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Search Results (61,897)

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25 pages, 3546 KiB  
Article
Dynamic Stiffness Measurements of Road Pavements by Means of Impact Hammer in a Non-Resonant Configuration
by Matteo Bolognese, Erica Greco, Francesco Bianco and Gaetano Licitra
Appl. Sci. 2025, 15(2), 651; https://doi.org/10.3390/app15020651 (registering DOI) - 10 Jan 2025
Abstract
The different sources of noise in a vehicle have long been known, and they include noise from the engine and other mechanical parts, aerodynamic noise, and rolling noise. More specifically, the latter concerns the interaction between the tire and the road surface, and [...] Read more.
The different sources of noise in a vehicle have long been known, and they include noise from the engine and other mechanical parts, aerodynamic noise, and rolling noise. More specifically, the latter concerns the interaction between the tire and the road surface, and so it is also known as Tire–Road Noise (TRN). One of the parameters influencing TRN is pavement stiffness. The empirical measurement of pavement stiffness, and in particular, its frequency spectrum (dynamic stiffness), is not easy to determine, and only in the last decade have studies emerged about this subject. In these works, two different instrumental chains are employed as follows: the impact hammer one and the dynamic exciter (shaker) one, which has established itself over time as a reference. The objective of this work is to develop a system for the dynamic stiffness measurements of road pavements using the impact hammer capable of producing a similar performance to the shaker while minimizing costs. During the work, a measurement aid device named Test Automation Device (TAD) was designed and implemented to increase the quality of the measurements. In line with the practical execution of the measurement, the analysis and the representation of the results were optimized to obtain results that adhere to the stiffness model proposed in the literature. In the present paper, the TAD, the measurement optimization work, the data analysis performed, and the proposed representation method will be described. Finally, we will present the results obtained and possible future perspectives. Full article
16 pages, 3784 KiB  
Article
The Effect of Variable Ratios of Na2O/K2O Oxides in Glazes Containing BaO, ZnO, and ZrO2: Structural Analysis, Characteristic Temperatures, and Surface Properties
by Janusz Partyka, Dawid Kozień and Katarzyna Pasiut
Appl. Sci. 2025, 15(2), 648; https://doi.org/10.3390/app15020648 - 10 Jan 2025
Abstract
In this paper, the glazes of a multicomponent system (SiO2-Al2O3-CaO-MgO-Na2O-K2O-BaO-ZnO-ZrO2) were examined. This work focuses on five glazes and the difference between them as the molar ratio of the alkali oxides [...] Read more.
In this paper, the glazes of a multicomponent system (SiO2-Al2O3-CaO-MgO-Na2O-K2O-BaO-ZnO-ZrO2) were examined. This work focuses on five glazes and the difference between them as the molar ratio of the alkali oxides Na2O/K2O. Analysis of fired glazes focused on changes in phase composition (qualitative and quantitative) microstructure performed during observations made by scanning electron microscopy (SEM). The changing molar ratios were also studied in the structure analysis based on the result of data obtained by middle infrared (MIR) and Raman spectroscopy. The characteristic temperatures of the analyzed glazes were also designated using high-stage microscopy. Surface properties such as the color and roughness of the fired glazes were measured by means of a spectrometer and confocal microscopy as well. The amount and type of crystalline phases with the molar ratio of alkali oxides in the analyzed glazes were changed. In the glazes, the crystalline phase of a solid solution of plagioclase was obtained. The results obtained indicate that glazes with a predominant potassium oxide are characterized by lower characteristic temperatures and greater surface smoothness. Structure analysis indicates a different role for the five-molar ratio of Na2O/K2O. Full article
(This article belongs to the Special Issue Novel Ceramic Materials: Processes, Properties and Applications)
22 pages, 11309 KiB  
Article
Exploring Adsorption Performance of Functionalized Mesoporous Silicas with a Different Pore Structure as Strong Cation-Exchange Sorbents for Solid-Phase Extraction of Atropine and Scopolamine
by Fernando L. Vera-Baquero, Sonia Morante-Zarcero, Damián Pérez-Quintanilla and Isabel Sierra
Appl. Sci. 2025, 15(2), 646; https://doi.org/10.3390/app15020646 - 10 Jan 2025
Abstract
In this work, mesoporous silicas with two types of mesoporous structures were synthesized and functionalized with sulfonic acid groups: MCM-41-SO3H (honeycomb-like hexagonal structure) and MSU-2-SO3H (three-dimensional porous structure with wormhole pores). The synthesized materials were characterized by X-ray diffraction, [...] Read more.
In this work, mesoporous silicas with two types of mesoporous structures were synthesized and functionalized with sulfonic acid groups: MCM-41-SO3H (honeycomb-like hexagonal structure) and MSU-2-SO3H (three-dimensional porous structure with wormhole pores). The synthesized materials were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, nitrogen adsorption–desorption, Fourier-transform infrared spectroscopy, 29Si solid-state nuclear magnetic resonance spectroscopy, and elemental analysis. The obtained functionalized materials were evaluated as sorbents for strong cation-exchange solid-phase extraction (SPE) to determine their efficiency in the adsorption and desorption of tropane alkaloids (atropine and scopolamine). The loading solvents, loading volume, analyte concentration, and elution volume were studied, using 50 mg of both materials. Analyses were carried out by ultra-high performance liquid chromatography coupled to triple quadrupole tandem mass spectrometry. The synthesized MCM-41-SO3H material presented the highest recovery efficiency and has proven to be a promising sorbent for strong cation-exchange SPE of atropine and scopolamine in aqueous media. The high degree of functionalization of MCM-41-SO3H and the high accessibility of the sulfonic groups for the target analytes, due to the regularity and uniformity of their pores, maximize the contact between the alkaloids and the sorbent, favoring efficient adsorption. Full article
(This article belongs to the Special Issue New Trends in Functional and Multifunctional Advanced Materials)
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Figure 1

Figure 1
<p>Schematic of the evaluation of mesoporous silicas as sorbents in the solid-phase extraction of tropane alkaloids (TAs).</p>
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<p>Extracted Ion Chromatograms (EIC) of the most intense production and Mass Spectra (MS<sup>2</sup>) obtained for atropine (<span class="html-italic">m</span>/<span class="html-italic">z</span> 290.5 &gt; 123.9) and scopolamine (<span class="html-italic">m</span>/<span class="html-italic">z</span> 303.5 &gt; 137.9) in a standard solution containing 1 μg/L of each analyte in methanol using the chromatographic method described in <a href="#sec2dot5-applsci-15-00646" class="html-sec">Section 2.5</a>.</p>
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<p>X-ray diffraction (XRD) patterns of MCM-41 (green color) and MSU-2 (blue color).</p>
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<p>Transmission electron microscopy (TEM) of (<b>a</b>) MCM-41 and (<b>b</b>) MSU-2 material. In the case of MCM-41, TEM images show a distribution of parallel pores along the [100] axis (see inset image) and a hexagonal pore distribution in a honeycomb pattern along the [001]. The scale bars correspond to 100 nm and 50 nm, in the case of MSU-2, the scale bars correspond to 200 nm and 2 µm.</p>
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<p>Scanning electron microscopy (SEM) micrographs of (<b>a</b>) MCM-41 and (<b>b</b>) MSU-2 material. In the case of the MSU-2 two different magnifications are shown, the scale bars correspond to 20 µm and 4 µm.</p>
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<p>Nitrogen adsorption–desorption isotherms of (<b>a</b>) bare MCM-41 and MSU-2 and (<b>b</b>) functionalized MCM-41-SO<sub>3</sub>H and MSU-2-SO<sub>3</sub>H. Pore size distribution curves of (<b>c</b>) bare MCM-41 and MSU-2, (<b>d</b>) functionalized MCM-41-SO<sub>3</sub>H and MSU-2-SO<sub>3</sub>H.</p>
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<p>Fourier-transform infrared spectra (FT-IR) of (<b>a</b>) bare MCM-41 and functionalized MCM-41-SO<sub>3</sub>H and (<b>b</b>) bare MSU-2 and functionalized MSU-2-SO<sub>3</sub>H.</p>
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<p><sup>29</sup>Si solid-state nuclear magnetic resonance spectra (<sup>29</sup>Si-PDA-MAS-NMR) of (<b>a</b>) bare MCM-41 and functionalized MCM-41-SO<sub>3</sub>H and (<b>b</b>) bare MSU-2 and functionalized MSU-2-SO<sub>3</sub>H.</p>
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<p>Different types of interactions that can occur between TAs with the MCM-41-SO<sub>3</sub>H sorbent used for solid phase extraction.</p>
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<p>Atropine and scopolamine recoveries (% ± SD) obtained in SPE assays using 50 mg of MSU-2-SO<sub>3</sub>H or MCM-41-SO<sub>3</sub>H as sorbents when the target analytes were loaded in 10 mL of acidified (pH 1) methanol, methanol:water (50:50, <span class="html-italic">v</span>/<span class="html-italic">v</span>), ethanol or water (0.1 µg/L of each analyte) and eluted with 3 mL of 5% methanolic ammonia solution. For the remaining conditions, see <a href="#applsci-15-00646-f002" class="html-fig">Figure 2</a>. Error bars represent the standard deviation of replicate samples (<span class="html-italic">n</span> = 3). In each graphic, a different letter indicates a statistically significant difference (<span class="html-italic">p</span> ≤ 0.05).</p>
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<p>Atropine and scopolamine recoveries (% ± SD) obtained in SPE assays using 50 mg of MSU-2-SO<sub>3</sub>H or MCM-41-SO<sub>3</sub>H as sorbents when the target analytes were loaded in 10 mL of acidified (pH 1) ethanol or water (0.1 µg/L of each analyte) and eluted with 3 or 6 mL of 5% methanolic ammonia solution. For the remaining conditions, see <a href="#applsci-15-00646-f002" class="html-fig">Figure 2</a>. Error bars represent the standard deviation of replicate samples (<span class="html-italic">n</span> = 3). In each graphic, a different letter indicates a statistically significant difference (<span class="html-italic">p</span> ≤ 0.05).</p>
Full article ">Figure 12
<p>Atropine and scopolamine recoveries (% ± SD) obtained in SPE assays using 50 mg of MSU-2-SO<sub>3</sub>H or MCM-41-SO<sub>3</sub>H as sorbents when the target analytes were loaded in 5, 10, or 20 mL of acidified (pH 1) ethanol or water (0.1 µg/L of each analyte) and eluted with 6 mL of 5% methanolic ammonia solution. For the remaining conditions, see <a href="#applsci-15-00646-f002" class="html-fig">Figure 2</a>. Error bars represent the standard deviation of replicate samples (<span class="html-italic">n</span> = 3). In each graphic, a different letter indicates a statistically significant difference (<span class="html-italic">p</span> ≤ 0.05).</p>
Full article ">Figure 13
<p>Atropine and scopolamine recoveries (% ± SD) obtained in SPE assays using 50 mg of MSU-2-SO<sub>3</sub>H or MCM-41-SO<sub>3</sub>H as sorbents when the target analytes were loaded in 10 mL of acidified (pH 1) ethanol or water (0.1 to 30 µg/L of each analyte) and eluted with 6 mL of 5% methanolic ammonia solution. For the remaining conditions, see <a href="#applsci-15-00646-f002" class="html-fig">Figure 2</a>. Error bars represent the standard deviation of replicate samples (<span class="html-italic">n</span> = 3). In each graphic, a different letter indicates a statistically significant difference (<span class="html-italic">p</span> ≤ 0.05).</p>
Full article ">
18 pages, 2159 KiB  
Article
Influence of the Thermoplastic Fiber Ratio on the Mechanical Properties of Recycled Carbon Fibers During the Carding Process
by Jean Ivars, Ahmad Rashed Labanieh and Damien Soulat
Materials 2025, 18(2), 302; https://doi.org/10.3390/ma18020302 - 10 Jan 2025
Abstract
This study investigates the impact of carding and blending recycled carbon fibers (rCF) with crimped thermoplastic polypropylene (PP) fibers on the mechanical properties of rCF, using a Weibull statistical approach. Tensile properties of rCF were evaluated before and after carding with varying rCF/PP [...] Read more.
This study investigates the impact of carding and blending recycled carbon fibers (rCF) with crimped thermoplastic polypropylene (PP) fibers on the mechanical properties of rCF, using a Weibull statistical approach. Tensile properties of rCF were evaluated before and after carding with varying rCF/PP blend ratios (100/0%, 85/15%, 70/30%, and 50/50%). A comparison between the two-parameter and three-parameter Weibull models showed that the two-parameter model provided a better fit for rCF properties before carding. The results show that adding crimped PP fibers during carding helps to decrease the stress-at-break disparity and move their distribution to higher values. Furthermore, a slight increase in tensile modulus was observed in carded rCF, with higher PP ratios associated with smaller scatter modulus distributions. Elongation at break remained consistent, with the Weibull modulus increasing slightly with carding and the inclusion of PP fibers, indicating improved consistency. Overall, carding rCF with PP fibers helped in the mechanical property uniformity of the resulting carded webs without compromising tensile performance. This work shows the potential of the carding process with or without thermoplastic fibers to efficiently realign and give continuity to discontinuous recycled carbon fibers. Full article
(This article belongs to the Topic Advanced Composites Manufacturing and Plastics Processing)
22 pages, 1648 KiB  
Article
Hake Fish Preservation Using Plant-Based Impregnated Polylactic Acid Food Films as Active Packaging
by Fini Sánchez-García, Noelia D. Machado, María Tirado-Fernández, Cristina Cejudo-Bastante, Ana M. Roldán, Casimiro Mantell-Serrano and Lourdes Casas-Cardoso
Appl. Sci. 2025, 15(2), 643; https://doi.org/10.3390/app15020643 - 10 Jan 2025
Abstract
Global fish consumption has steadily increased; however, fishery products are difficult to preserve. Active packaging has emerged as an alternative to improve its conservation. In this work, fresh hake fillets were packaged in commercial polylactic acid films impregnated with olive leaf extract using [...] Read more.
Global fish consumption has steadily increased; however, fishery products are difficult to preserve. Active packaging has emerged as an alternative to improve its conservation. In this work, fresh hake fillets were packaged in commercial polylactic acid films impregnated with olive leaf extract using supercritical CO2. The impregnation was performed at 35 °C and 400 bar for 1 h. The ABTS assay was used to determine the antioxidant activity, and migration tests were performed using food simulants A and D2 for 10 days at 5 °C. The fresh fillets were packaged in impregnated and control films and stored for 12 days at 4 °C. The microbiological, physical (drip loss, aw, pH, and color) and chemical parameters (total volatile base and trimethylamine) were analyzed. The impregnated films presented a 706 μg extract mg−1 polymer, showing a 2-fold extract release using food simulant D2 than simulant A. After hake storage using impregnated films, reduced microbial count, and drip loss, maintaining the pH stability was obtained. The color turned yellowish and no detectable olfactory presence of the extract was noted. The chemical parameters were similar in both types of films. The proposed biodegradable packaging with olive by-products preserves moisture and controls microbial growth, representing an eco-friendly alternative. Full article
(This article belongs to the Special Issue Applications of Analytical Chemistry in Food Science)
Show Figures

Figure 1

Figure 1
<p>Schematic of the supercritical solvent impregnation process (P = pressure, T = temperature, BPR = back pressure regulator).</p>
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<p>Appearance of the hake fillets packaged into impregnated and non-impregnated films. (<b>a</b>) Conformation of the package and (<b>b</b>) appearance along storage.</p>
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<p>Color variation (ΔE) of the (<b>a</b>) flesh, (<b>b</b>) light skin, and (<b>c</b>) dark skin. Dotted lines indicate the tendency lines of the data along storage time. Lowercase letters indicate differences between the impregnated and control samples at the same storage time. Capital letters indicate differences along storage days in the same treatment (<span class="html-italic">p</span> &lt; 0.05) (<span class="html-italic">n</span> = 4).</p>
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<p>Evolution of (<b>a</b>) drip loss (%), (<b>b</b>) water activity (a<sub>w</sub>), and (<b>c</b>) pH during preservation at 4 °C at each sampling point. Data are expressed as the mean ± standard deviation (<span class="html-italic">n</span> = 3). Lowercase letters indicate differences between the impregnated and control samples at the same storage time. Capital letters indicate differences along storage days in the same treatment (<span class="html-italic">p</span> &lt; 0.05).</p>
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<p>Evolution of the (<b>a</b>) total volatile base (TVB-N) and (<b>b</b>) trimethylamine (TMA-N) during preservation at 4 °C at each sampling point. Data are expressed as the mean ± standard deviation (<span class="html-italic">n</span> = 3). Lowercase letters indicate differences between the impregnated and control samples at the same storage time. Capital letters indicate differences along storage days in the same treatment (<span class="html-italic">p</span> &lt; 0.05).</p>
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<p>Evolution of the microbial count (log UFC g<sup>−1</sup> of sample) during preservation at 4 °C at each sampling point. Data are expressed as the mean ± standard deviation (<span class="html-italic">n</span> = 2). Lowercase letters indicate differences between the impregnated and control samples at the same storage time. Capital letters indicate differences along storage days in the same treatment (<span class="html-italic">p</span> &lt; 0.05).</p>
Full article ">
30 pages, 1888 KiB  
Article
Non-Stoichiometric BaxMn0.7Cu0.3O3 Perovskites as Catalysts for CO Oxidation: Optimizing the Ba Content
by Álvaro Díaz-Verde, Emerson Luiz dos Santos Veiga, Héctor Beltrán-Mir, María José Illán-Gómez and Eloísa Cordoncillo-Cordoncillo
Nanomaterials 2025, 15(2), 103; https://doi.org/10.3390/nano15020103 - 10 Jan 2025
Abstract
In this work, a series of BaxMn0.7Cu0.3O3 samples (x: 1, 0.9, 0.8, and 0.7, BxMC) was synthesized, characterized, and used as catalysts for CO oxidation reaction. All formulations were active for CO oxidation in the tested [...] Read more.
In this work, a series of BaxMn0.7Cu0.3O3 samples (x: 1, 0.9, 0.8, and 0.7, BxMC) was synthesized, characterized, and used as catalysts for CO oxidation reaction. All formulations were active for CO oxidation in the tested conditions. A correlation between the electrical conductivity, obtained by impedance spectroscopy, and the reducibility of the samples, obtained by H2-TPR, was observed. The Ba0.8Mn0.7Cu0.3O3 composition (B0.8MC) showed the best catalytic performance (comparable to that of the 1% Pt/Al2O3 reference sample) during tests conducted under conditions similar to those found in the exhaust gases of current gasoline engines. The characterization data suggest the simultaneous presence of a high Mn(IV)/Mn(III) surface ratio, oxygen vacancies, and reduced copper species, these two latter being key properties for ensuring a high CO conversion percentage as both are active sites for CO oxidation. The reaction temperature and the reactant atmosphere composition seem to be the most important factors for achieving a good catalytic performance, as they strongly determine the location and stability of the reduced copper species. Full article
(This article belongs to the Section Energy and Catalysis)
20 pages, 973 KiB  
Article
A Distributed Energy-Throughput Efficient Cross-Layer Framework Using Hybrid Optimization Algorithm
by Pratap Singh, Nitin Mittal, Vikas Mittal, Tapankumar Trivedi, Ashish Singh, Szymon Łukasik and Rohit Salgotra
Mathematics 2025, 13(2), 224; https://doi.org/10.3390/math13020224 - 10 Jan 2025
Abstract
Magnetic induction (MI)-operated wireless sensor networks (WSNs), due to their similar performance in air, underwater, and underground mediums, are rapidly emerging networks that offer a wide range of applications, including mine prevention, power grid maintenance, underground pipeline monitoring, and upstream oil monitoring. MI-based [...] Read more.
Magnetic induction (MI)-operated wireless sensor networks (WSNs), due to their similar performance in air, underwater, and underground mediums, are rapidly emerging networks that offer a wide range of applications, including mine prevention, power grid maintenance, underground pipeline monitoring, and upstream oil monitoring. MI-based wireless underground sensor networks (WUSNs), utilizing small antenna coils, offer a viable solution by providing consistent channel conditions. The cross-layer protocols address the specific challenges of WUSNs, leading to improved network performance and enhanced operational capabilities in real-world applications. This work proposes a distributed cross-layer solution, leveraging the hybrid marine predator naked mole rat algorithm (MPNMRA) for MI-operated WUSNs. The solution, called DECMN (distributed energy-throughput efficient cross-layer network using MPNMRA), is designed to optimize the MI communication channels, MI relay coils (MI waveguide), and MI waveguide with 3D coils to fulfill quality of service (QoS) parameters, while achieving energy savings and throughput gains. DECMN utilizes the interactions between various layers to develop cross-layer protocols based on MPNMRA. Simulation results demonstrate the effectiveness of DECMN, offering energy savings, increased throughput, and reliable transmissions within the performance limits. Full article
19 pages, 4686 KiB  
Article
Comparison of Aging Performances and Mechanisms: Super-Durable Fire-Resistant “Xuan Paper” Versus Chinese Traditional Xuan Paper
by Li-Ying Dong, Ying-Jie Zhu, Jin Wu and Han-Ping Yu
Molecules 2025, 30(2), 263; https://doi.org/10.3390/molecules30020263 - 10 Jan 2025
Abstract
Paper is a thin nonwoven material made from cellulose fibers as the main raw material together with some additives. Paper is highly flammable, leading to the destruction of countless precious ancient books, documents, and art works in fire disasters. In recent years, researchers [...] Read more.
Paper is a thin nonwoven material made from cellulose fibers as the main raw material together with some additives. Paper is highly flammable, leading to the destruction of countless precious ancient books, documents, and art works in fire disasters. In recent years, researchers have made a lot of efforts in order to obtain more durable and fire-retardant paper. Owing to the successful synthesis of ultralong hydroxyapatite (HAP) nanowires as a new kind of inorganic nanofiber material, it becomes possible to develop a new kind of super-durable and fire-resistant paper. Recently, the authors’ research group prepared a new kind of fire-resistant “Xuan paper” consisting of ultralong HAP nanowires. In this article, the super-durable fire-resistant “Xuan paper” based on ultralong HAP nanowires and the traditional Xuan paper based on cellulose fibers were evaluated by the accelerated aging method for 1200 days at 105 °C in air, which is the equivalent of 10,000 years of natural aging in the ambient environment. The aging mechanism of the traditional Xuan paper was further investigated by studying the fiber length/width and their distributions, morphology, infrared spectroscopy, thermogravimetric analysis, H–nuclear magnetic resonance spectra, and C–nuclear magnetic resonance spectra of cellulose fibers before and after the accelerated aging. The durability, properties, and mechanism of the fire-resistant “Xuan paper” based on ultralong HAP nanowires during the accelerated aging were studied. The experiments reveal the reasons for the deteriorated properties and reduced durability by aging of the traditional Xuan paper based on cellulose fibers, and the mechanism for the super-durability and excellent performances of the fire-resistant “Xuan paper” based on ultralong HAP nanowires during the accelerated aging process. Full article
(This article belongs to the Section Nanochemistry)
11 pages, 4553 KiB  
Article
Safety Autonomous Platform for Data-Driven Risk Management Based on an On-Site AI Engine in the Electric Power Industry
by Dongyeop Lee, Daesik Lim and Joonwon Lee
Appl. Sci. 2025, 15(2), 630; https://doi.org/10.3390/app15020630 - 10 Jan 2025
Abstract
The electric power industry poses significant risks to workers with a wide range of hazards such as electrocution, electric shock, burns, and falls. Regardless of the types and characteristics of these hazards, electric power companies should protect their workers and provide a safe [...] Read more.
The electric power industry poses significant risks to workers with a wide range of hazards such as electrocution, electric shock, burns, and falls. Regardless of the types and characteristics of these hazards, electric power companies should protect their workers and provide a safe and healthy working environment, but it is difficult to identify the potential health and safety risks present in their workplace and take appropriate action to keep their workers free from harm. Therefore, this paper proposes a novel safety autonomous platform (SAP) for data-driven risk management in the electric power industry. It can automatically and precisely provide a safe and healthy working environment with the cooperation of safety mobility gateways (SMGs) according to the safety rule and risk index data created by the risk level of a current task, a worker profile, and the output of an on-site artificial intelligence (AI) engine in the SMGs. We practically implemented the proposed SAP architecture using the Hadoop ecosystem and verified its feasibility through a performance evaluation of the on-site AI engine and real-time operation of risk assessment and alarm notification for data-driven risk management. Full article
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Figure 1

Figure 1
<p>Safety autonomous platform architecture and its overall cooperation with safety mobility gateways on providing data-driven risk management.</p>
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<p>Data-driven risk management procedure among the safety autonomous platform, safety mobility gateways, supervisors, and workers.</p>
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<p>On-site AI engine with multimodal ensemble models for risk assessment and alarm notification in safety mobility gateways (SMGs).</p>
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<p>Estimation of the risk index with the safety rule considering the risk level of a current task, a worker profile, the output of an ensemble model in an on-site AI engine, etc.</p>
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<p>Experimental results of facial detection with the customized Dlib/CNN model (<b>upper</b>) and anomaly detection of biometric index (BI) data with the customized TadGAN model (<b>lower</b>) that can be applied to ensemble models in an on-site AI engine.</p>
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<p>Experimental results of object detection with the customized YOLOv7 model applied to ensemble models in an on-site AI engine.</p>
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<p>Experimental results of data-driven risk management (assessment and alarm notification) between the safety autonomous platform (<b>left</b>) and the supervisor with a tablet PC (<b>right</b>).</p>
Full article ">
20 pages, 10708 KiB  
Article
Evaluation of 3D Models of Archaeological Remains of Almenara Castle Using Two UAVs with Different Navigation Systems
by Juan López-Herrera, Serafín López-Cuervo, Enrique Pérez-Martín, Miguel Ángel Maté-González, Consuelo Vara Izquierdo, José Martínez Peñarroya and Tomás R. Herrero-Tejedor
Heritage 2025, 8(1), 22; https://doi.org/10.3390/heritage8010022 - 10 Jan 2025
Abstract
Improvements in the navigation systems incorporated into unmanned aerial vehicles (UAVs) and new sensors are improving the quality of 3D mapping results. In this study, two flights were compared over the archaeological remains of the castle of Almenara, situated in Cuenca, Spain. We [...] Read more.
Improvements in the navigation systems incorporated into unmanned aerial vehicles (UAVs) and new sensors are improving the quality of 3D mapping results. In this study, two flights were compared over the archaeological remains of the castle of Almenara, situated in Cuenca, Spain. We performed one with a DJI Phantom 4 (DJI Innovations Co., Ltd., Shenzhen, China) and the other with a Matrice 300 RTK (DJI Innovations Co., Ltd., Shenzhen, China) and the new Zenmuse P1 camera (45 mp, RGB sensor). With the help of the new software incorporated into the Zenmuse P1 camera gimbal, we could significantly reduce the flight time. We analysed the data obtained with these two UAVs and the built-in RGB sensors, comparing the flight time, the point cloud, and its resolution and obtaining a three-dimensional reconstruction of the castle. We describe the work and the flights carried out, depending on the type of UAV and its RTK positioning system. The improvement in the positioning system provides improvements in flight accuracy and data acquisition. We compared the results obtained in similar studies, and thanks to the advances in UAVs and their sensors with better resolution, we managed to reduce the data collection time and obtained 3D models with the same results as those from other types of sensors. The accuracies obtained with the RTK and the P1 camera are very high. The volumes calculated for a future archaeological excavation are precise, and the 3D models obtained by these means are excellent for the preservation of the cultural asset. These models can have various uses, such as the preservation of an asset of cultural interest, or even its dissemination and analysis in various studies. We propose to use this technology for similar studies of archaeological documentation and the three-dimensional reconstruction and visualisation of cultural heritage in virtual visits on the web. Full article
(This article belongs to the Special Issue 3D Reconstruction of Cultural Heritage and 3D Assets Utilisation)
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<p>The castle of Almenara (<b>a</b>), located in Cuenca (Spain) (<b>b</b>) in the municipality of Puebla de Almenara (2°50′31″ W, 39°47′28″ N) (<b>c</b>). View of the municipality of Puebla de Almenara and the castle of Almenara, Cuenca (Spain), in the foothills of Sierra Jarameña (<b>d</b>). WGS84 spatial reference system.</p>
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<p>The location of the castle treated in this study with its lights and shadows. Own source image from drone flight using Phantom 4. Spatial reference system WGS_1984_UTM_Zone_30N.</p>
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<p>The location of the castle treated in this study with its lights and shadows. Own source of flight patterns used: (<b>a</b>) Phantom 4 nadiral flight; (<b>b</b>) Phantom 4 oblique flight; and (<b>c</b>) Matrice 300 RTK–P1 with one nadiral and four independent oblique flights, one for each direction.</p>
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<p>Flight patterns used: Matrice 300 RTK–P1 SmartOblique flight Omega angles: blue (135° SE), red (45° NW), green (45° NE), and yellow (135° SW); the flight combined all with a Kappa angle.</p>
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<p>Workflow followed in the process of UAV data acquisition (<b>a</b>); processing and 3D model creation (<b>b</b>); and 3D model evaluation (<b>c</b>).</p>
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<p>Three-dimensional point cloud model of the castle of Almenara. (<b>a</b>) Northeast, (<b>b</b>) northwest, (<b>c</b>) southeast, and (<b>d</b>) southwest views.</p>
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<p>Planimetry of the walled enclosure obtained from the generated orthophotography and the 3D point cloud model of the Almenara castle.</p>
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<p>Three-dimensional model of the point cloud of the Almenara castle with recreation of virtual walls.</p>
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<p>A comparative plot of accuracies obtained between both point clouds P1 vs. Phantom 4 and castle control points at different altitudes with an R2 of 0.9.</p>
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<p>Profile and errors obtained at different altitudes with the quality control performed with Total Stations and GNSS RTK.</p>
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<p>Images (<b>a</b>,<b>c</b>) correspond to the Phantom 4 point cloud and (<b>b</b>,<b>d</b>) correspond to the Matrice 300 RTK and P1.</p>
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<p>Images (<b>a</b>,<b>c</b>) correspond to the Phantom 4 point cloud and (<b>b</b>,<b>d</b>) correspond to the Matrice 300 RTK and P1.</p>
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<p>Images (<b>a</b>,<b>c</b>) correspond to the Phantom 4 point cloud and (<b>b</b>,<b>d</b>) correspond to the Matrice 300 RTK and P1.</p>
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<p>Images (<b>a</b>,<b>c</b>) correspond to the Phantom 4 point cloud and (<b>b</b>,<b>d</b>) correspond to the Matrice 300 RTK and P1.</p>
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<p>A digital model of surfaces in the area near the castle and generation of the TIN model for the estimate of volume (in grey). The perimeter of the study is defined as the base area.</p>
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<p>A DSM in the area near the collapsed wall and cross-sectional profile of the terrain.</p>
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27 pages, 1282 KiB  
Article
Plucking Point and Posture Determination of Tea Buds Based on Deep Learning
by Chengju Dong, Weibin Wu, Chongyang Han, Zhiheng Zeng, Ting Tang and Wenwei Liu
Agriculture 2025, 15(2), 144; https://doi.org/10.3390/agriculture15020144 - 10 Jan 2025
Abstract
Tea is a significant cash crop grown widely around the world. Currently, tea plucking predominantly relies on manual work. However, due to the aging population and increasing labor costs, machine plucking has become an important trend in the tea industry. The determination of [...] Read more.
Tea is a significant cash crop grown widely around the world. Currently, tea plucking predominantly relies on manual work. However, due to the aging population and increasing labor costs, machine plucking has become an important trend in the tea industry. The determination of the plucking position and plucking posture is a critical prerequisite for machine plucking tea leaves. In order to improve the accuracy and efficiency of machine plucking tea leaves, a method is presented in this paper to determine the plucking point and plucking posture based on the instance segmentation deep learning network. In this study, tea images in the dataset were first labeled using the Labelme software (version 4.5.13), and then the LDS-YOLOv8-seg model was proposed to identify the tea bud region and plucking area. The plucking points and the central points of the tea bud’s bounding box were calculated and matched as pairs using the nearest point method (NPM) and the point in range method (PIRM) proposed in this study. Finally, the plucking posture was obtained according to the results of the feature points matching. The matching results on the test dataset show that the PIRM has superior performance, with a matching accuracy of 99.229% and an average matching time of 2.363 milliseconds. In addition, failure cases of feature points matching in the plucking posture determination process were also analyzed in this study. The test results show that the plucking position and posture determination method proposed in this paper is feasible for machine plucking tea. Full article
14 pages, 4009 KiB  
Article
Synergistic Integration of Mesocarbon Microbeads, Graphitic Nanofibers, and Mesoporous Carbon for Advanced Supercapacitor Electrodes
by Palanisamy Rajkumar, Vediyappan Thirumal, Kisoro Yoo and Jinho Kim
Crystals 2025, 15(1), 64; https://doi.org/10.3390/cryst15010064 - 10 Jan 2025
Abstract
In this study, a novel multiscale carbon architecture was developed by integrating mesocarbon microbeads (MCMBs), graphitic nanofibers (GNFs), and mesoporous carbon, aimed at enhancing the performance of symmetric supercapacitors. The unique combination of spherical MCMB particles, conductive GNF nanofibers, and mesoporous carbon sheets [...] Read more.
In this study, a novel multiscale carbon architecture was developed by integrating mesocarbon microbeads (MCMBs), graphitic nanofibers (GNFs), and mesoporous carbon, aimed at enhancing the performance of symmetric supercapacitors. The unique combination of spherical MCMB particles, conductive GNF nanofibers, and mesoporous carbon sheets resulted in a highly effective electrode material, offering improved conductivity, increased active sites for charge storage, and enhanced structural stability. The fabricated MCMB/GNF/MC architecture demonstrated a remarkable specific capacitance of 393 F g−1 at 1 A g−1 in a three-electrode system, significantly surpassing the performance of individual MCMBs and MCMB/GNF electrodes. Furthermore, the architecture was incorporated into a symmetric supercapacitor (SSC) device, where it achieved a capacitance of 86 F g−1 at 1 A g−1. The device exhibited excellent cycling stability, retaining 92% of its initial capacitance after 10,000 charge–discharge cycles, with an outstanding coulombic efficiency of 99%. At optimal operating conditions, the SSC device delivered an energy density of 11 Wh kg−1 at a power density of 500 W kg−1, making it a promising candidate for high-performance energy-storage applications. This multiscale carbon architecture represents a significant advancement in the design of electrode materials for symmetric supercapacitors, offering a balance of high energy and power density, long-term stability, and excellent scalability for practical applications. This work not only contributes to the development of high-performance electrode materials but also paves the way for scalable, long-lasting supercapacitors for future energy-storage technologies. Full article
13 pages, 7720 KiB  
Article
Calculation of the Optimal Magnetic Duty Cycle for a Graded Coaxial Magnet of a Rotary Type Magnetic Refrigerator
by Chih-Hao Lee, Pai-Hsiang Cheng, Keh-Chyang Leou, Chih-Ming Hsieh and Yu-Chuan Su
Energies 2025, 18(2), 289; https://doi.org/10.3390/en18020289 - 10 Jan 2025
Abstract
In the design of a rotary-type magnetic refrigerator, a high field of a coaxial magnet is desired. Typically, a high-field design can be achieved with a small duty cycle, which might not be optimized from the viewpoint of the thermal hydraulics of a [...] Read more.
In the design of a rotary-type magnetic refrigerator, a high field of a coaxial magnet is desired. Typically, a high-field design can be achieved with a small duty cycle, which might not be optimized from the viewpoint of the thermal hydraulics of a magnetic refrigerator. In this work, a numerical simulation analysis of a graded coaxial magnet designed using a COMSOL program for a rotary-type active magnetic refrigeration (AMR) system was performed. The magnet structures are based on neodymium–iron–boron permanent magnets with thin gadolinium (Gd) and gadolinium-terbium alloy (Gd-Tb) plates as AMR materials. For a rotary-type magnetic cooling system, from the thermal–hydraulic point of view, the best duty cycle of a coaxial magnet should be 50% if the magnetic field can be kept constant during the period of duty cycles. However, the simulation calculation shows a serious reduction in the magnetic field strength at higher duty cycles, resulting in lower magnetic cooling efficiency. After considering the thermos-hydraulic part, the optimized duty cycle is around 30% in the case of a temperature span of 8 K between the hot and cold ends on a rotary-type magnetic cooling system. By applying graded Gd-Tb alloy along the flow direction, the performance of magnetic refrigeration improves significantly. Compared to a pure Gd AMR system, it is demonstrated that more than three times the increase in the cooling capacity can be achieved. Full article
(This article belongs to the Section K: State-of-the-Art Energy Related Technologies)
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<p>The cross-section of a rotary cylindrical magnet. The red arrows are the directions of magnetization of permanent magnets.</p>
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<p>The magnetic field distribution calculated by the COMSOL program on the schematic configuration in <a href="#energies-18-00289-f001" class="html-fig">Figure 1</a>. (<b>a</b>) magnetic field strength, and (<b>b</b>) magnetic field vector.</p>
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<p>(<b>a</b>) The heat transfer boundary conditions used in the thermal–hydraulic analysis of the magnetic refrigerator. There is no thermal flux at the purple boundary; the thermal flux and temperature are continuously smooth at the green boundaries. (<b>b</b>) The simplified 2-segment AMR along the flow direction; (<b>c</b>) The simplified 3-segment AMR along the flow direction employed in the COMSOL simulation.</p>
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<p>The magnetic field distribution on Gd as a function of rotating time with the magnetization angle at θ = 45 degrees.</p>
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<p>The maximum magnetic field on Gd under four different pole face angles, ϕ, as functions of magnetization angles, θ.</p>
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<p>The cross-section of a rotary-type cylindrical magnet with a pole face angle of 90 degrees and magnetization angle of 45 degrees. The amount of Nd-Fe-B immaterial used is increased significantly compared to <a href="#energies-18-00289-f001" class="html-fig">Figure 1</a>.</p>
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<p>The magnetic field distribution on Gd as a function of rotating time under four different pole face angles with a magnetization angle of 45 degrees is shown in <a href="#energies-18-00289-f006" class="html-fig">Figure 6</a>.</p>
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<p>The maximum magnetic field applied on Gd under different magnetic duty cycles operated at different magnetization angles of 15 degrees (black squares) and 45 degrees (red circles). The blue curve is the maximum magnetic field if more than 29% of the amount of Nd-Fe-B is used in the rotator (see <a href="#energies-18-00289-t001" class="html-table">Table 1</a>).</p>
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<p>A typical temperature change at the cold side as a function of time with hot ends at 298 K at the beginning and no thermal load at the boundary of the cold side. The duty cycles of magnetization-demagnetization are 15% (orange), 21% (red), 29% (green), 36% (light green), and 50% (blue), respectively.</p>
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<p>The cooling power of a rotary magnetic refrigeration system with the 290 K (red circles) and 293 K (blue triangles) fixed at the cold end.</p>
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<p>Simulated temperature variations in the cold heat exchangers over cycles when AMR regenerators made of pure Gd, pure Tb, and Gd-Tb (1:1) alloy are used [<a href="#B6-energies-18-00289" class="html-bibr">6</a>]. (Figure permission from IEEE).</p>
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<p>Relationship between composition (x) and cooling capacity ratio of two-segment regenerators. Cases with the same geometry (r) are grouped as curves [<a href="#B6-energies-18-00289" class="html-bibr">6</a>]. (Figure permission from IEEE).</p>
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<p>Relationship between geometry (r) and the cooling capacity ratio of two-segment AMR regenerators. Cases with the same composition (x) are grouped as curves [<a href="#B6-energies-18-00289" class="html-bibr">6</a>]. (Figure permission from IEEE).</p>
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<p>Simulated temperature variations of the cold heat exchangers over cycles when two- and three-segment AMR regenerators of 10 cm in total length are used [<a href="#B6-energies-18-00289" class="html-bibr">6</a>]. (Figure permission from IEEE).</p>
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19 pages, 731 KiB  
Article
Extracting Fruit Disease Knowledge from Research Papers Based on Large Language Models and Prompt Engineering
by Yunqiao Fei, Jingchao Fan and Guomin Zhou
Appl. Sci. 2025, 15(2), 628; https://doi.org/10.3390/app15020628 - 10 Jan 2025
Abstract
In China, fruit tree diseases are a significant threat to the development of the fruit tree industry, and knowledge about fruit tree diseases is the most needed professional knowledge for fruit farmers and other practitioners in the fruit tree industry. Research papers are [...] Read more.
In China, fruit tree diseases are a significant threat to the development of the fruit tree industry, and knowledge about fruit tree diseases is the most needed professional knowledge for fruit farmers and other practitioners in the fruit tree industry. Research papers are the primary sources of professional knowledge that represent the cutting-edge progress in fruit disease research. Traditional knowledge engineering methods for knowledge acquisition require extensive and cumbersome preparatory work, and they demand a high level of professional background and information technology skills from the handlers. This paper, from the perspective of fruit tree industry knowledge dissemination, aims at users such as fruit farmers, fruit tree experts, fruit tree knowledge communicators, and information gatherers. It proposes a fast, cost-effective, and low-technical-barrier method for extracting fruit tree disease knowledge from research paper abstracts—K-Extract, based on large language models (LLMs) and prompt engineering. Under zero-shot conditions, K-Extract utilizes conversational LLMs to automate the extraction of fruit tree disease knowledge. The K-Extract method has constructed a comprehensive classification system for fruit tree diseases and, through a series of optimized prompt questions, effectively overcomes the deficiencies of LLM models in providing factual accuracy. This paper tests multiple LLM models available in the Chinese market, and the results show that K-Extract can seamlessly integrate with any conversational LLM model, with the DeepSeek model and the Kimi model performing particularly well. The experimental results indicate that LLM models have a high accuracy rate in handling judgment tasks and simple knowledge Q&A tasks. The K-Extract method is simple, efficient, and accurate, and can serve as a convenient tool for knowledge extraction in the agricultural field. Full article
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<p>Complete workflow diagram of the K-Extract method.</p>
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<p>Knowledge extraction process.</p>
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<p>Accuracy of the five large language models.</p>
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<p>Precision of the five large language models.</p>
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27 pages, 4655 KiB  
Article
Coupling Beams’ Shear Capacity Prediction by Hybrid Support Vector Regression and Particle Swarm Optimization
by Emad A. Abood, Mustafa Kamal Al-Kamal, Sabih Hashim Muhodir, Nadia Moneem Al-Abdaly, Luís Filipe Almeida Bernardo, Dario De Domenico and Hamza Imran
Buildings 2025, 15(2), 191; https://doi.org/10.3390/buildings15020191 - 10 Jan 2025
Viewed by 62
Abstract
In structures with reinforced concrete walls, coupling beams join individual walls to produce a rigid assembly that withstands sideways forces. A precise forecasting of the critical shear capacity is essential to avoid early shear failure and attain the desired ductility performance of coupled [...] Read more.
In structures with reinforced concrete walls, coupling beams join individual walls to produce a rigid assembly that withstands sideways forces. A precise forecasting of the critical shear capacity is essential to avoid early shear failure and attain the desired ductility performance of coupled shear wall systems in earthquake design. This paper examines the ability of Support Vector Regression (SVR) in predicting the shear performance of coupling beams. SVR is a distinguished machine learning regression method that has been positively utilized in former works to forecast the performance of several structural members. Nevertheless, the capability of this regression method deeply relies on picking its best hyperparameters. To handle this, a heuristic optimization procedure named Particle Swarm Optimization (PSO) was merged with SVR to select the optimal hyperparameters. The data of RC coupling beams collected from the previous works were utilized to build the proposed model. Several performance metrics, including RMSE, R2, and MAE, were employed to compare the performance of the optimized model against a baseline SVR model and previous approaches. Analytical results indicate that the new optimized prediction model can assist civil engineers in designing RC coupling beam structures more effectively and outperforms existing models in predicting the shear strength of such beams. Full article
(This article belongs to the Section Building Structures)
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<p>The behavior of hybrid coupled shear walls based on different coupling degrees: (<b>a</b>) typical coupled shear wall behavior and (<b>b</b>) distribution of strain [<a href="#B2-buildings-15-00191" class="html-bibr">2</a>].</p>
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<p>Illustration of Support Vector Regression (SVR) with different kernel functions: (<b>a</b>) linear, (<b>b</b>) nonlinear [<a href="#B58-buildings-15-00191" class="html-bibr">58</a>].</p>
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<p>PSO-SVR optimization methodology.</p>
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<p>Histograms of input and output variables: (<b>a</b>) <math display="inline"><semantics> <msub> <mi>L</mi> <mi>n</mi> </msub> </semantics></math> (mm), (<b>b</b>) <span class="html-italic">h</span> (mm), (<b>c</b>) <math display="inline"><semantics> <msub> <mi>b</mi> <mi>w</mi> </msub> </semantics></math> (mm), (<b>d</b>) <math display="inline"><semantics> <msubsup> <mi>f</mi> <mi>c</mi> <mo>′</mo> </msubsup> </semantics></math> (MPa), (<b>e</b>) <math display="inline"><semantics> <msub> <mi>A</mi> <mi>s</mi> </msub> </semantics></math> (mm<sup>2</sup>), (<b>f</b>) <math display="inline"><semantics> <msub> <mi>f</mi> <mrow> <mi>y</mi> <mi>t</mi> </mrow> </msub> </semantics></math> (MPa), (<b>g</b>) <math display="inline"><semantics> <msub> <mi>A</mi> <mi>h</mi> </msub> </semantics></math> (mm<sup>2</sup>), (<b>h</b>) <math display="inline"><semantics> <msub> <mi>f</mi> <mrow> <mi>y</mi> <mi>h</mi> </mrow> </msub> </semantics></math> (MPa), (<b>i</b>) <math display="inline"><semantics> <msub> <mi>A</mi> <mi>t</mi> </msub> </semantics></math> (mm<sup>2</sup>), (<b>j</b>) <math display="inline"><semantics> <msub> <mi>f</mi> <mrow> <mi>y</mi> <mi>t</mi> </mrow> </msub> </semantics></math> (MPa), (<b>k</b>) <math display="inline"><semantics> <msub> <mi>A</mi> <mrow> <mi>v</mi> <mi>d</mi> </mrow> </msub> </semantics></math> (mm<sup>2</sup>), (<b>l</b>) <math display="inline"><semantics> <msub> <mi>f</mi> <mrow> <mi>y</mi> <mi>v</mi> </mrow> </msub> </semantics></math> (MPa), (<b>m</b>) <math display="inline"><semantics> <mi>γ</mi> </semantics></math> (degrees), (<b>n</b>) <math display="inline"><semantics> <msub> <mi>V</mi> <mi>n</mi> </msub> </semantics></math> (kN).</p>
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<p>Boxplot of the output variable.</p>
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<p>Heatmap of variable correlations for coupling beam parameters.</p>
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<p>Cross-bslidation tesults for PSO-SVR model: (<b>a</b>) RMSE across folds, (<b>b</b>) <math display="inline"><semantics> <msup> <mi>R</mi> <mn>2</mn> </msup> </semantics></math> across folds, (<b>c</b>) MAE across folds.</p>
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<p>Predicted vs. actual shear capacity for PSO-SVR and SVR models in training and testing phases. (<b>a</b>) PSO-SVR training set. (<b>b</b>) PSO-SVR testing set. (<b>c</b>) SVR training set. (<b>d</b>) SVR testing set.</p>
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<p>PSO-SVR versus SVR relative percentage errors of testing set.</p>
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<p>Model performance was evaluated using 300 Monte Carlo simulations, presented with the average and standard deviation for (<b>a</b>) RMSE, (<b>b</b>) MAE, and (<b>c</b>) R<sup>2</sup>.</p>
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<p>Tylor diagram for model evaluation [<a href="#B50-buildings-15-00191" class="html-bibr">50</a>,<a href="#B51-buildings-15-00191" class="html-bibr">51</a>,<a href="#B52-buildings-15-00191" class="html-bibr">52</a>,<a href="#B53-buildings-15-00191" class="html-bibr">53</a>].</p>
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<p>Global importance of predictors.</p>
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<p>SHAP summary plot.</p>
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<p>SHAP dependence plot.</p>
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