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Search Results (13,394)

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13 pages, 2999 KiB  
Article
Generative AI-Driven Data Augmentation for Crack Detection in Physical Structures
by Jinwook Kim, Joonho Seon, Soohyun Kim, Youngghyu Sun, Seongwoo Lee, Jeongho Kim, Byungsun Hwang and Jinyoung Kim
Electronics 2024, 13(19), 3905; https://doi.org/10.3390/electronics13193905 (registering DOI) - 2 Oct 2024
Abstract
The accurate segmentation of cracks in structural materials is crucial for assessing the safety and durability of infrastructure. Although conventional segmentation models based on deep learning techniques have shown impressive detection capabilities in these tasks, their performance can be restricted by small amounts [...] Read more.
The accurate segmentation of cracks in structural materials is crucial for assessing the safety and durability of infrastructure. Although conventional segmentation models based on deep learning techniques have shown impressive detection capabilities in these tasks, their performance can be restricted by small amounts of training data. Data augmentation techniques have been proposed to mitigate the data availability issue; however, these systems often have limitations in texture diversity, scalability over multiple physical structures, and the need for manual annotation. In this paper, a novel generative artificial intelligence (GAI)-driven data augmentation framework is proposed to overcome these limitations by integrating a projected generative adversarial network (ProjectedGAN) and a multi-crack texture transfer generative adversarial network (MCT2GAN). Additionally, a novel metric is proposed to evaluate the quality of the generated data. The proposed method is evaluated using three datasets: the bridge crack library (BCL), DeepCrack, and Volker. From the simulation results, it is confirmed that the segmentation performance can be improved by the proposed method in terms of intersection over union (IoU) and Dice scores across three datasets. Full article
(This article belongs to the Special Issue Generative AI and Its Transformative Potential)
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<p>Process of generating a synthesized crack dataset in the proposed dataset synthesis framework.</p>
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<p>Structure of ProjectedGAN.</p>
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<p>Structure of MCT2GAN.</p>
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<p>Process of quality evaluation.</p>
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<p>Crack images generated from GAN-based methods.</p>
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<p>Performance metrics of generated crack image sample in training process.</p>
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<p>Samples of the generated crack images in the training process. The images in the first row are the synthesized crack images. The images in the second row are the overlapped images between the ground truth and the predicted mask of the synthesized image from the pre-trained FCN model.</p>
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31 pages, 23417 KiB  
Article
Enhanced Blue Band Vegetation Index (the Re-Modified Anthocyanin Reflectance Index (RMARI)) for Accurate Farmland Shelterbelt Extraction
by Xinle Zhang, Jiming Liu, Linghua Meng, Chuan Qin, Zeyu An, Yihao Wang and Huanjun Liu
Remote Sens. 2024, 16(19), 3680; https://doi.org/10.3390/rs16193680 (registering DOI) - 2 Oct 2024
Abstract
Farmland shelterbelts are aimed at farmland protection and productivity improvement, environmental protection and ecological balance, as well as land use planning and management. Farmland shelterbelts play a vital role in determining the structural integrity and overall effectiveness of farmland, and assessing the dynamic [...] Read more.
Farmland shelterbelts are aimed at farmland protection and productivity improvement, environmental protection and ecological balance, as well as land use planning and management. Farmland shelterbelts play a vital role in determining the structural integrity and overall effectiveness of farmland, and assessing the dynamic changes within these protective forests accurately and swiftly is essential to maintaining their protective functions as well as for policy formulation and effectiveness evaluation in relevant departments. Traditional methods for extracting farmland shelterbelt information have faced significant challenges due to the large workload required and the inconsistencies in the accuracy of existing methods. For example, the existing vegetation index extraction methods often have significant errors, which remain unresolved. Therefore, developing a more efficient extraction method with greater accuracy is imperative. This study focused on Youyi Farm in Heilongjiang Province, China, utilizing satellite data with spatial resolutions ranging from 0.8 m (GF-7) to 30 m (Landsat). By taking into account the growth cycles of farmland shelterbelts and variations in crop types, the optimal temporal window for extraction is identified based on phenological analysis. The study introduced a new index—the Re-Modified Anthocyanin Reflectance Index (RMARI)—which is an improvement on existing vegetation indexes, such as the NDVI and the improved original ARI. Both the accuracy and extraction results showed significant improvements, and the feasibility of the RMARI was confirmed. The study proposed four extraction schemes for farmland shelterbelts: (1) spectral feature extraction, (2) extraction using vegetation indexes, (3) random forest extraction, and (4) RF combined with characteristic index bands. The extraction process was implemented on the GEE platform, and results from different spatial resolutions were compared. Results showed that (1) the bare soil period in May is the optimal time period for extracting farmland shelterbelts; (2) the RF method combined with characteristic index bands produces the best extraction results, effectively distinguishing shelterbelts from other land features; (3) the RMARI reduces background noise more effectively than the NDVI and ARI, resulting in more comprehensive extraction outcomes; and (4) among the satellite images analyzed—GF-7, Planet, Sentinel-2, and Landsat OLI 8—GF-7 achieves the highest extraction accuracy (with a Kappa coefficient of 0.95 and an OA of 0.97), providing the most detailed textural information. However, comprehensive analysis suggests that Sentinel-2 is more suitable for large-scale farmland shelterbelt information extraction. This study provides new approaches and technical support for periodic dynamic forestry surveys, providing valuable reference points for agricultural ecological research. Full article
(This article belongs to the Special Issue Mapping Essential Elements of Agricultural Land Using Remote Sensing)
13 pages, 520 KiB  
Article
Composition and Quality of Honey Bee Feed: The Methodology and Monitoring of Candy Boards
by Soraia I. Falcão, Michel Bocquet, Robert Chlebo, João C. M. Barreira, Alessandra Giacomelli, Maja Ivana Smodiš Škerl and Giancarlo Quaglia
Animals 2024, 14(19), 2836; https://doi.org/10.3390/ani14192836 - 1 Oct 2024
Viewed by 450
Abstract
The nutritional status of a honey bee colony is recognized as a key factor in ensuring a healthy hive. A deficient flow of nectar and pollen in the honey bee colony immediately affects its development, making room for pathogen proliferation and, consequently, for [...] Read more.
The nutritional status of a honey bee colony is recognized as a key factor in ensuring a healthy hive. A deficient flow of nectar and pollen in the honey bee colony immediately affects its development, making room for pathogen proliferation and, consequently, for a reduction in the activities and strength of the colony. It is, therefore, urgent for the beekeepers to use more food supplements and/or substitutes in apiary management, allowing them to address colony nutritional imbalances according to the beekeeper’s desired results. In this context, the commercial market for beekeeping products is growing rapidly due to low regulation of animal food products and the beekeeper’s willingness to guarantee healthy colonies. There are numerous products (bee food additives) currently available on the worldwide market, with a highly variable and sometimes even undefined composition, claiming a set of actions at the level of brood stimulation, energy supplementation, queen rearing support, reduction of Varroa reproduction levels, improvement of the intestinal microflora of bees, Nosema prevention, and improvement of the health of honey bee colonies infested by American foulbrood, among others. To address this issue, the members of the COLOSS (Honey Bee Research Association) NUTRITION Task Force are proposing, for the first time, action on honey bee feed control and monitoring. In our common study, we focused on candy board composition and quality parameters. For that, a selected number of commercial candy boards usually found in Europe were analyzed in terms of water and ash content, pH, acidity, 5-hydroxymethylfurfural, sugars, C3-C4 sugar origin, and texture. Results revealed differences between the values found and the ones displayed on the label, demonstrating the need for regulation of the quality of these products. Full article
(This article belongs to the Special Issue Apiculture and Challenges for Future—2nd Edition)
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<p>Three-dimensional distribution of CB markers according to the discriminant function coefficients defined from the assayed quality parameters.</p>
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19 pages, 24741 KiB  
Article
Estimation of Soil Salinity by Combining Spectral and Texture Information from UAV Multispectral Images in the Tarim River Basin, China
by Jiaxiang Zhai, Nan Wang, Bifeng Hu, Jianwen Han, Chunhui Feng, Jie Peng, Defang Luo and Zhou Shi
Remote Sens. 2024, 16(19), 3671; https://doi.org/10.3390/rs16193671 - 1 Oct 2024
Viewed by 281
Abstract
Texture features have been consistently overlooked in digital soil mapping, especially in soil salinization mapping. This study aims to clarify how to leverage texture information for monitoring soil salinization through remote sensing techniques. We propose a novel method for estimating soil salinity content [...] Read more.
Texture features have been consistently overlooked in digital soil mapping, especially in soil salinization mapping. This study aims to clarify how to leverage texture information for monitoring soil salinization through remote sensing techniques. We propose a novel method for estimating soil salinity content (SSC) that combines spectral and texture information from unmanned aerial vehicle (UAV) images. Reflectance, spectral index, and one-dimensional (OD) texture features were extracted from UAV images. Building on the one-dimensional texture features, we constructed two-dimensional (TD) and three-dimensional (THD) texture indices. The technique of Recursive Feature Elimination (RFE) was used for feature selection. Models for soil salinity estimation were built using three distinct methodologies: Random Forest (RF), Partial Least Squares Regression (PLSR), and Convolutional Neural Network (CNN). Spatial distribution maps of soil salinity were then generated for each model. The effectiveness of the proposed method is confirmed through the utilization of 240 surface soil samples gathered from an arid region in northwest China, specifically in Xinjiang, characterized by sparse vegetation. Among all texture indices, TDTeI1 has the highest correlation with SSC (|r| = 0.86). After adding multidimensional texture information, the R2 of the RF model increased from 0.76 to 0.90, with an improvement of 18%. Among the three models, the RF model outperforms PLSR and CNN. The RF model, which combines spectral and texture information (SOTT), achieves an R2 of 0.90, RMSE of 5.13 g kg−1, and RPD of 3.12. Texture information contributes 44.8% to the soil salinity prediction, with the contributions of TD and THD texture indices of 19.3% and 20.2%, respectively. This study confirms the great potential of introducing texture information for monitoring soil salinity in arid and semi-arid regions. Full article
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<p>Flowchart of the study.</p>
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<p>The survey area, including: (<b>a</b>) location of the Xinjiang Province in China, (<b>b</b>) orthophoto map of the UAV and the location of sampling points, (<b>c</b>) DJI Phantom 4 Pro Multispectral Edition, (<b>d</b>) calibrated reflective panel captured by a multispectral camera, (<b>e</b>) the soil type, and (<b>f</b>) the main vegetation types.</p>
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<p>Feature window size.</p>
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<p>The estimation accuracy of RF at different feature window sizes.</p>
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<p>Correlation plot between spectral information and SSC.</p>
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<p>Correlation plot between OD texture features and SSC within (<b>a</b>) texture features in the blue band, (<b>b</b>) texture features in the green band, (<b>c</b>) texture features in the red band, (<b>d</b>) texture features in the red-edge band, and (<b>e</b>) texture features in the near-infrared band.</p>
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<p>Correlation plot between the TD texture index and SSC.</p>
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<p>Optimal correlation plot between the THD texture index and SSC.</p>
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<p>Evaluation of all feature-selected datasets and the accuracy of the three models. SPI, OD, TD, and THD represent the spectral information, one-dimensional texture index, two-dimensional texture index, and three-dimensional texture index, respectively. SO, SOT, and SOTT represent the spectral information + one-dimensional texture index, spectral information + one-dimensional texture index + two-dimensional texture index, and spectral information + one-dimensional texture index + two-dimensional texture index + three-dimensional texture index, respectively.</p>
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<p>SSC map derived from RF, CNN, and PLSR models.</p>
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<p>Variable importance of feature variables using the RF model. Where (<b>a</b>) represents the factor importance of different variables, and (<b>b</b>) represents the factor importance of different variable types.</p>
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16 pages, 1678 KiB  
Article
Genome-Wide Association Analyses Defined the Interplay between Two Major Loci Controlling the Fruit Texture Performance in a Norwegian Apple Collection (Malus × domestica Borkh.)
by Liv Gilpin, Fabrizio Costa, Dag Røen and Muath Alsheikh
Horticulturae 2024, 10(10), 1049; https://doi.org/10.3390/horticulturae10101049 - 1 Oct 2024
Viewed by 227
Abstract
Increasing consumption of apples (Malus domestica Borkh.) produced in Norway requires the availability of superior cultivars and extended marketability. Favorable texture and slow softening are important traits for consumer appreciation and postharvest performance. Apple texture has been well characterized using both sensory [...] Read more.
Increasing consumption of apples (Malus domestica Borkh.) produced in Norway requires the availability of superior cultivars and extended marketability. Favorable texture and slow softening are important traits for consumer appreciation and postharvest performance. Apple texture has been well characterized using both sensory evaluation and instrumental assessments, and major quantitative trait loci (QTL) have been detected. With texture being targeted as an important trait and markers being publicly available, marker-assisted selection has already been implemented into several breeding programs. When focusing solely on a limited set of markers linked to well-investigated major QTLs, most minor-effect QTLs are normally excluded. To find novel potential SNP markers suitable to assist in selection processes, we selected a subset of accessions from a larger apple collection established in Norway based on the favorable alleles of two markers previously associated with texture, enabling the investigation of a minor part of the variance initially masked by the effect of major loci. The subset was employed to conduct a genome-wide association study aiming to search for associations with texture dynamics and retainability. QTL regions related to texture at harvest, postharvest, and for the storage index were identified on chromosomes 3, 12, and 16. Specifically, the SNPs located on chromosome 12 were shown to be potential novel markers for selection of crispness retention during storage, a valuable storability trait. These newly detected QTLs and underlying SNPs will represent a potential set of markers for the selection of the most favorable accessions characterized by superior fruit texture properties in ongoing breeding programs. Full article
(This article belongs to the Special Issue Advanced Postharvest Technology in Processed Horticultural Products)
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<p>Map of identified texture-related SNP markers across the 60 accessions in NAAC2 (green) and previously reported texture-related genetic markers [<a href="#B25-horticulturae-10-01049" class="html-bibr">25</a>,<a href="#B37-horticulturae-10-01049" class="html-bibr">37</a>,<a href="#B38-horticulturae-10-01049" class="html-bibr">38</a>,<a href="#B39-horticulturae-10-01049" class="html-bibr">39</a>,<a href="#B40-horticulturae-10-01049" class="html-bibr">40</a>,<a href="#B41-horticulturae-10-01049" class="html-bibr">41</a>,<a href="#B42-horticulturae-10-01049" class="html-bibr">42</a>] in apple (black). The two markers (SNP_FB_0003490 and the MdACO1 SNP marker) used for preselecting the subset defined as the NAAC2 in the NAAC1 are marked on chromosome 10, and the identification of the SNP_FB_0003490 marker in the NAAC1 is depicted in the Manhattan plot, using the MLMM GWAS model and FDR correction. Created with <a href="http://BioRender.com" target="_blank">BioRender.com</a>, accessed on 30 September 2024.</p>
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<p>Two-dimensional PCA plots of variables illustrating the fruit texture variability evaluated in the NAAC2, at harvest (<b>A</b>), postharvest (<b>B</b>), and for the storage index (<b>C</b>). The loading variables yield force (P1), maximum force (P2), final force (P3), number of force peaks (P4), force strain area (P5), force linear distance (P6), Young’s Modulus (P7), mean force (P8), number of acoustic peaks (P9), maximum acoustic pressure (P10), mean acoustic pressure (P11), and acoustic linear distance (P12) are colored according to group: mechanical (red) and acoustic (blue). The mechanical parameter “number of force peaks” has been reported [<a href="#B7-horticulturae-10-01049" class="html-bibr">7</a>] to correlate with the acoustic parameters, hence the yellow coloration.</p>
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<p>Manhattan plots using FarmCPU and MLMM with a minor allele frequency ≥5% and FDR corrected significance thresholds of the NAAC2 genotypes, together with phenotypic data collected at harvest, postharvest, and for the storage index in 2022. The mechanical texture signature is depicted at the upper half of the figure (Dim1), and significant associations were detected on chromosome 3 at postharvest and chromosome 16 for the storage index. The acoustic texture signature is depicted at the lower half of the figure (Dim2), and for this texture parameter, chromosome 12 was mapped as a novel region at both harvest and for the storage index.</p>
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<p>Marker associations for Dim1 postharvest/storage index and Dim2 harvest/storage index with a narrowed-in view on chromosomes 3, 12, and 16, with the most significant markers marked in red. The left panels depict the phenotypic distribution of the markers with the most significant signal for the storage index among NAAC2 apple accessions grouped according to their genotype in this SNP. Different lowercase letters are significant differences, defined by Tukey’s multiple comparisons of means at 95% family-wise confidence level between the homozygous and heterozygous alleles.</p>
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32 pages, 6198 KiB  
Review
A Review on Preparation of Palladium Oxide Films
by Petre Badica and Adam Lőrinczi
Coatings 2024, 14(10), 1260; https://doi.org/10.3390/coatings14101260 - 1 Oct 2024
Viewed by 312
Abstract
Fabrication aspects of PdO thin films and coatings are reviewed here. The work provides and organizes the up-to-date information on the methods to obtain the films. In recent years, the interest in Pd oxide for different applications has increased. Since Pd can be [...] Read more.
Fabrication aspects of PdO thin films and coatings are reviewed here. The work provides and organizes the up-to-date information on the methods to obtain the films. In recent years, the interest in Pd oxide for different applications has increased. Since Pd can be converted into PdO, it is instructive to pay attention to the preparation of the pure and the alloyed Pd films, heterostructures, and nanoparticles synthesized on different substrates. The development of PdO films is presented from the early reports on coatings’ formation by oxidation of Pd foils and wires to present technologies. Modern synthesis/growth routes are gathered into chemical and physical categories. Chemical methods include hydrothermal, electrochemical, electroless deposition, and coating methods, such as impregnation, precipitation, screen printing, ink jet printing, spin or dip coating, chemical vapor deposition (CVD), and atomic layer deposition (ALD), while the physical ones include sputtering and cathodic arc deposition, laser ablation, ion or electron beam-induced deposition, evaporation, and supersonic cluster beam deposition. Analysis of publications indicates that many as-deposited Pd or Pd-oxide films are granular, with a high variety of morphologies and properties targeting very different applications, and they are grown on different substrates. We note that a comparative assessment of the challenges and quality among different films for a specific application is generally missing and, in some cases, it is difficult to make a distinction between a film and a randomly oriented, powder-like (granular), thin compact material. Textured or epitaxial films of Pd or PdO are rare and, if orientation is observed, in most cases, it is obtained accidentally. Some practical details and challenges of Pd oxidation toward PdO and some specific issues concerning application of films are also presented. Full article
(This article belongs to the Special Issue Advances of Nanoparticles and Thin Films)
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<p>Arbitrary classification of the technological routes to obtain Pd and PdO coatings.</p>
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<p>Adapted from [<a href="#B98-coatings-14-01260" class="html-bibr">98</a>]. (<b>a</b>) Electrochemical gas sensor arrangement (30 mL glass cell): RE—reference electrode; MFC—mass flow controller and the inlet for the gas covered with fluorinated ethylene propylene (FEP) H<sub>2</sub> gas-permeable membrane; WE—working electrode, PdO thin film of 1 μm thickness on ITO substrate; CE—counter electrode, Pt rod. (<b>b</b>) Room-temperature response by using the sensing arrangement from (<b>a</b>) when passing a H<sub>2</sub> gas (10%–70% in Ar) into the cell for 200 s and for a constant potential on electrodes of 1 V.</p>
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<p>Reproduced with permission from [<a href="#B106-coatings-14-01260" class="html-bibr">106</a>]. PdO sensor resistance at different ozone concentrations as a function of time at an operating temperature of 220 °C. SA denotes synthetic air. Note that ozone (O<sub>3</sub>) is harmful to human health, similar to other oxidizing gases, such as NO<sub>x</sub>, SO<sub>2</sub>, and Cl<sub>2</sub>. It is a by-product of many modern technologies, and its interaction under sunlight with volatile hydrocarbons produces many toxic organic compounds.</p>
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<p>Reproduced with permission from [<a href="#B121-coatings-14-01260" class="html-bibr">121</a>]. (<b>i</b>) TEM images taken on (<b>a</b>,<b>b</b>) ZnO and (<b>c</b>,<b>d</b>) ZnO-PdO. (<b>ii</b>) Response to toluene and ethanol of the structures from (<b>i</b>) at different operating temperatures.</p>
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<p>Reproduced with permission from [<a href="#B124-coatings-14-01260" class="html-bibr">124</a>]. (<b>a</b>–<b>c</b>) SEM images of Pd/PdO films obtained by thermolysis in air, low vacuum, and N<sub>2</sub>. (<b>d</b>–<b>f</b>) SEM images of films from (<b>a</b>–<b>c</b>) were taken at higher magnification. (<b>g</b>–<b>i</b>) SEM images on cross-sections of the films from (<b>a</b>–<b>c</b>).</p>
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<p>Reproduced with permission from [<a href="#B167-coatings-14-01260" class="html-bibr">167</a>]. (<b>a</b>) SEM image of the porous Pd thin film on AAO substrate prepared by <span class="html-italic">dc</span> magnetron sputtering and post-annealed at 200 °C, and (<b>b</b>) room-temperature response at various hydrogen concentrations in nitrogen carrier gas. On the Pd film, Au electrodes (10 mm × 3 mm) were deposited by thermal evaporation.</p>
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<p>Reproduced with permission from [<a href="#B176-coatings-14-01260" class="html-bibr">176</a>]. SEM images of reactively sputtered films in different oxygen atmospheres: (<b>a</b>) 15%, (<b>b</b>) 20%, (<b>c</b>) 25%, and (<b>d</b>) 30%.</p>
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<p>Reproduced with permission from [<a href="#B185-coatings-14-01260" class="html-bibr">185</a>]. (<b>a</b>) Optical sensor arrangement based on optical absorbance of the sample when irradiated from a source of a halogen lamp in the spectral range of 400–800 nm. (<b>b</b>) Response time (calculated as the average time to change from 5% to 95% of the absorbance) at room temperature of the samples with different thicknesses to 5 vol.% H<sub>2</sub> gas in nitrogen.</p>
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<p>Reproduced with permission from [<a href="#B225-coatings-14-01260" class="html-bibr">225</a>]. Fabrication of a typical Pd/MOS (MOS—metal oxide semiconductor) capacitor hydrogen sensor. The hydrogen diffuses from the metal Pd gate (active element) and creates a dipole layer at the (Pd/SiO<sub>2</sub>) interface that changes the work function of the active element. The response, R (%) = (C<sub>H</sub> − C<sub>N</sub>)/C<sub>N</sub> × 100, where C<sub>H</sub> and C<sub>N</sub> are the capacitance of the sensor in hydrogen gas and pure nitrogen, respectively. The carrier gas is nitrogen, argon, and air.</p>
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<p>Reproduced with permission from [<a href="#B245-coatings-14-01260" class="html-bibr">245</a>]. SEM images showing the morphology of Ir<sub>(1−x)</sub>Pd<sub>x</sub>O<sub>y</sub> films deposited on 316 SS substrates for: (<b>a</b>) x = 0.14, (<b>b</b>) x = 0.50, (<b>c</b>) x = 0.90, and (<b>d</b>) x = 0.95. Map of morphology summarizing results from (<b>a</b>–<b>d</b>) depending on the composition of the Ir<sub>(1−x)</sub>Pd<sub>x</sub>O<sub>y</sub> films (<b>e</b>).</p>
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15 pages, 4890 KiB  
Article
Surface Tribological Properties Enhancement Using Multivariate Linear Regression Optimization of Surface Micro-Texture
by Zhenghui Ge, Qifan Hu, Haitao Zhu and Yongwei Zhu
Coatings 2024, 14(10), 1258; https://doi.org/10.3390/coatings14101258 - 1 Oct 2024
Viewed by 214
Abstract
This work aims to provide a comprehensive understanding of the structural impact of micro-texture on the properties of bearing capacity and friction coefficient through numerical simulation and theoretical calculation. Compared to the traditional optimization method of single-factor analysis (SFA) and orthogonal experiment, the [...] Read more.
This work aims to provide a comprehensive understanding of the structural impact of micro-texture on the properties of bearing capacity and friction coefficient through numerical simulation and theoretical calculation. Compared to the traditional optimization method of single-factor analysis (SFA) and orthogonal experiment, the multivariate linear regression (MLA) algorithm can optimize the structure parameters of the micro-texture within a wider range and analyze the coupling effect of the parameters. Therefore, in this work, micro-textures with varying texture size, area ratio, depth, and geometry were designed, and their impact on the bearing capacity and friction coefficient was investigated using SFA and MLA algorithms. Both methods obtained the optimal structures, and their properties were compared. It was found that the MLA algorithm can further improve the friction coefficient based on the SFA results. The optimal friction coefficient of 0.070409 can be obtained using the SFA method with a size of 500 µm, an area ratio of 40%, a depth of 5 µm, and a geometry of the slit, having a 10.7% reduction compared with the texture-free surface. In comparison, the friction coefficient can be further reduced to 0.067844 by the MLA algorithm under the parameters of size of 600 µm, area ratio of 50%, depth of 9 µm, and geometry of the slit. The final optimal micro-texture surface shows a 15.6% reduction in the friction coefficient compared to the texture-free surfaces and a 4.9% reduction compared to the optimal surfaces obtained by SFA. Full article
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<p>Two-dimensional geometric model with different surface micro-textures.</p>
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<p>Boundary condition settings of micro-textured watershed.</p>
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<p>Flow chart of the research procedure.</p>
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<p>Pressure distribution of oil film on the square micro-texture surfaces with varying sizes from 25 µm to 600 µm under different texture sizes, at depth of 5 µm and with an area ratio of 50%.</p>
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<p>(<b>a</b>) Load-bearing capacity and (<b>b</b>) friction force variation of texture-free and square micro-texture surfaces with different texture sizes, at a depth of 5 µm and with an area ratio of 50%.</p>
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<p>Pressure distributions of oil film on the square micro-texture surfaces with varying area ratios from 10% to 50% under different area ratios, at a depth of 5 µm and with a length of 500 µm.</p>
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<p>(<b>a</b>) Load-bearing capacity and (<b>b</b>) friction force variation of texture-free and square micro-texture surfaces under different area ratios, at a depth of 5 µm and with a length of 500 µm.</p>
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<p>Pressure distributions of oil film on the square micro-texture surfaces with varying depths from 1 µm to 9 µm, with an area ratio of 40% and a length of 500 µm.</p>
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<p>(<b>a</b>) Load-bearing capacity and (<b>b</b>) friction force variation of texture-free and square micro-texture surfaces at different depths, with an area ratio of 40% and a length of 500 µm.</p>
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<p>Pressure distribution contours of different texture shapes with a length of 500 µm, an area ratio of 40%, and a depth of 5 µm. (<b>a</b>–<b>d</b>) are pressure clouds for square, rectangle, circle, and slit, respectively.</p>
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<p>(<b>a</b>) Load-bearing capacity and friction force of different texture geometries with a length of 500 µm, an area ratio of 40%, and a depth of 5 µm. (<b>b</b>) Standard deviation of load-bearing capacity and friction coefficient under different variants.</p>
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14 pages, 7436 KiB  
Article
Comparative Study on Mechanical Properties and Microstructure Evolution of Mg-3Zn-1Mn/Sn Alloy through Ca-La-Ce Addition
by Ke Hu, Tingting Tian, Yunfeng She, Xiaoming Guo, Lixia She, Junjie Huang, Xiaomin Huo, Xiao Liu, Zhaoting Xiong and Chao Lu
Materials 2024, 17(19), 4840; https://doi.org/10.3390/ma17194840 - 30 Sep 2024
Viewed by 289
Abstract
This study systematically investigates the influence of the composite addition of Ce, La, and Ca elements on the microstructure evolution and mechanical properties of Mg-3Zn-1Mn/Sn (wt.%) alloys. It indicates that the strength of Mg-Zn-Mn series alloys is superior to that of Mg-Zn-Sn series [...] Read more.
This study systematically investigates the influence of the composite addition of Ce, La, and Ca elements on the microstructure evolution and mechanical properties of Mg-3Zn-1Mn/Sn (wt.%) alloys. It indicates that the strength of Mg-Zn-Mn series alloys is superior to that of Mg-Zn-Sn series alloys, due to the stronger restriction of nanosized Mn particles on the recrystallization process and grain growth compared with Mg2Sn phases. The addition of the Ca-La-Ce elements significantly enhances the strength of the Mg-3Zn-1Sn alloy (YS increased by approximately 92.5%, UTS increased by approximately 29.2%, and EL decreased by nearly 52.2%), while for the Mg-3Zn-1Mn alloy, a balanced effect on both the strength and performance can be achieved. This difference mainly lies in the more pronounced refined effect on the grain size and the formation of a bimodal grain structure with strip-like un-DRXed grains and surrounding fine DRXed grains for the Mg-3Zn-1Sn alloy. In contrast, the addition of the Ca-La-Ce elements has a less obvious hindrance on the recrystallization process in the Mg-Zn-Mn series alloy, while significantly weakening the extrusion texture while refining the grains. Through in-depth characterization and experimental analysis, it is found that Sn and Ca can promote the formation of brittle and fine secondary phases. A nanoscale Sn phase (Mg2Sn phase) is more likely to accumulate at the grain boundaries, and the size of the nanoscale Ca2Mg6Zn3 in Mg-Zn-Mn series alloys is finer and more dispersed than that in Mg-Zn-Sn series alloys, thus strongly hindering recrystallization and refining the recrystallized structure of the alloy. Full article
32 pages, 720 KiB  
Article
Development of Novel Honey- and Oat-Based Cocoa Beverages—A Comprehensive Analysis of the Impact of Drying Temperature and Mixture Composition on Physical, Chemical and Sensory Properties
by Kristina Tušek and Maja Benković
Molecules 2024, 29(19), 4665; https://doi.org/10.3390/molecules29194665 - 30 Sep 2024
Viewed by 226
Abstract
This research aimed to assess the influence of drying temperature (50, 60 and 70 °C), honey/oat flour ratio (60:40, 50:50 and 40:60) and cocoa contents (5, 6.25 and 7.5 g/100 g) on the physical (color, moisture content, bulk density, flowability (Hausner ratio, Carr [...] Read more.
This research aimed to assess the influence of drying temperature (50, 60 and 70 °C), honey/oat flour ratio (60:40, 50:50 and 40:60) and cocoa contents (5, 6.25 and 7.5 g/100 g) on the physical (color, moisture content, bulk density, flowability (Hausner ratio, Carr index), dispersibility, solubility, and particle size), chemical (total dissolved solids, conductivity, pH, amount of sugar, color, total polyphenolic content, and antioxidant activity), and sensory properties (powder appearance, color, odor; and beverage appearance, color, odor, sweetness, bitterness, taste, texture) of a newly developed cocoa powder mixture in which honey was used as a sweetener and oat flour as a filler. Also, a further aim of this study was to optimize the composition of the mixture based on chemical, physical and sensory properties. Based on the optimization results, the highest total polyphenolic content and antioxidant activity were achieved at 70 °C with a honey/oat ratio of 50% and a cocoa content of 7.5 g. Drying temperature has a significant effect on powder odor and beverage odor, as well as on beverage bitterness, while the honey/oat flour ratio has a significant effect on color, with primarily values L* and a*. The cocoa contents mostly affect total polyphenolic content and antioxidant activity. Full article
(This article belongs to the Special Issue Plant Foods Ingredients as Functional Foods and Nutraceuticals III)
30 pages, 13385 KiB  
Article
Enhancing 3D Models with Spectral Imaging for Surface Reflectivity
by Adam Stech, Patrik Kamencay and Robert Hudec
Sensors 2024, 24(19), 6352; https://doi.org/10.3390/s24196352 - 30 Sep 2024
Viewed by 165
Abstract
The increasing demand for accurate and detailed 3D modeling in fields such as cultural heritage preservation, industrial inspection, and scientific research necessitates advanced techniques to enhance model quality. This paper addresses this necessity by incorporating spectral imaging data to improve the surface detail [...] Read more.
The increasing demand for accurate and detailed 3D modeling in fields such as cultural heritage preservation, industrial inspection, and scientific research necessitates advanced techniques to enhance model quality. This paper addresses this necessity by incorporating spectral imaging data to improve the surface detail and reflectivity of 3D models. The methodology integrates spectral imaging with traditional 3D modeling processes, offering a novel approach to capturing fine textures and subtle surface variations. The experimental results of this paper underscore the advantages of incorporating spectral imaging data in the creation of 3D models, particularly in terms of enhancing surface detail and reflectivity. The achieved experimental results demonstrate that 3D models generated with spectral imaging data exhibit significant improvements in surface detail and accuracy, particularly for objects with intricate surface patterns. These findings highlight the potential of spectral imaging in enhancing 3D model quality. This approach offers significant advancements in 3D modeling, contributing to more precise and reliable representations of complex surfaces. Full article
(This article belongs to the Special Issue 3D Reconstruction with RGB-D Cameras and Multi-sensors)
17 pages, 3210 KiB  
Article
Composting as a Cleaner Production Strategy for the Soil Resource of Potato Crops in Choconta, Colombia
by Angie Tatiana Ortega-Ramírez, Daniela García Moreno and Miriam Reyes Tovar
Resources 2024, 13(10), 137; https://doi.org/10.3390/resources13100137 - 30 Sep 2024
Viewed by 363
Abstract
Choconta is the municipality in Colombia with the greatest prevalence of potato planting, representing 70.90% of the total territory. However, this crop has been affected by the presence of pests, diseases, and chemical contaminants from pesticides and chemical fertilizers that deteriorate the soil [...] Read more.
Choconta is the municipality in Colombia with the greatest prevalence of potato planting, representing 70.90% of the total territory. However, this crop has been affected by the presence of pests, diseases, and chemical contaminants from pesticides and chemical fertilizers that deteriorate the soil and, therefore, the quality of the final product. Compost (organic waste with specific characteristics and made from waste generated in Choconta) was studied as a sustainable production strategy to increase soil quality and thereby the quality of the local potato crop. For this purpose, a 3 × 2 experiment design was implemented with three treatments (0%, 25%, and 50% compost) and two variables (young potato and mature potato) in duplicate for 4 months. In this experiment, the use of compost led to an improved final product, which went from a floury texture to a dense and creamy texture. The use of compost also reduced the levels of heavy metals, such as lead, with a higher removal in treatment 3 (50% composting). The estimated direct cost of the composting process was USD 280.85, slightly lower than that of the application of fertilizers at USD 294.48. The use of fertilizers has a higher environmental impact due to the use of chemical products that have environmental and health implications. Using compost did not influence tuber harvest time but had a positive impact on tuber texture quality and on soil resources through the reduction in heavy metals, especially lead (16.40–18.03 ppm for treatment 1, 17.96–18.49 ppm for treatment 2, and 15.67–17.88 ppm for treatment 3). Using compost could be environmentally and economically beneficial for local farmers, and it promotes the circular economy and sustainable communities. Full article
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<p>Location of Choconta in Cundinamarca.</p>
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<p>Setup for potato cultivation.</p>
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<p>Mineral presence in the soil sample.</p>
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<p>Characterization of the tuber.</p>
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<p>Sustainability analysis.</p>
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20 pages, 11340 KiB  
Article
Synergistic Effects of Surface Texture and Cryogenic Treatment on the Tribological Performance of Aluminum Alloy Surfaces
by Rui Liu, Xiwen Deng, Xuejian Sun, Jilin Lei, Dewen Jia, Wengang Chen and Qiang Ji
Lubricants 2024, 12(10), 336; https://doi.org/10.3390/lubricants12100336 - 30 Sep 2024
Viewed by 230
Abstract
In order to improve the tribological properties of the 7075-T6 aluminum alloy used on the rotor surface, a combined method of cryogenic treatment and laser surface texture treatment was applied. Various tests, including metallographic microscopy, scanning electron microscopy, elemental analysis, microhardness measurements, were [...] Read more.
In order to improve the tribological properties of the 7075-T6 aluminum alloy used on the rotor surface, a combined method of cryogenic treatment and laser surface texture treatment was applied. Various tests, including metallographic microscopy, scanning electron microscopy, elemental analysis, microhardness measurements, were conducted to examine the wear morphology and modification mechanism of the treated 7075-T6 aluminum alloy surface. A numerical simulation model of surface texture was established using computational fluid dynamics to analyze the lubrication characteristics of V-shaped texture. The research finding that the 7075-T6 aluminum alloy experienced grain refinement during the cryogenic treatment process, enhancing the wear resistance of the V-shaped textures. This improvement delayed the progression of fatigue wear, abrasive wear, and oxidative wear, thereby reducing friction losses. The designed V-shaped texture contributes to reducing contact area, facilitating the capture and retention of abrasives, and enhancing oil film load-bearing capacity, thereby improving tribological performance. The synergistic effect of cryogenic treatment reduced the friction coefficient by 24.8% and the wear loss by 66.4%. Thus, the combination of surface texture and cryogenic treatment significantly improved the tribological properties of the 7075-T6 aluminum alloy. Full article
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<p>Rotor-seal wear.</p>
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<p>Texture preparation of specimen surfaces.</p>
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<p>Friction and wear experimental testing.</p>
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<p>Texture simulation model.</p>
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<p>Grid model diagram of texture: (<b>a</b>) The relationship between the average pressure on the internal surface of the texture and the number of grids; (<b>b</b>) Grid model of texture.</p>
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<p>Microhardness of specimens with different heat treatment processes (The error line represents the standard error).</p>
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<p>Microstructure of different process treatments: (<b>a</b>,<b>b</b>) under OM; (<b>c</b>–<b>f</b>) under SEM.</p>
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<p>Energy dispersive spectroscopy (EDS) results for coarse two-phase particles.</p>
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<p>Texture topography.</p>
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<p>Pressure distribution and velocity vector distribution in the fluid domain.</p>
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<p>Friction coefficient versus time.</p>
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<p>Average friction coefficients of different samples (Corresponding to the average friction coefficient in <a href="#lubricants-12-00336-f011" class="html-fig">Figure 11</a>).</p>
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<p>Metallurgical microscope wear marks: (<b>a</b>) ST; (<b>b</b>) SCT; (<b>c</b>) SAT; (<b>d</b>) SCAT; (<b>e</b>) STT; (<b>f</b>) SCTT; (<b>g</b>) SATT; (<b>h</b>) SCATT.</p>
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<p>Amount of wear and tear on the sample (The error line represents the standard error).</p>
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<p>3D images of wear mark (<b>a</b>) SAT; (<b>b</b>) SCAT; (<b>c</b>) SATT; (<b>d</b>) SCATT.</p>
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<p>Wear patterns of fabrics (<b>a</b>) STT; (<b>b</b>) SCTT; (<b>c</b>) SATT; (<b>d</b>) SCATT.</p>
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<p>Schematic diagram of friction mechanism: (<b>a</b>) Schematic representation illustrating the improvement of friction mechanism through cryogenic treatment; (<b>b</b>) Schematic representation of the friction mechanism with surface texture, b-I is a schematic diagram of abrasive particle generation, b-II is the mechanism diagram of texture wear reduction.</p>
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24 pages, 31908 KiB  
Article
Fabrication of Textured 0.685(Na0.5Bi0.5)TiO3-0.065BaTiO3-0.25SrTiO3 Electrostrictive Ceramics by Templated Grain Growth Using NaNbO3 Templates and Characterization of Their Electrical Properties
by Kiran Andleeb, Doan Thanh Trung, John G. Fisher, Tran Thi Huyen Tran, Jong-Sook Lee, Woo-Jin Choi and Wook Jo
Crystals 2024, 14(10), 861; https://doi.org/10.3390/cryst14100861 - 30 Sep 2024
Viewed by 262
Abstract
Electrostrictive materials based on (Na0.5Bi0.5)TiO3 are promising lead-free candidates for high-precision actuation applications, yet their properties require further improvement. This study aims to enhance the electromechanical properties of a predominantly electrostrictive composition, 0.685(Na0.5Bi0.5)TiO3 [...] Read more.
Electrostrictive materials based on (Na0.5Bi0.5)TiO3 are promising lead-free candidates for high-precision actuation applications, yet their properties require further improvement. This study aims to enhance the electromechanical properties of a predominantly electrostrictive composition, 0.685(Na0.5Bi0.5)TiO3-0.065BaTiO3-0.25SrTiO3, by using templated grain growth. Textured ceramics were prepared with 1~9 wt% NaNbO3 templates. A high Lotgering factor of 95% was achieved with 3 wt% templates and sintering at 1200 °C for 12 h. Polarization and strain hysteresis loops confirmed the ergodic nature of the system at room temperature, with unipolar strain significantly improving from 0.09% for untextured ceramics to 0.23% post-texturing. A maximum normalized strain, Smax/Emax (d33*), of 581 pm/V was achieved at an electric field of 4 kV/mm for textured ceramics. Textured ceramics also showed enhanced performance over untextured ceramics at lower electric fields. The electrostrictive coefficient Q33 increased from 0.017 m4C−2 for untextured ceramics to 0.043 m4C−2 for textured ceramics, accompanied by reduced strain hysteresis, making the textured 0.685(Na0.5Bi0.5)TiO3-0.065BaTiO3-0.25SrTiO3 composition suitable for high-precision actuation applications. Dielectric properties measured between −193 °C and 550 °C distinguished the depolarization, Curie–Weiss and Burns temperatures, and activation energies for polar nanoregion transitions and dc conduction. Dispersive dielectric constants were found to observe the “two” law exhibiting a temperature dependence double the value of the Curie–Weiss constant, with shifts of about 10 °C per frequency decade where the non-dispersive THz limit was identified. Full article
(This article belongs to the Special Issue Advanced Ferroelectric, Piezoelectric and Dielectric Ceramics)
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<p>Experimental procedure of tape-casting and sample preparation.</p>
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<p>XRD pattern of calcined 0.685NBT-0.065BT-0.25ST powder.</p>
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<p>SEM micrographs of (<b>a</b>) Bi<sub>2.5</sub>Na<sub>3.5</sub>Nb<sub>5</sub>O<sub>18</sub> precursor; (<b>b</b>) NaNbO<sub>3</sub> templates. XRD patterns of (<b>c</b>) Bi<sub>2.5</sub>Na<sub>3.5</sub>Nb<sub>5</sub>O<sub>18</sub> precursor; (<b>d</b>) NaNbO<sub>3</sub> templates.</p>
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<p>XRD patterns and their magnified view of (<b>a</b>) samples with different NN template content sintered at 1200 °C for 12 h; (<b>c</b>) 3 wt% NN template samples sintered for different times at 1200 °C. Lotgering factor <span class="html-italic">f</span> and relative density plots as a function of (<b>b</b>) NN template content; (<b>d</b>) sintering time (3 wt% NN template samples).</p>
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<p>SEM micrographs of cross-sections of: (<b>a</b>,<b>b</b>) polished and thermally etched non-textured (12 h sintering time) samples; (<b>c</b>,<b>d</b>) textured (3 wt % NaNbO<sub>3</sub> templates 12 h sintering time) samples.</p>
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<p>(<b>a</b>) EPMA elemental mapping of textured sample; (<b>b</b>) SEM micrograph without thermal etching of the textured sample.</p>
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<p>XRD patterns of 3 wt% NN template textured samples (<b>a</b>) T1 and (<b>b</b>) T2.</p>
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<p>Polarization and strain vs. electric field hysteresis loops of (<b>a</b>,<b>d</b>) untextured; (<b>b</b>,<b>e</b>) 3 wt% NN template textured sample T1; (<b>c</b>,<b>f</b>) 3 wt% NN template textured sample T2.</p>
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<p>(<b>a</b>) Bipolar P-E loops; (<b>b</b>) current density loops; (<b>c</b>) bipolar S-E loops; (<b>d</b>) S-P<sup>2</sup> plots for 3 wt% textured and non-textured samples.</p>
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<p>Unipolar polarization and strain vs. electric field hysteresis loops of (<b>a</b>,<b>d</b>) untextured; (<b>b</b>,<b>e</b>) 3 wt% NN template textured sample T1; (<b>c</b>,<b>f</b>) 3 wt% NN template textured sample T2.</p>
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<p>Dielectric and AC conductivity properties of the untextured sample at selected frequencies over the temperature range of 550 °C~−193 °C measured on cooling: (<b>a</b>) temperature dependence plots of relative (real) permittivity in linear and logarithmic scale; (<b>b</b>) the reciprocal permittivity in a full and low range; (<b>c</b>) loss tangents in logarithmic and a magnified linear scale; (<b>d</b>) the imaginary permittivity in a magnified linear scale and in the logarithmic scale; (<b>e</b>) the Arrhenius plots of the AC conductivity. The characteristic temperatures and the slopes are indicated (see <a href="#crystals-14-00861-t003" class="html-table">Table 3</a>). The star symbol represents the dielectric constant estimated from the P-E hysteresis loop (<a href="#crystals-14-00861-f009" class="html-fig">Figure 9</a>).</p>
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<p>Dielectric and AC conductivity properties of a 3 wt% NN template textured sample at selected frequencies over the temperature range of 550 °C~−193 °C measured on cooling: (<b>a</b>) temperature dependence plots of relative (real) permittivity in linear and logarithmic scale; (<b>b</b>) the reciprocal permittivity in a full and low range; (<b>c</b>) loss tangents in logarithmic and a magnified linear scale; (<b>d</b>) the imaginary permittivity in a magnified linear scale and in the logarithmic scale; (<b>e</b>) the Arrhenius plots of the AC conductivity. The characteristic temperatures and the slopes are indicated (see <a href="#crystals-14-00861-t003" class="html-table">Table 3</a>). The star symbol represents the dielectric constant estimated from the P-E hysteresis loop (<a href="#crystals-14-00861-f009" class="html-fig">Figure 9</a>).</p>
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19 pages, 2867 KiB  
Article
Storage Effects on the Physicochemical Properties, Phytochemical Composition, and Sugars in Red-Fleshed Cultivars, ‘Rubycot’ Plumcot, and ‘Queen Garnet’ Plum
by Gethmini Kavindya Kodagoda, Hung Trieu Hong, Tim J. O’Hare, Bruce Topp, Yasmina Sultanbawa and Michael Erich Netzel
Molecules 2024, 29(19), 4641; https://doi.org/10.3390/molecules29194641 - 29 Sep 2024
Viewed by 314
Abstract
Domestic storage conditions can have a significant impact on the composition of phytochemicals and sugars in stone fruits. This study aimed to evaluate the effect of two domestic storage temperatures (4 and 23 °C) on the physicochemical properties, phytochemical composition, and sugars of [...] Read more.
Domestic storage conditions can have a significant impact on the composition of phytochemicals and sugars in stone fruits. This study aimed to evaluate the effect of two domestic storage temperatures (4 and 23 °C) on the physicochemical properties, phytochemical composition, and sugars of ‘Rubycot’ (RC) plumcot, a novel stone fruit variety, and ‘Queen Garnet’ (QG) plum. Initially, RC had a lower total anthocyanin concentration (TAC) than QG, but TAC in RC increased significantly (p < 0.05) during storage, peaking at +95% after 7 days at 23 °C, while QG reached +60% after 14 days. At 4 °C, TAC increased for both varieties (RC +30%, QG +27%). RC had a higher initial total phenolic content (TPC), which also increased for both fruits. QG had a significantly higher initial total quercetin concentration (TQC), increasing by 40% (p < 0.05) at 23 °C. The initial total carotenoid concentration in QG was higher than that in RC, but after 10 days at 23 °C, RC had a higher carotenoid concentration than QG. Both varieties showed similar sugar profiles, with QG starting higher but decreasing over time at both storage temperatures. Results from this study showed that ambient storage significantly increases total anthocyanins, total quercetins, and TPC in RC and QG. However, it is important to evaluate the textural and sensory properties of stored RC and QG in terms of consumer acceptability of the stored fruits. Full article
(This article belongs to the Special Issue Advances in Functional Foods)
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<p>(<b>A</b>,<b>B</b>) RC plumcot, (<b>C</b>) QG plum.</p>
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<p>TPC (as gallic acid equivalents) in RC and QG. Data are presented as mean ± SE (<span class="html-italic">n</span> = 4–6). Different uppercase and lowercase letters indicate significant (<span class="html-italic">p</span> &lt; 0.05) differences between storage days for each storage temperature for each fruit type.</p>
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<p>Total anthocyanin concentration of RC and QG during storage. Data are presented as mean ± SE (<span class="html-italic">n</span> = 4–6). Different uppercase and lowercase letters indicate significant (<span class="html-italic">p</span> &lt; 0.05) differences between storage days for each storage temperature.</p>
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<p>Total quercetin concentrations (calculated as quercetin-3-glucoside equivalents) in RC and QG during storage. Data are presented as mean ± SE (<span class="html-italic">n</span> = 4–6). Different uppercase and lowercase letters indicate significant (<span class="html-italic">p</span> &lt; 0.05) differences between storage days for each storage temperature.</p>
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<p>Individual quercetin glycosides and quercetin in RC and QG at day 0. Q3R, quercetin-3-rutinoside; Q3G, quercetin-3-glucoside; Q3, quercetin-3-glucosyl-xyloside; Q4, quercetin-3-xyloside; Q5, quercetin-3-rhamnoside; Q6, isorhamnetin-3-rutinoside; Q, quercetin. Data are presented as mean ± SE (<span class="html-italic">n</span> = 6).</p>
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<p>Individual carotenoids in RC and QG at day 0. Data are presented as mean ± SE (<span class="html-italic">n</span> = 4–6).</p>
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<p>Total carotenoids (calculated as lutein equivalents) in RC and QG. Data are presented as mean ± SE (<span class="html-italic">n</span> = 4–6). Different uppercase and lowercase letters indicate significant (<span class="html-italic">p</span> &lt; 0.05) differences between storage days for each storage temperature.</p>
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<p>Individual sugars in RC and QG during storage. Data are presented as mean ± SE (<span class="html-italic">n</span> = 6).</p>
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<p>Total sugars in QG and RC during storage. Data are presented as mean ± SE (<span class="html-italic">n</span> = 6). Different uppercase and lowercase letters indicate significant (<span class="html-italic">p</span> &lt; 0.05) differences between storage days for each storage temperature.</p>
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<p>Mass spectrum and inserts of fragmentations of peonidin-3-rutinoside.</p>
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<p>Mass spectrum and inserts of fragmentations and UV spectra of quercetin-3-glucoside.</p>
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15 pages, 10697 KiB  
Article
A Feature of the Horizontal Directional Solidification (HDS) Method Affects the Microstructure of Al2O3/YAG Eutectic Ceramics
by Juraj Kajan, Grigori Damazyan, Vira Tinkova, Anna Prnová, Monika Michálková, Peter Švančárek, Tomáš Gregor, Alena Akusevich, Branislav Hruška and Dušan Galusek
Crystals 2024, 14(10), 858; https://doi.org/10.3390/cryst14100858 - 29 Sep 2024
Viewed by 320
Abstract
The solidification processes of two compositions, hypereutectic (21.0 mol% Y2O3–79.0 mol% Al2O3) and eutectic (18.5 mol% Y2O3–81.5 mol% Al2O3), were used via the horizontal directional solidification (HDS) [...] Read more.
The solidification processes of two compositions, hypereutectic (21.0 mol% Y2O3–79.0 mol% Al2O3) and eutectic (18.5 mol% Y2O3–81.5 mol% Al2O3), were used via the horizontal directional solidification (HDS) method to produce two ingots with dimensions of 317 × 220 × 35 mm and 210 × 180 × 35 mm, respectively. The first ingot was heterogeneous and characterized by a two-layer structure with an expressed horizontal boundary, which is parallel to the solidification direction (an experimental fact observed for the first time), separating eutectic-type ceramics in the upper layer from the lower one containing the YAG dendrites. Considering the heat transfer feature characteristic of the HDS method and its action during the solidification of materials scattering thermal radiation, an explanation of the occurrence of such structure has been proposed. On this basis, the solidification parameters of the second ingot, providing its homogeneous structure, were selected. Characterization of the crystallographic texture and microstructure of both ingots revealed the advantage of the second solidification processing conditions. Full article
(This article belongs to the Special Issue Structural and Characterization of Composite Materials)
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<p>Digital photos of DSE ceramic ingot No. 1 (<b>a</b>) and the studied specimen (<b>b</b>).</p>
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<p>The scheme of the specimen and sample arrangement for the two DSE ceramic ingots. Samples 1, 2, and 1’, 2’ refer to the ingots No. 1 and No. 2, respectively.</p>
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<p>The samples prepared for EBSD analysis were cut out from the lower layer (1) and upper one (2) of the DSE ceramic ingot No. 1; SD—solidification direction, S/L—interface slope, HE—heat extraction.</p>
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<p>EBSD analysis results of DSE ceramic ingot No. 1: BC-maps (light-grey—YAG, dark-grey—eutectic-type structure), Elemental maps (Al—pink, Y—green), and Phase maps of the sample 1 (patterns 1–5) and sample 2 (patterns 6, 7) shown in <a href="#crystals-14-00858-f003" class="html-fig">Figure 3</a>.</p>
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<p>Schematic view of HDS furnace: container with the raw material—1, the melt—2, solidified part—3, heaters—4, thermal insulation—5. Insert: the schematic image of the slope angle of the S/L interface.</p>
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<p>XRD patterns of (<b>top</b>) and (<b>bottom</b>) layers of DSE ceramic ingot No. 1.</p>
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<p>Digital photos of DSE ceramic ingot No. 2 (<b>a</b>) and the studied specimen (<b>b</b>).</p>
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<p>EBSD analysis results of DSE ceramic ingot No. 2: BC-maps (light-grey—YAG, dark-grey—eutectic-type structure), Elemental maps (Al—pink, Y—green), and Phase maps of the samples 1’ (<b>a</b>) and 2’ (<b>b</b>).</p>
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<p>Typical crystallographic orientation EBSD maps, IPFs, and the corresponding 3D crystal orientation images (YAG—cubes and Al<sub>2</sub>O<sub>3</sub>—hexagonal prisms) of Al<sub>2</sub>O<sub>3</sub>/YAG eutectics No. 1 (samples 1 (<b>a</b>) and 2 (<b>b</b>)). Insert: crystallographic orientation map of the eutectic-type structure between YAG dendrites (pattern 1) × 1000.</p>
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<p>Typical crystallographic orientation EBSD maps and the corresponding 3D crystal orientation Images (YAG—cubes and Al<sub>2</sub>O<sub>3</sub>—hexagonal prism), IPFs of Al<sub>2</sub>O<sub>3</sub> and YAG of Al<sub>2</sub>O<sub>3</sub>/YAG eutectics No. 2 (Samples 1’ (<b>a</b>) and 2’ (<b>b</b>)).</p>
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<p>SEM images of the samples corresponding to the DSE ingots No. 1 (<b>a</b>) and No. 2 (<b>b</b>).</p>
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