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Search Results (2,122)

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27 pages, 1857 KiB  
Review
Water, Ecosystem Services, and Urban Green Spaces in the Anthropocene
by Marianna Olivadese and Maria Luisa Dindo
Land 2024, 13(11), 1948; https://doi.org/10.3390/land13111948 - 19 Nov 2024
Viewed by 160
Abstract
As urban centers worldwide face the escalating impacts of climate change, rapid urbanization, and increasing water scarcity, the need for sustainable water management practices to enhance urban resilience in the Anthropocene has become critical. This study explores how ancient water management practices—including Roman [...] Read more.
As urban centers worldwide face the escalating impacts of climate change, rapid urbanization, and increasing water scarcity, the need for sustainable water management practices to enhance urban resilience in the Anthropocene has become critical. This study explores how ancient water management practices—including Roman aqueducts, Maya rainwater harvesting systems, and ancient Chinese flood control techniques—can be adapted to address contemporary water challenges in modern cities. We evaluate these historical practices through a lens of contemporary environmental pressures, including climate change, urbanization, and resource scarcity. By integrating ancient methods with modern technologies, we propose adaptive solutions to enhance urban water resilience. Case studies from five cities (Singapore, Copenhagen, Mexico City, Los Angeles, and Philadelphia) illustrate how modern green infrastructure, inspired by ancient techniques, is being successfully implemented to manage stormwater, mitigate urban flooding, and improve water conservation. By integrating historical practices with modern technologies—such as advanced filtration systems and water recycling—these cities are enhancing their water resilience and sustainability. The findings suggest that urban planners can draw valuable lessons from historical systems to design adaptive, climate-resilient cities that balance human needs with ecological sustainability. This paper concludes with actionable recommendations for future urban planning, emphasizing the importance of decentralized water systems, nature-based solutions, and community engagement to ensure sustainable urban water management in the Anthropocene. Full article
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<p>Locations of both ancient civilizations (blue marker) and modern cities (red marker) interconnected by water management practices.</p>
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<p>Evolution of water management from ancient to modern techniques.</p>
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11 pages, 1546 KiB  
Article
Effect of Different Partial Pressures on H2 Production with Parageobacillus thermoglucosidasius DSM 6285
by Magda Stephania Ardila, Habibu Aliyu, Pieter de Maayer and Anke Neumann
Fermentation 2024, 10(11), 592; https://doi.org/10.3390/fermentation10110592 (registering DOI) - 19 Nov 2024
Viewed by 138
Abstract
The ability of Parageobacillus thermoglucosidasius to produce H2 from CO via the water–gas shift (WGS) reaction makes it a compelling microorganism for biofuels research. Optimizing this process requires evaluating parameters such as pressure. This study aimed to understand how H2 production [...] Read more.
The ability of Parageobacillus thermoglucosidasius to produce H2 from CO via the water–gas shift (WGS) reaction makes it a compelling microorganism for biofuels research. Optimizing this process requires evaluating parameters such as pressure. This study aimed to understand how H2 production is affected by increasing CO, N2, and H2 partial pressures to 1.0, 2.0, and 3.0 bar. Increasing CO partial pressure can improve the solubility of the gas in the liquid phase. However, raising CO partial pressure to 3.0 bar had an inhibitory effect, delaying and reducing H2 production. By contrast, increasing N2 and H2 partial pressures to 3.0 bar had positive effects, reaching a H2 production of 9.2 mmol and 130 mmol, respectively. Analysis of the electron balance at the end of the fermentation process showed that the selectivity toward H2 production reached 95%, with the remainder of electrons deriving from CO and glucose directed at organic acid production, mainly acetate, followed by formate. Full article
(This article belongs to the Special Issue Fermentative Biohydrogen Production, 2nd Edition)
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<p>(<b>A</b>) Gas partial pressures during fermentations with different pCO. The blue lines denote H<sub>2</sub> production, while the green and orange lines represent CO and CO<sub>2</sub>. (<b>B</b>) Formate, acetate, and lactate production in the different pCO. Formate, acetate, and lactate are indicated in grey, red, and blue, respectively.</p>
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<p>(<b>A</b>) Gas partial pressures during fermentations with different pN<sub>2</sub>. The blue lines denote H<sub>2</sub> production, while the green and orange lines represent CO and CO<sub>2</sub>. (<b>B</b>) Formate, acetate, and lactate production in the different pCO. Formate, acetate, and lactate are indicated in grey, red and blue, respectively.</p>
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<p>(<b>A</b>) Gas partial pressures during fermentations with different pH<sub>2</sub>. The blue lines denote H<sub>2</sub> production, while the green and orange represent CO and CO<sub>2</sub>. (<b>B</b>) Formate, acetate, and lactate production in the different pCO. Formate, acetate and lactate are indicated in grey, red, and blue, respectively.</p>
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<p>Electron selectivity for the different (<b>A</b>) N<sub>2</sub>, (<b>B</b>) H<sub>2</sub>, and (<b>C</b>) CO partial pressures.</p>
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15 pages, 5621 KiB  
Article
Isosorbide-Based Acrylic Pressure-Sensitive Adhesives Through UV-Cured Crosslinking with a Balance Between Adhesion and Cohesion
by Jiajie Lv, Qingjun Wang and Hongfeng Xie
Polymers 2024, 16(22), 3178; https://doi.org/10.3390/polym16223178 - 14 Nov 2024
Viewed by 633
Abstract
The development of sustainable pressure-sensitive adhesives (PSAs) from natural biomass resources has attracted increasing attention owing to their non-toxic, biocompatible, and biodegradable features. In this study, a bio-based acrylic PSA with tunable adhesion and cohesion was synthesized by a selective chemical modification of [...] Read more.
The development of sustainable pressure-sensitive adhesives (PSAs) from natural biomass resources has attracted increasing attention owing to their non-toxic, biocompatible, and biodegradable features. In this study, a bio-based acrylic PSA with tunable adhesion and cohesion was synthesized by a selective chemical modification of isosorbide-5-acrylate (IA) and its copolymerization with butyl acrylate and acrylic acid through UV-curing crosslinking. During the UV-curing process, the synthesized isosorbide diacrylate ester (IDAE) served as the crosslinker, effectively improving the crosslinking degree of PSA. The impact of IA and IDAE on the mechanical properties of PSA was studied. Moreover, to achieve a balance between adhesion and cohesion, the optimal composition was identified. The addition of IA significantly enhances the stiffness of PSA. Furthermore, the combined effect of IA and IDAE improves the overall adhesion properties of the PSA. The optimal bio-based PSA demonstrates a peel force of 13.9 N/25 mm and a persistent time of 6820 min, promising to replace traditional petroleum-based PSAs. Full article
(This article belongs to the Section Polymer Chemistry)
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<p><sup>1</sup>H NMR spectra of IA (<b>a</b>) and IDEA (<b>b</b>).</p>
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<p>Synthetic mechanism of PSA and schematic of the preparation process of PSAs.</p>
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<p><sup>1</sup>H NMR spectra of BA-IA<sub>0</sub>-AA<sub>2</sub> (<b>a</b>), BA-IA<sub>5</sub>-AA<sub>2</sub> (<b>b</b>), and BA-IA<sub>10</sub>-AA<sub>2</sub> (<b>c</b>).</p>
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<p>GPC chromatograms of the prepolymers.</p>
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<p>FTIR spectra of the prepolymers, BA, AA, and IA monomers.</p>
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<p>FTIR spectra of the PSAs, IDAE, and BA samples.</p>
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<p>Gel fractions of PSAs with different IDAE concentrations.</p>
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<p>The 180° peel force (<b>a</b>) and initial tack numbers (<b>b</b>) of PSAs.</p>
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<p>Cohesion failure patterns of BA-IA<sub>0</sub>-AA<sub>2</sub>-0 (<b>a</b>), BA-IA<sub>0</sub>-AA<sub>2</sub>-0.5 (<b>b</b>), BA-IA<sub>0</sub>-AA<sub>2</sub>-1 (<b>c</b>), BA-IA<sub>0</sub>-AA<sub>2</sub>-2 (<b>d</b>), BA-IA<sub>5</sub>-AA<sub>2</sub>-0 (<b>e</b>), and BA-IA<sub>5</sub>-AA<sub>2</sub>-0.5 (<b>f</b>).</p>
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<p>DSC heating scan of the selected PSAs.</p>
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<p>Plots of storage and loss modulus versus frequency (<b>a</b>) and viscoelastic windows (<b>b</b>) of PSAs.</p>
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<p>Carbohydrate feedstocks used for preparing bio-based PSAs.</p>
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<p>Synthetic routes of IA and IDAE (<b>a</b>) and the prepolymer (BA-IA<sub>α</sub>-AA<sub>β</sub>) (<b>b</b>).</p>
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18 pages, 6370 KiB  
Article
Comparative Study on the Prevention and Control Effects of Rockburst Between Hydraulic Fracturing Sections and Blank Sections
by Shuo Yang, Jiang Bian, Aixin Liu, Xiaoyang Li, Fuhong Li, Xingen Ma and Siyuan Gong
Sensors 2024, 24(22), 7281; https://doi.org/10.3390/s24227281 - 14 Nov 2024
Viewed by 260
Abstract
Influenced by various factors such as the complex environment and high key layers in coal mines, hydraulic fracturing technology has gradually become the main means of controlling the hard roof strata to prevent and control rockburst in recent years, which can effectively release [...] Read more.
Influenced by various factors such as the complex environment and high key layers in coal mines, hydraulic fracturing technology has gradually become the main means of controlling the hard roof strata to prevent and control rockburst in recent years, which can effectively release the stress on the roof, reduce the intensity of pressure, and ensure the safe and efficient mining of the working face in coal mines. However, the current research on hydraulic fracturing to prevent and control rockburst is mostly limited to optimizing fracturing parameters and monitoring and evaluating fracturing effects, and there are few studies on blank sections, which cannot guarantee the overall prevention and control effect of rockburst, or increase unnecessary construction costs. In this paper, for the directional long borehole staged hydraulic fracturing project, triangular-type blank sections and regular-type blank sections are defined, and the rockburst prevention and control effects of fracturing sections and triangular-type blank sections during fracturing are compared and analyzed by the underground–ground integrated microseismic monitoring technology and transient electromagnetic detection technology, and the rockburst prevention and control effects of fracturing sections and regular-type blank sections during the coal extraction period are compared and analyzed by the underground–ground integrated microseismic monitoring data such as microseismic energy level and frequency as well as the online stress monitoring data. The results show that leaving the triangular-type blank sections can result in reduced construction costs without compromising the effectiveness of rockburst prevention and control. Additionally, the performance of rockburst prevention and control in regular-type blank sections is notably superior to that observed in other working faces without hydraulic fracturing. However, when compared to fracturing sections, the efficacy of rockburst prevention and control in regular-type blank sections remains relatively inferior. Therefore, during the design of fracturing boreholes, it is imperative to strive for maximum coverage of regular-type blank sections. The research findings of this paper comprehensively summarize two prevalent types of blank sections encountered in directional long borehole staged hydraulic fracturing projects. A rigorous comparative analysis is undertaken to evaluate the rockburst prevention and control effects between fractured sections and blank sections. This comparative evaluation serves as a valuable reference for the optimal design of fracturing boreholes, ensuring a balance between achieving effective rockburst prevention and control measures and minimizing economic costs. Full article
(This article belongs to the Section Physical Sensors)
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<p>The 1802 workface hydraulic fracturing program.</p>
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<p>Hydraulic fracturing blank section.</p>
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<p>The underground–ground integrated microseismic monitoring system.</p>
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<p>Transient electromagnetic detection.</p>
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<p>Microseismic distribution during fracturing.</p>
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<p>Microseismic distribution during fracturing.</p>
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<p>Ideal microseismic monitoring results.</p>
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<p>Transient electromagnetic detection results for drilling field 1.</p>
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<p>Transient electromagnetic detection results for drilling field 2.</p>
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<p>Percentage of microseismic events of different energy levels in different regions.</p>
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<p>Comparison of daily total energy during the coal extraction period.</p>
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<p>Comparison of daily average energy during the coal extraction period.</p>
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<p>Comparison of daily maximum energy during the coal extraction period.</p>
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<p>Comparison of microseismic frequency during the coal extraction period.</p>
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<p>Stress monitoring results.</p>
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18 pages, 2082 KiB  
Systematic Review
The Use of Wearable Sensors and Machine Learning Methods to Estimate Biomechanical Characteristics During Standing Posture or Locomotion: A Systematic Review
by Isabelle J. Museck, Daniel L. Brinton and Jesse C. Dean
Sensors 2024, 24(22), 7280; https://doi.org/10.3390/s24227280 - 14 Nov 2024
Viewed by 359
Abstract
Balance deficits are present in a variety of clinical populations and can negatively impact quality of life. The integration of wearable sensors and machine learning technology (ML) provides unique opportunities to quantify biomechanical characteristics related to balance outside of a laboratory setting. This [...] Read more.
Balance deficits are present in a variety of clinical populations and can negatively impact quality of life. The integration of wearable sensors and machine learning technology (ML) provides unique opportunities to quantify biomechanical characteristics related to balance outside of a laboratory setting. This article provides a general overview of recent developments in using wearable sensors and ML to estimate or predict biomechanical characteristics such as center of pressure (CoP) and center of mass (CoM) motion. This systematic review was conducted according to PRISMA guidelines. Databases including Scopus, PubMed, CINHAL, Trip PRO, Cochrane, and Otseeker databases were searched for publications on the use of wearable sensors combined with ML to predict biomechanical characteristics. Fourteen publications met the inclusion criteria and were included in this review. From each publication, information on study characteristics, testing conditions, ML models applied, estimated biomechanical characteristics, and sensor positions were extracted. Additionally, the study type, level of evidence, and Downs and Black scale score were reported to evaluate methodological quality and bias. Most studies tested subjects during walking and utilized some type of neural network (NN) ML model to estimate biomechanical characteristics. Many of the studies focused on minimizing the necessary number of sensors and placed them on areas near or below the waist. Nearly all studies reporting RMSE and correlation coefficients had values <15% and >0.85, respectively, indicating strong ML model estimation accuracy. Overall, this review can help guide the future development of ML algorithms and wearable sensor technologies to estimate postural mechanics. Full article
(This article belongs to the Section Wearables)
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<p>Pyramid for artificial intelligence scientific evidence [<a href="#B24-sensors-24-07280" class="html-bibr">24</a>]. <span class="html-italic">Adapted from</span> “<span class="html-italic">The artificial intelligence evidence-based medicine pyramid,” by Bellini, V., et al., 2023, World J Crit Care Med, 2023. 12(2): p. 89–91. Copyright 2023. Reprinted with permission</span>.</p>
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<p>PRISMA flow diagram.</p>
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<p>Summary of the different ML models applied in the reviewed studies.</p>
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<p>Sensor placement locations and the percentage of studies included in this review that consider each position (percentages are based on counts of studies that included that specific sensor location and may not add up to 100%).</p>
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<p>Wearable sensor characteristics.</p>
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20 pages, 4790 KiB  
Article
Development and Quality Enhancement of Fried Fish Cake Prototype with Transglutaminase, Trehalose, and Herbal Oil for Room Temperature Distribution
by Ye Youl Kim, Khawaja Muhammad Imran Bashir, Seonyeong Kang, Yongjoon Park, Jae Hak Sohn and Jae-Suk Choi
Gels 2024, 10(11), 740; https://doi.org/10.3390/gels10110740 - 14 Nov 2024
Viewed by 284
Abstract
This study focuses on developing a fried fish cake prototype with improved quality and extended shelf-life, enabling room-temperature distribution through an innovative high-temperature and high-process retort method. Surimi-based products typically necessitate cold storage and a refrigerated distribution system, affecting their physical properties and [...] Read more.
This study focuses on developing a fried fish cake prototype with improved quality and extended shelf-life, enabling room-temperature distribution through an innovative high-temperature and high-process retort method. Surimi-based products typically necessitate cold storage and a refrigerated distribution system, affecting their physical properties and flavor while escalating costs. By incorporating Transglutaminase (TGase), trehalose, and herbal oils, and optimizing the heating process using the response surface methodology, this research addresses challenges related to changes in physical properties, color, and off-flavors during high-temperature and high-pressure treatment. The addition of 0.37% ACTIVA-K TGase significantly enhanced gel strength by promoting protein cross-linking, while 0.75% trehalose improved color stability by suppressing browning, thus enhancing visual appeal. A 0.1% concentration of bay oil effectively enhanced the flavor profile by masking undesirable odors without compromising the sensory quality. Optimized processing conditions maximized DPPH radical scavenging activity, whiteness, and gel strength, ensuring superior product quality and safety. Nutritional analysis confirmed a balanced composition of moisture, protein, essential amino acids, and minerals, in accordance with Korean national standards for acid values. Microstructural examination revealed a uniform network structure, contributing to excellent texture and sensory evaluations. Shelf-life predictions indicated a storage duration of approximately 19 months, surpassing commercially available products and offering a competitive edge. This novel approach allows surimi-based products to be stored and distributed at room temperature, while also providing the potential for increased profitability. Full article
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<p>Three-dimensional response surface graph illustrating the correlation between independent variables (X1, X2, and X3) and dependent variables (Y1, Y2, and Y3). X1: Amount of antioxidant added (%); X2: Temperature conditions during the high-temperature and high-pressure treatment process (°C); X3: Time conditions in the high-temperature and high-pressure treatment process (min); Y1: DPPH (%); Y2: Whiteness; Y3: Gel strength (g × cm).</p>
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<p>Protein distribution pattern in the developed fried fish cake prototype and the controls observed by SDS-PAGE. M: Molecular weight marker; A: Control 1; B: Control 2; C: Control 3; D: Developed fried fish cake prototype.</p>
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<p>Scanning electron microscope results of controls and the developed fried fish cake prototype (Photo magnification: ×400).</p>
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20 pages, 5340 KiB  
Article
Parameter Analysis of Anion Exchange Membrane Water Electrolysis System by Numerical Simulation
by Shing-Cheng Chang, Ru-En Gu and Yen-Hsin Chan
Energies 2024, 17(22), 5682; https://doi.org/10.3390/en17225682 - 13 Nov 2024
Viewed by 383
Abstract
Anion exchange membrane electrolysis, which combines the advantages of both alkaline electrolysis and proton-exchange membrane electrolysis, is a promising technology to reduce the cost of hydrogen production. The present work focused on the study of the electrochemical phenomena of AEM electrolysis and the [...] Read more.
Anion exchange membrane electrolysis, which combines the advantages of both alkaline electrolysis and proton-exchange membrane electrolysis, is a promising technology to reduce the cost of hydrogen production. The present work focused on the study of the electrochemical phenomena of AEM electrolysis and the investigation of the key factors of the AEM hydrogen production system. The numerical model is established according to electrochemical reactions, polarization phenomena, and the power consumption of the balance of plant components of the system. The effects of operation parameters, including the temperature and hydrogen pressure of the electrolyzer, electrolyte concentration, and hydrogen supply pressure on the energy efficiency are studied. The basic electrochemical phenomena of AEM water electrolysis cells are analyzed by simulations of reversible potential and activation, and ohmic and concentration polarizations. The results reveal that increasing the operating temperature and hydrogen production pressure of the AEM electrolyzer has positive effects on the system’s efficiency. By conducting an optimization analysis of the electrolyzer temperature—which uses the heat energy generated by the electrochemical reaction of the electrolyzer to minimize the power consumption of the electrolyte pump and heater—the AEM system with an electrolyzer operating at 328 K and 30 bar can deliver hydrogen of pressure up to 200 bar under an energy efficiency of 56.4%. Full article
(This article belongs to the Section A5: Hydrogen Energy)
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<p>Schematic diagram of the AEM water electrolysis system.</p>
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<p>Polarization phenomena on AEM water electrolysis.</p>
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<p>Temperature effects on the polarization phenomena: (<b>a</b>) activation polarization; (<b>b</b>) ohmic polarization; and (<b>c</b>) concentration polarization.</p>
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<p>Temperature effects on the performance of AEM water electrolysis.</p>
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<p>Pressure effects on the polarization phenomena: (<b>a</b>) activation polarization; (<b>b</b>) ohmic polarization; and (<b>c</b>) concentration polarization.</p>
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<p>Pressure effects on the polarization phenomena: (<b>a</b>) activation polarization; (<b>b</b>) ohmic polarization; and (<b>c</b>) concentration polarization.</p>
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<p>Temperature effects on the performance of AEM water electrolysis.</p>
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<p>Electrolyte concentration effects on the polarization phenomena: (<b>a</b>) activation polarization; (<b>b</b>) ohmic polarization; and (<b>c</b>) concentration polarization.</p>
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<p>Electrolyte concentration effects on the polarization phenomena: (<b>a</b>) activation polarization; (<b>b</b>) ohmic polarization; and (<b>c</b>) concentration polarization.</p>
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<p>Electrolyte concentration effects on the performance of AEM water electrolysis.</p>
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<p>Energy efficiency of AEM system for 30 bar hydrogen supply.</p>
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<p>Energy efficiency of AEM system for 200 bar hydrogen supply.</p>
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<p>Energy efficiency of AEM system for 30–200 bar hydrogen supply with hydrogen production pressure of 1–30 bar.</p>
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<p>Energy efficiency of AEM system with hydrogen production pressure at 1 bar/30 bar applying for 30–200 bar hydrogen supply.</p>
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<p>Optimum operating temperature analysis of AEM system at hydrogen production pressure of 30 bar applied for 30–200 bar hydrogen supply.</p>
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17 pages, 2180 KiB  
Article
The Role of Benthic TA and DIC Fluxes on Carbon Sequestration in Seagrass Meadows of Dongsha Island
by Lan-Feng Fan, En-Cheng Kang, Mariche B. Natividad, Chin-Chang Hung, Yung-Yen Shih, Wei-Jen Huang and Wen-Chen Chou
J. Mar. Sci. Eng. 2024, 12(11), 2061; https://doi.org/10.3390/jmse12112061 - 13 Nov 2024
Viewed by 568
Abstract
Coastal blue carbon ecosystems sequester carbon, storing it as plant biomass and particulate organic matter in sediments. Recent studies emphasize the importance of incorporating dissolved inorganic and organic forms into carbon assessments. As sediment-stored organic matter decomposes, it releases dissolved inorganic carbon (DIC) [...] Read more.
Coastal blue carbon ecosystems sequester carbon, storing it as plant biomass and particulate organic matter in sediments. Recent studies emphasize the importance of incorporating dissolved inorganic and organic forms into carbon assessments. As sediment-stored organic matter decomposes, it releases dissolved inorganic carbon (DIC) and total alkalinity (TA), both of which are critical for regulating the partial pressure of CO2 (pCO2) and thus carbon sequestration. This study investigated the role of benthic DIC and TA fluxes in carbon sequestration within seagrass meadows in Dongsha Island’s inner lagoon (IL) during the winter and summer seasons. Chamber incubation experiments revealed elevated benthic DIC and TA fluxes compared to global averages (107 ± 75.9 to 119 ± 144 vs. 1.3 ± 1.06 mmol m−2 d−1 for DIC, and 69.7 ± 40.7 to 75.8 ± 81.5 vs. 0.52 ± 0.43 mmol m−2 d−1 for TA). Despite DIC fluxes being approximately 1.5 times higher than TA fluxes, water pCO2 levels remained low (149 ± 26 to 156 ± 18 µatm). Mass balance calculations further indicated that benthic DIC was predominantly reabsorbed into plant biomass through photosynthesis (−135 to −128 mmol m−2 d−1). Conversely, TA accumulated in the water and was largely exported (−60.3 to −53.7 mmol m−2 d−1), demonstrating natural ocean alkalinity enhancement (OAE). This study highlights the crucial role of IL seagrass meadows in coastal carbon sequestration through net autotrophy and carbonate dissolution. Future research should explore the global implications of these processes and assess the potential of natural OAE in other coastal blue carbon ecosystems. Full article
(This article belongs to the Section Chemical Oceanography)
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<p>Geographical map showing the locations of Dongsha Atoll, Dongsha Island, and the designated sampling sites around Dongsha Island (upper panels). The lower panels include photographs of the seagrass meadow on the southern shore (SS) and the chamber incubation setup in the seagrass meadow of the inner lagoon (IL).</p>
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<p>Time-series observations of water depth (<b>A1</b>–<b>A4</b>), temperature (<b>B1</b>–<b>B4</b>), salinity (<b>C1</b>–<b>C4</b>), and DO (<b>D1</b>,<b>D2</b>) at the southern shore (SS, red squares) and inner lagoon (IL, blue circles) of Dongsha Island during summer (solid symbols) and winter (open symbols). Solid black lines in A1 to A4 represent trends predicted from the 2021 Tide Tables.</p>
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<p>Daily variations in pH (<b>A1</b>–<b>A4</b>) at 25 °C, <span class="html-italic">p</span>CO<sub>2</sub> in situ (<b>B1</b>–<b>B4</b>), DIC (<b>C1</b>–<b>C4</b>) and TA (<b>D1</b>,<b>D2</b>) at the southern shore (SS, red squares) and inner lagoon (IL, blue circles) of Dongsha Island during summer (solid symbols) and winter (open symbols). The horizontal dashed lines in panels (<b>A1</b>–<b>A4</b>,<b>B1</b>–<b>B4</b>) represent the average pH in the open northern South China Sea (8.1, Chou et al. [<a href="#B46-jmse-12-02061" class="html-bibr">46</a>]) and the monthly average atmospheric <span class="html-italic">p</span>CO<sub>2</sub> (406 µatm, NOAA-ESRL MLO [<a href="#B47-jmse-12-02061" class="html-bibr">47</a>]), respectively.</p>
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<p>Vertical porewater profiles of pH (<b>A</b>), DIC (<b>B</b>), TA (<b>C</b>), Ω<sub>Ar</sub> (<b>D</b>), and Ca<sup>2+</sup> (<b>E</b>) at the southern shore (SS, red square) and inner lagoon (IL, blue circles) of Dongsha Island during summer (solid symbols) and winter (open symbols).</p>
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<p>Chamber incubation results showing pH at 25 °C (<b>A1</b>,<b>A2</b>), DIC (<b>B1</b>,<b>B2</b>), and TA (<b>C1</b>,<b>C2</b>) in the inner lagoon of Dongsha Island during winter (left, open symbols) and summer (right, solid symbols).</p>
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<p>Conceptual diagrams summarizing the mass balance (mmol m<sup>−2</sup> d<sup>−1</sup>) of dissolved inorganic carbon (DIC, 1) and total alkalinity (TA, 2) in the inner lagoon of Dongsha Island during winter (<b>A1</b>,<b>A2</b>) and summer (<b>B1</b>,<b>B2</b>). The water system dynamics (d(H DIC)/dt and d(H TA)/dt) are influenced by sediment emissions (F<sup>SEDI</sup>), air–sea CO<sub>2</sub> exchange (F<sup>GAS</sup>), lateral advection (F<sup>ADVH</sup>), and net biological community (NBC) effects. Positive values represent carbon fluxes into the lagoon, while negative values indicate carbon fluxes out of the lagoon.</p>
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<p>A conceptual diagram illustrating two different pathways for organic carbon cycles: one solely focused on the metabolic cycle (green title, enclosed by a green dashed line), where both DIC and TA budgets show a net-zero impact; the other coupled with carbonate dissolution and DIC reabsorption by the autotrophic activity of seagrasses (blue title), leading to elevated TA accumulation in the water column, which is largely advected out of the lagoon. This represents natural ocean alkalinity enhancement and contributes to more effective carbon sequestration. Under the blue title, for example, “DIC +1 &amp; TA +2” indicates that DIC increases by 1 unit and TA increases by 2 units when processes 1 and 4 are combined. We have noted this in the figure caption. “DIC +1 &amp; TA +2” under the blue title, for instance, indicates that DIC increases by 1 unit and TA by 2 units when processes 1 and 4 are combined. Changes in DIC and TA during other processes are expressed similarly.</p>
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29 pages, 3011 KiB  
Review
Sodium Chloride Cotransporter in Hypertension
by Annalisa Castagna, Gabriele Mango, Nicola Martinelli, Luigi Marzano, Sara Moruzzi, Simonetta Friso and Francesca Pizzolo
Biomedicines 2024, 12(11), 2580; https://doi.org/10.3390/biomedicines12112580 - 11 Nov 2024
Viewed by 772
Abstract
The sodium chloride cotransporter (NCC) is essential for electrolyte balance, blood pressure regulation, and pathophysiology of hypertension as it mediates the reabsorption of ultrafiltered sodium in the renal distal convoluted tubule. Given its pivotal role in the maintenance of extracellular fluid volume, the [...] Read more.
The sodium chloride cotransporter (NCC) is essential for electrolyte balance, blood pressure regulation, and pathophysiology of hypertension as it mediates the reabsorption of ultrafiltered sodium in the renal distal convoluted tubule. Given its pivotal role in the maintenance of extracellular fluid volume, the NCC is regulated by a complex network of cellular pathways, which eventually results in either its phosphorylation, enhancing sodium and chloride ion absorption from urines, or dephosphorylation and ubiquitination, which conversely decrease NCC activity. Several factors could influence NCC function, including genetic alterations, hormonal stimuli, and pharmacological treatments. The NCC’s central role is also highlighted by several abnormalities resulting from genetic mutations in its gene and consequently in its structure, leading to dysregulation of blood pressure control. In the last decade, among other improvements, the acquisition of knowledge on the NCC and other renal ion channels has been favored by studies on extracellular vesicles (EVs). Dietary sodium and potassium intake are also implicated in the tuning of NCC activity. In this narrative review, we present the main cornerstones and recent evidence related to NCC control, focusing on the context of blood pressure pathophysiology, and promising new therapeutical approaches. Full article
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<p>Sodium reabsorption along the nephron. Most of the sodium reabsorption occurs in the proximal tubule (pink) via NHE3, which mediates about 70% of the Na<sup>+</sup> transport, followed by NKCC2 in the thick ascending limb (green), which is responsible for 25%. About 5% of Na<sup>+</sup> reabsorption occurs in the distal tubule, which includes the distal convoluted tubule (purple) and the collecting duct (magenta). The NCC is located only in the proximal part of the distal convoluted tubule, while ENaC is present in both distal convoluted tubule and collecting duct. A representation of the NCC dimeric structure is also illustrated in the blow-up. Figure created in <a href="http://BioRender.com" target="_blank">BioRender.com</a> [<a href="#B6-biomedicines-12-02580" class="html-bibr">6</a>].</p>
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<p>Three-dimensional structure of the NCC dimer embedded in the apical cell membrane. This schematic representation highlights the functional domains of the transporter: (1) the extracellular domain (green); (2) the transmembrane domain (red); and (3) the cytosolic domain (blue). A close-up of one ion binding pocket, located within the transmembrane domain, shows three binding sites: one for Na<sup>+</sup> (magenta); one for Cl<sup>−</sup> (cyan); and one for polythiazide, a thiazide diuretic (yellow). The representation is based on the structural prediction provided by the Orientations of Proteins in Membranes (OPM) database [<a href="#B22-biomedicines-12-02580" class="html-bibr">22</a>] of the NCC inward-facing conformation obtained by Fan et al. [<a href="#B20-biomedicines-12-02580" class="html-bibr">20</a>] (PDB ID: 8FHO). PyMOL (Schrödinger, LLC) was used to visualize the structure and generate the image. Figure created in <a href="http://BioRender.com" target="_blank">BioRender.com</a> [<a href="#B6-biomedicines-12-02580" class="html-bibr">6</a>].</p>
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<p>Post-translational modifications regulating NCC activity in the DCT. NCC phosphorylation (yellow) is primarily mediated by the WNK-SPAK/OSR1 kinase cascade. WNK1 and WNK4 (with-no-lysine kinases) activate SPAK (STE20/SPS1-related proline/alanine-rich kinase) and OSR1 (oxidative stress-response protein 1), which, in turn, phosphorylate the NCC, increasing its transport activity in the apical membrane. WNK autophosphorylation is stimulated by low Cl<sup>−</sup> intracellular levels, which result from a decrease in K<sup>+</sup> intracellular concentration. These changes are, respectively, mediated by basolateral chlorine (light blue) and potassium channels (pink). Cab39 (calcium binding protein 39) is another regulator of NCC phosphorylation since it is required for SPAK activation. NCC dephosphorylation (red) leads to a reduction in its activity and is carried out by protein phosphatases PP1, PP3, and PP4. PP1 is regulated by protein phosphatase 1 inhibitor-1 (I-1) through the cAMP/PKA pathway. A rise in cAMP levels activates PKA (protein kinase A), which phosphorylates I-1, preventing PP1 from dephosphorylating the NCC. Ubiquitination (purple) is another key regulatory mechanism that affects NCC function. WNK abundance is controlled by an E3 ubiquitin ligase complex composed of KLHL3 (Kelch-like protein 3) and CUL3 (Cullin 3). This complex tags the NCC with ubiquitin (Ub), marking it for proteasomal degradation. KLHL3 acts as adapter for WNK, and its phosphorylation prevents this binding. PP3 is responsible for KLHL3 activation through dephosphorylation. Additionally, NEDD4-2, another ubiquitin ligase, directly mediates NCC degradation through ubiquitination. Figure created in <a href="http://BioRender.com" target="_blank">BioRender.com</a> [<a href="#B6-biomedicines-12-02580" class="html-bibr">6</a>].</p>
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<p>Physiological stimuli that modulate NCC activity. The key signaling pathways involved in NCC regulation by various hormones are illustrated. Arginine vasopressin (AVP, blue) binds to the V<sub>2</sub> receptor (V<sub>2</sub>R) on the basolateral membrane, activating adenylate cyclase 6 (AC6), which increases cyclic AMP (cAMP) levels. Elevated cAMP stimulates protein kinase A (PKA), leading to: (a) stimulation of WNK-SPAK/OSR1-NCC cascade through WNK kinase phosphorylation; (b) inhibition of protein phosphatase 1 (PP1) by phosphorylating its inhibitor, I-1, maintaining the phosphorylated state of the NCC; (c) phosphorylation and inactivation of Kelch-like protein 3 (KLHL3), diminishing WNK ubiquitination and consequent degradation. Aldosterone (ALDO, orange) enhances the NCC in both a mineralocorticoid receptor (MR)-dependent and MR-independent manner. Binding to MR, it could stimulate serum- and glucocorticoid-regulated kinase 1 (SGK1), which activates WNKs and simultaneously inhibits NEDD4-2-mediated ubiquitination. On the other hand, aldosterone stimulates ENaC-mediated potassium secretion, eventually inducing hypokalemia. Low extracellular K<sup>+</sup> levels are sensed by DCT cells through Kir4.1/Kir5.1 K<sup>+</sup> channels, which, once active, lead to a drop in K<sup>+</sup> intracellular concentration, stimulating basolateral Cl<sup>−</sup> transport through ClC-Kb. A decrease in intracellular Cl<sup>−</sup> levels releases the inhibition of WNK kinases, enabling their autophosphorylation and thus stimulating WNK-SPAK/OSR1-NCC pathway. Cortisol (CORT, red) may exert the same effect as aldosterone, likely through the interaction with the glucocorticoid receptor (GR). Angiotensin II (ANGII, purple) binds to the angiotensin II type 1 receptor (AT1R), activating protein kinase C (PKC), which catalyzes both WNK and KLHL3 phosphorylation. Angiotensin II activates the NCC via AngII receptor type 1 (AT1R), stimulating the WNK4-SPAK kinase cascade and the phosphorylation of KLHL. Angiotensin II can also induce aldosterone and ENaC-mediated hypokalemia, thereby triggering potassium sensing through Kir4.1/Kir5.1 K<sup>+</sup> channels. Insulin (INS, green) activates the phosphoinositide 3-kinase (PI3K) pathway, leading to the activation of protein kinase B (AKT). AKT stimulates NCC activity through the phosphorylation of both WNK kinases and KLHL3. Figure created in <a href="http://BioRender.com" target="_blank">BioRender.com</a> [<a href="#B6-biomedicines-12-02580" class="html-bibr">6</a>].</p>
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<p>Pharmacological modulation of NCC function in the DCT. Inhibitors are shown in red, while enhancers are shown in light blue. Thiazide diuretics directly inhibit NCC blocking ion translocation, while mineralocorticoid receptor antagonists (MRA) act indirectly, blocking the MR-mediated effect of aldosterone. Loop diuretics (LD) activate the NCC, increasing the amount of sodium delivered to the DCT and the secretion of aldosterone, which increases NCC activity in both an MR-dependent and an MR-independent manner. Calcineurin inhibitors (CNI) decrease PP3-mediated dephosphorylation of NCC, basolateral K<sup>+</sup> channel, and KLHL3, thus stimulating NCC activity at various levels. Salbutamol (SALB) could activate basolateral K<sup>+</sup> channel through a signaling pathway likely mediated by β<sub>2</sub>-adrenergic receptor. A drop in K<sup>+</sup> intracellular concentration eventually triggers WNK-SPAK/OSR1-NCC cascade. SGLT2 inhibitors (SGLT2i, shown in purple) may influence NCC activity, increasing the delivery of glucose and fructose to the DCT and possibly stimulating a signaling pathway involving the calcium-sensing receptor (CaSR) and protein kinase C (PKC). Figure created in <a href="http://BioRender.com" target="_blank">BioRender.com</a> [<a href="#B6-biomedicines-12-02580" class="html-bibr">6</a>].</p>
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13 pages, 3818 KiB  
Article
Chalcopyrite CuFeS2: Solid-State Synthesis and Thermoelectric Properties
by Jin-Sol Kim and Il-Ho Kim
Materials 2024, 17(22), 5497; https://doi.org/10.3390/ma17225497 - 11 Nov 2024
Viewed by 402
Abstract
The optimal conditions for synthesizing a pure chalcopyrite CuFeS2 phase were thoroughly investigated through the combination of mechanical alloying (MA) and hot pressing (HP) processes. The MA process was performed at a rotational speed of 350 rpm for durations ranging from 6 [...] Read more.
The optimal conditions for synthesizing a pure chalcopyrite CuFeS2 phase were thoroughly investigated through the combination of mechanical alloying (MA) and hot pressing (HP) processes. The MA process was performed at a rotational speed of 350 rpm for durations ranging from 6 to 24 h under an Ar atmosphere, ensuring proper mixing and alloying of the starting materials. Afterward, MA-synthesized chalcopyrite powder was subjected to HP at temperatures between 723 K and 823 K under a pressure of 70 MPa for 2 h in a vacuum. This approach aimed to achieve phase consolidation and densification. A thermal analysis via differential scanning calorimetry (DSC) revealed distinct endothermic peaks at the range of 740–749 K and 1169–1170 K, corresponding to the synthesis of the chalcopyrite phase and its melting point, respectively. An X-ray diffraction (XRD) analysis confirmed the successful synthesis of the tetragonal chalcopyrite phase across all samples. However, a minor secondary phase, identified as Cu1.1Fe1.1S2 (talnakhite), was observed in the sample hot-pressed at the highest temperature of 823 K. This secondary phase could result from slight compositional deviations or local phase transformations at elevated temperatures. The thermoelectric properties of the CuFeS2 samples were evaluated as a function of the HP temperatures. As the HP temperature increased, the electrical conductivity exhibited a corresponding rise, likely due to enhanced densification and reduced grain boundary resistance. However, this increase in electrical conductivity was accompanied by a decrease in both the Seebeck coefficient and thermal conductivity. The reduction in the Seebeck coefficient could be attributed to the higher carrier concentration resulting from improved electrical conductivity, while the decrease in thermal conductivity was likely due to reduced phonon scattering facilitated by the grain boundaries. Among the samples, the one that was hot-pressed at 773 K displayed the most favorable thermoelectric performance. It achieved the highest power factor of 0.81 mWm−1K−1 at 523 K, indicating a good balance between the Seebeck coefficient and electrical conductivity. Additionally, this sample achieved a maximum figure-of-merit (ZT) of 0.32 at 723 K, a notable value for chalcopyrite-based thermoelectric materials, indicating its potential for mid-range temperature applications. Full article
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<p>Thermal analysis plots via (<b>a</b>) TG and (<b>b</b>) DSC of CuFeS<sub>2</sub> powders synthesized by MA.</p>
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<p>XRD patterns of CuFeS<sub>2</sub> powders synthesized using MA.</p>
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<p>XRD patterns of CuFeS<sub>2</sub> compacts prepared using the MA–HP process.</p>
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<p>SEM images of CuFeS<sub>2</sub> synthesized using the MA–HP process.</p>
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<p>EDS elemental analysis of HP823K2H specimen.</p>
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<p>Electrical conductivity of CuFeS<sub>2</sub> with different HP temperatures.</p>
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<p>Seebeck coefficient of CuFeS<sub>2</sub> with different HP temperatures.</p>
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<p>Power factor of CuFeS<sub>2</sub> with different HP temperatures.</p>
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<p>Thermal conductivity of CuFeS<sub>2</sub> with different HP temperatures.</p>
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<p>ZT values of CuFeS<sub>2</sub> with different HP temperatures.</p>
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12 pages, 1574 KiB  
Article
Proprioceptive Training Improves Postural Stability and Reduces Pain in Cervicogenic Headache Patients: A Randomized Clinical Trial
by Mohamed Abdelaziz Emam, Tibor Hortobágyi, András Attila Horváth, Salma Ragab and Magda Ramadan
J. Clin. Med. 2024, 13(22), 6777; https://doi.org/10.3390/jcm13226777 - 11 Nov 2024
Viewed by 469
Abstract
Background: Headache is one of the leading causes of disability in the world. Neck proprioception, pain, and postural control are interconnected in both healthy individuals and those with chronic neck pain. This study examines the effects of proprioceptive training using a gaze direction [...] Read more.
Background: Headache is one of the leading causes of disability in the world. Neck proprioception, pain, and postural control are interconnected in both healthy individuals and those with chronic neck pain. This study examines the effects of proprioceptive training using a gaze direction recognition task on postural stability and pain in cervicogenic headache patients. Methods: Patients with cervicogenic headache (n = 34, age: 35–49 y) were randomized into a control group (CON), receiving only selected physical therapy rehabilitation or to an experimental group (EXP), performing proprioceptive training using a gaze direction recognition task plus selected physical therapy rehabilitation. Both programs consisted of 24, 60 min long sessions over 8 weeks. Postural stability was assessed by the modified clinical test of sensory integration of balance (mCTSIB) and a center of pressure test (COP) using the HUMAC balance system. Neck pain was assessed by a visual analog scale. Results: In all six tests, there was a time main effect (p < 0.001). In three of the six tests, there were group by time interactions so that EXP vs. CON improved more in postural stability measured while standing on foam with eyes closed normalized to population norms, COP velocity, and headache (all p ≤ 0.006). There was an association between the percent changes in standing on foam with eyes closed normalized to population norms and percent changes in COP velocity (r = 0.48, p = 0.004, n = 34) and between percent changes in COP velocity and percent changes in headache (r = 0.44, p = 0.008, n = 34). Conclusions: While we did not examine the underlying mechanisms, proprioceptive training in the form of a gaze direction recognition task can improve selected measures of postural stability, standing balance, and pain in cervicogenic headache patients. Full article
(This article belongs to the Section Clinical Rehabilitation)
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<p>Flowchart of patient recruitment and study participation. This flowchart illustrates the number of patients screened, enrolled, and excluded at each stage of the study. It details the progression from initial recruitment through to final analysis, highlighting reasons for exclusion and the final sample sizes for the control (CON) and experimental (EXP) groups.</p>
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<p>Individual pre- and post-intervention data for six outcomes. Each symbol represents one patient. Intervention effects are shown for: (<b>A</b>) HSEO (hard surface, eyes open), (<b>B</b>) HSEC (hard surface, eyes closed), (<b>C</b>) SSEO (soft surface, eyes open), (<b>D</b>) SSEC (soft surface, eyes closed), (<b>E</b>) COP (center of pressure velocity, cm·s<sup>−1</sup>), and (<b>F</b>) VAS (visual analog scale of neck pain, mm). Units for (<b>A</b>–<b>D</b>) are % relative to population data. Pre = before intervention, Post = after intervention.</p>
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<p>(<b>A</b>) Percent changes in SSEC (soft surface, eyes closed) versus percent changes in COP velocity. (<b>B</b>) Percent changes in COP velocity versus percent changes in neck pain. In both panels, open symbols (n = 17) represent the control group, and filled symbols (n = 17) represent the ex-perimental group.</p>
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22 pages, 1236 KiB  
Article
Exploring the Impact of After-Hours Work Connectivity on Employee Performance: Insights from a Job Crafting Perspective
by Chuanhao Fan, Tianfeng Dong and Jiaxin Wang
Behav. Sci. 2024, 14(11), 1078; https://doi.org/10.3390/bs14111078 - 11 Nov 2024
Viewed by 476
Abstract
With the leapfrog development of information and communication technology and the intensification of external competition among enterprises, after-hours work connectivity through communication devices has become a new norm in the workplace. While it offers certain conveniences, the constant connectivity it entails also imposes [...] Read more.
With the leapfrog development of information and communication technology and the intensification of external competition among enterprises, after-hours work connectivity through communication devices has become a new norm in the workplace. While it offers certain conveniences, the constant connectivity it entails also imposes significant pressure on employees. How to comprehensively understand and rationally treat after-hours work connectivity has become an issue that organizations need to pay great attention to. Based on conservation of resources theory, this study analyzed 407 questionnaires to explore the “double-edged sword” effect of after-hours work connectivity on employee performance and analyzed the moderating effect of the psychological contract. The results indicate the following: (1) Proactive pathway: after-hours work connectivity promotes employees’ job crafting behaviors toward approach-oriented adjustments, thereby enhancing job performance. (2) Passive pathway: after-hours work connectivity encourages employees’ job crafting behaviors toward avoidance-oriented adjustments, leading to decreased job performance. (3) The psychological contract positively moderates the relationship between after-hours work connectivity and approach-oriented job crafting and negatively moderates the relationship between after-hours work connectivity and avoidance-oriented job crafting, regulating both the positive and negative coping pathways. The research findings contribute to assisting organizations in adopting a dialectical perspective towards and effectively utilizing after-hours work connectivity. This aids in achieving a balance between organizational effectiveness and employee well-being, seeking a mutually beneficial work paradigm, and providing managerial recommendations to promote sustainable organizational development. Full article
(This article belongs to the Section Organizational Behaviors)
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<p>Theoretical model diagram.</p>
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<p>Path analysis results. *** <span class="html-italic">p</span> &lt; 0.001, ** <span class="html-italic">p</span> &lt; 0.01.</p>
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<p>Map of the moderating effect of the psychological contract.</p>
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<p>Map of the moderating effect of the psychological contract.</p>
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13 pages, 239 KiB  
Article
Balance Ability Characteristics and Related Factors in Athletes Across Different Sports: A Preliminary Study
by Yasuhiro Suzuki, Yukiyo Shimizu, Kazushi Maruo, Takumi Tsubaki, Yuuki Tanabe and Yasushi Hada
Healthcare 2024, 12(22), 2240; https://doi.org/10.3390/healthcare12222240 - 11 Nov 2024
Viewed by 547
Abstract
Background: We conducted a cross-sectional study to examine two-leg- and one-leg-type balance characteristics in athletes and explore factors related to their balance ability. Methods: A total of 213 participants, including athletes from various sports (gymnastics, boat racing, swimming, soccer, judo, and baseball) and [...] Read more.
Background: We conducted a cross-sectional study to examine two-leg- and one-leg-type balance characteristics in athletes and explore factors related to their balance ability. Methods: A total of 213 participants, including athletes from various sports (gymnastics, boat racing, swimming, soccer, judo, and baseball) and non-athletes, were included (142 men, 71 women, average age 21.5 ± 2.1 years). Balance ability was classified into two-leg and one-leg types using the modified index of postural stability (mIPS) in a two-leg stance and the one-legged stance duration with eyes closed (OLS). Body composition, upper and lower limb strength, and lower limb sensation were also measured. To examine the balance characteristics of each sport, the mIPS and OLS were used as dependent variables in a multiple regression model with age, height, weight, and sex as independent variables. Results: The results showed a significantly higher mIPS in gymnastics (estimate: 0.22) and boat racing (0.14), and it was lower in swimming (−0.25). The OLS was significantly higher in soccer (16.98), judo (16.23), gymnastics (9.77), and baseball (9.12) and significantly lower in swimming (7.93). Additionally, the mIPS was independently associated with knee extension strength (0.12), sensory motor variables (−0.004), and height (−0.01). The OLS was associated with skeletal muscle mass (1.85) and height (−1.42). Conclusions: In summary, gymnasts showed superior two-leg and one-leg balance; boat racers excelled in two-leg balance; swimmers showed inferior two-leg but better one-leg balance; and soccer, judo, and baseball athletes demonstrated superior one-leg balance. Additionally, the mIPS was associated with knee extensor strength, plantar pressure sensation, and height, whereas the OLS was associated with skeletal muscle mass and height. Full article
20 pages, 23698 KiB  
Article
Application of Capillary Barrier Systems for Slope Stabilization Under Extreme Rainfall: A Case Study of National Highway 10, India
by Yusen Cheng and Yangyang Li
Infrastructures 2024, 9(11), 201; https://doi.org/10.3390/infrastructures9110201 - 10 Nov 2024
Viewed by 557
Abstract
Global warming has led to an increase in extreme rainfall events, which often result in landslides, posing significant threats to infrastructure and human life. This study evaluated the effectiveness of the Capillary Barrier System (CBS) in enhancing slope stability along a vulnerable section [...] Read more.
Global warming has led to an increase in extreme rainfall events, which often result in landslides, posing significant threats to infrastructure and human life. This study evaluated the effectiveness of the Capillary Barrier System (CBS) in enhancing slope stability along a vulnerable section of India’s National Highway 10 (NH10) during maximum daily rainfall. The GEOtop model was employed to conduct water balance simulations and obtain the pore–water pressure (PWP), which was then used to calculate the Factor of Safety (FoS). Results showed that CBS effectively delayed the rise in PWP, leading to lower peak values and smaller areas of very high and high risk levels. Spatial distribution mapping further confirmed that CBS minimized very high risk zones. At three historical landslide points, CBS slopes generally maintained FoS values above 1, demonstrating enhanced stability and improved resilience to extreme rainfall. These findings highlight the potential of CBS as a viable strategy for slope reinforcement in regions susceptible to heavy rainfall. Full article
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<p>Overview of the study area. (<b>a</b>) The full extent of India’s NH10. (<b>b</b>) Study section of NH10 with a 3 km buffer zone.</p>
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<p>Maps used in GEOtop modeling: (<b>a</b>) DEM; (<b>b</b>) slope angle; (<b>c</b>) aspect.</p>
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<p>Curve fitting for residual soil: conversion from the Gardner equation to the Van Genuchten equation.</p>
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<p>Curve fitting for CBS: conversion from the Fredlund and Xing equation to the Van Genuchten equation. (<b>a</b>). Fine−grained soil. (<b>b</b>). Coarse−grained soil.</p>
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<p>Schematic diagrams of the original slope and CBS slope. The red dots indicate the center of each layer where the PWP values are calculated. (<b>a</b>). Original slope with eight residual soil layers. (<b>b</b>). CBS slope with fine− and coarse−grained soil layers in the top three layers.</p>
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<p>The workflow of the GEOtop model.</p>
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<p>Variations in the average PWP for the original and CBS slopes at various depths.</p>
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<p>Variations in the percentage of pixels for each risk category between the original slope and CBS slope at various depths. (<b>a</b>). Very high risk. (<b>b</b>). High risk. (<b>c</b>). Moderate risk. (<b>d</b>). Low risk.</p>
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<p>Risk distribution at a depth of 0.8 m for original slope and CBS slope at different rainfall stages.</p>
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<p>The location of each landslide point.</p>
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<p>Variations in the FoS for each landslide point. (<b>a</b>). North point. (<b>b</b>). Central point. (<b>c</b>). South point.</p>
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<p>Risk distribution at a depth of 1.25 m for the original slope and CBS slope at different rainfall stages.</p>
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<p>Risk distribution at a depth of 1.75 m for the original slope and CBS slope at different rainfall stages.</p>
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13 pages, 1830 KiB  
Article
Light Clenching Differentially Affects Balance Ability According to Occlusal Contact Stability
by Mutsumi Takahashi, Yogetsu Bando, Takuya Fukui and Masaaki Sugita
Appl. Sci. 2024, 14(22), 10314; https://doi.org/10.3390/app142210314 - 9 Nov 2024
Viewed by 560
Abstract
Objectives: The purpose of this study was to determine the stability of occlusal contacts based on the left–right distribution of the occlusal contact area, divide participants into well-balanced and unbalanced groups, and clarify the effect of light clenching on the balance ability. Methods: [...] Read more.
Objectives: The purpose of this study was to determine the stability of occlusal contacts based on the left–right distribution of the occlusal contact area, divide participants into well-balanced and unbalanced groups, and clarify the effect of light clenching on the balance ability. Methods: Forty-one healthy men completed occlusal contact examinations with pressure-sensitive films, and the participants were allocated to the balanced occlusal contact (BOC) group or the unbalanced occlusal contact (UOC) group. The balance ability was measured using a center of gravity sway meter. The static balance in standing and dynamic balance using the cross test were assessed. Measurements were performed in the mandibular rest position (RP) or with light clenching (LC). Differences in the balance ability between the participant groups due to clenching and correlations between the static and dynamic balance were analyzed. Results: Differences in the balance ability due to clenching were observed only in the BOC group, with the static balance higher with LC, and the dynamic balance higher in the RP condition (p < 0.01). Significant correlations were observed between the static and dynamic balance except for the UOC group with LC (p < 0.01, p < 0.05). Conclusions: The results of this study suggested that occlusion affects the postural control when occlusal contact is stable but does not affect the postural control when occlusal contact is unstable. Full article
(This article belongs to the Special Issue Orthodontics and Maxillofacial Surgery)
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<p>Research design flowchart.</p>
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<p>Analysis results of occlusal contact state. The arrows indicate the left–right distribution of occlusal contact area (%). (<b>A</b>) Example of a result from a participant that was allocated to the balanced occlusal contact (BOC) group. (<b>B</b>) Example of a result from a participant that was allocated to the unbalanced occlusal contact (UOC) group.</p>
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<p>Comparison of the outer peripheral area (ENV-area) by occlusal balance and clenching. Measurements are expressed as means ± SD. Error bars indicate standard error of the mean. BOC: balanced occlusal contact group, UOC: unbalanced occlusal contact group, RP: mandibular rest position, LC: light clenching. ** <span class="html-italic">p</span> &lt; 0.01: denotes statistically significant difference.</p>
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<p>Comparison of the length of locus per unit area (LNG/E-area) by occlusal balance and clenching. Measurements are expressed as means ± SD. Error bar indicates standard error of the mean. BOC: balanced occlusal contact group, UOC: unbalanced occlusal contact group, RP: mandibular rest position, LC: light clenching. ** <span class="html-italic">p</span> &lt; 0.01: denotes statistically significant difference.</p>
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<p>Comparison of the rectangular area (REC-area) by occlusal balance and clenching. Measurements are expressed as means ± SD. Error bars indicate standard error of the mean. BOC: balanced occlusal contact group, UOC: unbalanced occlusal contact group, RP: mandibular rest position, LC: light clenching. ** <span class="html-italic">p</span> &lt; 0.01: denotes statistically significant difference.</p>
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<p>Correlation between static and dynamic balance in the balanced occlusal contact group (BOC). (<b>A</b>,<b>B</b>) Condition of mandibular rest position (RP), (<b>C</b>,<b>D</b>) condition of light clenching (LC). REC-area: rectangular area, ENV-area: outer peripheral area, LNG/E-area: length of locus per unit area.</p>
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<p>Correlation between static and dynamic balance in the unbalanced occlusal contact group (UOC). (<b>A</b>,<b>B</b>) Condition of mandibular rest position (RP), (<b>C</b>,<b>D</b>) condition of light clenching (LC). REC-area: rectangular area, ENV-area: outer peripheral area, LNG/E-area: length of locus per unit area.</p>
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