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Search Results (4,028)

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Keywords = thermal image

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19 pages, 3200 KiB  
Article
High-Resolution Remotely Sensed Evidence Shows Solar Thermal Power Plant Increases Grassland Growth on the Tibetan Plateau
by Naijing Liu, Huaiwu Peng, Zhenshi Zhang, Yujin Li, Kai Zhang, Yuehan Guo, Yuzheng Cui, Yingsha Jiang, Wenxiang Gao and Donghai Wu
Remote Sens. 2024, 16(22), 4266; https://doi.org/10.3390/rs16224266 (registering DOI) - 15 Nov 2024
Abstract
Solar energy plays a crucial role in mitigating greenhouse gas emissions in the context of global climate change. However, its deployment for green electricity generation can significantly influence regional climate and vegetation dynamics. While prior studies have examined the impacts of solar power [...] Read more.
Solar energy plays a crucial role in mitigating greenhouse gas emissions in the context of global climate change. However, its deployment for green electricity generation can significantly influence regional climate and vegetation dynamics. While prior studies have examined the impacts of solar power plants on vegetation, the accuracy of these assessments has often been constrained by the availability of publicly accessible multispectral, high-resolution remotely sensed imagery. Given the abundant solar energy resources and the ecological significance of the Tibetan Plateau, a thorough evaluation of the vegetation effects associated with solar power installations is warranted. In this study, we utilize sub-meter resolution imagery from the GF-2 satellite to reconstruct the fractional vegetation cover (FVC) at the Gonghe solar thermal power plant through image classification, in situ sampling, and sliding window techniques. We then quantify the plant’s impact on FVC by comparing data from the pre-installation and post-installation periods. Our findings indicate that the Gonghe solar thermal power plant is associated with a 0.02 increase in FVC compared to a surrounding control region (p < 0.05), representing a 12.5% increase relative to the pre-installation period. Notably, the enhancement in FVC is more pronounced in the outer ring areas than near the central tower. The observed enhancement in vegetation growth at the Gonghe plant suggests potential ecological and carbon storage benefits resulting from solar power plant establishment on the Tibetan Plateau. These findings underscore the necessity of evaluating the climate and ecological impacts of renewable energy facilities during the planning and design phases to ensure a harmonious balance between clean energy development and local ecological integrity. Full article
(This article belongs to the Special Issue Remote Sensing of Mountain and Plateau Vegetation)
22 pages, 13669 KiB  
Article
Equivalent Heat Source Model of Thermal Relay Contact Based on Surface Roughness of Silver–Magnesium–Nickel Contact
by Bo Li, Huimin Liang, Pinmou Li, Yuexian Li and Aobo Wang
Materials 2024, 17(22), 5583; https://doi.org/10.3390/ma17225583 - 15 Nov 2024
Viewed by 103
Abstract
In a sealed electromagnetic relay, the change in the surface roughness mainly depends on the collision wear between the contact and the moving reed and the ablation effect of the arc on the contact surface based on the strong correlation between the contact [...] Read more.
In a sealed electromagnetic relay, the change in the surface roughness mainly depends on the collision wear between the contact and the moving reed and the ablation effect of the arc on the contact surface based on the strong correlation between the contact resistance and the surface roughness of the Ag-Mg-Ni contact. With a change in contact resistance, the contact temperature increase in a hermetically sealed electromagnetic relay (HSER) is greatly affected. Under extreme overload conditions, the contact surface is severely ablated by the arc, and the roughness increases rapidly with the number of cycles, which greatly affects the contact resistance of the contact surface and the reliability of the relay. A thermal model of a relay contact system based on the surface roughness of Ag-Mg-Ni contacts was established in this paper by analyzing the effect of an arc on the surface roughness of Ag-Mg-Ni contacts under heavy overload conditions. The arc image of the Ag-Mg-Ni contact was recorded using a double-axis arc photographing platform, and the moving track of the arc center under overload conditions was drawn. This paper explored the patterns of arc center movement on the contact surface and the effects of the arc on the surface roughness of the contacts by analyzing the probabilities of the arc center appearing in various locations. A mathematical model correlating the number of contact cycles with contact resistance was established. Subsequently, a finite element simulation model for the equivalent heat source of the contact was developed. The theoretical model error was less than 10%. The accuracy of the equivalent heat source model was verified by comparing the measured data with the simulation results. Full article
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<p>Flowchart of research in this paper.</p>
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<p>Overload double-axis arc photographing platform.</p>
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<p>Direct view (side) of arc image in positive Y direction of NO contact: (<b>a</b>) is the arc image at frame 0 (arcing point); (<b>b</b>) is the arc image at frame 6 (0.15 ms); (<b>c</b>) is the arc image at frame 12 (0.3 ms); (<b>d</b>) is the arc image at frame 15 (0.38 ms).</p>
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<p>Direct view (front) of arc image in positive X direction of NO contact: (<b>a</b>) is the arc image at frame 0 (arcing point); (<b>b</b>) is the arc image at frame 6 (0.15 ms); (<b>c</b>) is the arc image at frame 12 (0.3 ms); (<b>d</b>) is the arc image at frame 15 (0.38 ms).</p>
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<p>Schematic diagram of coordinate axis direction.</p>
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<p>Arc center scatter of NO contact.</p>
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<p>Arc center trajectory of NO contact.</p>
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<p>Arc ablation region distribution of NO contact.</p>
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<p>Comparison of arc center trajectories of NO contact: (<b>a</b>) is a photograph of the contact morphology; (<b>b</b>) is the comparison between the arc center track and contact.</p>
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<p>Comparison of arc ablation distribution of NO contact: (<b>a</b>) is a photograph of the contact morphology; (<b>b</b>) is the comparison between the arc ablation distribution and contact.</p>
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<p>Arc center trajectory distribution for different numbers of cycles of NO contact: (<b>a</b>) is the arc center trajectory distribution after 20 cycles; (<b>b</b>) is the arc center trajectory distribution after 40 cycles; (<b>c</b>) is the arc center trajectory distribution after 60 cycles; (<b>d</b>) is the arc center trajectory distribution after 80 cycles; and (<b>e</b>) is the arc center trajectory distribution after 100 cycles.</p>
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<p>Arc center trajectory distribution for different numbers of cycles of NO contact: (<b>a</b>) is the arc center trajectory distribution after 20 cycles; (<b>b</b>) is the arc center trajectory distribution after 40 cycles; (<b>c</b>) is the arc center trajectory distribution after 60 cycles; (<b>d</b>) is the arc center trajectory distribution after 80 cycles; and (<b>e</b>) is the arc center trajectory distribution after 100 cycles.</p>
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<p>The occurrence probability of an arc center with NO contact changes for different numbers of cycles.</p>
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<p>Three-dimensional scanning panorama of contact morphology: (<b>a</b>) is the contact morphology of the relay contact without any cycles of operation; (<b>b</b>) is the contact morphology after 100 cycles under 6-times load.</p>
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<p>The complete image of the contact after 100 cycles under 6-times load.</p>
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<p>Surface morphology of the ablation region magnified 10 times: (<b>a</b>) is the surface morphology without cycles; (<b>b</b>) is the surface morphology after 100 cycles under 6-times load.</p>
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<p>Surface roughness scanning of the contact ablation region for 100 cycles of a 6-times load cycle.</p>
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<p>Function of surface roughness variation with the number of cycles under 6-times load.</p>
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<p>Contact resistance for different loads and numbers of cycles.</p>
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<p>CAD model of contact and movable reed: (<b>a</b>) is the CAD model of the contact; (<b>b</b>) is the CAD model of the movable reed.</p>
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<p>Dynamic reed–contact simulation model.</p>
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<p>Dynamic reed–contact meshing model.</p>
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<p>Schematic diagram of the measured point.</p>
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<p>Simulated temperature cloud map: (<b>a</b>) is the temperature cloud map at 0 s (the beginning of the heat transfer); (<b>b</b>) is the temperature cloud map at 0.5 s (during the heat transfer); (<b>c</b>) is the temperature cloud map at 1.0 s (during the heat transfer); (<b>d</b>) is the temperature cloud map at 2.0 s (the end of the heat transfer).</p>
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<p>Temperature curve of the measured point.</p>
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<p>The system structure of the thermal characteristic testing system.</p>
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<p>Temperature curve for 10,000 cycles under rated load (2 A).</p>
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<p>Transient temperature curve for 100 cycles under different loads: (<b>a</b>) is the transient temperature curve under 2-times load (4 A); (<b>b</b>) is the transient temperature curve under 4-times load (8 A); (<b>c</b>) is the transient temperature curve under 6-times load (12 A).</p>
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21 pages, 7459 KiB  
Article
Deep Learning for Urban Tree Canopy Coverage Analysis: A Comparison and Case Study
by Grayson R. Morgan, Danny Zlotnick, Luke North, Cade Smith and Lane Stevenson
Geomatics 2024, 4(4), 412-432; https://doi.org/10.3390/geomatics4040022 - 14 Nov 2024
Viewed by 202
Abstract
Urban tree canopy (UTC) coverage, or area, is an important metric for monitoring changes in UTC over large areas within a municipality. Several methods have been used to obtain these data, but remote sensing image classification is one of the fastest and most [...] Read more.
Urban tree canopy (UTC) coverage, or area, is an important metric for monitoring changes in UTC over large areas within a municipality. Several methods have been used to obtain these data, but remote sensing image classification is one of the fastest and most reliable over large areas. However, most studies have tested only one or two classification methods to accomplish this while using costly satellite imagery or LiDAR data. This study seeks to compare three urban tree canopy cover classifiers by testing a deep learning U-Net convolutional neural network (CNN), support vector machine learning classifier (SVM) and a random forests machine learning classifier (RF) on cost-free 2012 aerial imagery over a small southern USA city and midsize, growing southern USA city. The results of the experiment are then used to decide the best classifier and apply it to more recent aerial imagery to determine canopy changes over a 10-year period. The changes are subsequently compared visually and statistically with recent urban heat maps derived from thermal Landsat 9 satellite data to compare the means of temperatures within areas of UTC loss and no change. The U-Net CNN classifier proved to provide the best overall accuracy for both cities (89.8% and 91.4%), while also requiring the most training and classification time. When compared spatially with city heat maps, city periphery regions were most impacted by substantial changes in UTC area as cities grow and the outer regions get warmer. Furthermore, areas of UTC loss had higher temperatures than those areas with no canopy change. The broader impacts of this study reach the urban forestry managers at the local, state/province, and national levels as they seek to provide data-driven decisions for policy makers. Full article
(This article belongs to the Topic Geocomputation and Artificial Intelligence for Mapping)
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<p>Study areas (<b>A</b>) Georgetown TX and (<b>B</b>) Laurel MS within the United States of America.</p>
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<p>Land surface temperature (LST) maps for Georgetown (<b>A</b>) and Laurel (<b>B</b>) and the quality assessment overlay in pink. The pink colors indicate regions where the uncertainty is higher.</p>
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<p>A general workflow of the experiment and case study.</p>
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<p>Training and validation samples used for classification and accuracy assessment of the 2012 NAIP images (water included for map purpose only).</p>
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<p>Comparison of the original NAIP image (<b>A</b>), the RF classifier results (<b>B</b>), SVM classifier results (<b>C</b>), and the U-Net classifier results (<b>D</b>) for Laurel, MS. Light green represents grass, dark green is urban tree canopy, and yellow is urban and other classes combined.</p>
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<p>Comparison of the original NAIP image (<b>A</b>), the RF classifier results (<b>B</b>), SVM classifier results (<b>C</b>), and the U-Net classifier results (<b>D</b>) for Georgetown, TX. Light green represents grass, dark green is urban tree canopy, and yellow is urban and other classes combined.</p>
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<p>Canopy changes (in blue) overlaid on the heat maps for Georgetown (<b>A</b>) and Laurel (<b>B</b>).</p>
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<p>Laurel Mississippi example of tree canopy loss or change using the 2012 NAIP image (<b>A</b>), 2023 NAIP image (<b>B</b>), heat map (<b>C</b>), and heat map showing detected canopy loss (<b>D</b>).</p>
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<p>Georgetown, TX first example of tree canopy loss or change using the 2012 NAIP image (<b>A</b>), 2023 NAIP image (<b>B</b>), heat map (<b>C</b>), and heat map showing detected canopy loss (<b>D</b>).</p>
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<p>Georgetown, TX second example of tree canopy loss or change using the 2012 NAIP image (<b>A</b>), 2023 NAIP image (<b>B</b>), heat map (<b>C</b>), and heat map showing detected canopy loss (<b>D</b>).</p>
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19 pages, 3906 KiB  
Article
Adaptive Enhancement of Thermal Infrared Images for High-Voltage Cable Buffer Layer Ablation
by Hao Zhan, Jing Zhang, Yuhao Lan, Fan Zhang, Qinqing Huang, Kai Zhou and Chengde Wan
Processes 2024, 12(11), 2543; https://doi.org/10.3390/pr12112543 - 14 Nov 2024
Viewed by 272
Abstract
In recent years, ablation of the buffer layer in high-voltage cables has become a prevalent issue compromising the reliability of power transmission systems. Given the internal location of these faults, direct monitoring and assessment are challenging, resulting in numerous undetected ablation hazards. Previous [...] Read more.
In recent years, ablation of the buffer layer in high-voltage cables has become a prevalent issue compromising the reliability of power transmission systems. Given the internal location of these faults, direct monitoring and assessment are challenging, resulting in numerous undetected ablation hazards. Previous practice has demonstrated that detecting buffer layer ablation through surface temperature distribution changes is feasible, offering a convenient, efficient, and non-destructive approach. However, the variability in heat generation and the subtle temperature differences in thermal infrared images, compounded by noise interference, can impair the accuracy and timeliness of fault detection. To overcome these challenges, this paper introduces an adaptive enhancement method for the thermal infrared imaging of high-voltage cable buffer layer ablation. The method involves an Average Gradient Weighted Guided Filtering (AGWGF) technique to decompose the image into background and detail layers, preventing noise amplification during enhancement. The background layer, containing the primary information, is enhanced using an improved Contrast Limited Adaptive Histogram Equalization (CLAHE) to accentuate temperature differences. The detail layer, rich in high-frequency content, undergoes improved Adaptive Bilateral Filtering (ABF) for noise reduction. The enhanced background and detail layers are then fused and stretched to produce the final enhanced thermal image. To vividly depict temperature variations in the buffer layer, pseudo-color processing is applied to generate color-infrared thermal images. The results indicate that the proposed method’s enhanced images and pseudo-colored infrared thermal images provide a clearer and more intuitive representation of temperature differences compared to the original images, with an average increase of 2.17 in information entropy and 8.38 in average gradient. This enhancement facilitates the detection and assessment of buffer layer ablation faults, enabling the prompt identification of faults. Full article
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<p>High-voltage cable longitudinal cross-sectional view.</p>
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<p>Buffer layer ablation fault cable dissection diagram.</p>
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<p>The images captured by an HIKMICRO infrared thermal imager. From <b>left</b> to <b>right</b>, from <b>top</b> to <b>bottom</b>, they are respectively referred to as Image 1 to Image 9.</p>
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<p>Flow chart of the proposed adaptive thermal infrared image enhancement method.</p>
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<p>Visual quality comparison. The images in the first column are the original and enhanced thermal infrared images, and the corresponding pseudo-colored infrared images are shown in the second column.</p>
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<p>Visual quality comparison. The images in the first column are the original and enhanced thermal infrared images, and the corresponding pseudo-colored infrared images are shown in the second column.</p>
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<p>Visual quality comparison. The images in the first column are the original and enhanced thermal infrared images, and the corresponding pseudo-colored infrared images are shown in the second column.</p>
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<p>Visual quality comparison. The images in the first column are the original and enhanced thermal infrared images, and the corresponding pseudo-colored infrared images are shown in the second column.</p>
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<p>Visual quality comparison. The images in the first column are the original and enhanced thermal infrared images, and the corresponding pseudo-colored infrared images are shown in the second column.</p>
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19 pages, 3389 KiB  
Review
Non-Destructive Evaluation of Physicochemical Properties for Egg Freshness: A Review
by Tae-Gyun Rho and Byoung-Kwan Cho
Agriculture 2024, 14(11), 2049; https://doi.org/10.3390/agriculture14112049 - 14 Nov 2024
Viewed by 222
Abstract
Egg freshness is a critical factor that influences the egg’s nutritional value, safety, and overall quality; consequently, it is a priority for both producers and consumers. This review examines the factors that affect egg freshness, and it evaluates both traditional and modern methods [...] Read more.
Egg freshness is a critical factor that influences the egg’s nutritional value, safety, and overall quality; consequently, it is a priority for both producers and consumers. This review examines the factors that affect egg freshness, and it evaluates both traditional and modern methods for assessing egg freshness. Traditional techniques, such as the Haugh unit test and candling, have long been utilized; however, they have limitations, which are primarily due to their destructive nature. The review also highlights advanced non-destructive methods, including Vis-NIR spectroscopy, ultrasonic testing, machine vision, thermal imaging, hyperspectral imaging, Raman spectroscopy, and NMR/MRI technologies. These techniques offer rapid and accurate assessments while preserving the integrity of the eggs. Despite the current challenges related to calibration and implementation, integrating artificial intelligence (AI) and machine learning with these innovative technologies presents a promising avenue for the improvement of freshness evaluation. This development could revolutionize quality control processes in the egg industry, ensuring consistently high-quality eggs for consumers. Full article
(This article belongs to the Section Agricultural Product Quality and Safety)
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<p>Internal structure of an egg.</p>
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<p>The terms used to define the three degrees of distinctness of yolk shadow outline (in the U.S. Standards of Quality for Shell Eggs) [<a href="#B17-agriculture-14-02049" class="html-bibr">17</a>]. (<b>a</b>) The yolk outline is slightly defined; (<b>b</b>) the yolk outline is fairly well defined; (<b>c</b>) the yolk outline is plainly visible.</p>
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<p>Egg grader demonstrating the use of a Haugh meter by measuring the height of the thick albumen [<a href="#B17-agriculture-14-02049" class="html-bibr">17</a>].</p>
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<p>Changes in the size of air cells taken with a thermal imaging camera (from day 0 to day 21).</p>
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<p>Nuclear magnetic images of eggs on days 0, 7, 14, 21, 28, and 35 of storage. The images were obtained using an MesoMR, conducted with a 0.55 T (23 MHz for protons), 60 mm vertical bore MR system. The egg samples were stored at 25 °C and 50–60% relative humidity with their blunt end up [<a href="#B89-agriculture-14-02049" class="html-bibr">89</a>]. (Reprinted with permission of Elsevier, Amsterdam, Copyright © 2020).</p>
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13 pages, 3187 KiB  
Article
Enhancing Medium-Chain Fatty Acid Delivery Through Bigel Technology
by Manuela Machado, Eduardo M. Costa, Sara Silva, Sérgio C. Sousa, Ana Maria Gomes and Manuela Pintado
Gels 2024, 10(11), 738; https://doi.org/10.3390/gels10110738 - 14 Nov 2024
Viewed by 225
Abstract
This study presents the development and characterization of medium-chain fatty acid (MCFA)-loaded bigels, using coconut oil as the MCFA source. The bigels exhibited high oil binding capacity, ranging from 87% to 98%, effectively retaining MCFAs within the matrix, with lauric acid (C12) being [...] Read more.
This study presents the development and characterization of medium-chain fatty acid (MCFA)-loaded bigels, using coconut oil as the MCFA source. The bigels exhibited high oil binding capacity, ranging from 87% to 98%, effectively retaining MCFAs within the matrix, with lauric acid (C12) being the main component detected within the bigels at 178.32 ± 0.10 mg/g. Physicochemical analysis, including FTIR and scanning electron microscopy, confirmed stable fatty acid incorporation and a cohesive, smooth structure. The FTIR spectra displayed O-H and C=O stretching vibrations, indicating hydrogen bonding within the matrix, while the SEM images showed uniform lipid droplet distribution with stable phase separation. Thermal stability tests showed that the bigels were stable for 5 days at 50 °C, with oil retention and structural integrity unchanged. Rheological testing indicated a solid-like behavior, with a high elastic modulus (G′) that consistently exceeded the viscous modulus (G″), which is indicative of a strong internal structure. In simulated gastrointestinal digestion, the bigels achieved significantly higher MCFA retention than the pure oil, particularly in the gastric phase, with recovery percentages of 38.1% for the bigels and 1.7% for the oil (p < 0.05), suggesting enhanced bioavailability. Cell-based cytotoxicity assays showed low cytotoxicity, and permeability testing in a co-culture Caco-2/HT29-MTX model revealed a controlled, gradual MCFA release, with approximately 10% reaching the basolateral side over 6 h. These findings highlight MCFA-loaded bigels as a promising platform for nutraceutical applications; they provided stability, safety, and controlled MCFA release, with significant potential for functional foods aimed at enhancing fatty acid bioavailability. Full article
(This article belongs to the Section Gel Processing and Engineering)
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Graphical abstract

Graphical abstract
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<p>(<b>A</b>): FTIR spectra of bigels and their components (coconut oil, geleol, CMC, and tween 80). (<b>B</b>): Identification of the major functional groups in oil and bigel FTIR spectra.</p>
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<p>The microstructure of bigels using SEM technology.</p>
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<p>Impact of temperature on bigel’s MCFA amount (<b>A</b>) and oil binding capacity (<b>B</b>) during the 5 days of storage at 50 °C. ns means no significant differences (<span class="html-italic">p</span> &gt; 0.05), * means significant differences (<span class="html-italic">p</span> &lt; 0.05), and *** means significant differences (<span class="html-italic">p</span> &lt; 0.001) and **** means significant differences (<span class="html-italic">p</span> &lt; 0.0001).</p>
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<p>Rheological properties of bigels during thermal stability (T0—day 0, T1—day 1, T2—day 2, T3—day 3, T4—day 5); (<b>A</b>) elastic modulus G′; (<b>B</b>) viscous modulus G″; (<b>C</b>) complex viscosity η*; (<b>D</b>) instantaneous viscosity η′.</p>
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<p>Recovery percentages after gastrointestinal tract: saturated (<b>A</b>), monounsaturated (<b>B</b>), polyunsaturated (<b>C</b>), and medium-chain fatty acids (<b>D</b>). The release profile of MCFAs during gastrointestinal tract (<b>E</b>). * means significant differences at (<span class="html-italic">p</span> &lt; 0.05), ** means significant differences (<span class="html-italic">p</span> &lt; 0.01), *** means significant differences (<span class="html-italic">p</span> &lt; 0.001) and **** means significant differences (<span class="html-italic">p</span> &lt; 0.0001).</p>
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<p>Effect of digested oil and bigel upon Caco-2 and HT29-MTX metabolism. ns means no significant differences (<span class="html-italic">p</span> &gt; 0.05). The dotted line represents the 30% cytotoxicity limit, as defined by the ISO 10993-5 [<a href="#B26-gels-10-00738" class="html-bibr">26</a>].</p>
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<p>(<b>A</b>): Membrane stability as TEER (%) and (<b>B</b>): MCFA permeability over 6 h. ns means no significant differences, * means significant differences (<span class="html-italic">p</span> &lt; 0.05) and *** means significant differences (<span class="html-italic">p</span> &lt; 0.001).</p>
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<p>Schematic representation of bigel production.</p>
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16 pages, 7426 KiB  
Article
Assessment of Tube–Fin Contact Materials in Heat Exchangers: Guidelines for Simulation and Experiments
by László Budulski, Gábor Loch, László Lenkovics, Mihály Baumann, Balázs Cakó, Tamás Zsebe, Zoltán Meiszterics, Gyula Ferenc Vasvári, Boldizsár Kurilla, Tamás Bitó, Géza György Várady and Dávid Csonka
Energies 2024, 17(22), 5681; https://doi.org/10.3390/en17225681 - 13 Nov 2024
Viewed by 444
Abstract
This paper describes experiments on finned tube heat exchangers, focusing on reducing the thermal contact resistance at the contact between the pipe and the lamella. Various contact materials, such as solders and adhesives, were investigated. Several methods of establishing contact were tested, including [...] Read more.
This paper describes experiments on finned tube heat exchangers, focusing on reducing the thermal contact resistance at the contact between the pipe and the lamella. Various contact materials, such as solders and adhesives, were investigated. Several methods of establishing contact were tested, including blowtorch soldering, brazing, and furnace soldering. Thermal camera measurements were carried out to assess the performance of the contact materials. Moreover, finite element analysis was performed to evaluate the contact materials and establish guidelines in the fin–tube connection modeling by comparing simplified models with the realistic model. Blowtorch brazing tests were successful while soldering attempts failed. During the thermographic measurements, reflective surfaces could be measured after applying a thin layer of paint with high emissivity. These measurements did not provide valuable results; thus, the contact materials were assessed using a finite element analysis. The results from the finite element analysis showed that all the inspected contact materials provided better heat transfer than not using a contact material. The heat transfer rate of the tight-fit realistic model was found to be 33.65 for air and 34.9 for the Zn-22Al contact material. This finding could be utilized in developing heat exchangers with higher heat transfer with the same size. Full article
(This article belongs to the Special Issue Heat Transfer in Heat Exchangers)
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<p>(<b>a</b>) Dimensions of the lamellae prepared for testing; (<b>b</b>) The formed lamella fixed with contact material.</p>
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<p>Lamella measurement setup in a Tichelmann system.</p>
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<p>Contact models for FEA.</p>
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<p>Mesh images of the contact regions of the realistic and the 45° loose fit models.</p>
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<p>Thermal imaging of a specimen with reflective surfaces.</p>
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<p>The difference between a matte-painted surface (brighter yellow-orange) and an unpainted reflective surface (blue-violet).</p>
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<p>Surface temperature values of the small and the large samples.</p>
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<p>Thermal images of different measurement samples. (<b>a</b>) Large surface sample; (<b>b</b>) Small surface sample 1 (40 mm × 40 mm); (<b>c</b>) Small surface sample 2 (40 mm × 40 mm).</p>
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<p>Thermal image of the 200 mm × 116 mm lamella and measurement point locations.</p>
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<p>Line histogram with temperature values (Minimum: 31.5 °C, Maximum: 43.7 °C, Mean: 34.8 °C).</p>
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<p>Total heat transfer rate values of the models for each contact material and air in Watts.</p>
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<p>Total heat transfer rate by geometries and contact materials.</p>
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<p>Heat transfer rate as the factor of thermal conductivity of the contact materials.</p>
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13 pages, 8022 KiB  
Article
On the Effect of Randomly Oriented Grain Growth on the Structure of Aluminum Thin Films Deposited via Magnetron Sputtering
by Vagelis Karoutsos, Nikoletta Florini, Nikolaos C. Diamantopoulos, Christina Balourda, George P. Dimitrakopulos, Nikolaos Bouropoulos and Panagiotis Poulopoulos
Coatings 2024, 14(11), 1441; https://doi.org/10.3390/coatings14111441 - 13 Nov 2024
Viewed by 287
Abstract
The microstructure of aluminum thin films, including the grain morphology and surface roughness, are key parameters for improving the thermal or electrical properties and optical reflectance of films. The first step in optimizing these parameters is a thorough understanding of the grain growth [...] Read more.
The microstructure of aluminum thin films, including the grain morphology and surface roughness, are key parameters for improving the thermal or electrical properties and optical reflectance of films. The first step in optimizing these parameters is a thorough understanding of the grain growth mechanisms and film structure. To investigate these issues, thin aluminum films with thicknesses ranging from 25 to 280 nm were coated on SiOx/Si substrates at ambient temperature under high-vacuum conditions and a low argon pressure of 3 × 10−3 mbar (0.3 Pa) using the radio frequency magnetron sputtering method. Quantitative analyses of the surface roughness and nanograin characteristics were conducted using atomic force microscopy (AFM), transmission electron microscopy (TEM), and X-ray diffraction. Changes in specular reflectance were measured using ultraviolet–visible and near-infrared spectroscopy. The low roughness values obtained from the AFM images resulted in high film reflectivity, even for thicker films. TEM and AFM results indicate monomodal, randomly oriented grain growth without a distinct columnar or spherical morphology. Using TEM cross-sectional images and the dependence of the grain size on the film thickness, we propose a grain growth mechanism based on the diffusion mobility of aluminum atoms through grain boundaries. Full article
(This article belongs to the Section Thin Films)
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<p>XRD pattern of the 280 nm thick Al film deposited on SiO<sub>x</sub>/Si.</p>
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<p>(<b>a</b>) Cross-sectional high-angle annular dark-field (HAADF) STEM image of the Al/Si heterostructure. (<b>b</b>) Corresponding layered image of EDS maps. The inset illustrates the interfacial region with the oxygen signal due to the SiO<sub>x</sub> interlayer.</p>
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<p>AFM images of the deposited Al films for the following samples: (<b>a</b>) ALM1, (<b>b</b>) ALM2, (<b>c</b>) ALM3, (<b>d</b>) ALM4, (<b>e</b>) ALM5, and (<b>f</b>) ALM6. All image dimensions are 1 × 1 μm<sup>2</sup>, except for image (<b>a</b>), whose dimensions are 500 × 500 nm<sup>2</sup>.</p>
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<p>Grain size distribution histograms corresponding to each AFM image in <a href="#coatings-14-01441-f003" class="html-fig">Figure 3</a>; d<sub>g</sub> denotes the mean grain size obtained by the Gaussian function fitted to each histogram.</p>
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<p>Measured average RMS roughness for the six film surfaces (<a href="#coatings-14-01441-t002" class="html-table">Table 2</a>) plotted as a function of film thickness.</p>
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<p>Reflectance spectra of two Al thin films with different thicknesses deposited on glass substrate.</p>
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<p>(<b>a</b>) Cross-sectional bright-field TEM image of a region of the Al/Si heterostructure obtained along the [1<math display="inline"><semantics> <mrow> <mover accent="true"> <mrow> <mn>1</mn> </mrow> <mo>¯</mo> </mover> </mrow> </semantics></math>0]Si zone axis of the substrate. SAED patterns obtained from the substrate and the Al film are given as insets. Reflections from diffracting planes are denoted on the SAED patterns. In the case of the Al film, its polycrystalline character yields a ring-type SAED pattern. (<b>b</b>) The 3D AFM surface image of the same film.</p>
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<p>(<b>a</b>) Cross-sectional bright field TEM image showing another region of the Al/Si heterostructure. (<b>b</b>,<b>c</b>) Corresponding dark field TEM images obtained with different reflections of the film, showing diffraction contrast from different crystallites. In (<b>b</b>), the arrows indicate smaller-sized crystallites near the heterointerface.</p>
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<p>(<b>a</b>) HRTEM image along the [1<math display="inline"><semantics> <mrow> <mover accent="true"> <mrow> <mn>1</mn> </mrow> <mo>¯</mo> </mover> </mrow> </semantics></math>0] zone axis of Si, showing in atomic resolution the polycrystalline Al epilayer grown on the Si substrate. Moiré fringes in the Al film are due to the overlap of grains along the projection direction. (<b>b</b>) GPA phase map illustrating the phase changes in the epilayer due to its polycrystalline structure. The inset is the corresponding diffractogram indicating the selected spatial periodicities close to 220 Si that were employed for creating the phase map.</p>
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<p>Measured average grain diameter obtained by distribution histograms of <a href="#coatings-14-01441-f003" class="html-fig">Figure 3</a> plotted as a function of film thickness.</p>
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30 pages, 16269 KiB  
Article
Nanotechnology-Driven Delivery of Caffeine Using Ultradeformable Liposomes-Coated Hollow Mesoporous Silica Nanoparticles for Enhanced Follicular Delivery and Treatment of Androgenetic Alopecia
by Nattanida Thepphankulngarm, Suwisit Manmuan, Namon Hirun and Pakorn Kraisit
Int. J. Mol. Sci. 2024, 25(22), 12170; https://doi.org/10.3390/ijms252212170 - 13 Nov 2024
Viewed by 489
Abstract
Androgenetic alopecia (AGA) is caused by the impact of dihydrotestosterone (DHT) on hair follicles, leading to progressive hair loss in men and women. In this study, we developed caffeine-loaded hollow mesoporous silica nanoparticles coated with ultradeformable liposomes (ULp-Caf@HMSNs) to enhance caffeine delivery to [...] Read more.
Androgenetic alopecia (AGA) is caused by the impact of dihydrotestosterone (DHT) on hair follicles, leading to progressive hair loss in men and women. In this study, we developed caffeine-loaded hollow mesoporous silica nanoparticles coated with ultradeformable liposomes (ULp-Caf@HMSNs) to enhance caffeine delivery to hair follicles. Caffeine, known to inhibit DHT formation, faces challenges in skin penetration due to its hydrophilic nature. We investigated caffeine encapsulated in liposomes, hollow mesoporous silica nanoparticles (HMSNs), and ultradeformable liposome-coated HMSNs to optimize drug delivery and release. For ultradeformable liposomes (ULs), the amount of polysorbate 20 and polysorbate 80 was varied. TEM images confirmed the mesoporous shell and hollow core structure of HMSNs, with a shell thickness of 25–35 nm and a hollow space of 80–100 nm. SEM and TEM analysis showed particle sizes ranging from 140–160 nm. Thermal stability tests showed that HMSNs coated with ULs exhibited a Td10 value of 325 °C and 70% residue ash, indicating good thermal stability. Caffeine release experiments indicated that the highest release occurred in caffeine-loaded HMSNs without a liposome coating. In contrast, systems incorporating ULp-Caf@HMSNs exhibited slower release rates, attributable to the dual encapsulation mechanism. Confocal laser scanning microscopy revealed that ULs-coated particles penetrated deeper into the skin than non-liposome particles. MTT assays confirmed the non-cytotoxicity of all HMSN concentrations to human follicle dermal papilla cells (HFDPCs). ULp-Caf@HMSNs promoted better cell viability than pure caffeine or caffeine-loaded HMSNs, highlighting enhanced biocompatibility without increased toxicity. Additionally, ULp-Caf@HMSNs effectively reduced ROS levels in DHT-damaged HFDPCs, suggesting they are promising alternatives to minoxidil for promoting hair follicle growth and reducing hair loss without increasing oxidative stress. This system shows promise for treating AGA. Full article
(This article belongs to the Special Issue Properties and Applications of Nanoparticles and Nanomaterials)
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<p>Schematic diagram of the formation of Caf@HMSNs, Lp-Caf@HMSNs, and derivatives.</p>
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<p>The FT-IR spectra of HMSNs and LpTW20-HMSNs.</p>
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<p>FE-SEM images of (<b>a</b>,<b>b</b>) HMSNs and (<b>c</b>,<b>d</b>) LpTW20-HMSNs (Insets: distribution of particle size images). TEM images of (<b>e</b>,<b>f</b>) SiO<sub>2</sub>@CTAB-SiO<sub>2</sub> Core/Shell Nanoparticles and (<b>g</b>,<b>h</b>) HMSNs after etching.</p>
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<p>The adsorption–desorption isotherms of HMSNs (lower curve in blue is adsorption, the upper curve in red is desorption; insets show pore size distributions).</p>
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<p>Powder XRD patterns obtained from the HCl/ethanol extraction method for as-synthesized HMSNs and LpTW20-HMSNs (lower curve in red is LpTW20-HMSNs and upper curve in blue is HMSNs).</p>
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<p>TGA analysis of HMSNs and LpTW20-HMSNs.</p>
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<p>The images of (<b>a</b>) TGA analysis and (<b>b</b>) FT-IR spectra of pure Caf, HMSNs, and Caf@HMSNs.</p>
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<p>Release behavior of Caf in PBS (pH = 7.4) at 37.5 °C of LpTW20-Caf@HMSNs, LpTW80-Caf@HMSNs, LpTW2080-Caf@HMSNs, Lp-Caf@HMSNs, Caf@HMSNs, and Caf@LpTW20. Data are expressed as mean and SD (<span class="html-italic">n</span> = 3). * <span class="html-italic">p</span> &lt; 0.05 when compared to Caf@LpTW20 and Caf@HMSNs.</p>
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<p>Cumulative amount per area of Caf from LpTW20-Caf@HMSNs, LpTW80-Caf@HMSNs, LpTW2080-Caf@HMSNs, Lp-Caf@HMSNs, Caf@HMSNs, and Caf@LpTW20 though the porcine skin. Data are expressed as mean and SD (<span class="html-italic">n</span> = 3). * <span class="html-italic">p</span> &lt; 0.01 when compared to Caf@LpTW20.</p>
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<p>The CLSM images illustrate the penetration of porcine skin after treatment with (<b>a</b>) FITC@HMSNs for one hour, (<b>b</b>) LpTW20-FITC@HMSNs for one hour, (<b>c</b>) FITC@HMSNs for six hours, and (<b>d</b>) LpTW20-FITC@HMSNs for six hours. The fluorescence intensity profiles at varying skin depths for (<b>e</b>) Rhodamine B (568 nm) and (<b>f</b>) FITC (488 nm). The cross-sectional CLSM images of (<b>g</b>) hair follicles treated with LpTW20-FITC@HMSNs for six hours, along with the corresponding fluorescence intensity profiles within the hair follicles and the fluorescence intensity profiles across the skin layers for LpTW20-FITC@HMSNs at six hours show (<b>h</b>) red fluorescence from Rhodamine B labeling the particles, (<b>i</b>) green fluorescence from FITC, and (<b>j</b>) a merged image combining (<b>h</b>) and (<b>i</b>) (10× objective lens).</p>
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<p>The effect of various Caf concentrations and formulations on HFDPCs viability. Data are expressed as mean and SD (<span class="html-italic">n</span> = 3). * <span class="html-italic">p</span> &lt; 0.01 when compared to HMSNs.</p>
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<p>The images of cell morphology and aggregation behavior of HFDPCs treated with Caf at concentrations of (<b>a</b>) 0.0125 mg mL<sup>−1</sup> and (<b>b</b>) 0.0250 mg mL<sup>−1</sup> for various time intervals (0–72 h).</p>
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<p>The effects of MNX, 0.0125, and 0.025 mg mL<sup>−1</sup> concentrations of pure Caf, HMSNs, Caf@HMSNs, and LpTW20-Caf@HMSNs on ROS levels in DHT-damaged HFDPCs were assessed. Fluorescence microscopy was used to capture DCF-DA images, where the intensity of green fluorescence correlates with ROS concentration.</p>
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14 pages, 2909 KiB  
Article
Laser-Induced Decomposition and Mechanical Degradation of Carbon Fiber-Reinforced Polymer Subjected to a High-Energy Laser with Continuous Wave Power up to 120 kW
by Sebastian Schäffer, Stefan Reich, Dominic Heunoske, Martin Lueck, Johannes Wolfrum and Jens Osterholz
J. Compos. Sci. 2024, 8(11), 471; https://doi.org/10.3390/jcs8110471 - 13 Nov 2024
Viewed by 309
Abstract
Carbon fiber-reinforced polymer (CFRP), noted for its outstanding properties including high specific strength and superior fatigue resistance, is increasingly employed in aerospace and other demanding applications. This study investigates the interactions between CFRP composites and high-energy lasers (HEL), with continuous wave laser powers [...] Read more.
Carbon fiber-reinforced polymer (CFRP), noted for its outstanding properties including high specific strength and superior fatigue resistance, is increasingly employed in aerospace and other demanding applications. This study investigates the interactions between CFRP composites and high-energy lasers (HEL), with continuous wave laser powers reaching up to 120 kW. A novel automated sample exchange system, operated by a robotic arm, minimizes human exposure while enabling a sequence of targeted laser tests. High-speed imaging captures the rapid expansion of a plume consisting of hot gases and dust particles during the experiment. The research significantly advances empirical models by systematically examining the relationship between laser power, perforation times, and ablation rates. It demonstrates scalable predictions for the effects of high-energy laser radiation. A detailed examination of the damaged samples, both visually and via micro-focused computed X-ray tomography, offers insights into heat distribution and ablation dynamics, highlighting the anisotropic thermal properties of CFRP. Compression after impact (CAI) tests further assess the residual strength of the irradiated samples, enhancing the understanding of CFRP’s structural integrity post-irradiation. Collectively, these tests improve the knowledge of the thermal and mechanical behavior of CFRP under extreme irradiation conditions. The findings not only contribute to predictive modeling of CFRP’s response to laser irradiation but enhance the scalability of these models to higher laser powers, providing robust tools for predicting material behavior in high-performance settings. Full article
(This article belongs to the Special Issue Carbon Fiber Composites, Volume III)
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<p>Experimental setup includes an automated sample exchange, operated by a robotic arm.</p>
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<p>A gas cloud expands rapidly caused by laser irradiation of a CFRP plate with 120 kW and a beam size of 20 mm. The plate is perforated after 0.4 s.</p>
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<p>Damage zones of irradiated CFRP samples of two tested materials (P = 120 kW, Ø = 20 mm, d = 4 mm). The heat affected zone (HAZ) extends to areas outside the applied laser spot.</p>
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<p>Perforation times as a function of laser power in a double-logarithmic representation for a beam diameter of 20 mm and different sample thicknesses d. In this diagram, a linear decrease of the logarithm of the perforation time with increase of the logarithm of the laser power can be observed, represented by the solid and dashed lines.</p>
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<p>Volume damage as a function of perforation time in a double-logarithmic representation for various laser powers.</p>
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<p>Volume removal rate as a function of laser power. Symbols: <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>r</mi> </mrow> <mrow> <mi>v</mi> <mi>o</mi> <mi>l</mi> </mrow> </msub> </mrow> </semantics></math> determined from experimental data and Equation (4). Lines: linear fit.</p>
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<p>µCT-scan cross-sections of irradiated CFRP samples reveal details of the heat affected zone and the delamination of fibers. The holes created have a conical shape (M18-1/G939, d = 6 mm).</p>
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<p>Residual compressive strength of laser irradiated CFRP samples determined in accordance with the compression after impact procedure.</p>
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12 pages, 3620 KiB  
Article
Multifunctional Near-Infrared Luminescence Performance of Nd3+ Doped SrSnO3 Phosphor
by Dejian Hou, Jin-Yan Li, Rui Huang, Wenxing Zhang, Yi Zhang, Zhenxu Lin, Hongliang Li, Jianhong Dong, Huihong Lin and Lei Zhou
Photonics 2024, 11(11), 1060; https://doi.org/10.3390/photonics11111060 - 12 Nov 2024
Viewed by 420
Abstract
The phosphors with persistent luminescence in the NIR (near-infrared) region and the NIR-to-NIR Stokes luminescence properties have received considerable attention owing to their inclusive application prospects in the in vivo imaging field. In this paper, Nd3+ doped SrSnO3 phosphors with remarkable [...] Read more.
The phosphors with persistent luminescence in the NIR (near-infrared) region and the NIR-to-NIR Stokes luminescence properties have received considerable attention owing to their inclusive application prospects in the in vivo imaging field. In this paper, Nd3+ doped SrSnO3 phosphors with remarkable NIR emission performance were prepared using a high temperature solid state reaction method; the phase structure, morphology, and luminescence properties were discussed systematically. The SrSnO3 host exhibits broadband NIR emission (800–1300 nm) with absorptions in the near ultraviolet region. Nd3+ ions emerge excellent NIR-to-NIR Stokes luminescence under 808 nm laser excitation, with maximum emission at around ~1068 nm. The concentration-dependent luminescence properties, temperature dependent emission, and the luminescence decay curves of Nd3+ in the SrSnO3 host were also studied. The Nd3+ doped SrSnO3 phosphors exhibit exceptional thermal stability; the integrated emission intensity can retain approximately 66% at 423 K compared to room temperature. Most importantly, NIR persistent luminescence also can be observed for the SrSnO3:Nd3+ samples, which is in the first and second biological windows. A possible mechanism was proposed for the persistent NIR luminescence of Nd3+ based on the thermo-luminescence spectra. Consequently, the exciting results indicate that multifunctional NIR luminescence has been successfully realized in the SrSnO3:Nd3+ phosphors. Full article
(This article belongs to the Section Biophotonics and Biomedical Optics)
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<p>(<b>a</b>) Rietveld refinement of the undoped SrSnO<sub>3</sub> host lattice at room temperature. (<b>b</b>) XRD patterns of Nd<sup>3+</sup> doped SrSnO<sub>3</sub> phosphors Sr<sub>1−x</sub>Nd<sub>x</sub>SnO<sub>3</sub>.</p>
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<p>(<b>a</b>) SEM image of the SrSnO<sub>3</sub> host sample. (<b>b</b>) SEM image and the corresponding EDS mapping results of the SrSnO<sub>3</sub> host sample.</p>
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<p>(<b>a</b>) Diffuse reflection spectra of the SrSnO<sub>3</sub> and Sr<sub>0.99</sub>Nd<sub>0.01</sub>SnO<sub>3</sub> samples. Inset is a plot of [<span class="html-italic">hv</span>ln{(R<sub>max</sub>−R<sub>min</sub>)/(R−R<sub>min</sub>)}]<sup>2</sup> against energy (eV) for the SrSnO<sub>3</sub> sample, where R is reflectance. (<b>b</b>) Excitation and emission spectra of the SrSnO<sub>3</sub> host lattice.</p>
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<p>(<b>a</b>) Luminescence excitation and emission spectra of Sr<sub>0.99</sub>Nd<sub>0.01</sub>SnO<sub>3</sub> at room temperature. (<b>b</b>) Emission spectra of Sr<sub>1−x</sub>Nd<sub>x</sub>SnO<sub>3</sub> under 312 nm ultraviolet light excitation. (<b>c</b>) Emission spectra of Sr<sub>1−x</sub>Nd<sub>x</sub>SnO<sub>3</sub> upon 808 nm laser excitation; inset is the integrated emission intensity dependent on Nd<sup>3+</sup> doping concentration (x value). (<b>d</b>) Luminescence decay curves of Sr<sub>1−x</sub>Nd<sub>x</sub>SnO<sub>3</sub> at room temperature (λ<sub>ex</sub> = 582 nm, λ<sub>em</sub> = 1068 nm).</p>
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<p>(<b>a</b>) Emission spectra of the Sr<sub>0.99</sub>Nd<sub>0.01</sub>SnO<sub>3</sub> sample in the 298–523 K temperature range; the excitation wavelength is 582 nm. (<b>b</b>) Integrated emission intensity depending on temperature; the curve was normalized by the value at 298 K. (<b>c</b>) The relationships between ln[(I<sub>0</sub>/I) − 1] and 1/(<span class="html-italic">k</span>T). (<b>d</b>) Luminescence decay curves of Sr<sub>0.99</sub>Nd<sub>0.01</sub>SnO<sub>3</sub> at different temperatures (λ<sub>ex</sub> = 582 nm, λ<sub>em</sub> = 1068 nm).</p>
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<p>(<b>a</b>) Persistent luminescence spectra of the SrSnO<sub>3</sub> and Sr<sub>0.99</sub>Nd<sub>0.01</sub>SnO<sub>3</sub> samples. (<b>b</b>) Persistent luminescence decay curves of the Sr<sub>0.99</sub>Nd<sub>0.01</sub>SnO<sub>3</sub> sample, the curves were obtained by monitoring the emission wavelength at 970 nm and 1068 nm, respectively. Before measurements, the phosphor was first pre-irradiated by 287 nm ultraviolet light for 5 min. (<b>c</b>) TL curves of the Sr<sub>0.99</sub>Nd<sub>0.01</sub>SnO<sub>3</sub> sample. Before measurements, the phosphor was first pre-irradiated by 287 nm ultraviolet light for 5 min. (<b>d</b>) The persistent luminescence mechanism of Nd<sup>3+</sup> in the host.</p>
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11 pages, 4564 KiB  
Article
Managing Residual Heat Effects in Femtosecond Laser Material Processing by Pulse-on-Demand Operation
by Jaka Petelin, Matevž Marš, Jaka Mur and Rok Petkovšek
J. Manuf. Mater. Process. 2024, 8(6), 254; https://doi.org/10.3390/jmmp8060254 - 12 Nov 2024
Viewed by 495
Abstract
Femtosecond laser processing combines highly accurate structuring with low residual heating of materials, low thermal damage, and nonlinear absorption processes, making it suitable for the machining of transparent brittle materials. However, with high average powers and laser pulse repetition rates, residual heating becomes [...] Read more.
Femtosecond laser processing combines highly accurate structuring with low residual heating of materials, low thermal damage, and nonlinear absorption processes, making it suitable for the machining of transparent brittle materials. However, with high average powers and laser pulse repetition rates, residual heating becomes relevant. Here, we present a study of the femtosecond laser pulse-on-demand operation regime, combined with regular scanners, aiming to improve throughput and quality of processing regardless of the scanner’s capabilities. We developed two methods to define the needed pulse-on-demand trigger sequences that compensate for the initial accelerating scanner movements. The effects of pulse-on-demand operation were studied in detail using direct process monitoring with a fast thermal camera and indirect process monitoring with optical and topographical surface imaging of final structures, both showing clear advantages of pulse-on-demand operation in precision, thermal effects, and structure shape control. The ability to compensate for irregular scanner movement is the basis for simplified, cheaper, and faster femtosecond laser processing of brittle and heat-susceptible materials. Full article
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<p>(<b>a</b>) Experimental setup schematic. (<b>b</b>) An example PoD sequence of pulses.</p>
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<p>(<b>a</b>) Chosen frames from a high-speed camera sequence and respective recognized crater positions. (<b>b</b>) Graph of reconstructed crater positions and the final PoD sequence for 4 m/s target scanner speeds and laser frequency 100 kHz. (<b>c</b>) Graph showing PoD sequence position deviation from target position. (<b>d</b>) Microscope picture of PoD sequence presented in (<b>b</b>). Both scalebars in (<b>a</b>,<b>d</b>) represent 200 µm.</p>
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<p>Crater distributions using (<b>a</b>) 20 kHz, (<b>b</b>) 30 kHz, and (<b>c</b>) 50 kHz repetition rates at 4 m/s target scanning speed. (<b>d</b>) PoD sequence craters at 100 kHz laser repetition rate and 4 m/s target scanner speed, as calculated from microscope-based method and applied for processing. (<b>e</b>) Graph of reconstructed positions from (<b>a</b>–<b>c</b>) and the fit for calculating PoD sequence. All scalebars in (<b>a</b>–<b>d</b>) represent 200 µm.</p>
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<p>Fast IR camera showing temperature evolution on steel with (<b>a</b>) regular processing and (<b>b</b>) PoD processing. (<b>c</b>) Comparison graph for the hotspot temperature (moving position) using regular fixed frequency processing (blue) vs. PoD (orange). All scalebars (line below timestamp) in (<b>a</b>,<b>b</b>) represent 200 µm.</p>
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<p>Fast IR camera showing temperature evolution on glass with (<b>a</b>) regular processing and (<b>b</b>) PoD processing. (<b>c</b>) Comparison graph for the hotspot temperature (moving position) using regular fixed frequency processing (blue) vs. PoD (orange). All scalebars (line below timestamp) in (<b>a</b>,<b>b</b>) represent 200 µm.</p>
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<p>Wide channels in glass processed using (<b>a</b>) regular processing and (<b>b</b>) PoD processing, both showing horizontal and vertical cross-section topography measurements.</p>
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<p>Wide channels in stainless steel processed using (<b>a</b>) regular processing and (<b>b</b>) PoD processing, both showing horizontal and vertical cross-section topography measurements.</p>
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34 pages, 4136 KiB  
Review
Synthesis, Functionalization, and Biomedical Applications of Iron Oxide Nanoparticles (IONPs)
by Mostafa Salehirozveh, Parisa Dehghani and Ivan Mijakovic
J. Funct. Biomater. 2024, 15(11), 340; https://doi.org/10.3390/jfb15110340 - 12 Nov 2024
Viewed by 499
Abstract
Iron oxide nanoparticles (IONPs) have garnered significant attention in biomedical applications due to their unique magnetic properties, biocompatibility, and versatility. This review comprehensively examines the synthesis methods, surface functionalization techniques, and diverse biomedical applications of IONPs. Various chemical and physical synthesis techniques, including [...] Read more.
Iron oxide nanoparticles (IONPs) have garnered significant attention in biomedical applications due to their unique magnetic properties, biocompatibility, and versatility. This review comprehensively examines the synthesis methods, surface functionalization techniques, and diverse biomedical applications of IONPs. Various chemical and physical synthesis techniques, including coprecipitation, sol–gel processes, thermal decomposition, hydrothermal synthesis, and sonochemical routes, are discussed in detail, highlighting their advantages and limitations. Surface functionalization strategies, such as ligand exchange, encapsulation, and silanization, are explored to enhance the biocompatibility and functionality of IONPs. Special emphasis is placed on the role of IONPs in biosensing technologies, where their magnetic and optical properties enable significant advancements, including in surface-enhanced Raman scattering (SERS)-based biosensors, fluorescence biosensors, and field-effect transistor (FET) biosensors. The review explores how IONPs enhance sensitivity and selectivity in detecting biomolecules, demonstrating their potential for point-of-care diagnostics. Additionally, biomedical applications such as magnetic resonance imaging (MRI), targeted drug delivery, tissue engineering, and stem cell tracking are discussed. The challenges and future perspectives in the clinical translation of IONPs are also addressed, emphasizing the need for further research to optimize their properties and ensure safety and efficacy in medical applications. This review aims to provide a comprehensive understanding of the current state and future potential of IONPs in both biosensing and broader biomedical fields. Full article
(This article belongs to the Section Biomaterials and Devices for Healthcare Applications)
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<p>The crystal structure of (<b>a</b>) magnetite and (<b>b</b>) maghemite, where Fe<sup>2+</sup> ions are represented by black spheres, Fe<sup>3+</sup> ions by green spheres, and O<sup>2−</sup> ions by red spheres. Reprinted from reference [<a href="#B2-jfb-15-00340" class="html-bibr">2</a>].</p>
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<p>An overview diagram of this paper including the synthesis, functionalization, and biomedical applications of iron oxide nanoparticles (IONPs).</p>
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<p>A schematic illustration of the synthesis of IONPs. (<b>a</b>) The synthesis of iron oxide nanoparticles via the sol–gel method: iron nitrate and citric acid are mixed, forming an iron oxide gel, followed by drying, annealing, and grinding to obtain α-Fe<sub>2</sub>O<sub>3</sub> nanoparticles. (<b>b</b>) The synthesis of iron oxide nanoparticles via the green chemistry method: ferrous sulfate is combined with plant extract and sodium hydroxide, centrifuged, and oven-dried to produce a brownish-black powder for storage [<a href="#B29-jfb-15-00340" class="html-bibr">29</a>,<a href="#B30-jfb-15-00340" class="html-bibr">30</a>].</p>
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<p>Schematic illustration of IONPs synthesis via coprecipitation technique. Reprinted from reference [<a href="#B49-jfb-15-00340" class="html-bibr">49</a>].</p>
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<p>Schematic illustration of IONPs synthesis via sol–gel technique.</p>
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<p>Schematic illustration of IONPs synthesis via thermal breakdown technique. Reprinted from reference [<a href="#B49-jfb-15-00340" class="html-bibr">49</a>].</p>
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<p>Schematic illustration of IONPs synthesis via microemulsion technique.</p>
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<p>Multiple surface functionalizations of magnetic IONPs.</p>
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<p>The timeline of magnetic nanoparticles in therapeutic and imaging applications. Reprinted from reference [<a href="#B212-jfb-15-00340" class="html-bibr">212</a>].</p>
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29 pages, 61165 KiB  
Article
LiDAR-360 RGB Camera-360 Thermal Camera Targetless Calibration for Dynamic Situations
by Khanh Bao Tran, Alexander Carballo and Kazuya Takeda
Sensors 2024, 24(22), 7199; https://doi.org/10.3390/s24227199 - 10 Nov 2024
Viewed by 571
Abstract
Integrating multiple types of sensors into autonomous systems, such as cars and robots, has become a widely adopted approach in modern technology. Among these sensors, RGB cameras, thermal cameras, and LiDAR are particularly valued for their ability to provide comprehensive environmental data. However, [...] Read more.
Integrating multiple types of sensors into autonomous systems, such as cars and robots, has become a widely adopted approach in modern technology. Among these sensors, RGB cameras, thermal cameras, and LiDAR are particularly valued for their ability to provide comprehensive environmental data. However, despite their advantages, current research primarily focuses on the one or combination of two sensors at a time. The full potential of utilizing all three sensors is often neglected. One key challenge is the ego-motion compensation of data in dynamic situations, which results from the rotational nature of the LiDAR sensor, and the blind spots of standard cameras due to their limited field of view. To resolve this problem, this paper proposes a novel method for the simultaneous registration of LiDAR, panoramic RGB cameras, and panoramic thermal cameras in dynamic environments without the need for calibration targets. Initially, essential features from RGB images, thermal data, and LiDAR point clouds are extracted through a novel method, designed to capture significant raw data characteristics. These extracted features then serve as a foundation for ego-motion compensation, optimizing the initial dataset. Subsequently, the raw features can be further refined to enhance calibration accuracy, achieving more precise alignment results. The results of the paper demonstrate the effectiveness of this approach in enhancing multiple sensor calibration compared to other ways. In the case of a high speed of around 9 m/s, some situations can improve the accuracy about 30 percent higher for LiDAR and Camera calibration. The proposed method has the potential to significantly improve the reliability and accuracy of autonomous systems in real-world scenarios, particularly under challenging environmental conditions. Full article
(This article belongs to the Section Radar Sensors)
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<p>Visualization of the system including RGB cameras, thermal cameras, and LiDAR. 360 RGB camera and 360 thermal camera are made from independent cameras to remove blind spots. Images and point clouds are compensated to decrease negative impacts of motion. Then, point clouds and images are used for sensor calibration based on extracted features.</p>
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<p>Visualization of the target detected by two types of cameras. The (<b>left image</b>) is the target detected by the RGB camera and the (<b>right image</b>) is the target detected by the thermal camera.</p>
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<p>Our system includes sensors: LiDAR Velodyne Alpha Prime, LadyBug-5 camera, 6 FLIR ADK cameras, LiDAR Ouster-128, LiDAR Ouster-64 and LiDAR Hesai Pandar.</p>
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<p>Visualization of stitching 360 thermal images and 360 RGB images.</p>
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<p>Pipeline of the registration process. The approach is divided into two parts, one part focuses on detecting key points from RGB images and thermal images, while the other part detects key points from images converted from LiDAR point clouds. For images generated from LiDAR point clouds, a velocity estimation step is required to perform distortion correction, ensuring the accurate positioning of the scanned points. After getting results from distortion correction, external parameters of LiDAR, 360 RGB camera and 360 thermal camera can be calibrated.</p>
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<p>Visualization of features extracted from RGB images.</p>
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<p>Pipeline of our approach. The first step is enhancing images by Retinex Decomposition. The second step is to extract key features from <math display="inline"><semantics> <mrow> <mi>n</mi> <mo>+</mo> <mn>1</mn> </mrow> </semantics></math> consecutive images. The third step is using MobileNetV3 to remove noise features on moving objects.</p>
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<p>The (<b>above image</b>) shows results before being enhanced by Retinex Decomposition. The (<b>below image</b>) shows results after being enhanced by Retinex Decomposition.</p>
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<p>The (<b>above image</b>) including the red rectangles shows reliable features extracted from <math display="inline"><semantics> <mrow> <mi>n</mi> <mo>+</mo> <mn>1</mn> </mrow> </semantics></math> consecutive RGB images. The (<b>below image</b>) including the green rectangles shows reliable features after filtering by MobileNetV3.</p>
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<p>Visualization of features extracted from thermal images.</p>
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<p>Visualization of image projection. (<b>a</b>) shows the 3D point cloud data from the LiDAR. (<b>b</b>) presents the 2D image data with the intensity channel. (<b>c</b>) presents the 2D image data with the range channel. The height of the image is 128, corresponding to the number of channels in the LiDAR.</p>
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<p>Visualization of key points extracted from LiDAR images. (<b>a</b>) simulates key points across two frames, while (<b>b</b>) simulates selecting key points with similarity across the two frames.</p>
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<p>Pipeline of our approach. Key features of projected images are extracted by Superpoint enhanced by LSTM. These features are matched to find pair points in two consecutive frames.</p>
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<p>Pipeline of the ego-motion compensation process. First, the point clouds are converted into two-dimensional images using Spherical Projection. Key features are then identified within these range images, and corresponding point pairs are matched. By matching key feature pairs, the distance between frames can be determined, allowing for velocity estimation. Finally, velocity and timestamp will be used to resolve ego-motion compensation and point cloud accumulation.</p>
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<p>Visualization of distortion correction. The motion of the vehicle is presented by the circles, and the LiDAR is also sotating while the vehicle is in motion. (<b>a</b>) shows the actual shape of the obstacle. (<b>b</b>) depicts the shape of the obstacle scanned by LiDAR. (<b>c</b>) illustrates the shape of the obstacle after distortion correction.</p>
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<p>Visualization of the differences in distortion correction on 3D point clouds within a frame with a speed of 54 km/h and a frequency of 10 Hz. The red part shows the original points of the point clouds, while the green part shows the corrected points. The left image shows points on the <math display="inline"><semantics> <mrow> <mi>x</mi> <mi>y</mi> </mrow> </semantics></math>-plane. The right image shows points on the <math display="inline"><semantics> <mrow> <mi>y</mi> <mi>z</mi> </mrow> </semantics></math>-plane.</p>
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<p>Visualization of distortion correction of cameras. The blue rectangle is the actual shape, and the red rectangle is the shape distorted by ego-motion.</p>
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<p>Visualization of 360 RGB–LiDAR images calibration. The (<b>above image</b>) including the red rectangles indicate the calibration results before applying correction. The (<b>below image</b>) including the green rectangles indicates the calibration results after applying correction.</p>
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<p>Visualization of 360 RGB–thermal images calibration. The (<b>above image</b>) includes red rectangles that indicate the calibration results before applying correction. The (<b>below image</b>) includes green rectangles that indicate the calibration results after applying correction.</p>
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<p>Visualization of point clouds extracted from Ouster OS1-128 and Velodyne Alpha prime.</p>
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<p>Visualization of image projection. (<b>a</b>) presents the 2D image data with the intensity channel from Ouster OS1-128. (<b>b</b>) presents the 2D image data with the range channel from Ouster OS1-128. (<b>c</b>) presents the 2D image data with the intensity channel from Velodyne Alpha prime. (<b>d</b>) presents the 2D image data with the range channel from Velodyne Alpha prime.</p>
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<p>Visualization of velocity comparison between estimated velocity and ground truth over a continuous duration of 720 s. The intervals between approximately 100 to 200 s and 400 to 500 s corresponded to periods when the vehicle was turning. Conversely, the intervals from 0 to approximately 100 s, 200 to 400 s, and 500 to 600 s represented phases when the vehicle was moving straight. The vehicle decelerated and came to a halt between 600 and 720 s. The maximum observed velocity difference was 0.36 m/s, while the average velocity difference over the 720 s period was 0.03 m/s, as in <a href="#sensors-24-07199-t001" class="html-table">Table 1</a>.</p>
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<p>Comparison with CNN, RIFT, RI-MFM by MAE.</p>
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<p>Comparison with CNN, RIFT, RI-MFM by Accuracy.</p>
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<p>Comparison with CNN, RIFT, RI-MFM by RMSE.</p>
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<p>Red points represent the results of calibration without distortion correction, while blue points represent the results with distortion correction in static situations. The dashed line is the results from the target based method.</p>
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<p>Red points and blue points represent the results of calibration without and with distortion correction in dynamic situations. The dashed lines present the results using the actual data.</p>
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<p>Comparison of error in rotation and translation of three methods.</p>
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17 pages, 5439 KiB  
Article
Chemical and Thermal Changes in Mg3Si2O5 (OH)4 Polymorph Minerals and Importance as an Industrial Material
by Ahmet Şaşmaz, Ayşe Didem Kılıç and Nevin Konakçı
Appl. Sci. 2024, 14(22), 10298; https://doi.org/10.3390/app142210298 - 8 Nov 2024
Viewed by 564
Abstract
Serpentine (Mg3Si2O5(OH)4), like quartz, dolomite and magnesite minerals, is a versatile mineral group characterized by silica and magnesium silicate contents with multiple polymorphic phases. Among the phases composed of antigorite, lizardite, and chrysotile, lizardite and [...] Read more.
Serpentine (Mg3Si2O5(OH)4), like quartz, dolomite and magnesite minerals, is a versatile mineral group characterized by silica and magnesium silicate contents with multiple polymorphic phases. Among the phases composed of antigorite, lizardite, and chrysotile, lizardite and chrysotile are the most prevalent phases in the serpentinites studied here. The formation process of serpentinites, which arise from the hydrothermal alteration of peridotites, influences the ratio of light rare earth elements (LREE) to heavy rare earth elements (HREE). In serpentinites, the ratio of light rare earth elements (LREE)/heavy rare earth elements (HREE) provides insights into formation conditions, geochemical evolution, and magmatic processes. The depletion of REE compositions in serpentinites indicates high melting extraction for fore-arc/mantle wedge serpentinites. The studied serpentinites show a depletion in REE concentrations compared to chondrite values, with HREE exhibiting a lesser degree of depletion compared to LREE. The high ΣLREE/ΣHREE ratios of the samples are between 0.16 and 4 ppm. While Ce shows a strong negative anomaly (0.1–12), Eu shows a weak positive anomaly (0.1–0.3). This indicates that fluid interacts significantly with rock during serpentinization, and highly incompatible elements (HIEs) gradually become involved in the serpentinization process. While high REE concentrations indicate mantle wedge serpentinites, REE levels are lower in mid-ocean ridge serpentinites. The enrichment of LREE in the analyzed samples reflects melt/rock interaction with depleted mantle and is consistent with rock–water interaction during serpentinization. The gradual increase in highly incompatible elements (HIEs) suggests that they result from fluid integration into the system and a subduction process. The large differential thermal analysis (DTA) peak at 810–830 °C is an important sign of dehydration, transformation reactions and thermal decomposition, and is compatible with H2O phyllosilicates in the mineral structure losing water at this temperature. In SEM images, chrysotile, which has a fibrous structure, and lizardite, which has a flat appearance, transform into talc as a result of dehydration with increasing temperature. Therefore, the sudden temperature drop observed in DTA graphs is an indicator of crystal form transformation and CO2 loss. In this study, the mineralogical and structural properties and the formation of serpentinites were examined for the first time using thermo-gravimetric analysis methods. In addition, the mineralogical and physical properties of serpentinites can be recommended for industrial use as additives in polymers or in the adsorption of organic pollutants. As a result, the high refractory nature of examined serpentine suggests that it is well-suited for applications involving high temperatures. This includes industries such as metallurgy and steel production, glass manufacturing, ceramic production, and the chemical industry. Full article
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<p>(<b>A</b>) Distribution of ophiolites (green color) in the study area and its surroundings [<a href="#B2-applsci-14-10298" class="html-bibr">2</a>]. (<b>B</b>) Simplified geological map [<a href="#B1-applsci-14-10298" class="html-bibr">1</a>].</p>
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<p>Serpentinite samples with mesh (<b>A</b>,<b>B</b>) and bastite (<b>C</b>,<b>D</b>).</p>
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<p>Optical microscope (OM) view of thin sections taken from serpentinites. Olivine (Ol) and orthopyroxene (opx) minerals surrounded by lizardite (<b>A</b>) and chrysotile (<b>B</b>).</p>
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<p>Chondrite (<b>a</b>) and primitive mantle spider (<b>b</b>) diagrams of serpentinites [<a href="#B41-applsci-14-10298" class="html-bibr">41</a>].</p>
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<p>Discriminating diagrams of serpentine minerals.</p>
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<p>The DTA and TGA thermograms of the serpentinite samples: (<b>a</b>) Sample 2, (<b>b</b>) Sample 5, (<b>c</b>) Sample 6.</p>
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<p>SEM images of the serpentinite samples. (<b>a</b>) Sample 2, (<b>b</b>) Sample 5, (<b>c</b>) Sample 6.</p>
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<p>Whole-rock X-Ray diffraction (XRD) spectra of selected samples.</p>
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