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20 pages, 3533 KiB  
Article
Experimenting with Sustainable Hospitality: A Life Cycle Assessment Analysis of the Set-Up Phase of a Public Hostel in Italy
by Aysegul Gungor and Rossella Moscarelli
Tour. Hosp. 2025, 6(1), 40; https://doi.org/10.3390/tourhosp6010040 (registering DOI) - 3 Mar 2025
Abstract
This paper investigates a sustainable proposal for tourist hospitality. It presents a Life Cycle Assessment (LCA) analysis to evaluate the set-up phase of a new hostel by comparing two different scenarios of interior design: one with new furniture and another with reused furniture [...] Read more.
This paper investigates a sustainable proposal for tourist hospitality. It presents a Life Cycle Assessment (LCA) analysis to evaluate the set-up phase of a new hostel by comparing two different scenarios of interior design: one with new furniture and another with reused furniture (collected thanks to the involvement of the local community). This LCA analysis is applied to the case of a public hostel located in a small village along the Italian VENTO cycleway. By focusing on the reuse of existing structures and objects, rather than constructing or producing new ones, the study aims to explore environmentally conscious hospitality, which can also include positive social impacts. The results of the analysis also demonstrate the relevance of applying sustainable practices during the setting-up phase of the hospitality building, enlarging the usual approach that is more dedicated to the “using” phase (concerning the energy savings in heating and cooling or the reduction in plastic waste, the laundering of towels and bedding, and the single-use of personal care products). Full article
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<p>Map of the VENTO cycleway (700 km, Venice–Turin), highlighting the location of Castelnuovo Bocca d’Adda. Source: Elaborated by the authors, inspired by the study conducted by the VENTO research team from the Department of Architecture and Urban Studies (DAStU) at Politecnico di Milano.</p>
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<p>Location of Casa Peroni in Castelnuovo Bocca d’Adda, near the VENTO cycleway. Source: Elaborated by the authors.</p>
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<p>Life cycle representation illustrating the emissions associated with new furniture production (Scenario 1) and reused furniture (Scenario 2). Source: Elaborated by the authors, inspired by the study conducted by (<a href="#B41-tourismhosp-06-00040" class="html-bibr">Hrafnkelsdóttir, 2022</a>).</p>
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<p>Repurposing of Casa Peroni (red frame): (<b>a</b>) existing state (2022), (<b>b</b>) construction phase (2024), (<b>c</b>) final state (anticipated 2025) Source: elaborated from photos (<b>a</b>,<b>b</b>) by Piùlento; the render (<b>c</b>) was elaborated by Piùlento.</p>
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<p>Final layout with furniture arrangement: (<b>a</b>) ground floor plan with (1) technical room, (2) entrance and reception area, (3) shared bathroom, (4) 8-person accommodation unit; (<b>b</b>) first floor plan with (5) multipurpose open plan space, (6) 2-person accommodation unit, (7) 3-person accommodation unit. Source: Elaborated by the authors based on projects by “Ingegneria Locatelli” (Villa d’Almè—BG).</p>
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23 pages, 4717 KiB  
Article
Evaluation of the Self-Weight Consolidation of Clay-Rich High Water Content Slurries in a Benchtop Centrifuge
by Mahmoud Ahmed, Nicholas A. Beier and Heather Kaminsky
Geotechnics 2025, 5(1), 18; https://doi.org/10.3390/geotechnics5010018 (registering DOI) - 3 Mar 2025
Abstract
Oil sands tailings consist of a combination of sand, fine particles, water, and residual unextracted bitumen in varying ratios. The management of these mine waste tailings is largely influenced by their consolidation behavior. Large strain consolidation testing, such as the multi-step large strain [...] Read more.
Oil sands tailings consist of a combination of sand, fine particles, water, and residual unextracted bitumen in varying ratios. The management of these mine waste tailings is largely influenced by their consolidation behavior. Large strain consolidation testing, such as the multi-step large strain consolidation (MLSC) test, is commonly used to determine consolidation properties but requires considerable time. A benchtop centrifuge (BTC) apparatus was proposed to derive the consolidation parameters of the following three clay-rich oil sands tailings slurries: two samples of high-plasticity fluid fine tailings (FFT) and one of low-plasticity FFT. Comparison with the MLSC tests illustrates that the BTC-derived compressibility data closely matched the MLSC test’s compressibility curve within the BTC stress range. However, the hydraulic conductivity from the BTC test was an order of magnitude higher than that from the MLSC test. The consistency of the BTC method and the validation of scaling laws were confirmed through modeling-of-models tests, showing a consistent average void ratio regardless of the specimen height or gravity scale. The influence of the small radius of the BTC was found to be minimal. The limitations of the BTC in the physical modeling of the consolidation behavior are discussed and their impact on the interpretation of the observed consolidation behavior is addressed. Overall, the BTC test provides a rapid method to gain insight on high-water-content slurries’ large strain consolidation behavior. Full article
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<p>(<b>a</b>) Particle size distribution of the three oil sands tailings and (<b>b</b>) the Casagrande plasticity chart for all tailings samples.</p>
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<p>(<b>a</b>) Beckman Coulter Avanti<sup>®</sup> J-26XP centrifuge, (<b>b</b>) Beckman Coulter JS-4.3 rotor with sample bottles installed, and (<b>c</b>) BTC sample bottle filled with tailings (5.8 cm internal diameter).</p>
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<p>Determination of the initial settlement rate for one solid content of the tested samples.</p>
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<p>Matching the consolidation curve from FSCA numerical simulations with the curve derived from centrifuge modeling: (<b>a</b>) fitting power law function to the final void ratio–effective stress distribution and (<b>b</b>) fitting the FFT-91-10.8 numerical simulation interface height curve with the BTC modeling curve.</p>
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<p>Average void ratio vs. prototype elapsed time from the modeling-of-model tests: (<b>a</b>) FFT-91-10.8 and (<b>b</b>) FFT-71-5.8.</p>
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<p>Benchtop centrifuge versus geotechnical beam centrifuge modeling results: (<b>a</b>) prototype height and (<b>b</b>) average void ratio.</p>
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<p>Temporal variation in the settlement interface height for one replicate: (<b>a</b>) FFT-91-10.8, (<b>b</b>) FFT-89-7.8, and (<b>c</b>) FFT-71-5.8.</p>
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<p>Experimental data of the BTC test: (<b>a</b>) compressibility and (<b>b</b>) hydraulic conductivity.</p>
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<p>Estimation of the consolidation parameters from one replicate: (<b>a</b>) compressibility curves from the index properties profile, (<b>b</b>) fitting the BTC-measured interface height to the FSCA numerical simulation, and (<b>c</b>) back-calculated hydraulic conductivity–void ratio relationships.</p>
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<p>Experimental data of the MLSC test: (<b>a</b>) compressibility and (<b>b</b>) hydraulic conductivity.</p>
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<p>MLSC vs. BTC compressibility results for the tested oil sands tailings: (<b>a</b>) FFT-91-10.8, (<b>b</b>) FFT-89-7.8, and (<b>c</b>) FFT-71-5.8.</p>
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<p>MLSC vs. BTC hydraulic conductivity results for the tested oil sands tailings: (<b>a</b>) FFT-91-10.8, (<b>b</b>) FFT-89-7.8, and (<b>c</b>) FFT-71-5.8.</p>
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17 pages, 9894 KiB  
Article
Real-Time Automatic Identification of Plastic Waste Streams for Advanced Waste Sorting Systems
by Robert Giel, Mateusz Fiedeń and Alicja Dąbrowska
Sustainability 2025, 17(5), 2157; https://doi.org/10.3390/su17052157 - 2 Mar 2025
Abstract
Despite the significant recycling potential, a massive generation of plastic waste is observed year after year. One of the causes of this phenomenon is the issue of ineffective waste stream sorting, primarily arising from the uncertainty in the composition of the waste stream. [...] Read more.
Despite the significant recycling potential, a massive generation of plastic waste is observed year after year. One of the causes of this phenomenon is the issue of ineffective waste stream sorting, primarily arising from the uncertainty in the composition of the waste stream. The recycling process cannot be carried out without the proper separation of different types of plastics from the waste stream. Current solutions in the field of automated waste stream identification rely on small-scale datasets that insufficiently reflect real-world conditions. For this reason, the article proposes a real-time identification model based on a CNN (convolutional neural network) and a newly constructed, self-built dataset. The model was evaluated in two stages. The first stage was based on the separated validation dataset, and the second was based on the developed test bench, a replica of the real system. The model was evaluated under laboratory conditions, with a strong emphasis on maximally reflecting real-world conditions. Once included in the sensor fusion, the proposed approach will provide full information on the characteristics of the waste stream, which will ultimately enable the efficient separation of plastic from the mixed stream. Improving this process will significantly support the United Nations’ 2030 Agenda for Sustainable Development. Full article
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<p>Scope of research in the context of the Digital Twin framework for waste-sorting systems.</p>
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<p>Architectural diagram of YOLOv5 [<a href="#B24-sustainability-17-02157" class="html-bibr">24</a>,<a href="#B25-sustainability-17-02157" class="html-bibr">25</a>,<a href="#B26-sustainability-17-02157" class="html-bibr">26</a>].</p>
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<p>Architecture of the proposed model for automatic waste stream identification based on YOLOv5.</p>
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<p>Main stages of dataset creation for automatic waste identification.</p>
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<p>Example of collected waste: (<b>a</b>) including only target objects; (<b>b</b>) including contaminants.</p>
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<p>Distribution of label locations for (<b>a</b>) basic dataset (for model 1a and 1b) and (<b>b</b>) extended dataset (for model 2).</p>
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<p>Scheme of the developed test bed.</p>
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<p>The developed test bed.</p>
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<p>The morphology of the Polish plastic waste stream compared to the morphology of the prepared sample.</p>
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<p>Progression of precision, recall, and mAP throughout the YOLOv5 training process (actual results with solid line and smoothed trend with dotted line) for (<b>a</b>) model 1a, (<b>b</b>) model 1b, and (<b>c</b>) model 2.</p>
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<p>Confusion matrices generated by the trained YOLO models: (<b>a</b>) model 1a, (<b>b</b>) model 1b, and (<b>c</b>) model 2.</p>
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<p>The visualization of the model’s performance under conditions replicating a real-world sorting facility (the red box shows detected HDPE, while the pink one – tetrapak).</p>
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28 pages, 8440 KiB  
Article
Feasibility Study of Biodegradable Vegetable Peels as Sustainable Fluid Loss Additives in Water-Based Drilling Fluids
by Olajide Ibrahim Oladipo, Foad Faraji, Hossein Habibi, Mardin Abdalqadir, Jagar A. Ali and Perk Lin Chong
J 2025, 8(1), 10; https://doi.org/10.3390/j8010010 - 1 Mar 2025
Viewed by 231
Abstract
Drilling fluids are vital in oil and gas well operations, ensuring borehole stability, cutting removal, and pressure control. However, fluid loss into formations during drilling can compromise formation integrity, alter permeability, and risk groundwater contamination. Water-based drilling fluids (WBDFs) are favored for their [...] Read more.
Drilling fluids are vital in oil and gas well operations, ensuring borehole stability, cutting removal, and pressure control. However, fluid loss into formations during drilling can compromise formation integrity, alter permeability, and risk groundwater contamination. Water-based drilling fluids (WBDFs) are favored for their environmental and cost-effective benefits but often require additives to address filtration and rheological limitations. This study explored the feasibility of using vegetable waste, including pumpkin peel (PP), courgette peel (CP), and butternut squash peel (BSP) in fine (75 μm) and very fine (10 μm) particle sizes as biodegradable WBDF additives. Waste vegetable peels were processed using ball milling and characterized via FTIR, TGA, and EDX. WBDFs, prepared per API SPEC 13A with 3 wt% of added additives, were tested for rheological and filtration properties. Results highlighted that very fine pumpkin peel powder (PP_10) was the most effective additive, reducing fluid loss and filter cake thickness by 43.5% and 50%, respectively. PP_10 WBDF maintained mud density, achieved a pH of 10.52 (preventing corrosion), and enhanced rheological properties, including a 50% rise in plastic viscosity and a 44.2% increase in gel strength. These findings demonstrate the remarkable potential of biodegradable vegetable peels as sustainable WBDF additives. Full article
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<p>Flowchart of procedural steps.</p>
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<p>Process flow diagram for the synthesis and characterization of biodegradable drilling fluid additives from vegetable peels.</p>
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<p>EDX analysis for (<b>a</b>) butternut squash peel, (<b>b</b>) courgette peel, (<b>c</b>) pumpkin peel, and FESEM analysis for (<b>d</b>) butternut squash peel, (<b>e</b>) courgette peel, and (<b>f</b>) pumpkin peel.</p>
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<p>FTIR analysis for (<b>a</b>) butternut squash peel, (<b>b</b>) courgette peel, and (<b>c</b>) pumpkin peel.</p>
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<p>TGA analysis for (<b>a</b>) butternut squash peel, (<b>b</b>) courgette peel, and (<b>c</b>) pumpkin peel.</p>
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<p>TGA analysis for (<b>a</b>) butternut squash peel, (<b>b</b>) courgette peel, and (<b>c</b>) pumpkin peel.</p>
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<p>Yield point, plastic viscosity, and apparent viscosity of base mud (BM) and biodegradable drilling fluids with vegetable peel additives at particle sizes (<b>a</b>) below 75 µm and (<b>b</b>) below 10 µm.</p>
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<p>Initial and final gel strength of BM and biodegradable drilling fluids with vegetable peel additives at particle sizes (<b>a</b>) below 75 µm and (<b>b</b>) below 10 µm.</p>
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<p>The relationship between shear strain rate and shear stress of (<b>a</b>) biodegradable pumpkin peel at 75 µm particle size, (<b>b</b>) biodegradable pumpkin peel at 10 µm particle size, (<b>c</b>) biodegradable butternut squash peel at 75 µm particle size, (<b>d</b>) biodegradable at butternut squash peel 10 µm at particle size, (<b>e</b>) biodegradable courgette peel at 75 µm particle size, and (<b>f</b>) biodegradable courgette peel at 10 µm particle size.</p>
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<p>The relationship between shear strain rate and shear stress of (<b>a</b>) biodegradable pumpkin peel at 75 µm particle size, (<b>b</b>) biodegradable pumpkin peel at 10 µm particle size, (<b>c</b>) biodegradable butternut squash peel at 75 µm particle size, (<b>d</b>) biodegradable at butternut squash peel 10 µm at particle size, (<b>e</b>) biodegradable courgette peel at 75 µm particle size, and (<b>f</b>) biodegradable courgette peel at 10 µm particle size.</p>
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<p>The relationship between shear strain rate and shear stress of (<b>a</b>) biodegradable pumpkin peel at 75 µm particle size, (<b>b</b>) biodegradable pumpkin peel at 10 µm particle size, (<b>c</b>) biodegradable butternut squash peel at 75 µm particle size, (<b>d</b>) biodegradable at butternut squash peel 10 µm at particle size, (<b>e</b>) biodegradable courgette peel at 75 µm particle size, and (<b>f</b>) biodegradable courgette peel at 10 µm particle size.</p>
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<p>(<b>a</b>) Viscosity and (<b>b</b>) shear stress as functions of shear rates of BM and biodegradable drilling fluids with vegetable peel additives at particle sizes below 75 µm and 10 µm.</p>
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<p>(<b>a</b>) Mud balance test, (<b>b</b>) pH analysis of BM, and biodegradable drilling fluids with vegetable peel additives at particle sizes below 75 µm and 10 µm.</p>
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<p>(<b>a</b>) Mud balance test, (<b>b</b>) pH analysis of BM, and biodegradable drilling fluids with vegetable peel additives at particle sizes below 75 µm and 10 µm.</p>
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<p>(<b>a</b>) Filtration rate over time, (<b>b</b>) filtration rate at 30 min of BM, and biodegradable drilling fluids with vegetable peel additives at particle sizes below 75 µm and 10 µm.</p>
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<p>Filter cakes thickness of BM and biodegradable drilling fluids with vegetable peel additives at particle sizes below 75 µm and 10 µm.</p>
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<p>Mechanism of filter cake formation on the borehole wall using BM and biodegradable drilling fluids with vegetable peel additives at particle sizes below 75 µm and 10 µm. The direction of the drilling mud during the operation is shown by the arrows.</p>
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17 pages, 1971 KiB  
Article
Evaluating Plastic Waste Management Strategies: Logistic Regression Insights on Pyrolysis vs. Recycling
by Dimitrios-Aristotelis Koumpakis, Christos Vlachokostas, Apostolos Tsakirakis and Savvas Petridis
Recycling 2025, 10(2), 33; https://doi.org/10.3390/recycling10020033 (registering DOI) - 1 Mar 2025
Viewed by 222
Abstract
The global plastic production total has risen to more than 400 million tons per year; this number is mainly driven by industrial appliances. In the EU, where the annual production is about 30 million tons, only 32% of plastic waste is recycled. Therefore, [...] Read more.
The global plastic production total has risen to more than 400 million tons per year; this number is mainly driven by industrial appliances. In the EU, where the annual production is about 30 million tons, only 32% of plastic waste is recycled. Therefore, a need for a robust and efficient waste management strategy has emerged. This study will introduce a novel logistic regression-based decision-making framework that focuses on the environment and the economy while also considering energy intensity and logistics. These factors reflect the use of Life Cycle Assessment (LCA) in this study, which is an approach that determines the selection of waste management strategies across different European countries. This study introduces a model with 94% sensitivity and 97% overall accuracy in order to compare pyrolysis and plastic waste recycling management methods. One of the main findings is the fact that pyrolysis demonstrated a maximum conversion efficiency of 88%; in comparison, the conversion efficiency for recycling was approximately 58%. Pyrolysis also generates by-products, such as syngas and pyrolytic oil, which are valuable. To conclude, this study is a tool for policymakers and industry leaders, so that they can make sustainable waste management decisions with data-driven and evidence-based reasoning. Full article
(This article belongs to the Special Issue Challenges and Opportunities in Plastic Waste Management)
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<p>Pyrolysis CO<sub>2</sub> emissions in recent years.</p>
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<p>Energy efficiency of pyrolysis.</p>
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<p>Waste conversion efficiency in recent years.</p>
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<p>Comparative results of scenarios in an EU context per percentage.</p>
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<p>Comparative results of scenarios in an EU context per ton of waste.</p>
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17 pages, 6220 KiB  
Article
Characterization of Morphological, Thermal, and Mechanical Performances and UV Ageing Degradation of Post-Consumer Recycled Polypropylene for Automotive Industries
by Matilde Arese, Beatrice Cavallo, Gabriele Ciaccio and Valentina Brunella
Materials 2025, 18(5), 1090; https://doi.org/10.3390/ma18051090 - 28 Feb 2025
Viewed by 168
Abstract
Considering the increasing use of plastics in vehicles, the need for sustainable management is becoming a matter of concern. The reintroduction of plastic originated from post-consumer waste in the vehicle manufacturing loop can also be a solution to meet the recent EU ELVs [...] Read more.
Considering the increasing use of plastics in vehicles, the need for sustainable management is becoming a matter of concern. The reintroduction of plastic originated from post-consumer waste in the vehicle manufacturing loop can also be a solution to meet the recent EU ELVs (end-of-life vehicles) legislation in terms of sustainability. This study focuses on post-consumer polypropylene (PP) compounds destined for automotive applications by assessing their morphological, thermal, and mechanical properties. Field Emission Scanning Electron Microscopy (FE-SEM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC) techniques were used. Since the ageing of these materials, caused by the thermo-oxidative degradation process, may compromise their performances, a comprehensive study of their behavior, in comparison to the virgin compound counterpart, was necessary to evaluate the fossil replacement possibility. Furthermore, an additional investigation was conducted after subjecting the materials to UV ageing in order to simulate the degradation effect of solar radiation, with the aim of determining the suitability of the recycled materials in long-term applications. In summary, the results support the feasibility of using recycled post-consumer materials mixed with virgin grade in automotive production, highlighting the stability of thermal and mechanical properties, critical for efficient manufacturing. This research underlines the noteworthy progress in the circularity of automotive plastics, providing a sustainable solution for integrating plastic material waste into new vehicle production. Full article
(This article belongs to the Section Polymeric Materials)
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<p>FE-SEM images of samples V-PP12 (<b>a</b>), R-PP12 (<b>b</b>), V-PP20 (<b>c</b>), and R-PP20 (<b>d</b>) after cryofracture in nitrogen, using SE detection. The white circles shown in the images were added to highlight the presence of small circular holes, which confirm the presence of an elastomeric phase within the polymer matrix.</p>
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<p>FE-SEM images of samples V-PP12 (<b>a</b>), R-PP12 (<b>b</b>), V-PP20 (<b>c</b>), and R-PP20 (<b>d</b>) after cryofracture in nitrogen, using BSE detection.</p>
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<p>(<b>a</b>) TG and DTG of V-PP12 and R-PP12 before ageing (<b>b</b>) TG and DTG of V-PP20 and R-PP20 before ageing.</p>
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<p>First heating melting peaks of samples V-PP12, R-PP12, V-PP20, and R-PP29 before ageing. Thermograms were acquired at 20 °C/min.</p>
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<p>Graphical illustration of ATR-FTIR transmission spectra of: (<b>a</b>) entire wavenumber range investigated of V-PP12 before ageing and R-PP12 after all ageing steps, (<b>a<sub>1</sub></b>) V-PP12 and R-PP12 magnification of CH2 and CH3 stretching vibration region, (<b>a<sub>2</sub></b>) V-PP12 and R-PP12 magnification of bending and skeletal vibration region; (<b>b</b>) entire wavenumber range investigated of V-PP20 before ageing and R-PP20 after all ageing steps, (<b>b<sub>1</sub></b>) V-PP20 and R-PP20 magnification of CH2 and CH3 stretching vibration region, (<b>b<sub>2</sub></b>) V-PP20 and R-PP20 magnification of bending and skeletal vibration region.</p>
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<p>Breakage results after multiaxial impact test at different temperatures: V-PP12 at 23 °C (<b>a<sub>1</sub></b>), V-PP12 at −10 °C (<b>b<sub>1</sub></b>), V-PP12 at −20 °C (<b>c<sub>1</sub></b>), V-PP12 at −30 °C (<b>d<sub>1</sub></b>); R-PP12 at 23 °C (<b>a<sub>2</sub></b>), R-PP12 at −10 °C (<b>b<sub>2</sub></b>), R-PP12 at −20 °C (<b>c<sub>2</sub></b>), R-PP12 at −30 °C (<b>d<sub>2</sub></b>); V-PP20 at 23 °C (<b>a<sub>3</sub></b>), V-PP20 at −10 °C (<b>b<sub>3</sub></b>), V-PP20 at −20 °C (<b>c<sub>3</sub></b>), V-PP20 at −30 °C (<b>d<sub>3</sub></b>); R-PP20 at 23 °C (<b>a<sub>4</sub></b>), R-PP20 at −10 °C (<b>b<sub>4</sub></b>), R-PP20 at −20 °C (<b>c<sub>4</sub></b>), R-PP20 at −30 °C (<b>d<sub>4</sub></b>).</p>
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<p>Impact energy results before and after ageing of samples V-PP12 and R-PP12 (<b>a</b>) and V-PP20 and R-PP20 (<b>b</b>).</p>
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<p>Tensile test results before and after ageing of samples V-PP12 and R-PP12 (<b>a</b>) and V-PP20 and R-PP20 (<b>b</b>).</p>
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<p>Flexural test results before and after ageing of samples V-PP12 and R-PP12 (<b>a</b>) and V-PP20 and R-PP20 (<b>b</b>).</p>
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15 pages, 1396 KiB  
Article
Disposable Paper Cups: A Study on Potentially Toxic Elements, Radiological Impact, and Feasibility of Valuable Elements Recovery
by Mahmoud Mohery, Ahmed Mindil, Sheldon Landsberger and Mohamed Soliman
Toxics 2025, 13(3), 179; https://doi.org/10.3390/toxics13030179 - 28 Feb 2025
Viewed by 164
Abstract
This study characterizes single-use paper cups with respect to potentially toxic elements, radiological impact, and the potential of economic metals recovery from incineration residue. Thirty-six elements were identified in the analysis of paper cups, including naturally occurring radionuclides 40K, Th, and U, [...] Read more.
This study characterizes single-use paper cups with respect to potentially toxic elements, radiological impact, and the potential of economic metals recovery from incineration residue. Thirty-six elements were identified in the analysis of paper cups, including naturally occurring radionuclides 40K, Th, and U, as well as potentially toxic elements such as Al, Ba, Co, Cr, Cu, Mn, Mo, and V using neutron activation analysis. The determined mass fractions varied significantly, with Mg, Al, and Ca present in notably high concentrations. A comparison with plastic cups revealed higher mass fractions of most elements in paper cups. The study also evaluated the potential for valuable element recovery from the incineration ash of paper cups. It demonstrated a promising potential for recovery of Cu—especially from blue and green cups—and Mg, as their mass fractions are above the ore cut-off grade. The amount of CO2 emissions from the incineration of paper cups was estimated at 1.77 kg/kg. The activity concentrations of 40K, Th, and U were estimated in the incineration ash, with 40K accounting for around half of the total detected activity. The median radioactivity was 35 Bq/kg. Although the radioactivity levels are low, they should be considered due to the large volume of paper cup waste. The radiological risk was assessed using various hazard indices, indicating minimal risk to human health. The dose rate and the annual dose are well below the recommended limits, and the excess lifetime cancer risk (ELCR) of 2.17 × 10−5 is well below the typical safety limit. Full article
(This article belongs to the Section Metals and Radioactive Substances)
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<p>Evaluation of the analysis results of quality control reference materials.</p>
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<p>Comparison between the elemental compositions of paper and plastic cups.</p>
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<p>Elemental composition as a function of the color of the examined paper cup.</p>
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<p>Enriched factors of elements in incineration ash of paper cups (based on the median values of determined mass fractions of these elements).</p>
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<p>Activity concentration in the incineration ash of paper cups.</p>
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15 pages, 864 KiB  
Article
Climate Change vs. Circular Economy: Challenges of the Most Common Route for Recycling Gold from WEEE
by Benjamin Fritz and Mario Schmidt
Sustainability 2025, 17(5), 2086; https://doi.org/10.3390/su17052086 - 28 Feb 2025
Viewed by 170
Abstract
Gold production poses significant environmental challenges, including resource depletion, CO2 emissions, and toxic chemical usage. Similarly, improper WEEE management harms the environment. However, WEEE contains valuable metals such as gold, making it central to circular economy (CE) strategies and an alternative to [...] Read more.
Gold production poses significant environmental challenges, including resource depletion, CO2 emissions, and toxic chemical usage. Similarly, improper WEEE management harms the environment. However, WEEE contains valuable metals such as gold, making it central to circular economy (CE) strategies and an alternative to mining. This study assesses the climate impact of pyrometallurgical gold recovery from WEEE using life cycle assessment (LCA). The study found that the carbon footprint of producing gold pyrometallurgically from WEEE is 2000 kg CO2eq/kg. These emissions are largely tied to the carbon content of waste, meaning that low-carbon energy sources have a limited impact. This creates a conflict between CE goals and CO2 reduction. Scenario analysis shows that utilizing waste heat for district heating significantly lowers emissions. The other strategies used to improve the environmental performance include separating the plastic fraction before smelting, using biogenic plastic in WEEE, and carbon capture and storage (CCS). Transport accounts for just 10% of the total carbon footprint. Future regulations must address multiple factors—EEE production, waste management, smelter infrastructure, global socioeconomic dynamics, and consumer behavior—as higher recycling rates alone will not solve WEEE challenges. Full article
(This article belongs to the Special Issue Electronic Waste Management and Sustainable Development (2nd Edition))
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<p>Process contribution of WEEE recycling for the whole product basket in SC0 highlighting the role of quicklime.</p>
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<p>Allocation analysis based on the contribution of each metal to the carbon footprint of the whole product basket and comparing the results to the literature results (<a href="#app1-sustainability-17-02086" class="html-app">Supplement Table S4</a>).</p>
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<p>Scenario analysis for the carbon footprint of gold from WEEE in economic allocation.</p>
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14 pages, 5948 KiB  
Article
Nano Cobalt-Loaded Porous Carbon Derived from Waste Plastic for Efficient Persulfate Activation and Tetracycline Degradation
by Yueyue Luo, Xiuxiu Zhang, Yu Zhang, Jianchao Wang and Chongqing Wang
Nanomaterials 2025, 15(5), 371; https://doi.org/10.3390/nano15050371 - 27 Feb 2025
Viewed by 171
Abstract
The excessive utilization and emission of waste plastics have caused serious damage to the environment, and it is of great significance to explore high-value utilization methods for these waste plastics. To address this challenge, functional nano cobalt-loaded porous carbon materials (CoPC) with excellent [...] Read more.
The excessive utilization and emission of waste plastics have caused serious damage to the environment, and it is of great significance to explore high-value utilization methods for these waste plastics. To address this challenge, functional nano cobalt-loaded porous carbon materials (CoPC) with excellent antibiotic wastewater removal properties were prepared by one-step pyrolysis using waste PET plastics as a carbon source, a process described in this paper. Characterization revealed that the obtained CoPC-2 catalysts had a high degree of defects, a large specific surface area (343.41 m2/g), and an abundant pore structure. Degradation results displayed that CoPC-2 removed 87.93% of 20 mg/L tetracycline with a reaction rate constant of 0.0668 min−1. Moreover, CoPC-2 exhibited excellent degradation performance for tetracycline over a wide range of pH levels (4–10) and in coexistence with multiple inorganic anions. Electron paramagnetic resonance and radical quenching experiments revealed that radicals (·OH, and SO4·) and non-radicals (1O2) pathway participated in tetracycline degradation, with the non-radical pathway being dominant. This study not only offers promising prospects for resource utilization of waste plastics, but also provides novel approaches for the design of functional nanomaterials for antibiotic wastewater treatment. Full article
(This article belongs to the Special Issue Nanomaterials for Sustainable Water Remediation)
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<p>Preparation diagram of the CoPC catalyst.</p>
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<p>(<b>a</b>) XRD, (<b>b</b>) FT-IR, and (<b>c</b>) Raman spectra of PET-800 and CoPC catalysts; (<b>d</b>) Thermogravimetric curve of the CoPC-2 catalyst precursor.</p>
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<p>(<b>a</b>) N<sub>2</sub> adsorption–desorption isotherms and (<b>b</b>) pore size distribution curves of PET-800 and CoPC catalyst; SEM images of (<b>c</b>) PET-800 and (<b>d</b>–<b>f</b>) CoPC-2 catalyst; (<b>g</b>) EDS mapping of CoPC-2.</p>
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<p>(<b>a</b>) Degradation performance of TC and (<b>b</b>) Linear fitting of pseudo-first-order kinetics of PMS, PET-800, and CoPC composites.</p>
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<p>Effects of (<b>a</b>) catalyst dosage, (<b>c</b>) PMS dosage, (<b>e</b>) TC concentration, and (<b>g</b>) solution pH on TC degradation by CoPC-2; Linear fitting of the pseudo-first-order kinetic equation of (<b>b</b>) catalyst dosage, (<b>d</b>) PMS dosage, (<b>f</b>) TC concentration, and (<b>h</b>) solution pH; (<b>i</b>) Effects of solution temperature on TC degradation and linear fitting of the pseudo-first-order kinetic equation.</p>
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<p>Influences of (<b>a</b>) inorganic anions and (<b>b</b>) humic acid on TC degradation.</p>
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<p>(<b>a</b>) Influence of radical scavengers on TC degradation; (<b>b</b>) Linear fitting of the pseudo-first-order kinetic equation; EPR spectra of (<b>c</b>) ·OH and SO<sub>4</sub>·<sup>−</sup>, and (<b>d</b>) <sup>1</sup>O<sub>2</sub> in the CoPC-2/PMS system.</p>
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<p>Degradation mechanism of TC in the CoPC-2/PMS system.</p>
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17 pages, 2395 KiB  
Article
Enhancing Polypropylene Biodegradability Through Additive Integration for Sustainable and Reusable Laboratory Applications
by Kanittika Samneingjam, Juthamas Mahajaroensiri, Maysinee Kanathananun, Cristina Velasco Aranda, Mario Muñoz and Somchoke Limwongsaree
Polymers 2025, 17(5), 639; https://doi.org/10.3390/polym17050639 - 27 Feb 2025
Viewed by 413
Abstract
The environmental challenges posed by laboratory plastic waste, particularly single-use items, underscore the urgent need for sustainable alternatives. This study investigated the development of reusable and biodegradable labware, addressing both functional and environmental demands. The content of the biodegradable additive in the polypropylene [...] Read more.
The environmental challenges posed by laboratory plastic waste, particularly single-use items, underscore the urgent need for sustainable alternatives. This study investigated the development of reusable and biodegradable labware, addressing both functional and environmental demands. The content of the biodegradable additive in the polypropylene (PP) varied from 1% to 2% by weight via twin-screw extrusion, followed by injection molding to fabricate test specimens. Three different grades of PP were also compared. Optical, mechanical, and thermal properties were systematically assessed before and after repetitive autoclave sterilization for up to 10 cycles (121 °C, 15 min, 0.11 MPa). Additionally, cytotoxicity following electron beam irradiation (E-Beam 25 and 50 kGy) was evaluated in compliance with ISO 10993-5, alongside biodegradability studies conducted under ASTM D5511 conditions. The results demonstrate that the biodegradable additive stabilized the appearance and enhanced the flexural and impact strengths of PP without compromising thermal stability, particularly after five autoclave cycles. Cytotoxicity assays confirmed the biocompatibility of the additive-modified PP, while biodegradability tests indicated moderate degradation, with 12% biodegradation achieved over 6 months compared to negligible degradation in the negative control. These findings highlight the potential of additive-modified PP as a sustainable solution for reusable labware, balancing durability with improved environmental performance and providing a viable step toward more sustainable laboratory practices. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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<p>Flow chart for sample preparation, testing processes and dimensions of testing sample.</p>
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<p>Optical properties of PP1 without additive (PP1, black), PP1 with 1% additive (PP1 + A1%, blue), and PP1 with 2% additive (PP1 + A2%, red) at Origin and after consecutive cycles of autoclave (from 1 cycle to 10 cycles, marked as #1 to #10, respectively): (<b>a</b>) transmission, (<b>b</b>) L*, (<b>c</b>) a*, and (<b>d</b>) b*.</p>
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<p>Appearance of Origin samples and samples after 10 cycles of autoclave: (<b>a</b>) PP1, (<b>b</b>) PP1 + A1%, and (<b>c</b>) PP1 + A2%.</p>
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<p>Mechanical properties of PP1 without additive (PP1, black), PP1 with 1% additive (PP1 + A1%, blue), and PP1 with 2% additive (PP1 + A2%, red) at Origin and after consecutive cycles of autoclave (from 1 cycle to 10 cycles, marked as #1 to #10, respectively): (<b>a</b>) tensile strength, (<b>b</b>) flexural strength, (<b>c</b>) Young’s modulus, and (<b>d</b>) impact strength.</p>
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<p>Mechanical properties of two grades of PP (PCR PP and HM PP) without additive (w/o) and PP with additive (2%) at Origin (grey), after autoclaving 5 cycles (blue) and autoclaving 10 cycles (pink): (<b>a</b>) tensile strength, (<b>b</b>) flexural strength, (<b>c</b>) Young’s modulus, and (<b>d</b>) impact strength.</p>
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<p>The percentage of cell survival (% viability) after incubation with extracts from PP box and PP box containing 2% by weight of biodegradable additive (PP box + A2%), which were E-Beam irradiation treated at dose of (<b>a</b>) 25 kGy (green) and (<b>b</b>) 50 kGy (orange).</p>
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<p>Appearance of samples from a soil burial test for 4 months: (<b>a</b>) PP, (<b>b</b>,<b>c</b>) PP + A2%.</p>
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<p>ASTM D5511 biodegradation results: (<b>a</b>) cumulative gas volume and (<b>b</b>) %biodegradation over 27 weeks. %Biodegradation of the positive control was in the range of 78.7 ± 0.3% during the testing period.</p>
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21 pages, 300 KiB  
Article
Correlation Between Post-Pandemic Climate Change Advocacy on TikTok and Knowledge, Attitude, and Adaptation Practices Among TikTok Users in Nigeria
by Charity A. Ben-Enukora, Mary P. Soroaye, Agwu A. Ejem, Chika E. Asogwa, Success E. U. Ojih and Daniel T. Ezegwu
Journal. Media 2025, 6(1), 36; https://doi.org/10.3390/journalmedia6010036 - 27 Feb 2025
Viewed by 98
Abstract
This study examined the relationship between climate change advocacy on TikTok and knowledge, attitude, and adaptation practices among TikTok users in Nigeria. This study employed quantitative methods, using content analysis and cross-sectional survey approaches to generate data. An API tool was used to [...] Read more.
This study examined the relationship between climate change advocacy on TikTok and knowledge, attitude, and adaptation practices among TikTok users in Nigeria. This study employed quantitative methods, using content analysis and cross-sectional survey approaches to generate data. An API tool was used to scrape 342 TikTok videos, out of which 16 videos with comprehensive information about climate change were purposively selected, and 381 survey participants were purposively selected from 23.84 million TikTok users in Nigeria. The data were presented in simple frequency tables, while the Pearson’s Correlation analysis was conducted on the survey data acquired to draw inferences. The results of the content analysis suggest that users in Nigeria have contributed a little in providing comprehensive climate advocacy content on TikTok; most of available videos emanated from official sources and projected the anthropogenic nature of the climate crisis but denoted a pessimistic and alarming tone, which may induce despair and outright disregard for the messages. The survey results depict limited exposure to climate change content on TikTok, even though the knowledge of climate change was adequate. More so, polarised perceptions and attitudes, and maladaptive practices in tree planting as well as plastic and household wastes management were observed. The correlation coefficients show a negative and statistically non-significant correlation between exposure to climate advocacy on TikTok and knowledge, attitude, and adaptation practices, but there is a positive but insignificant relationship between the perception of climate change advocacy on TikTok and adaptation practices. These findings suggest the need for more intentional policies that will drive positive attitudinal changes and adaptation practices among young people in Nigeria. Full article
13 pages, 524 KiB  
Review
E-Cigarette and Environment
by Ancuta-Alina Constantin and Florin-Dumitru Mihălțan
Environments 2025, 12(3), 72; https://doi.org/10.3390/environments12030072 - 27 Feb 2025
Viewed by 189
Abstract
Environmental exposure to e-cigarettes is a significant yet often overlooked issue in the medical field. In this review, we examine various aspects of exposure mechanisms, including the risks of secondhand and thirdhand vaping. Our findings highlight numerous environmental concerns related to the fabrication, [...] Read more.
Environmental exposure to e-cigarettes is a significant yet often overlooked issue in the medical field. In this review, we examine various aspects of exposure mechanisms, including the risks of secondhand and thirdhand vaping. Our findings highlight numerous environmental concerns related to the fabrication, consumption, and waste management of e-cigarettes. Additionally, we address the pressing issue of plastic pollution linked to vaping products. We also explore methods to protect passive vapers and propose strategies aimed at mitigating the environmental impact of e-cigarettes as well as safeguarding innocent bystanders. Full article
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<p>Disposal behaviors among young e-cigarette users (Truth Initiative Study 2020) [<a href="#B54-environments-12-00072" class="html-bibr">54</a>].</p>
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15 pages, 2296 KiB  
Article
Plasma Gasification of Medical Plastic Waste to Syngas in a Greenhouse Gas (CO2) Environment
by Andrius Tamošiūnas, Mindaugas Milieška, Dovilė Gimžauskaitė, Mindaugas Aikas, Rolandas Uscila, Kęstutis Zakarauskas, Sebastian Fendt, Sebastian Bastek and Hartmut Spliethoff
Sustainability 2025, 17(5), 2040; https://doi.org/10.3390/su17052040 - 27 Feb 2025
Viewed by 149
Abstract
The global coronavirus (COVID-19) pandemic in early 2020 caused the amount of medical waste, especially plastic waste, to increase. The pandemic exacerbated the plastic waste management problem, including the need to find more sustainable treatment methods. This study investigated the sustainable conversion of [...] Read more.
The global coronavirus (COVID-19) pandemic in early 2020 caused the amount of medical waste, especially plastic waste, to increase. The pandemic exacerbated the plastic waste management problem, including the need to find more sustainable treatment methods. This study investigated the sustainable conversion of plastic waste (FFP2-type face masks) to syngas via pure CO2 plasma gasification to recover energy and reduce environmental pollution. A direct current (DC) thermal arc plasma torch of 40.6–68.4 kW power generated the plasma stream. Carbon dioxide (CO2), as a greenhouse gas (GHG), was used as the main plasma-forming gas and gasifying agent. The 140thermal feedstock input plasma gasification system was used in the study. The effect of the CO2-to-C ratio on the gasification performance efficiency was investigated. The best CO2 plasma gasification process performance was obtained at a CO2-to-C ratio of 2.34. In these conditions, the main syngas components (H2 + CO) comprised 80.46 vol.% (H2: 24.62 vol.% and CO: 55.84 vol.%) and the following values were seen for the heating value of the syngas (LHVsyngas: 13.88 MJ/Nm3), the syngas yield (3.13 Nm3/kgFFP2), the tar content in the syngas (23.0 g/Nm3), the carbon conversion efficiency (CCE: 70.6%), and the cold gas efficiency (CGE: 47.8%). Additionally, the plasma gasification process mass and energy balance were evaluated. It was demonstrated that CO2 plasma gasification could be a promising thermochemical treatment technology for sustainable plastic waste disposal and the simultaneous utilization of greenhouse gases, such as carbon dioxide. Full article
(This article belongs to the Section Energy Sustainability)
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<p>Plasma gasification system.</p>
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<p>Gas concentration changes during the plasma gasifier preheating step with no feeding of the FFP2 pellets, and later during gasification with feeding of the FFP2 pellets.</p>
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<p>Effect of the CO<sub>2</sub>-to-C ratio on producer gas content.</p>
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<p>Effect of the CO<sub>2</sub>-to-C ratio on the LHV of syngas and the H<sub>2</sub>/CO ratio.</p>
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<p>Effect of the CO<sub>2</sub>-to-C ratio on the yield of syngas, H<sub>2</sub>, and CO.</p>
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<p>Effect of the CO<sub>2</sub>-to-C ratio on the CCE and CGE.</p>
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<p>Mass balance of the FFP2 plastic pellets gasification in the CO<sub>2</sub> thermal plasma at a CO<sub>2</sub>-to-C ratio of 2.34.</p>
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<p>Sankey diagram for the energy flow of the FFP2 plastic pellets gasification in the CO<sub>2</sub> thermal plasma at a CO<sub>2</sub>-to-C ratio of 2.34.</p>
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16 pages, 2647 KiB  
Article
Mechanical Properties of PVC/TPU Blends Enhanced with a Sustainable Bio-Plasticizer
by Yitbarek Firew Minale, Ivan Gajdoš, Pavol Štefčák, Tamás Szabó, Annamaria Polyákné Kovács, Andrea Ádámné Major and Kálmán Marossy
Sustainability 2025, 17(5), 2033; https://doi.org/10.3390/su17052033 - 26 Feb 2025
Viewed by 355
Abstract
The development of sustainable and mechanically versatile polymeric materials is essential to meet the growing demand for eco-friendly, high-performance products. This study investigates the mechanical properties of blends comprising polyvinyl chloride (PVC), thermoplastic polyurethane (TPU), and glycerol diacetate monolaurate, a bio-based plasticizer derived [...] Read more.
The development of sustainable and mechanically versatile polymeric materials is essential to meet the growing demand for eco-friendly, high-performance products. This study investigates the mechanical properties of blends comprising polyvinyl chloride (PVC), thermoplastic polyurethane (TPU), and glycerol diacetate monolaurate, a bio-based plasticizer derived from waste cooking oil, addressing the underexplored combined effects of these components. By varying the proportions, the blends’ tensile strength, elasticity, elongation at break, and hardness were tailored for diverse applications. Incorporating the bio-plasticizer significantly enhanced the PVC’s flexibility and elongation at break, while reducing its tensile strength and rigidity. The addition of TPU further enhanced the elasticity, toughness, and resilience, with the final properties governed by synergistic interactions between PVC’s rigidity, TPU’s elasticity, and the plasticizer’s softening effects. Dynamic mechanical analysis (DMA) confirmed that the bio-plasticizer enhanced the compatibility between the PVC and TPU, leading to ternary PVC/TPU/bio-plasticizer blends with an improved elasticity and elongation at break, without a significant loss in tensile strength. These blends exhibited a broad range of tunable properties, enabling applications from flexible films to impact-resistant components. Overall, these findings highlight the potential of PVC/TPU/bio-plasticizer systems to deliver high-performance materials with enhanced sustainability. This work offers valuable insights for developing greener polymer systems and advancing the creation of tailored materials for diverse industrial applications in alignment with global sustainability goals. Full article
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<p>The molecular structure of glycerol diacetate monolaurate.</p>
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<p>Representative tensile test specimens of the polymer blends.</p>
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<p>DMA curve of polymer blend samples.</p>
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<p>Stress–strain curves of the tested polymer blends.</p>
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<p>Tensile strength and Young’s modulus of polymer blends with varying compositions.</p>
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<p>Elongation at break of polymer blends with varying compositions.</p>
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<p>(<b>a</b>) Stress localization and neck formation in Rigid PVC; (<b>b</b>) uniform deformation in plasticized PVC under tensile load.</p>
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<p>Shore A and Shore D hardness of polymer blends with varying compositions.</p>
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14 pages, 8512 KiB  
Article
The Monitoring of Macroplastic Waste in Selected Environment with UAV and Multispectral Imaging
by Tomasz Oberski, Bartosz Walendzik and Marta Szejnfeld
Sustainability 2025, 17(5), 1997; https://doi.org/10.3390/su17051997 - 26 Feb 2025
Viewed by 169
Abstract
Plastic pollution is becoming an increasingly serious threat to the natural environment. Macroplastics, primarily polyethylene films, pose significant ecological and economic risks, particularly in the agricultural sector. Effective monitoring of their presence is necessary to evaluate the effectiveness of mitigation measures. Conventional techniques [...] Read more.
Plastic pollution is becoming an increasingly serious threat to the natural environment. Macroplastics, primarily polyethylene films, pose significant ecological and economic risks, particularly in the agricultural sector. Effective monitoring of their presence is necessary to evaluate the effectiveness of mitigation measures. Conventional techniques for identifying environmental contaminants, based on field studies, are often time-consuming and limited in scope. In response to these challenges, a study was conducted with the primary aim of utilizing unmanned aerial vehicles (UAVs), multispectral cameras, and classification tools to monitor macroplastic pollution. The model object for the study was an industrial compost pile. The performance of four object-oriented classifiers—Random Forest, k-Nearest Neighbor (k-NN), Maximum Likelihood, and Minimum Distance—was evaluated to effectively identify waste contamination. The best results were achieved with the k-NN classifier, which recorded a Matthews Correlation Coefficient (MCC) of 0.641 and an accuracy (ACC) of 0.891. The applied classifier identified a total 37.35% of the studied compost pile’s surface as contamination of plastic. The results of the study show that UAV technology, combined with multispectral imaging, can serve as an effective and relatively cost-efficient tool for monitoring macroplastic pollution in the environment. Full article
(This article belongs to the Section Environmental Sustainability and Applications)
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<p>Industrial composting facility area.</p>
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<p>DJI Phantom 4 Advanced with Parrot Sequoia+ camera.</p>
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<p>The photogrammetric flight sketch (PIX4Dmapper version 4.8.8); red dots—the location where the image was taken; blue crosses—ground control points.</p>
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<p>A real model of the compost pile (point cloud). The approximate study area is outlined in yellow.</p>
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<p>RGB image of the test area.</p>
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<p>Manually classified pixels covering various color (white, blue, gray and black) macroplastic; the brown background is organic matter.</p>
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<p>Spectral reflectance curves for films of different colors and organic matter.</p>
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<p>Visualization of the results for each classification model: (<b>A</b>) test area classified using the k-NN algorithm; (<b>B</b>) test area classified using the RF algorithm; (<b>C</b>) test area classified using the ML algorithm; (<b>D</b>) test area classified using the MD algorithm; and (<b>E</b>) test area classified manually.</p>
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<p>Classification map adjusted to real conditions.</p>
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<p>Compost pile area: (<b>A</b>) multispectral image and (<b>B</b>) image classification result obtained using the k-NN model.</p>
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