Search Results (103)

Graphene nanoplatelet aggregates (GNAs) are a low-cost, low-quality alternative to graphene nanoplatelets (GNPs), characterized by their three-dimensional stacked structure and porous surface morphology. Despite their affordability, limited research has been conducted on the effects of GNAs in cementitious systems. This study investigates the impact of GNAs on hydration kinetics, phase assemblage, mortar consistency, mechanical strength, bulk electrical resistivity, water absorption, and pore solution pH. Mortar mixtures with 0%, 0.05%, and 1% GNAs by cement weight were prepared using a water-to-cement ratio of 0.42 and cured for 28 days. The results showed that GNAs had minimal influence on hydration kinetics, with no significant changes in hydration products detected by XRD and TGA analyses. Mortar consistency consistently decreased with increasing GNA content. At 0.05%, GNAs had no significant effect on compressive strength or bulk electrical resistivity, whereas 1% GNAs reduced compressive strength by 10%. Water absorption was significantly lower in specimens with 1% GNAs as well, while pore solution pH increased at this dosage. The findings of this study indicate that the incorporation of GNAs at a 0.05% replacement level does not inherently enhance cementitious properties but can influence specific behaviors, such as workability and water absorption, when used at 1% dosages. Full article

The global reserve of sand has significantly decreased, and sand washing is predominantly favored due to its simplicity and low operational costs, but this method poses significant environmental risks like landslides, making its reuse essential for sustainability. In view of this challenge, based on the composite preparation method, an innovative approach was proposed to prepare an artificial soil substrate from sand-washing slurry. The physical and vegetative feasibility performance, including strength, density, water absorption, retention, electrical conductivity (EC), and pH; and microstructural characteristics, including X-ray diffraction (XRD), scanning electron microscopy (SEM), and nuclear magnetic resonance (NMR) of the artificial soil substrate with different proportions of cement and foaming agent were measured. Increasing the cement content to 30% of un-crushed artificial soil substrate specimens improved strength, whereas 40% reduced it due to the diminished pore-filling effect. Water absorption rates ranged from 29.22% to 36.68%, increasing with more foaming agent and decreasing with more cement, while the water retention time was 12–14 days, and incorporating foaming agent significantly increased water absorption. Leachate pH ranged from 11.99 to 12.18, and reduced to 7.82–8.28 with 5% phosphoric acid. The EC of the artificial soil substrate decreased by 88.64% to 93.59% after 10 wet–dry cycles, aligning with the standard. Artificial-soil-substrate-predominant products include calcite, quartz, and dolomite, with a pronounced silica content and soil substrate porosity ranging from 27.96% to 51.80%. From the microstructural test, calcium silicate hydrate gel, produced by cement hydration, effectively bound the sand-washing slurry, thereby improving strength. Full article

Mining activities often contaminate soils with heavy metals, generating environmental and health risks. This study investigates the ecotoxicity of muddy (Mw) and sandy (Sw) mining wastes on Phaseolus vulgaris and assesses the impact of five locally sourced biochar amendments on plant growth and soil pore water (SPW) properties. Most biochars improved water retention, except for argan nut shells (An) biochar, highlighting the importance of feedstock type. Sw supported better plant growth than Mw regardless of biochar addition, due to textural differences. Palm fronds (Pf) biochar significantly enhanced surface leaf area in Sw. SPW analysis revealed that biochar affected pH and electrical conductivity (EC) differently across soil types. Mw consistently increased pH, while Sw’s pH was biochar-dependent. A significant 5.1-fold EC increase was recorded in Sw amended with Pf. All biochars reduced Pb availability in Mw at planting, while Cu availability decreased in Sw at harvest. In Mw, Pb, Zn, and Cu, uptake and accumulation were unaffected by biochar, while a slight reduction was observed in Sw roots. A germination test with Lepidium sativum confirmed these findings, particularly the inhibition observed with An. This dual approach highlights the toxicity of mining soils and biochars’ potential as amendments for soil remediation programs. Full article

Over the years, the ammonia concentration in water streams and the environment is increasing at an alarming rate. Many membrane-based processes have been studied to alleviate this concern via adsorption and filtration. On the other hand, ammonia electro-oxidation is an approach of particular interest owing to its energetic and environmental benefits. Thus, a plausible alternative to combine these two paths is by using an electroconductive membrane (ECM) to complete the ammonia oxidation reaction (AOR). This combination of processes has been studied very limitedly, and it can be an area for development. Herein, we developed a multilayered membrane with hydrophilic and electrocatalytic properties capable of completing the AOR. The porosity of carbon black (CB) particles was embedded in the polymeric support (CBES) and the active side was composed of a triple layer consisting of polyamide/CB/Pt nanoparticles (PA:CB:Pt). The CBES increased the membrane porosity, changed the pores morphology, and enhanced water permeability and electroconductivity. The deposition of each layer was monitored and corroborated physically, chemically, and electrochemically. The final membrane CBES:PA:VXC:Pt reached higher water flux than its PSF counterpart (3.9 ± 0.3 LMH), had a hydrophilic surface (water contact angle: 19.8 ± 0.4°), and achieved the AOR at −0.3 V vs. Ag/AgCl. Our results suggest that ECMs with conductive material in both membrane layers enhanced their electrical properties. Moreover, this study is proof-of-concept that the AOR can be succeeded by a polymeric FO-ECMs. Full article

As a kind of industrial solid waste, lead–zinc waste slag can easily cause heavy metal migration in acid environments, resulting in safety risks. Along these lines, in this work, the waste slag of a lead–zinc mining area in western Qinling, Shaanxi, China, was selected as the experimental material. Seven groups of acid soaking solutions with different pH values were set up with three parallel samples in each group, and the acid soaking experiments were conducted for 100 days. During the experiment, the electrical conductivity, pH value, and heavy metal content of the solution, as well as the pore distribution and heavy metal content of the waste slag surface, were measured. The results showed that with pH = 4 and pH = 7 as the environmental limit values, the pH value, electrical conductivity (EC), and heavy metal contents in the solution changed to different types after the waste slag was soaked in the solution with a pH of less than 4 and the solution with a pH of 5–7. The release of heavy metals from waste slag exceeded the discharge standard in the environment with a pH of less than 4, and the pore structure of waste slag was obviously enhanced, especially in the soaking solution with an initial pH of 1. The maximum soaking amounts of Zn, Pb, and Cd were 2.584 mg/L, 1.28 mg/L, and 0.0169 mg/L, respectively, during the experiment, which did not meet the “Environmental quality standards for surface water” (GB 3838-2002) and could not be excreted as direct surface water. However, when the environmental pH was greater than 7, the heavy metals showed reverse adsorption. This result indicated that when the acid soaking solution entered the alkaline range, the heavy metal content in the solution was less, which can basically meet the discharge standard. However, the pores of waste slag continued to expand. Our work provides valuable insights into the treatment of waste slag and environmental protection in lead-zinc mining areas containing sulfur. Full article

Monitoring crude oil spills in coastal areas is challenging due to limitations in traditional in situ methods. Electrical resistivity imaging (ERI) offers a high-resolution approach to monitoring the subsurface spatial distribution of crude oil, but its effectiveness in highly-resistive, unsaturated coastal sands with varying salinity remains unexplored. This study assessed the effectiveness of ERI for monitoring crude oil spills in sandy soil using a 200 × 60 × 60 cm 3D sandbox filled with medium-fine-grained sand under unsaturated conditions. Two liters of crude oil were spilled under controlled conditions and monitored for 48 h using two surface ERI transects with 98 electrodes spaced every 2 cm and a dipole–dipole electrode array. The influence of varying salinity was simulated by varying the pore-fluid conductivities at four levels (0.6, 20, 50, and 85 mS/cm). After 48 h, the results show a percentage resistivity increase of 980%, 280%, 142%, and 70% for 0.6, 20, 50, and 85 mS/cm, respectively. The crude oil migration patterns varied with porewater salinity as higher salinity enhanced the crude oil retention at shallow depth. High salinity produces a smaller resistivity contrast, thus limiting the sensitivity of ERI in detecting the crude oil contaminant. These findings underscore the need to account for salinity variations when designing remediation strategies, as elevated salinity may restrict crude oil migration, resulting in localized contaminations. Full article

Tight sandstone oil reservoirs are characterized by complex structures, poor pore connectivity, and strong heterogeneity, with features such as low porosity and ultra-low permeability. Conventional methods for calculating saturation cannot accurately evaluate the hydrocarbon saturation of these reservoirs. To address this, a study was conducted from the perspective of non-electrical logging methods, focusing on the inherent nuclear magnetic resonance (NMR) characteristics of different fluids to develop a saturation calculation method that avoids the influence of the rock matrix, thus enabling precise saturation measurement in tight sandstone oil reservoirs. The traditional NMR porosity model was modified by segmenting it using the clay-bound water cutoff value, aiming to identify the distribution pattern of fluids in pores outside the clay-bound water zone. Through theoretical derivation and water spectrum function simulation, a water spectrum function and its parameter range suitable for the NMR T2 distribution in tight sandstone reservoirs were determined. Using core-sealed core saturation as a reference, the particle swarm optimization (PSO) algorithm was applied to optimize the parameter range and construct the final water spectrum function tailored to tight sandstone oil reservoirs. The accuracy and practicality of this method were validated by applying the derived water spectrum function to NMR logging in the exploration block, allowing for precise saturation calculations and the accurate evaluation of tight reservoir saturation. Full article

In recent years, highway infrastructure in the Ningxia region of China has rapidly advanced. Cement–loess is extensively utilized in the roadbed and foundation reinforcement. It is necessary to conduct micro–macro-analysis and model derivation of the electrical resistivity on Ningxia cement–loess, which are beneficial for both the practical application of electrical resistivity and the evaluation of the geotechnical properties of cement–loess. Therefore, a series of electrical resistivity measurements, microstructural observations (scanning electron microscopy), mineral analyses (thermogravimetric analysis), and theoretical analyses were adopted on the cement–loess. The following conclusions can be drawn: The electrical resistivity is negatively related to dry density and water content, while it is positively related to cement dosage and curing age. A cement dosage of 6% exhibits a lower hydration reaction potential compared to 12%, causing a slower increase in electrical resistivity. The formation of calcium silicate gel around particles results in particle clustering and pore filling, reducing the pore area and increasing electrical resistivity. Increased hydration also decreases microscopic orientation, contributing to a higher electrical resistivity of cement–loess. Finally, a new three-dimensional electrical resistivity model was created, finding that the electrical resistivity of Ningxia cement–loess was determined by the dry density, water content (ρ_d·w), cement dosage, and curing age (a_w·T) in an exponential function form. The new three-dimensional electrical resistivity model could be used in the high-efficiency evaluation of the cement–loess geotechnical parameter, offering valuable insights for the monitoring and maintenance of road infrastructure. Full article

In recent years, offshore wind farms have frequently encountered engineering geological disasters such as seabed liquefaction and scouring. Consequently, in situ monitoring has become essential for the safe siting, construction, and operation of these installations. Current technologies are hampered by limitations in single-parameter monitoring and insufficient probe-penetration depth, hindering comprehensive multi-parameter dynamic monitoring of seabed sediments. To address these challenges, we propose a foldable multi-sensor probe and establish an underwater adaptive continuous penetration system capable of concurrently measuring seabed elevation changes and sediment pore water pressure profiles. The reliability of the equipment design is confirmed through static analysis of the frame structure and sealed cabin. Furthermore, laboratory tests validate the stability and accuracy of the electrical and mechanical sensor measurements. Preliminary tests conducted in a harbor environment demonstrate the system’s effectiveness. Full article

Urea supplements, such as humic acids, could enhance fertilizer nitrogen use effectiveness. Melting is superior to mixing for humate urea application; however, the effects of diverse humate ureas from various coal sources on soil N supply remain unclear. This study compared the properties of two humic acids from different coal sources (HA1, weathered coal; HA2, lignite coal), and their impact on soil mineral N supply and the nitrate–ammonium ratio under flooded and 60% water-filled pore space (WFPS) over a 14-day incubation. Humate ureas stimulated soil mineral N accumulation and balanced the soil nitrate–ammonium ratio at 1:1; however, no significant difference existed between the two humate ureas under 60% WFPS. Humate urea enhanced soil ammonium nitrogen (NH₄⁺-N) retention and delayed nitrate nitrogen (NH₄⁻-N) release, leading to soil mineral N retention, especially in lignite humic acid urea (H2AU) treatments from lignite under flooding. Structural equation modeling (SEM) and linear regression revealed that humic acids elevated soil redox potential (Eh) and electrical conductivity (EC), stimulating soil N mineralization and adjusting the optimal nitrate–ammonium ratio. Humate urea improved soil mineral N supply compared to traditional urea treatments, and humic acids from lignite were more beneficial for crop cultivation from a mineral soil N supply perspective. These findings enhance our understanding of humate urea benefits and aid in optimizing humic acids application for N management. Full article

In order to reduce the content of sulfur and ash in coal, improve the desulfurization and deashing rates, a combined experiment method of microwave magnetic separation-flotation was proposed for raw coal. The desulfurization and deashing rates of three experiment methods, namely, single magnetic separation, microwave magnetic separation, and microwave magnetic separation–flotation, were compared. Taking the microwave magnetic separation–flotation experiment method as the main line, the effects of the microwave irradiation time, microwave power, grinding time, magnetic field intensity, plate seam width, foaming agent dosage, collector dosage, and inhibitor dosage on desulfurization and deashing were discussed, and the mechanism of microwave irradiation on magnetic separation and flotation was revealed. The results show that under the conditions of a microwave irradiation time of 60 s, a microwave power of 80% of the rated power (800 W), a grinding time of 8 min, a plate seam width (the plate seam width of a magnetic separator sorting box) of 1 mm, a magnetic field intensity of 2.32 T, a foaming agent dosage of 90 g/t, a collector dosage of 2125 g/t, and an inhibitor dosage of 1500 g/t, the desulfurization and deashing effect is the best. The desulphurization rate is 76.51%, the sulfur removal rate of pyrite is 96.50%, and the deashing rate is 61.91%. Microwaves have the characteristic of selective heating, and the thermal conductivity of organic matter in coal is greater than that of mineral. Microwave irradiation can improve the reactivity of pyrite in coal, pyrolyze pyrite into high-magnetic pyrite, improve the magnetic properties, and improve the magnetic separation effect. Therefore, microwave irradiation plays a role in promoting magnetic separation. Through microwave irradiation, the positive and negative charges in coal molecules constantly vibrate and create friction under the action of an electric field force, and the thermal action generated by this vibration and friction process affects the structural changes in oxygen-containing functional groups in coal. With the increase in the irradiation time and power, the hydrophilic functional groups of –OH and –COOH decrease and the hydrophilicity decreases. Microwave heating evaporates the water in the pores of coal samples and weakens surface hydration. At the same time, microwave irradiation destroys the structure of coal and impurity minerals, produces cracks at the junction, increases the surface area of coal to a certain extent, enhances the hydrophobicity, and then improves the effect of flotation desulfurization and deashing. Therefore, after the microwave irradiation of raw coal, the magnetic separation effect is enhanced, and the flotation desulfurization effect is also enhanced. Full article

Organosilicate glass (OSG) films are a critical component in modern electronic devices, with their electrical properties playing a crucial role in device performance. This comprehensive review systematically examines the influence of chemical composition, vacuum ultraviolet (VUV) irradiation, and plasma treatment on the electrical properties of these films. Through an extensive survey of literature and experimental findings, we elucidate the intricate interplay between these factors and the resulting alterations in electrical conductivity, dielectric constant, and breakdown strength of OSG films. Key focus areas include the impact of diverse organic moieties incorporated into the silica matrix, the effects of VUV irradiation on film properties, and the modifications induced by various plasma treatment techniques. Furthermore, the underlying mechanisms governing these phenomena are discussed, shedding light on the complex molecular interactions and structural rearrangements occurring within OSG films under different environmental conditions. It is shown that phonon-assisted electron tunneling between adjacent neutral traps provides a more accurate description of charge transport in OSG low-k materials compared to the previously reported Fowler–Nordheim mechanism. Additionally, the quality of low-k materials significantly influences the behavior of leakage currents. Materials retaining residual porogens or adsorbed water on pore walls show electrical conductivity directly correlated with pore surface area and porosity. Conversely, porogen-free materials, developed by Urbanowicz, exhibit leakage currents that are independent of porosity. This underscores the critical importance of considering internal defects such as oxygen-deficient centers (ODC) or similar entities in understanding the electrical properties of these materials. Full article

A solid phase of natural gas hydrates can form from dissolved gas in oil during cold water injection into shallow undersaturated oil reservoirs. This creates significant risks to oil production due to potential permeability reduction and flow assurance issues. Understanding the conditions under which gas hydrates form and their impact on reservoir properties is important for optimizing oil recovery processes and ensuring the safe and efficient operation of oil reservoirs subject to waterflooding. In this work, we present two fluid displacement experiments under temperature control using Bentheimer sandstone core samples. A large diameter core sample of 3 inches in diameter and 10 inches in length was instrumented with multiphysics sensors (i.e., ultrasonic, electrical conductivity, strain, and temperature) to detect the onset of hydrate formation during cooling/injection steps. A small diameter core sample of 1.5 inches in diameter and 12 inches in length was used in a coreflooding apparatus with high-precision pressure transducers to determine the effect of hydrate formation on rock permeability. The fluid phase transition to solid hydrate phase was detected during the displacement of live-oil with injected water. The experimental procedure consisted of cooling and injection steps. Gas hydrate formation was detected from ultrasonic measurements at 7 °C, while strain measurements registered changes at 4 °C after gas hydrate concentration increased further. Ultrasonic velocities indicated the pore-filling morphology of gas hydrates, resulting in a high hydrate saturation of theoretically up to 38% and a substantial risk of intrinsic permeability reduction in the reservoir rock due to pore blockage by hydrates. Full article

Addressing the poor performance of existing logging saturation models in low-permeability tight sandstone reservoirs and the challenges in determining model parameters, this study investigates the pore structure and fluid occurrence state of such reservoirs through petrophysical experiments and digital rock visualization simulations. The aim is to uncover new insights into fluid occurrence state and electrical conduction properties and subsequently develop a low-permeability tight sandstone reservoir saturation model with easily determinable parameters. This model is suitable for practical oilfield exploration and development applications with high evaluation accuracy. The research findings reveal that such reservoirs comprise three types of formation water: strongly bound water, weakly bound water, and free water. These types are found in non-connected micropores, poorly connected mesopores where fluid flow occurs when the pressure differential exceeds the critical value, and well-connected macropores. Furthermore, the three types of formation water demonstrate variations in their electrical conduction contributions. By inversely solving rock electrical experiment data, it was determined that for a single sample, the overall cementation index is the highest, followed by the cementation index of pore throats containing strongly bound water, and the lowest for the pore throats with free water. Building on the aforementioned insights, this study develops a parallel electrical pore cementation index term, ϕ^m′, to account for the differences among the three types of water and introduces a parallel electrical saturation model suitable for logging evaluation of low-permeability tight oil and gas reservoirs. This model demonstrated positive application effects in the logging evaluation of low-permeability tight gas reservoirs in a specific basin in the Chinese offshore area, thereby confirming the advantages of its application. Full article

In this work, the performance of the TEROS 12 electromagnetic sensor, which measures volumetric soil water content (θ), bulk soil electrical conductivity (σ_b), and temperature, is examined for a number of different soils, different θ and different levels of the electrical conductivity of the soil solution (EC_W) under laboratory conditions. For the above reason, a prototype device was developed including a low-cost microcontroller and suitable adaptation circuits for the aforementioned sensor. Six characteristic porous media were examined in a θ range from air drying to saturation, while four different solutions of increasing Electrical Conductivity (EC_w) from 0.28 dS/m to approximately 10 dS/m were used in four of these porous media. It was found that TEROS 12 apparent dielectric permittivity (ε_a) readings were lower than that of Topp’s permittivity–water content relationship, especially at higher soil water content values in the coarse porous bodies. The differences are observed in sand (S), sandy loam (SL) and loam (L), at this order. The results suggested that the relationship between experimentally measured soil water content (θ_m) and ε_a^0.5 was strongly linear (0.869 < R² < 0.989), but the linearity of the relation θ_m-ε_a^0.5 decreases with the increase in bulk EC (σ_b) of the soil. The most accurate results were provided by the multipoint calibration method (CAL), as evaluated with the root mean square error (RMSE). Also, it was found that ε_a degrades substantially at values of σ_b less than 2.5 dS/m while ε_a returns to near 80 at higher values. Regarding the relation ε_a-σ_b, it seems that it is strongly linear and that its slope depends on the pore water electrical conductivity (σ_p) and the soil type. Full article