gallic acid (GA) are natural compounds with potent activity against methicillin-resistant Staphylococcus aureus (MRSA), a significant global health concern. In this study, MG and GA were incorporated into cellulose acetate (CA) blended with poly(vinyl alcohol) (PVA) to create electrospun [...] Read more.
Methyl gallate (MG) and gallic acid (GA) are natural compounds with potent activity against methicillin-resistant Staphylococcus aureus (MRSA), a significant global health concern. In this study, MG and GA were incorporated into cellulose acetate (CA) blended with poly(vinyl alcohol) (PVA) to create electrospun nanofibers aimed at combating both methicillin-susceptible S. aureus (MSSA) and MRSA. Key electrospinning parameters—DC voltage, injection flow rate, and syringe tip–collector distance—were optimized, with the best conditions being a 1.5 mL/h flow rate, 30 cm distance, and 20 kV voltage. The resulting nanofiber mats were characterized by SEM, FTIR, DSC, tensile strength testing, contact angle measurement, swelling behavior, and release profiling. Antibacterial properties were assessed using the agar diffusion test. The obtained nanofibers had diameters ranging from 879.33 to 906.13 nm. Among the samples, MG-GA-CA/PVA exhibited the highest tensile strength, good flexibility, and improved stiffness, which was related to enhanced thermal stability and chemical interactions as shown by DSC and FTIR analyses. This formulation also displayed excellent hydrophilicity, swelling properties, and a consistent release profile over 8 to 24 h. Furthermore, MG-GA-CA/PVA showed superior antibacterial activity against both MSSA and MRSA, suggesting its potential as a strong, flexible, and effective anti-S. aureus material. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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<p>(<b>a</b>) The effect of the applied DC voltages (10, 15, 20, and 25 kV) at a distance of 20 cm and a flow rate of 1 mL/h, (<b>b</b>) the effect of injection flow rates (0.25, 0.50, 1.00, and 1.50 mL/h) at a distance of 20 cm and a voltage of 20 kV, and (<b>c</b>) the effect of the distance between the syringe tip and the collector (15, 20, 25, and 30 cm) at a flow rate of 1.5 mL/h and a voltage of 20 kV on the morphology of nanofibers, shown through SEM images at magnification of 15,000× and corresponding size diameter distribution (red histograms).</p>
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<p>SEM images of (<b>a1</b>,<b>a2</b>) CA/PVA, (<b>b1</b>,<b>b2</b>) MG-CA/PVA, (<b>c1</b>,<b>c2</b>) GA-CA/PVA, and (<b>d1</b>,<b>d2</b>) MG-GA-CA/PVA nanofiber patches at magnifications of 10,000× and 50,000× each, along with their fiber diameter distributions ((<b>a3</b>–<b>d3</b>), red histograms).</p>
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<p>FTIR spectra of CA/PVA, MG-CA/PVA, GA-CA/PVA, and MG-GA-CA/PVA nanofibers.</p>
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<p>DSC thermogram of CA/PVA, MG-CA/PVA, GA-CA/PVA, and MG-GA-CA/PVA nanofibers (heating rate 5 °C/min).</p>
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<p>(<b>a</b>) Stress and strain curves and (<b>b</b>) summarized mechanical properties of CA/PVA, MG-CA/PVA, GA-CA/PVA, and MG-GA-CA/PVA nanofibers. Data shown as mean ± S.D. (<span class="html-italic">n</span> = 5).</p>
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<p>(<b>a</b>) Average water contact angle on CA/PVA, MG-CA/PVA, GA-CA/PVA, and MG-GA-CA/PVA nanofiber mats and (<b>b</b>) the corresponding representative images of water droplets at 0 and 2 s from zone 2. Data shown as mean ± S.D. (<span class="html-italic">n</span> = 3).</p>
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<p>Degree of swelling of CA/PVA, MG-CA/PVA, GA-CA/PVA, and MG-GA-CA/PVA nanofiber mats and their corresponding figures. Data shown as mean ± S.D. (<span class="html-italic">n</span> = 3).</p>
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<p>Cumulative release of MG and GA at 8 and 24 h from CA/PVA electrospun. # not detected.</p>
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<p>The antibacterial activities of MG-CA/PVA, GA-CA/PVA, and MG-GA-CA/PVA compared with neat CA/PVA and ampicillin against <span class="html-italic">S. aureus</span> ATCC 25923 (MSSA) and 43300 (MRSA). Each symbol indicates the mean ± S.D. (<span class="html-italic">n</span> = 3). # The inhibition zone could not be determined. * Significant difference, <span class="html-italic">p</span> &lt; 0.05.</p>
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16 pages, 2604 KiB  
Article
Pectin–Chitosan Hydrogel Beads for Delivery of Functional Food Ingredients
by Eduardo Morales, Marcela Quilaqueo, Rocío Morales-Medina, Stephan Drusch, Rodrigo Navia, Agnès Montillet, Mónica Rubilar, Denis Poncelet, Felipe Galvez-Jiron and Francisca Acevedo
Foods 2024, 13(18), 2885; https://doi.org/10.3390/foods13182885 - 12 Sep 2024
Viewed by 1141
Abstract
A common challenge in hydrogel-based delivery systems is the premature release of low molecular weight encapsulates through diffusion or swelling and reduced cell viability caused by the low pH in gastric conditions. A second biopolymer, such as chitosan, can be incorporated to overcome [...] Read more.
A common challenge in hydrogel-based delivery systems is the premature release of low molecular weight encapsulates through diffusion or swelling and reduced cell viability caused by the low pH in gastric conditions. A second biopolymer, such as chitosan, can be incorporated to overcome this. Chitosan is usually associated with colonic drug delivery systems. We intended to formulate chitosan-coated pectin beads for use in delaying premature release of the encapsulate under gastric conditions but allowing release through disintegration under intestinal conditions. The latter is of utmost importance in delivering most functional food ingredients. Therefore, this study investigated the impact of formulation and process conditions on the size, sphericity, and dissolution behavior of chitosan-coated hydrogel beads prepared by interfacial coacervation. The size and sphericity of the beads depend on the formulation and range from approximately 3 to 5 mm and 0.82 to 0.95, respectively. Process conditions during electro-dripping may be modulated to tailor bead size. Depending on the voltage, bead size ranged from 1.5 to 4 mm. Confocal laser scanning microscopy and scanning electron microscopy confirmed chitosan shell formation around the pectin bead. Chitosan-coated beads maintained their size and shape in simulated gastric fluid but experienced structural damage in simulated intestinal fluid. Therefore, they represent a novel delivery system for functional food ingredients. Full article
(This article belongs to the Section Nutraceuticals, Functional Foods, and Novel Foods)
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<p>Viscosity curve for pectin with a degree of methyl-esterification of 30% (P30; top) and a degree of methyl-esterification of 35% (P35; bottom) in aqueous solution at a content of 0.5–3.0 wt.%.</p>
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<p>Viscosity curve of chitosan CsH in aqueous solution with 0.5 wt.% glacial acetic acid at a content of 0.5–3.0 wt.%.</p>
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<p>Zeta potential of pectin with a degree of methyl esterification of 30% (P30) or 35% (P35) and chitosan (CsH) in aqueous solution.</p>
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<p>Impact of pectin content and calcium chloride concentration (CaCl<sub>2</sub>) on mean hydrogel bead size (<b>A</b>–<b>C</b>) and sphericity (<b>D</b>–<b>F</b>) of pectin–chitosan beads at a chitosan content of 0.8 wt.% (<b>A</b>,<b>D</b>), 1.5% wt.% (<b>B</b>,<b>E</b>), or 2.2 wt.% (<b>C</b>,<b>F</b>).</p>
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<p>Impact of applied voltage during electrostatic droplet generation on bead size and sphericity for pectin–chitosan beads (2.2% pectin and 2.2% chitosan, extruded into a 130 mM calcium chloride solution).</p>
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<p>Microbead structure as revealed by scanning electron microscopy at varied magnifications (<b>A</b>,<b>C</b>,<b>D</b>) and and confocal laser scanning microscopy (<b>B</b>) where green colour indicates the presence of chitosan. (2.2 wt.% pectin solution extruded into an aqueous calcium chloride solution (130 mM) containing 2.2 wt.% chitosan CsH).</p>
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<p>Mean particle diameter of hydrogel beads (2.2 wt.% pectin solution extruded into an aqueous calcium chloride solution (130 mM) with or without 2.2 wt.% chitosan CsH) during incubation in simulated gastrointestinal fluids (SGF: simulated gastric fluid, SIF: simulated intestinal fluid, numbers indicate the duration of incubation in min).</p>
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20 pages, 8220 KiB  
Article
Passive Islanding Detection of Inverter-Based Resources in a Noisy Environment
by Hossein Amini, Ali Mehrizi-Sani and Reza Noroozian
Energies 2024, 17(17), 4405; https://doi.org/10.3390/en17174405 - 3 Sep 2024
Viewed by 633
Abstract
Islanding occurs when a load is energized solely by local generators and can result in frequency and voltage instability, changes in current, and poor power quality. Poor power quality can interrupt industrial operations, damage sensitive electrical equipment, and induce outages upon the resynchronization [...] Read more.
Islanding occurs when a load is energized solely by local generators and can result in frequency and voltage instability, changes in current, and poor power quality. Poor power quality can interrupt industrial operations, damage sensitive electrical equipment, and induce outages upon the resynchronization of the island with the grid. This study proposes an islanding detection method employing a Duffing oscillator to analyze voltage fluctuations at the point of common coupling (PCC) under a high-noise environment. Unlike existing methods, which overlook the noise effect, this paper mitigates noise impact on islanding detection. Power system noise in PCC measurements arises from switching transients, harmonics, grounding issues, voltage sags and swells, electromagnetic interference, and power quality issues that affect islanding detection. Transient events like lightning-induced traveling waves to the PCC can also introduce noise levels exceeding the voltage amplitude by more than seven times, thus disturbing conventional detection techniques. The noise interferes with measurements and increases the nondetection zone (NDZ), causing failed or delayed islanding detection. The Duffing oscillator nonlinear dynamics enable detection capabilities at a high noise level. The proposed method is designed to detect the PCC voltage fluctuations based on the IEEE standard 1547 through the Duffing oscillator. For the voltages beyond the threshold, the Duffing oscillator phase trajectory changes from periodic to chaotic mode and sends an islanded operation command to the inverter. The proposed islanding detection method distinguishes switching transients and faults from an islanded operation. Experimental validation of the method is conducted using a 3.6 kW PV setup. Full article
(This article belongs to the Section F3: Power Electronics)
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<p>Single line diagram of the study system.</p>
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<p>The block diagram of the study system and the proposed islanding detection method.</p>
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<p>Flowchart of the proposed islanding detection method using the Duffing equation.</p>
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<p>Phase trajectory of the Duffing oscillator for the voltage signal and the noise with <math display="inline"><semantics> <mrow> <mi>σ</mi> <mo>=</mo> <mn>0.21</mn> </mrow> </semantics></math> and the SNR = 25 dB: (<b>a</b>) simulation; (<b>b</b>) implementation.</p>
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<p>Experimental setup for islanding detection using Duffing oscillator.</p>
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<p>Detailed step-down voltage circuit for the ARM microcontroller.</p>
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<p>The Duffing oscillator phase trajectory in order mode at the normal operation of the system: (<b>a</b>) simulation; (<b>b</b>) implementation.</p>
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<p>Islanded operation of the system: (<b>a</b>) chaos phase trajectory of the Duffing oscillator in simulation, (<b>b</b>) <math display="inline"><semantics> <mrow> <mi>x</mi> <mo>−</mo> <mi>t</mi> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mrow> <mi>d</mi> <mi>x</mi> </mrow> <mrow> <mi>d</mi> <mi>t</mi> </mrow> </mfrac> </mstyle> <mo>−</mo> <mi>t</mi> </mrow> </semantics></math> diagrams in simulation, (<b>c</b>) chaos phase trajectory of the Duffing oscillator in implementation, and (<b>d</b>) <math display="inline"><semantics> <mrow> <mi>x</mi> <mo>−</mo> <mi>t</mi> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mrow> <mi>d</mi> <mi>x</mi> </mrow> <mrow> <mi>d</mi> <mi>t</mi> </mrow> </mfrac> </mstyle> <mo>−</mo> <mi>t</mi> </mrow> </semantics></math> diagrams in implementation.</p>
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<p><math display="inline"><semantics> <mrow> <mi>x</mi> <mo>−</mo> <mi>t</mi> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mrow> <mi>d</mi> <mi>x</mi> </mrow> <mrow> <mi>d</mi> <mi>t</mi> </mrow> </mfrac> </mstyle> <mo>−</mo> <mi>t</mi> </mrow> </semantics></math> diagrams of the Duffing oscillator in grid-connected operation: (<b>a</b>) simulation; (<b>b</b>) implementation.</p>
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<p>Noise effect on the proposed islanding detection method: (<b>a</b>) the noise signal in simulation, (<b>b</b>) distorted voltage signal with noise in simulation, (<b>c</b>) phase trajectory of the Duffing oscillator in order mode and normal operation of the system under the noise in simulation, (<b>d</b>) distorted voltage signal with noise in implementation, and (<b>e</b>) order mode of the phase trajectory for the Duffing oscillator in normal operation of the system under distorted voltage with the noise in implementation.</p>
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<p>NDZ comparison of the proposed islanding detection method with the passive islanding detection methods. Crimson represents the NDZ for [<a href="#B16-energies-17-04405" class="html-bibr">16</a>], blue for [<a href="#B18-energies-17-04405" class="html-bibr">18</a>], green for [<a href="#B7-energies-17-04405" class="html-bibr">7</a>], red for [<a href="#B31-energies-17-04405" class="html-bibr">31</a>], and black denotes the NDZ for the proposed method.</p>
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15 pages, 4627 KiB  
Article
Linear Actuators Based on Polyvinyl Alcohol/Lithium Chloride Hydrogels Activated by Low AC Voltage
by Tarek Dayyoub, Mikhail Zadorozhnyy, Kseniia V. Filippova, Lidiia D. Iudina, Dmitry V. Telyshev, Pavel V. Zhemchugov, Dmitriy G. Ladokhin and Aleksey Maksimkin
J. Compos. Sci. 2024, 8(8), 323; https://doi.org/10.3390/jcs8080323 - 15 Aug 2024
Viewed by 688
Abstract
The development of fast-responding electrically conductive polymers as actuators activated by low electrical current is now regarded as an urgent matter. Due to their limited electrical conductivity, actuators based on polymeric hydrogels must be activated using a high voltage (up to 200 V) [...] Read more.
The development of fast-responding electrically conductive polymers as actuators activated by low electrical current is now regarded as an urgent matter. Due to their limited electrical conductivity, actuators based on polymeric hydrogels must be activated using a high voltage (up to 200 V) and frequency (up to 500 Hz) when employing AC power. In this work, to improve the electrical conductivity of the hydrogel and decrease the required activation voltage of the hydrogel actuators, lithium chloride (LiCL) was added as a conductive filler to the polymer matrix of polyvinyl alcohol (PVA). In order to ascertain the deformation of actuators, activation and relaxation times, actuator efficiencies, and generated force under the conditions of activation, linear actuators that can be activated by extension/contraction (swelling/shrinking) cycles were prepared and investigated depending on the LiCl content, applied voltage, and frequency. Under a load of approximately 20 kPa and using a 90 V AC power at a 50 Hz frequency with a 30 wt.% LiCl content, it was found that the actuators’ total contraction, reinforced by a woven mesh braided material, was about 20% with a ~2.2 s activation time, while the actuators’ total extension, reinforced by a spiral weave material, was about 52% with a ~2.5 s activation time, after applying a 110 V AC at a 50 Hz frequency with a 10 wt.% LiCl content. Furthermore, as the lowest voltage, a 20 V AC power can operate these actuators by increasing the LiCl weight content to the same PVA mass content. Moreover, the PVA/LiCl hydrogels’ activation force can be greater than 0.5 MPa. The actuators that have been developed have broad applications in soft robotics, artificial muscles, medicine, and aerospace fields. Full article
(This article belongs to the Section Composites Applications)
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<p>Mechanism diagram of PVA hydrogel activation by AC power.</p>
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<p>Schematic process of preparation of PVA hydrogel.</p>
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<p>(<b>a</b>) Schematic process of crosslinking the PVA hydrogel; (<b>b</b>) chemical reaction of PVA and borax.</p>
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<p>(<b>a</b>) Schematic design for the hydrogel actuators; (<b>b</b>,<b>c</b>) two types of external reinforcement.</p>
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<p>(<b>a</b>) Measurement of actuation deformation by laser detector; (<b>b</b>) measurement of activation force by load cell.</p>
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<p>Extension values of activated actuators under (<b>a</b>) 50 Hz and (<b>b</b>) 500 Hz, activation time of actuators under (<b>c</b>) 50 Hz and (<b>d</b>) 500 Hz, and relaxation time of actuators under (<b>e</b>) 50 Hz and (<b>f</b>) 500 Hz.</p>
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<p>Contraction values of activated actuators under (<b>a</b>) 50 Hz and (<b>b</b>) 500 Hz, activation time of actuators under (<b>c</b>) 50 Hz and (<b>d</b>) 500 Hz, and relaxation time of actuators under (<b>e</b>) 50 Hz and (<b>f</b>) 500 Hz.</p>
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<p>Extension (<b>a</b>)/contraction (<b>b</b>) values, activation time (<b>c</b>,<b>d</b>), and relaxation time (<b>e</b>,<b>f</b>) of actuators based on hydrogels of PS1 and PS10.</p>
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<p>Extension (<b>a</b>)/contraction (<b>b</b>) values, activation time (<b>c</b>,<b>d</b>), and relaxation time (<b>e</b>,<b>f</b>) of actuators based on hydrogels of PS10.</p>
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20 pages, 12298 KiB  
Article
High-Definition Dynamic Voltage Restorer Systems Using Equivalent Time Sampling Techniques and Circular Structural Memory Filters
by Jae-ha Ko
Appl. Sci. 2024, 14(16), 6896; https://doi.org/10.3390/app14166896 - 6 Aug 2024
Viewed by 822
Abstract
Due to advances in power electronics technology and the evolution of automation devices, the number of electrical devices that are sensitive to power quality is rapidly increasing, and for this reason, users are increasing their demand for high quality. To meet power quality [...] Read more.
Due to advances in power electronics technology and the evolution of automation devices, the number of electrical devices that are sensitive to power quality is rapidly increasing, and for this reason, users are increasing their demand for high quality. To meet power quality demands, many power conversion devices are used, including dynamic voltage restorers (DVRs). DVRs are recognized as devices that can effectively manage problems such as voltage segments, swells, and harmonics. DVR control requires many samples for harmonic compensation, which has the disadvantage of being complicated to implement due to fast digital signal processing computation and the application of the cyclic discrete Fourier transform. In this paper, a high-precision DVR system configuration is proposed that compensates for harmonics using a periodically equivalent time-interval sampling technique and a novel circular-structured memory filter. The proposed circular-structured multi-pointer memory filter is an effective filter algorithm for high-precision input voltage measurement because it can remove noise and compensate for the delay of the phase angle of the filter in voltage measurement. A simulation and DVR prototype system were built, and the feasibility and effectiveness of the phase angle multi-filter voltage detection method and the compensation method were verified by experiments. Full article
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<p>Power quality compensation method by power system network.</p>
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<p>The structure of a typical ULTC. (<b>a</b>) Auto transformer type. (<b>b</b>) Serial transformer type.</p>
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<p>ULTC tap change operation principle.</p>
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<p>Tap changer with static switches.</p>
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<p>Basic principles of the DVR. (<b>a</b>) Equivalent circuit of DVR. (<b>b</b>) Basic Principles of DVR waveforms.</p>
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<p>Typical DVR system configuration. (<b>a</b>) Configuring DVR systems with transformers. (<b>b</b>) Configuring DVR systems with semiconductor devices.</p>
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<p>Typical DVR system configuration. (<b>a</b>) Configuring DVR systems with transformers. (<b>b</b>) Configuring DVR systems with semiconductor devices.</p>
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<p>Compensation characteristics as a function of DVR frequency. (<b>a</b>) Fundamental wave vector. (<b>b</b>) Harmonic vector.</p>
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<p>Proposed DVR system configuration.</p>
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<p>Compensation characteristics as a function of the frequency of the proposed DVR. (<b>a</b>) Fundamental wave vector. (<b>b</b>) Harmonic vector.</p>
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<p>Circular phase shifter.</p>
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<p>Operating principle of the circular structure filter. (<b>a</b>) Characteristics of an analog voltage filter. (<b>b</b>) Voltage AD sampling. (<b>c</b>) Phase shift voltage.</p>
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<p>Operating principle of the circular structure filter. (<b>a</b>) Characteristics of an analog voltage filter. (<b>b</b>) Voltage AD sampling. (<b>c</b>) Phase shift voltage.</p>
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<p>Multi-pointer memory filter with circular structure.</p>
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<p>Operating principle of the multi-pointer memory filter with circular structure.</p>
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<p>Circuit diagram for the configuration of the DVR system.</p>
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<p>Simulation results of the multi-pointer memory filter with circular structure.</p>
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<p>Simulation results of the filter characteristic analysis near the voltage zero point.</p>
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<p>Simulation result of DVR voltage compensation.</p>
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<p>Voltage compensation simulation results of the steady-state DVR.</p>
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<p>Filter characteristic analysis. (<b>a</b>) The waveform with grid voltage, circular structure multipoint filter output, and an analog filter output. (<b>b</b>) The steady-state waveform with grid voltage, circular structure multipoint filter output, and an analog filter output. (<b>c</b>) The phase difference waveform with grid voltage, circular structure multipoint filter output, and analog filter output.</p>
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<p>Filter characteristic analysis. (<b>a</b>) The waveform with grid voltage, circular structure multipoint filter output, and an analog filter output. (<b>b</b>) The steady-state waveform with grid voltage, circular structure multipoint filter output, and an analog filter output. (<b>c</b>) The phase difference waveform with grid voltage, circular structure multipoint filter output, and analog filter output.</p>
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<p>Results of the DVR voltage compensation experiment. (<b>a</b>) The waveform with conventional method, in which a harmonic component appears in the output voltage owing to the harmonic of the grid voltage. (<b>b</b>) The waveform with proposed method in which the output voltage becomes a sine wave.</p>
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<p>Results of the DVR voltage compensation experiment. (<b>a</b>) The waveform with conventional method, in which a harmonic component appears in the output voltage owing to the harmonic of the grid voltage. (<b>b</b>) The waveform with proposed method in which the output voltage becomes a sine wave.</p>
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<p>Results of the DVR load fluctuation experiment.</p>
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<p>Analysis of the voltage compensation waveforms in the DVR.</p>
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14 pages, 3916 KiB  
Article
Exploring Mixed Ionic–Electronic-Conducting PVA/PEDOT:PSS Hydrogels as Channel Materials for Organic Electrochemical Transistors
by Tatiana Gregorio, Dominique Mombrú, Mariano Romero, Ricardo Faccio and Álvaro W. Mombrú
Polymers 2024, 16(11), 1478; https://doi.org/10.3390/polym16111478 - 23 May 2024
Viewed by 1499
Abstract
Here, we report the preparation and evaluation of PVA/PEDOT:PSS-conducting hydrogels working as channel materials for OECT applications, focusing on the understanding of their charge transport and transfer properties. Our conducting hydrogels are based on crosslinked PVA with PEDOT:PSS interacting via hydrogen bonding and [...] Read more.
Here, we report the preparation and evaluation of PVA/PEDOT:PSS-conducting hydrogels working as channel materials for OECT applications, focusing on the understanding of their charge transport and transfer properties. Our conducting hydrogels are based on crosslinked PVA with PEDOT:PSS interacting via hydrogen bonding and exhibit an excellent swelling ratio of ~180–200% w/w. Our electrochemical impedance studies indicate that the charge transport and transfer processes at the channel material based on conducting hydrogels are not trivial compared to conducting polymeric films. The most relevant feature is that the ionic transport through the swollen hydrogel is clearly different from the transport through the solution, and the charge transfer and diffusion processes govern the low-frequency regime. In addition, we have performed in operando Raman spectroscopy analyses in the OECT devices supported by first-principle computational simulations corroborating the doping/de-doping processes under different applied gate voltages. The maximum transconductance (gm~1.05 μS) and maximum volumetric capacitance (C*~2.3 F.cm−3) values indicate that these conducting hydrogels can be promising candidates as channel materials for OECT devices. Full article
(This article belongs to the Section Polymer Analysis and Characterization)
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<p>Photo of the OECT device, zooming into the channel area (scale bar 100 μm) (<b>left panel</b>), and schematization showing top and front views (<b>right panel</b>).</p>
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<p><span class="html-italic">X</span>-ray diffraction patterns for PVA, PP-0, PP-3, PP-12, and PP-20 hydrogels.</p>
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<p>FT-IR spectra for PVA, PP-0, PP-3, PP-12, and PP-20 hydrogels with the asterisks (*) showing the most relevant vibrational modes associated with PEDOT:PSS.</p>
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<p>Raman spectra for PVA, PP-0, PP-3, PP-12, and PP-20 hydrogels with the asterisks (*) showing the most relevant vibrational modes associated with PEDOT:PSS.</p>
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<p>Swelling ratio (expressed in % <span class="html-italic">w</span>/<span class="html-italic">w</span>) for PP-0, PP-3, PP-12, and PP-20 hydrogels.</p>
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<p>SEM images collected in the secondary electron imaging mode for (<b>a</b>) PP-0, (<b>b</b>) PP-3, (<b>c</b>) PP-12, and (<b>d</b>) PP-20 hydrogels after adding a microliter drop of the electrolyte solution. (<b>e</b>) Schematization of the PVA interchain interactions via crosslinking and PVA/PEDOT:PSS interchain interactions via hydrogen bonding.</p>
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<p>Chronoamperometry at V<sub>ds</sub> = −0.5 V and V<sub>g</sub> = −0.3 V for PP-3, PP-12, and PP-20 (<b>left panel</b>). Output characteristic at V<sub>g</sub> = −0.3 V–+0.5 V (<b>middle panel</b>) and channel current/transconductance at V<sub>ds</sub> = −0.5 V (<b>right panel</b>) for the PP-12 hydrogel channel OECT devices working with 0.1 M KCl.</p>
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<p>(<b>a</b>) Impedance (Z) and total capacitance (C<sub>T</sub>) as a function of frequency and Nyquist/Bode plots obtained from impedance spectroscopy analyses where data is represented with circles and fitting is represented with lines while black and blue arrows indicate the corresponding axis (<b>b</b>) Schematization of the circuit model for the ionic–electronic transport for the PVA/PEDOT:PSS (PP-12) hydrogel channel OECT devices working with 0.1 M KCl, where atoms (colors) are potassium (purple) and chloride (green).</p>
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<p>In operando Raman spectra and <span class="html-italic">v</span>(C=C) peaks fitting with errors in parenthesis at selected applied gate voltages of V<sub>g</sub> = −0.6 and +0.6 V for the PVA/PEDOT:PSS (PP-12) hydrogel channel OECT device with KCl solutions with different concentrations (<b>left panel</b>) and optimized structures for the modeling of the OECT ON (V<sub>g</sub> &lt; 0), zero-gated (V<sub>g</sub> = 0), and OFF (V<sub>g</sub> &gt; 0) conditions (<b>right panel</b>). The lower frequency (1415–1443 cm<sup>−1</sup>) and the higher frequency (1443–1459 cm<sup>−1</sup>) C=C thiophene stretching mode fittings are represented in blue and black, respectively, and references for atoms (colors) are carbon (gray), oxygen (red), hydrogen (white), sulfur (yellow), chloride anion (green), and potassium cation (purple).</p>
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25 pages, 10880 KiB  
Article
Applications of Kepler Algorithm-Based Controller for DC Chopper: Towards Stabilizing Wind Driven PMSGs under Nonstandard Voltages
by Basiony Shehata Atia, Mohamed Metwally Mahmoud, I. M. Elzein, Abdel-Moamen Mohamed Abdel-Rahim, Abdulaziz Alkuhayli, Usama Khaled, Abderrahmane Beroual and Salma Abdelaal Shaaban
Sustainability 2024, 16(7), 2952; https://doi.org/10.3390/su16072952 - 2 Apr 2024
Cited by 7 | Viewed by 1143
Abstract
An optimization technique, the Kepler optimizer (KO), is presented to enable permanent magnet synchronous wind generators (PMSWG) to run safely under faults and to accomplish the goal of low-carbon efficient power delivery and sustainable development. Utility companies are struggling, which is preventing the [...] Read more.
An optimization technique, the Kepler optimizer (KO), is presented to enable permanent magnet synchronous wind generators (PMSWG) to run safely under faults and to accomplish the goal of low-carbon efficient power delivery and sustainable development. Utility companies are struggling, which is preventing the increase in wind penetration, in spite of the grid incorporation of PMSWG. One of these undisputed concerns is the grid-side voltage dip (VD) and swell (VS) at the PCC. Converters and DCL capacitors are particularly vulnerable to PCC nonstandard voltages because of an imbalance in the DCL input–output powers. Because of this, it is essential to provide WF-GCs to support grid operations, and developing techniques to realize FRTCs has become a crucial GC need. Installing an industrial braking chopper (BC) across the DCL is the suggested technique, due to its effectiveness and low price. In addition, a new KO-based control system for BC is used to enhance its effectiveness. Four situations were examined to assess and analyze the proposed control system regarding the transient response of the system. These situations exposed the investigated system to an irregular grid condition: without BC, with BC controlled by a hysteresis controller, and with BC controlled by KO-based PI (proposed) at (a) 100% VD, (b) 70% VD, (c) 30% VD, and (d) 20% VS. To verify the advantages and efficacy of the suggested control systems in the examined circumstances, MATLAB/SIMULINK was utilized. The simulation findings confirmed the feasibility of the suggested system as a whole and the control structures in suppression of all parameter transient changes, while also achieving FRTC. Furthermore, maintaining a steady DCL voltage serves as an advantage that would lengthen the electrical converters’ lifetime and shorten the time that the unit would be turned off if it happens to fail. Full article
(This article belongs to the Special Issue Energy Technology and Sustainable Energy Systems)
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<p>GC necessities that consist of (<b>a</b>) ride-through curve, and (<b>b</b>) support curve of Iq.</p>
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<p>Addressed system.</p>
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<p>BC control structure.</p>
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<p>Archetypal BC situation switches cast-off via the DCL.</p>
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<p>KOA flowchart.</p>
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<p>Configuration of the DCL in the BC-BTBC.</p>
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<p>Proposed strategy.</p>
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<p>Transient system parameters (SP) as a result of 100% VD.</p>
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<p>Transient system parameters (SP) as a result of 100% VD.</p>
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<p>Transient SP as a result of 70% VD.</p>
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<p>Transient SP as a result of 70% VD.</p>
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<p>Transient SP as a result of 70% VD.</p>
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<p>Transient SP as a result of 30% VD.</p>
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<p>Transient SP as a result of 30% VD.</p>
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<p>Transient SP as a result of 30% VD.</p>
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<p>Transient SP as a result of 20% VS.</p>
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<p>Transient SP as a result of 20% VS.</p>
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<p>Transient SP as a result of 20% VS.</p>
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<p>DCLV values under investigated scenarios.</p>
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26 pages, 4079 KiB  
Review
Dynamic Voltage Restorer as a Solution to Voltage Problems in Power Systems: Focus on Sags, Swells and Steady Fluctuations
by Nhlanhla Mbuli
Energies 2023, 16(19), 6946; https://doi.org/10.3390/en16196946 - 4 Oct 2023
Cited by 3 | Viewed by 2425
Abstract
In this study, the author presents the results of a survey on the utilisation of a dynamic voltage restorer (DVR) in power systems to alleviate voltage problems that result in sags, swells and fluctuations in voltage outside the required steady limits. A methodology [...] Read more.
In this study, the author presents the results of a survey on the utilisation of a dynamic voltage restorer (DVR) in power systems to alleviate voltage problems that result in sags, swells and fluctuations in voltage outside the required steady limits. A methodology based on the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) statement is adopted for conducting and reporting on the review, while the Scopus database is used to locate the relevant publications. A total of 68 publications qualify for inclusion in the survey. A bibliometric analysis covering the number of publications per annum, the top 10 most-cited journals and the top 10 most-cited publications is performed. The information from the selected publications is extracted, summarised and categorised into network scenarios for the use of DVRs, topologies and optimisation of DVRs; strategies for DVR controllers; and platforms that evaluate the feasibility of DVR topologies and controllers. Moreover, research trends and gaps are evaluated. Finally, potential areas for future research are proposed. This study provides an overview of the research on the use of a DVR to resolve voltage problems and is a resource for researchers generally interested in distributed flexible AC transmission systems (DFACTSs) and particularly interested in DVRs. Full article
(This article belongs to the Section F1: Electrical Power System)
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<p>Layout and components of a DVR [<a href="#B17-energies-16-06946" class="html-bibr">17</a>].</p>
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<p>Schematic representation of the PRIMSA-based methodology used.</p>
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<p>Main categories of the information extracted from the selected publications.</p>
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<p>Annual number and cumulative annual number of publications per annum.</p>
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<p>Network visualisation map of the keywords.</p>
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<p>Overlay visualisation map of the keywords.</p>
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<p>Overlay visualisation map using “dynamic voltage restorer” as the reference keyword.</p>
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<p>Overlay visualisation map using “voltage sag” as the reference keyword.</p>
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<p>Overlay visualisation map using “voltage swell” as the reference keyword.</p>
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<p>Overlay visualisation map using “voltage fluctuations” as the reference keyword.</p>
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12 pages, 16456 KiB  
Article
Chlorhexidine-Containing Electrospun Polymeric Nanofibers for Dental Applications: An In Vitro Study
by Luana Dutra de Carvalho, Bernardo Urbanetto Peres, Ya Shen, Markus Haapasalo, Hazuki Maezono, Adriana P. Manso, Frank Ko, John Jackson and Ricardo M. Carvalho
Antibiotics 2023, 12(9), 1414; https://doi.org/10.3390/antibiotics12091414 - 6 Sep 2023
Cited by 1 | Viewed by 1494
Abstract
Chlorhexidine is the most commonly used anti-infective drug in dentistry. To treat infected void areas, a drug-loaded material that swells to fill the void and releases the drug slowly is needed. This study investigated the encapsulation and release of chlorhexidine from cellulose acetate [...] Read more.
Chlorhexidine is the most commonly used anti-infective drug in dentistry. To treat infected void areas, a drug-loaded material that swells to fill the void and releases the drug slowly is needed. This study investigated the encapsulation and release of chlorhexidine from cellulose acetate nanofibers for use as an antibacterial treatment for dental bacterial infections by oral bacteria Streptococcus mutans and Enterococcus faecalis. This study used a commercial electrospinning machine to finely control the manufacture of thin, flexible, chlorhexidine-loaded cellulose acetate nanofiber mats with very-small-diameter fibers (measured using SEM). Water absorption was measured gravimetrically, drug release was analyzed by absorbance at 254 nm, and antibiotic effects were measured by halo analysis in agar. Slow electrospinning at lower voltage (14 kV), short target distance (14 cm), slow traverse and rotation, and syringe injection speeds with controlled humidity and temperature allowed for the manufacture of strong, thin films with evenly cross-meshed, uniform low-diameter nanofibers (640 nm) that were flexible and absorbed over 600% in water. Chlorhexidine was encapsulated efficiently and released in a controlled manner. All formulations killed both bacteria and may be used to fill infected voids by swelling for intimate contact with surfaces and hold the drug in the swollen matrix for effective bacterial killing in dental settings. Full article
(This article belongs to the Special Issue Nanocarriers-Based Antimicrobial Drug Delivery)
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<p>SEM photomicrographs of CA-PEO mats under different magnifications.</p>
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<p>SEM photomicrographs of CA-TTE mats under different magnifications.</p>
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<p>SEM photomicrographs of CA-CHX 0.3 mats under different magnifications.</p>
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<p>SEM photomicrographs of CA-CHX 1.2 mats under different magnifications.</p>
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<p>SEM photomicrographs of CA-PEO with post-spin treatment mats under different magnifications.</p>
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<p>Water absorption of chlorhexidine-loaded cellulose acetate nanofiber mats (0.3 and 1.2 indicate the loading % of chlorhexidine in cellulose acetate).</p>
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<p>Release of chlorhexidine (μg/mL) from the nanofiber mats.</p>
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<p>Comparison of the size of the inhibition halos against <span class="html-italic">S. mutans</span> formed around the different fiber mats and controls.</p>
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<p>Comparison of the size of the inhibition halos against <span class="html-italic">E. faecalis</span> formed around the different fiber mats and controls.</p>
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<p>The inhibition halos observed when the experimental mats were applied against <span class="html-italic">S. mutans</span> (<b>A</b>) and <span class="html-italic">E. faecalis</span> (<b>B</b>).</p>
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25 pages, 8709 KiB  
Review
A Review on AC Voltage Variation Compensators in Low Voltage Distribution Network
by Elżbieta Sztajmec and Paweł Szcześniak
Energies 2023, 16(17), 6293; https://doi.org/10.3390/en16176293 - 29 Aug 2023
Cited by 5 | Viewed by 1678
Abstract
Power quality is one of the most important aspects of the power system, especially in the distribution system. This system can be affected by such disturbances as short-term voltage sags/swells, long-term voltage increases/decreases over the normative limits, harmonic distortion, interruptions, etc. Maintaining the [...] Read more.
Power quality is one of the most important aspects of the power system, especially in the distribution system. This system can be affected by such disturbances as short-term voltage sags/swells, long-term voltage increases/decreases over the normative limits, harmonic distortion, interruptions, etc. Maintaining the electricity quality parameters in accordance with the applicable standards in the power distribution system will require the use of additional devices. The scientific literature on the subject indicates a very wide range of different topologies of AC voltage compensators. In this paper, different power electronics-based AC voltage compensator topologies are reviewed that are typically used with distribution energy systems. A summary of the properties and functionalities of the selected topologies has been presented. This review focuses mainly on the different topologies of the Unified Power Quality Controllers (UPQC) and Hybrid Transformers (HT). This review is divided into several sections. The first section presents the topologies used in UPQC and HT. The second section discusses selected control methods for these systems. The third section presents the basic properties of the systems related to compensating changes in the supply voltage and improvement of power quality. The fourth section presents the use of UPQC and HT systems. Finally, a summary and conclusions are presented. Full article
(This article belongs to the Section F1: Electrical Power System)
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<p>Issues related to the distribution power system.</p>
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<p>Power quality issues.</p>
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<p>Voltage variations occurring in a typical sinusoidal voltage signal.</p>
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<p>Voltage compensation devices.</p>
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<p>Topology of the HT consisting of power converter connected to AW and in series without CT. Where vs. is source voltage, and <span class="html-italic">v<sub>o</sub></span> is output voltage.</p>
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<p>Basic topology of the UPQC, also named in the literature as UPQC-R.</p>
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<p>Classification of the UPQC based on structure and voltage sag compensation.</p>
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<p>The UPQC with Current Source Inverter (CSI).</p>
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<p>The UPQC configuration for different power supply systems: (<b>a</b>) H-Bridge configuration in single-phase two-wire (1P2W) system; (<b>b</b>) the UPQC in three-phase three-wire (3P3W) system.</p>
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<p>The UPQC-L topology.</p>
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<p>The UPQC-I topology.</p>
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<p>The UPQC-MC topology.</p>
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<p>The UPQC-MD topology.</p>
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<p>The UPQC-ML topology.</p>
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<p>The UPQC-D topology.</p>
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<p>The UPQC-DG topology.</p>
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<p>The HT configurations depending on the power converter connection: (<b>a</b>) series connection without the CT; (<b>b</b>) series connection with CT; (<b>c</b>) connection to the LFT core; (<b>d</b>) shunt connection.</p>
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<p>The HT configurations, depending on the power converter connection: (<b>a</b>) connected to the auxiliary windings (AWs) and in series without the CT; (<b>b</b>) connected to the AWs and in series with the CT; (<b>c</b>) connected to the two AWs.</p>
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<p>The HT configurations, depending on the power converter connection: (<b>a</b>) connected to the secondary side and in series without the CT; (<b>b</b>) connected to the secondary side and in series with CT; (<b>c</b>) connected to both sides of the LFT in shunt configuration.</p>
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<p>Power converter topologies for the HT.</p>
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<p>Block diagrams of the exemplary basic control approach for (<b>a</b>) the series APF in the UPQC and (<b>b</b>) the shunt APF in the UPQC.</p>
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<p>Block diagrams of the exemplary basic control approach for (<b>a</b>) the series APF in the UPQC and (<b>b</b>) the shunt APF in the UPQC.</p>
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<p>Block diagram of the exemplary basic control approach in the single-phase HT with the AC/AC power converter.</p>
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16 pages, 4775 KiB  
Article
Fabrication and Characterization of Cu2+-Driven PTFE-Reinforced Artificial Muscle Polymer Membrane for Water Purification and Energy Harvesting Applications
by Venkata Dinesh Avvari and P. S. Rama Sreekanth
Membranes 2023, 13(9), 766; https://doi.org/10.3390/membranes13090766 - 29 Aug 2023
Cited by 3 | Viewed by 1314
Abstract
Ionic polymer membranes have not yet gained widespread practical application in areas such as water purification and energy harvesting due to their high cost and tendency to swell. The present study involved the fabrication of reinforced textile structures composed of polytetrafluoroethylene (PTFE)-reinforced Nafion [...] Read more.
Ionic polymer membranes have not yet gained widespread practical application in areas such as water purification and energy harvesting due to their high cost and tendency to swell. The present study involved the fabrication of reinforced textile structures composed of polytetrafluoroethylene (PTFE)-reinforced Nafion membranes coated with non-precious metals, copper and silver, as a surface electrode by applying a chemical decomposition technique. Several mechanical, contact angle measurement and dielectric tests were conducted on membranes to evaluate their mechanical, wettability and conductivity properties. From scanning electron microscopy, it is clear that the formation of surface electrodes with uniform dispersion of metal particles. Scratch test reveals the adhesive strength between the coated metal particles and membrane. The silver-activated copper-coated membrane has a high contact angle of 121°. Thus, the fabricated membranes can have good antibacterial and adsorption properties for water treatment. The copper-coated membrane has a high Young’s modulus of 779 ± 80 MPa and a tensile strength of 29.1 ± 8 MPa, whereas the elongation at break is more for silver-activated copper-coated samples recorded as 158 ± 4%. The viscoelastic behavior of the membranes was analyzed through dynamic mechanical analysis (DMA). A sharp rise in the storage modulus (E′) value of 4.8 × 1010 Pa at ~80 °C at a frequency of 1 Hz on metal surface electrodes signifies an improvement in the strength of the material in comparison to the initial pure membrane. The successful enhancement of conductivity on the membrane surface via chemical deposition on the silver-activated membrane is 1 × 10−4 (S/cm) and holds great potential for facilitating voltage transmission through the tribolayer in the nanogenerators. Full article
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<p>Electroless plating process of copper on TFRN membrane.</p>
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<p>(<b>a</b>) Pure membrane, (<b>b</b>) copper-activated copper-coated membrane (Cu-Cu), (<b>c</b>) copper-activated silver-coated membrane (Cu-Ag), and (<b>d</b>) silver-activated copper-coated membrane (Ag-Cu).</p>
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<p>(<b>a</b>) Cu-IPMC, (<b>b</b>) microstructure of pure PTFE-reinforced Nafion, (<b>c</b>) presence of ionic liquid with reinforcement, (<b>d</b>) SEM of electrode layer and cut section of PTFE, and (<b>e</b>) electrode thickness.</p>
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<p>(<b>a</b>) Cu-IPMC, (<b>b</b>) microstructure of pure PTFE-reinforced Nafion, (<b>c</b>) presence of ionic liquid with reinforcement, (<b>d</b>) SEM of electrode layer and cut section of PTFE, and (<b>e</b>) electrode thickness.</p>
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<p>FITR analysis of Cu-Cu, Cu-Ag, and Ag-Cu IPMC membranes.</p>
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<p>(<b>a</b>) Force-displacement curve, (<b>b</b>) Young’s modulus, and (<b>c</b>) tensile strength and elongation at break.</p>
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<p>Contact angle measurements on pure and chemical-plated polymer membranes.</p>
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<p>XRD analysis of (<b>a</b>) pure, (<b>b</b>) Cu-Cu, (<b>c</b>) Cu-Ag, and (<b>d</b>) Ag-Cu.</p>
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<p>Scratch test of (<b>a</b>) pure membrane, (<b>b</b>) copper-activated copper-coated membrane (Cu-Cu), (<b>c</b>) copper-activated silver-coated membrane (Cu-Ag), and (<b>d</b>) silver-activated copper-coated membrane (Ag-Cu).</p>
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<p>DMA analysis of (<b>a</b>) Cu-Cu, (<b>b</b>) Cu-Ag, and (<b>c</b>) Ag-Cu.</p>
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<p>A study on the dielectric properties of membranes, both pure and with deposited metals.</p>
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18 pages, 20746 KiB  
Article
Voltage Control in LV Distribution Grid Using AC Voltage Compensator with Bipolar AC/AC Matrix Choppers
by Elżbieta Sztajmec and Paweł Szcześniak
Appl. Sci. 2023, 13(15), 8736; https://doi.org/10.3390/app13158736 - 28 Jul 2023
Viewed by 1077
Abstract
The modern low-voltage distribution system is exposed to frequent changes in voltage amplitude due to the presence of high-power receivers with variable operating characteristics as well as distributed renewable energy sources whose generation levels depend on weather conditions. Maintaining the appropriate parameters related [...] Read more.
The modern low-voltage distribution system is exposed to frequent changes in voltage amplitude due to the presence of high-power receivers with variable operating characteristics as well as distributed renewable energy sources whose generation levels depend on weather conditions. Maintaining the appropriate parameters related to power quality in the context of permissible voltage levels more and more often requires the use of additional voltage regulators. These are static systems in which the values of taps on transformers are changed, or dynamic compensators using power electronic converters. This article presents the continuation of research on one of the proposals of AC voltage compensators based on a bipolar AC/AC converter. The general properties of the presented system are reviewed and an analysis of the range of generated output voltages depending on the phase shift of the compensating voltage are presented. The next part of the article presents the formulas for calculating the duty cycle factors for the control functions of individual converters. The verification of the determined dependencies is presented on the basis of simulation tests of the proposed system. At the end of this article, the disadvantages of the proposed open-loop control system regulation and a proposal for further research are indicated. Full article
(This article belongs to the Collection Advanced Power Electronics in Power Networks)
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<p>Diagram of the bipolar AC/AC controller based on matrix chopper (MC).</p>
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<p>Control characteristics of the bipolar AC/AC controller: (<b>a</b>) voltage transmittance, (<b>b</b>) phase of voltage transmittance.</p>
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<p>Structure of the voltage controller in phase 1 (AC/AC I).</p>
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<p>Diagram of the three-phase voltage compensator with a bipolar AC/AC controller.</p>
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<p>Voltage phasor diagram for AC/AC I (<a href="#applsci-13-08736-f004" class="html-fig">Figure 4</a>), where I—VIII are the number of sectors.</p>
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<p>Calculation of the output voltage vector amplitude in: (<b>a</b>) sector I, (<b>b</b>) sector II, (<b>c</b>) sector III, (<b>d</b>) sector IV, (<b>e</b>) sector V, (<b>f</b>) sector VI, (<b>g</b>) sector VII, (<b>h</b>) sector VIII.</p>
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<p>(<b>a</b>) Regulation range of the amplitude of the output voltage vector, (<b>b</b>) position angle of the output voltage vector calculated from the beginning of each sector.</p>
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<p>Voltage phasor diagram for AC/AC II, (<a href="#applsci-13-08736-f004" class="html-fig">Figure 4</a>), where I—VIII are the number of sectors.</p>
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<p>Voltage phasor diagram for AC/AC III, (<a href="#applsci-13-08736-f004" class="html-fig">Figure 4</a>), where I—VIII are the number of sectors.</p>
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<p>An example of determining the pulse duty ratios <math display="inline"><semantics><msub><mi>D</mi><mn>1</mn></msub></semantics></math> and <math display="inline"><semantics><msub><mi>D</mi><mn>2</mn></msub></semantics></math> in sector I.</p>
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<p>Block diagram of the control unit.</p>
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<p>Symmetrical voltage sag.</p>
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<p>Symmetrical overvoltage.</p>
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<p>Low-frequency voltage fluctuation.</p>
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<p>Voltage change in one phase.</p>
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<p>Voltage loss in one phase.</p>
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<p>Differences between the reference values and the measured values of the output voltages at a symmetrical three-phase voltage sag.</p>
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<p>An example of currents taken from the power grid during the operation of a voltage compensator.</p>
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26 pages, 8384 KiB  
Article
Horse Herd Optimized Intelligent Controller for Sustainable PV Interface Grid-Connected System: A Qualitative Approach
by Anupama Ganguly, Pabitra Kumar Biswas, Chiranjit Sain, Ahmad Taher Azar, Ahmed Redha Mahlous and Saim Ahmed
Sustainability 2023, 15(14), 11160; https://doi.org/10.3390/su151411160 - 18 Jul 2023
Cited by 9 | Viewed by 1640
Abstract
The need for energy is always increasing as civilization evolves. Renewable energy sources are crucial for meeting energy demands as conventional fuel resources are slowly running out. Researchers are working to extract the most amount of power possible from renewable resources. Numerous resources [...] Read more.
The need for energy is always increasing as civilization evolves. Renewable energy sources are crucial for meeting energy demands as conventional fuel resources are slowly running out. Researchers are working to extract the most amount of power possible from renewable resources. Numerous resources are in demand, including solar, wind, biomass, tidal, and geothermal resources. Solar energy outperformed all the aforementioned resources in terms of efficiency, cleanliness, and pollution freeness. Intermittency, however, is the resource’s main shortcoming. Maximum power point tracking algorithm (MPPT) integration is required for the system to achieve continuous optimum power by overcoming the feature of intermittency. However, generating electrical energy from solar energy has presented a significant problem in ensuring the output power’s quality within a reasonable range. Total harmonic distortion (THD), a phenomenon, may have an impact on the power quality. Depending on the properties of the load, variables like power factor, voltage sag/swell, frequency, and unbalancing may occur. The quality of power and its criterion exhibits a non-linear connection. The article’s primary objective is to analyze the PV interface grid-linked system’s qualitative and quantitative performance. With respect to varying solar irradiation conditions, partial shading conditions, and solar power quality within the acceptable dimension, a novel intelligent multiple-objective horse herd optimization (HHO)-based adaptive fractional order PID (HHO-AFOPID) controller is used to achieve this goal. Adaptive fractional order PID (AFOPID), conventional FOPID, and PID controllers were used to evaluate the performance of the suggested controller, which was then validated using a commercially available PV panel in MATLAB/Simulink by varying the productivity of non-conventional resources, the inverter’s level of uncertainty, and the potential at the grid’s end. In order to realize the features of the system, sensitivity examination is also carried out for solar energy’s sensitive parameters. The stability analysis of the proposed control topology is also carried out in terms of the integral absolute error (IAE) and integral time absolute error (ITAE). The examination of the sensitivity of variations in solar radiation in kilowatt per square meter per day is based on the total net present cost (TNPC) and levelized cost of energy (LCOE), as optimal dimension and energy cost are both aspects of priority. The suggested control methodology is an approach for the qualitative and quantitative performance analysis of a PV interface grid-oriented system. Full article
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<p>Combined model of photovoltaic generation.</p>
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<p>SPV with a bypass diode and blocking diode designed in series-shunt combination.</p>
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<p>Flowchart of the proposed HHO-AFOPID control algorithm.</p>
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<p>Block diagram of the proposed methodology.</p>
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<p>Experiment of the proposed HHO-AFOPID controller (<b>a</b>) under constant irradiation, (<b>b</b>) under changing irradiation, and (<b>c</b>) under various irradiation levels: 850 W/<math display="inline"><semantics> <mrow> <msup> <mrow> <mi mathvariant="normal">m</mi> </mrow> <mrow> <mn>2</mn> </mrow> </msup> </mrow> </semantics></math> and 500 W/<math display="inline"><semantics> <mrow> <msup> <mrow> <mi mathvariant="normal">m</mi> </mrow> <mrow> <mn>2</mn> </mrow> </msup> </mrow> </semantics></math>.</p>
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<p>Experiment of the proposed HHO-AFOPID controller (<b>a</b>) under constant irradiation, (<b>b</b>) under changing irradiation, and (<b>c</b>) under various irradiation levels: 850 W/<math display="inline"><semantics> <mrow> <msup> <mrow> <mi mathvariant="normal">m</mi> </mrow> <mrow> <mn>2</mn> </mrow> </msup> </mrow> </semantics></math> and 500 W/<math display="inline"><semantics> <mrow> <msup> <mrow> <mi mathvariant="normal">m</mi> </mrow> <mrow> <mn>2</mn> </mrow> </msup> </mrow> </semantics></math>.</p>
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<p>Features of the voltage of the dc link (<b>a</b>) under constant irradiation level and (<b>b</b>) under changing irradiation levels.</p>
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<p>Features of the voltage of the dc link (<b>a</b>) under constant irradiation level and (<b>b</b>) under changing irradiation levels.</p>
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<p>Experiment under the partial shading condition.</p>
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<p>Power quality analysis on the basis of (<b>a</b>) voltage deviations under HHO-AFOPID, (<b>b</b>) frequency under HHO-AFOPID, and (<b>c</b>) THD analysis under HHO-AFOPID.</p>
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<p>Power quality analysis on the basis of (<b>a</b>) voltage deviations under HHO-AFOPID, (<b>b</b>) frequency under HHO-AFOPID, and (<b>c</b>) THD analysis under HHO-AFOPID.</p>
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<p>Effect of varying solar irradiation on the total net present cost and levelized cost of energy.</p>
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13 pages, 3781 KiB  
Article
Semi-Interpenetrating Network Anion Exchange Membranes by Thiol–Ene Coupling Reaction for Alkaline Fuel Cells and Water Electrolyzers
by Zhiyu Jin, Xiuyang Zou, Guodong Xu, Zhe Sun and Feng Yan
Molecules 2023, 28(14), 5470; https://doi.org/10.3390/molecules28145470 - 17 Jul 2023
Cited by 1 | Viewed by 1493
Abstract
In this work, a thiol–ene coupling reaction was employed to prepare the semi-interpenetrating polymer network AEMs. The obtained QP-1/2 membrane exhibits high hydroxide conductivity (162.5 mS cm−1 at 80 °C) with a relatively lower swelling ratio, demonstrating its mechanical strength of 42 [...] Read more.
In this work, a thiol–ene coupling reaction was employed to prepare the semi-interpenetrating polymer network AEMs. The obtained QP-1/2 membrane exhibits high hydroxide conductivity (162.5 mS cm−1 at 80 °C) with a relatively lower swelling ratio, demonstrating its mechanical strength of 42 MPa. This membrane is noteworthy for its improved alkaline stability, as the semi-interpenetrating network effectively limits the attack of hydroxide. Even after being treated in 2 M NaOH at 80 °C for 600 h, 82.5% of the hydroxide conductivity is maintained. The H2/O2 fuel cell with QP-1/2 membrane displays a peak power density of 521 mW cm−2. Alkaline water electrolyzers based on QP-1/2 membrane demonstrated a current density of 1460 mA cm−2 at a cell voltage of 2.00 V using NiCoFe catalysts in the anode. All the results demonstrate that a semi-interpenetrating structure is a promising way to enhance the mechanical property, ionic conductivity, and alkaline stability of AEMs for the application of alkaline fuel cells and water electrolyzers. Full article
(This article belongs to the Topic Hydrogen Generation, Storage, and Utilization)
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Figure 1

Figure 1
<p>(<b>A</b>) SEM image of PAP-TP-85 AEM and corresponding EDS image of the distribution of F and N in it. (<b>B</b>) SEM image of QP-1/2 AEM and corresponding EDS image of the distribution of F and S in it. (<b>C</b>) The photo of PAP-TP-85 AEM and QP-1/2 AEM.</p>
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<p>(<b>A</b>) The TGA plots of QP-1/x AEMs and PAP-TP-85 AEM. (<b>B</b>) The DTG plots of QP-1/x AEMs and PAP-TP-85 AEM. (<b>C</b>) Water uptake rate of QP-1/x AEMs and PAP-TP-85 AEM under different temperatures. (<b>D</b>) Swelling ratio of QP-1/x AEMs and PAP-TP-85 AEM under different temperatures.</p>
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<p>(<b>A</b>) Mechanical properties of QP-1/x and PAP-TP-85 AEMs (dry membranes). (<b>B</b>) Ionic conductivity plots of OH<sup>−</sup> form QP-1/x and PAP-TP-85 AEMs at different temperatures.</p>
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<p>(<b>A</b>) FT-IR spectra of QP-1/2 AEM after continuous 600 h alkaline resistance test. (<b>B</b>) Residual ionic conductivities of QP-1/x and PAP-TP-85 AEMs after continuous 600 h alkaline resistance test.</p>
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<p>(<b>A</b>–<b>D</b>) SEM and EDS analysis of the QP-1/2-based MEA cross and surface section. (<b>E</b>) Polarization curves for alkaline water electrolysis based on QP-1/2 AEM at 40, 50, 60, 70, and 80 °C and ambient pressure by circulating a 1 M KOH solution in the anode and cathode at a rate of 3 mL min<sup>−1</sup>. (<b>F</b>) Polarization curves and power density curves of four AEMs. Testing conditions: 1000/1000 mL min<sup>−1</sup> A/C flow rate, 80 °C, without backpressure.</p>
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<p>Preparation route for QP-1/x (1/x = 1:1, 1:2, 1:3) AEMs with semi-interpenetrating network.</p>
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19 pages, 7512 KiB  
Article
Improvement of Fault Ride-Through Capability of Grid Connected Wind Turbine Based on a Switched Reluctance Generator Using a Dynamic Voltage Restorer
by Saeed A. AlGhamdi
Sustainability 2023, 15(14), 11061; https://doi.org/10.3390/su151411061 - 14 Jul 2023
Cited by 2 | Viewed by 1292
Abstract
This paper presents an improvement to the fault ride-through (FRT) capabilities for a wind turbine that employs a switched reluctance generator (SRG) using a dynamic voltage restorer (DVR). The wind turbine may be disconnected from the grid by voltage sag, swell, and faulty [...] Read more.
This paper presents an improvement to the fault ride-through (FRT) capabilities for a wind turbine that employs a switched reluctance generator (SRG) using a dynamic voltage restorer (DVR). The wind turbine may be disconnected from the grid by voltage sag, swell, and faulty line voltage in the grid. To improve the stator voltage of an SRG during grid failures, the DVR is applied to inject voltage at the point of common coupling (PCC) into the grid voltage. A control strategy for the DVR based on fuzzy logic controller (FLC) is proposed in this study to improve the FRT capability and meet the grid codes while avoiding the disconnection of the turbine from the grid. MATLAB/SIMULINK simulation validated the effectiveness and performance of this approach under three test cases: balanced sag, unbalanced sag, and a single line-to-ground fault. In addition, the total harmonic distortions utilizing different controllers were compared in sag mode. Furthermore, the simulation results exhibited significant improvement in transient and steady-state response, thus verifying the effectiveness of the control strategy compared to traditional methods. Full article
(This article belongs to the Section Energy Sustainability)
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<p>United States requirements for LVRT (FERC Order No. 661) [<a href="#B3-sustainability-15-11061" class="html-bibr">3</a>].</p>
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<p>Overall cross-sectional view of the 12/8 SRG: (<b>a</b>) Structure of machine and (<b>b</b>) A 3-ph SRG asymmetric half-bridge converter [<a href="#B4-sustainability-15-11061" class="html-bibr">4</a>].</p>
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<p>The performance of the SRG during regular system functioning: the output voltage, current, and power generated by SRG.</p>
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<p>The Wind system block diagram and DVR modules: (<b>a</b>) Wind system block diagram with DVR and (<b>b</b>) DVR modules.</p>
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<p>The DVR compensation scheme based on in-phase compensation.</p>
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<p>Matlab simulation model of the proposed DVR controller.</p>
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<p>Membership functions’ form and fuzzy subsets.</p>
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<p>System simulation model created in MATLAB.</p>
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<p>Results of simulations: Balanced sag voltage (<b>a</b>) voltage at G-bus in (V), (<b>b</b>) compensated voltage at PCC in (V), and (<b>c</b>) injected voltage by DVR in (V).</p>
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<p>The responses of the system under study: (<b>a</b>) Voltage magnitude in p.u. (<b>b</b>) SRG output voltage in V (<b>c</b>) SRG output current in A (<b>d</b>) SRG output power in kW.</p>
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<p>Results of simulations: Unbalanced sag voltage (<b>a</b>) voltage at G-bus in (V), (<b>b</b>) compensated voltage at PCC in (V), and (<b>c</b>) injected voltage by DVR in (V).</p>
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<p>The responses of the system under study: (<b>a</b>) Voltage magnitude in p.u. (<b>b</b>) SRG output voltage in V (<b>c</b>) SRG output current in A (<b>d</b>) SRG output power in kW.</p>
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<p>Results of simulations: 1 LG fault (<b>a</b>) voltage at G-bus in (V), (<b>b</b>) compensated voltage at PCC in (V), and (<b>c</b>) injected voltage by DVR in (V).</p>
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<p>The responses of the system under study: (<b>a</b>) Voltage magnitude in p.u. (<b>b</b>) SRG output voltage in V (<b>c</b>) SRG output current in A (<b>d</b>) SRG output power in kW.</p>
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<p>Voltage and current at the PCC bus using FFT: (<b>a</b>) THDv at VPCC with DVR-PI during sag mode, (<b>b</b>) THDv at VPCC with DVR-FLC during sag mode, (<b>c</b>) THDi with DVR-PI during sag mode, (<b>d</b>) THDi with DVR-FLC during sag mode.</p>
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