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10 pages, 1980 KiB  
Article
Gain Saturation of Encapsulated CdTe-Ag Quantum Dot Composite in SiO2
by Minwoo Kim, Agna Antony, Inhong Kim, Minju Kim and Kwangseuk Kyhm
Nanomaterials 2024, 14(23), 1950; https://doi.org/10.3390/nano14231950 (registering DOI) - 4 Dec 2024
Abstract
Amplified spontaneous emission of CdTe and CdTe-Ag quantum dot composites were compared for increasing the optical stripe length, whereby optical gain coefficients for various emission wavelengths were obtained. In the case of CdTe-Ag nanoparticle composites, we observed that plasmonic coupling causes both optical [...] Read more.
Amplified spontaneous emission of CdTe and CdTe-Ag quantum dot composites were compared for increasing the optical stripe length, whereby optical gain coefficients for various emission wavelengths were obtained. In the case of CdTe-Ag nanoparticle composites, we observed that plasmonic coupling causes both optical enhancement and quenching at different wavelengths, where the amplified spontaneous emission intensity becomes enhanced at short wavelengths but suppressed at long wavelengths (>600 nm). To analyze the logistic stripe length dependence of amplified spontaneous emission intensity, we used a differential method to obtain the gain coefficient beyond the amplification range. This analysis enabled us to find the limit of the commonly used fitting method in terms of a threshold length and a saturation length, where amplification begins and saturation ends, respectively. Full article
(This article belongs to the Section Nanophotonics Materials and Devices)
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<p>(<b>a</b>) CdTe-Ag QD composites encapsulated with SiO<sub>2</sub> are shown schematically with a Scanning Electron Microscopy (SEM) image. (<b>b</b>) The absorption spectrum of CdTe QDs, Ag QDs, and QD composites with 1:1 (CdTe:Ag) and 1:10 ratios. (<b>c</b>) The intensity distribution of an optical stripe. (<b>d</b>) The experimental setup of the VSLM for<math display="inline"><semantics> <mrow> <mtext> </mtext> <mi>x</mi> <mo>≈</mo> <mn>0</mn> <mtext> </mtext> </mrow> </semantics></math>and <math display="inline"><semantics> <mrow> <mi>x</mi> <mo>&gt;</mo> <mn>0</mn> </mrow> </semantics></math>.</p>
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<p>(<b>a</b>) Edge emission spectrum of CdTe QDs for increasing stripe lengths at 4 K. Inset shows edge emission at 0 <math display="inline"><semantics> <mrow> <mi mathvariant="sans-serif">μ</mi> </mrow> </semantics></math>m stripe length. (<b>b</b>) <math display="inline"><semantics> <mrow> <mi>d</mi> <mi>I</mi> <mo>(</mo> <mi>λ</mi> <mo>,</mo> <mi>x</mi> <mo>)</mo> <mo>/</mo> <mi>d</mi> <mi>x</mi> </mrow> </semantics></math> spectrum at different stripe lengths. (<b>c</b>) Stripe length-dependent edge emission intensity at various wavelengths. Inset shows edge emission intensity in log scale. (<b>d</b>) Stripe length dependence of <math display="inline"><semantics> <mrow> <mi>d</mi> <mi>I</mi> <mo>(</mo> <mi>λ</mi> <mo>,</mo> <mi>x</mi> <mo>)</mo> <mo>/</mo> <mi>d</mi> <mi>x</mi> </mrow> </semantics></math> at different wavelengths. Short stripe length range (<span class="html-italic">x</span> &lt; <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>x</mi> </mrow> <mrow> <mi mathvariant="normal">t</mi> <mi mathvariant="normal">h</mi> </mrow> </msub> </mrow> </semantics></math>) is shown in inset.</p>
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<p>(<b>a</b>) Edge emission spectrum of CdTe QDs and CdTe-Ag QD composites at 1:1 and 1:10 ratios. (<b>b</b>) Stripe length dependence of edge emission intensity (in log scale) selected at wavelength of 730 nm for CdTe QDs and CdTe-Ag QD composites at 1:1 and 1:10 ratios. (<b>c</b>) Variation of <math display="inline"><semantics> <mrow> <mi>d</mi> <mi>I</mi> <mo>(</mo> <mi>λ</mi> <mo>,</mo> <mi>x</mi> <mo>)</mo> <mo>/</mo> <mi>d</mi> <mi>x</mi> </mrow> </semantics></math> with stripe length for CdTe QDs and CdTe-Ag QD composites at 1:1 and 1:10 ratios at wavelength of 730 nm. (<b>d</b>–<b>f</b>) Gain spectrum of CdTe QDs and CdTe-Ag QD composite at 1:1 and 1:10 ratios obtained using fitting method shown in Equation (2) and differential method shown in Equation (3).</p>
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14 pages, 2385 KiB  
Article
Preparation of Nano- and Microparticles Obtained from Polymerization Reaction and Their Application to Surface Coating of Woody Materials
by Toshinori Shimanouchi, Daichi Hirota, Masafumi Yoshida, Kazuma Yasuhara and Yukitaka Kimura
Appl. Sci. 2024, 14(23), 11326; https://doi.org/10.3390/app142311326 - 4 Dec 2024
Abstract
A surface coating of polymer particles of different hydrophobicity and wide-ranged size is helpful for the surface modification of materials such as woody thin board (WTB) derived from biomass. A preparation method for polymer particles was, in this study, proposed using a capillary-type [...] Read more.
A surface coating of polymer particles of different hydrophobicity and wide-ranged size is helpful for the surface modification of materials such as woody thin board (WTB) derived from biomass. A preparation method for polymer particles was, in this study, proposed using a capillary-type flow system. Under hydrothermal conditions, the refinement of dispersed oil droplets in water (O/W emulsions) and the polymerization reaction could be simultaneously advanced, and polymer particles of polystyrene (PS), polyvinyl alcohol (PVA), polymethyl methacrylate (PMMA), and poly-L-lactic acid (PLLA) with a particle size of about 100 nm could be synthesized. The coating of polymer particles gave an improved effect on the water repellency of WTBs due to the hydrophobicity of polymer particles and an alteration of surface roughness, and it also provided long-term stability (more than 6 years). Full article
(This article belongs to the Section Green Sustainable Science and Technology)
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<p>(<b>a</b>) Chemical structures of monomers used in this study. (<b>b</b>) Capillary-type flow system for emulsification. Solution I included monomer, AIBN, and Tween 20 (0.006 mM). Solution II was Tween 20 (0.0045 mM). Flow rate ratio of Solutions I and II was 1:2.</p>
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<p>(<b>a</b>) Cryo-TEM images of O/W emulsion of styrene. (<b>b</b>) TEM image of nanoparticles made of PS. (<b>c</b>) Time course of mean diameter for PS particles. Samples at t = 0 and t &gt; 0 represent O/W emulsion without AIBN and after polymerization reaction, respectively. (<b>d</b>) Diamter distribution of PS<sub>800</sub>, PS<sub>210</sub>, and PS<sub>30</sub>. (<b>e</b>) Comparison of diameter of O/W emulsion with that of polymer particles. PSxx indicates PS with xx nm of final mean diameter.</p>
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<p>(<b>a</b>) Cryo-TEM images of O/W emulsions of MMA, VA, and LA. Black arrows represent O/W emulsion. (<b>b</b>) TEM images of polymer particles made of PMMA, PVA, and PLLA. (<b>c</b>) Typical time-course of polymerization of O/W emulsions. Flow rate ratio of Solutions I (0.30 mL/min) and II (0.60 mL/min) was 1:2. (<b>d</b>) Comparison of diameter of O/W emulsion with that of polymer particles.</p>
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<p>(<b>a</b>–<b>e</b>) SEM and (<b>f</b>–<b>h</b>) AFM images of bare WTB and WTBs coated by polystyrene particles with different diameters at two volume fractions (ϕ = 0.005 and 0.020). (<b>f′</b>–<b>h′</b>) Both side and top views of each AFM image. White and black arrows mean the step on the surface. Lines 1–1′, 2–2′, … and 7–7′ mean the step.</p>
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<p>Box plots of contact angles for WTBs coated by polymer particles at two ϕ values. “Bare” means the WTB without surface modification of polymer particles.</p>
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<p>A comparison of the contact angle of the WTB surface with the mean diameter of the polymer particles: (<b>a</b>) PS; (<b>b</b>) PMMA; (<b>c</b>) PVA; and (<b>d</b>) PLLA. White and gray keys represent WTBs modified at φ = 0.020 and 0.005, respectively. (<b>e</b>) The relationship between the contact angle limit of WTBs and logP values for each monomer. Dashed curve in (<b>a</b>–<b>d</b>) is a curve fitted with exponential relaxation.</p>
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<p>Long-term stability of WTBs. (<b>a</b>) WTBs modified with PS of different diameters and (<b>b</b>) four kinds of polymer particles. (<b>c</b>) Remaining ratio of WTBs. Initially, ten WTBs were prepared. Standard errors were calculated from four different experiments for each WTB.</p>
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24 pages, 3956 KiB  
Article
Grease, Oxygen, and Air Barrier Properties of Cellulose-Coated Copy Paper
by Ronald Sabo, Cody Schilling, Craig Clemons, Daniel Franke, Neil R. Gribbins, Michael Landry, Kimberly Hoxie and Peter Kitin
Polysaccharides 2024, 5(4), 783-806; https://doi.org/10.3390/polysaccharides5040049 (registering DOI) - 4 Dec 2024
Abstract
Cellulose nanomaterials have been demonstrated to be excellent barriers against grease, oxygen, and other vapors, but their implementation in packaging materials is challenging because of numerous technical and practical challenges. In this work, the oxygen, air, grease, and heptane barrier performance of copy [...] Read more.
Cellulose nanomaterials have been demonstrated to be excellent barriers against grease, oxygen, and other vapors, but their implementation in packaging materials is challenging because of numerous technical and practical challenges. In this work, the oxygen, air, grease, and heptane barrier performance of copy papers coated with cellulose nanocrystals (CNCs), oxidized cellulose nanofibrils (TOCNs), and carboxymethyl cellulose (CMC) weas examined. The effects of different materials and processing conditions were evaluated for their impacts on the resulting barrier properties. TOCN coatings demonstrated significantly better barrier properties than CNC and CMC coatings due to the long-range networked structure of TOCN suspensions eliciting enhanced film formation at the paper surface. Neat coatings of nanocellulose did not readily result in strong oxygen barriers, but the addition of CMC and/or an additional waterborne water barrier coating was found to result in oxygen barriers suitable for packaging applications (1 cm3/m2·day transmission at low humidity with a 10 g/m2 coating). Cast films and thick coatings of CMC were good barriers to oxygen, grease, and air, and its addition to cellulose nanomaterial suspensions aided the coating process and reduced coating defects. In all cases, the incorporation of additional processing aids or coatings was necessary to achieve suitable barrier properties. However, maintaining the strong barrier properties of nanocellulose coatings after creasing remains challenging. Full article
(This article belongs to the Special Issue Recent Progress on Lignocellulosic-Based Materials)
26 pages, 4125 KiB  
Article
An RNN-CNN-Based Parallel Hybrid Approach for Battery State of Charge (SoC) Estimation Under Various Temperatures and Discharging Cycle Considering Noisy Conditions
by Md. Shahriar Nazim, Md. Minhazur Rahman, Md. Ibne Joha and Yeong Min Jang
World Electr. Veh. J. 2024, 15(12), 562; https://doi.org/10.3390/wevj15120562 - 4 Dec 2024
Abstract
With the increasing use of lithium-ion (Li-ion) batteries in electric vehicles (EVs), accurately measuring the state of charge (SoC) has become crucial for ensuring battery reliability, performance, and safety. In addition, EVs operate in different environmental conditions with different driving styles, which also [...] Read more.
With the increasing use of lithium-ion (Li-ion) batteries in electric vehicles (EVs), accurately measuring the state of charge (SoC) has become crucial for ensuring battery reliability, performance, and safety. In addition, EVs operate in different environmental conditions with different driving styles, which also cause inaccurate SoC estimation resulting in reduced reliability and performance of battery management systems (BMSs). To address this issue, this work proposes a new hybrid method that integrates a gated recurrent unit (GRU), temporal convolution network (TCN), and attention mechanism. The TCN and GRU capture both long-term and short-term dependencies and the attention mechanism focuses on important features within input sequences, improving model efficiency. With inputs of voltage, current, and temperature, along with their moving average, the hybrid GRU-TCN-Attention (GTA) model is trained and tested in a range of operating cycles and temperatures. Performance metrics, including average RMSE (root mean squared error), MAE (mean absolute error), MaxE (maximum error), and R2 score indicates the model is performing well, with average values of 0.512%, 0.354%, 1.98%, and 99.94%, respectively. The proposed model performs well under both high and low noise conditions, with an RMSE of less than 2.18%. The proposed hybrid approach is consistently found to be superior when compared against traditional baseline models. This work offers a potential method for accurate SoC estimation in Li-ion batteries, which has an important impact on clean energy integration and battery management systems in EVs. Full article
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<p>Impact of noise addition on (<b>a</b>) voltage, (<b>b</b>) current, and (<b>c</b>) temperature at 0 °C.</p>
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<p>Proposed architecture.</p>
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<p>Causal convolution.</p>
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<p>(<b>a</b>) Dilated convolution, (<b>b</b>) dilated causal convolution.</p>
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<p>(<b>a</b>) Single TCN block, (<b>b</b>) TCN arrangement.</p>
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<p>(<b>a</b>) Single GRU block, (<b>b</b>) GRU block with attention.</p>
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<p>Attention mechanism.</p>
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<p>Performance of model for drive cycle HWFET at (<b>a</b>) 0° C, (<b>b</b>) 10 °C.</p>
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<p>Performance of model for drive cycle LA92 at (<b>a</b>) 0 °C, (<b>b</b>) 10 °C, and (<b>c</b>) 25 °C.</p>
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<p>Performance of model for drive cycle US06 at (<b>a</b>) 0 °C, (<b>b</b>) 10 °C, and (<b>c</b>) 25 °C.</p>
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<p>Performance of model for drive cycle UDDS at (<b>a</b>) 0 °C, (<b>b</b>) 10 °C, and (<b>c</b>) 25 °C.</p>
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<p>SoC estimation error (%) distribution for drive cycles (<b>a</b>) LA92 and (<b>b</b>) UDDS.</p>
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<p>SoC estimation error (%) distribution for drive cycles (<b>a</b>) US06 and (<b>b</b>) HWFET.</p>
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<p>SoC estimation error (%) distribution for drive cycles (<b>a</b>) LA92 and (<b>b</b>) UDDS under high noise conditions.</p>
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<p>SoC estimation noise distribution for drive cycles (<b>a</b>) US06 and (<b>b</b>) HWFET under high noise conditions.</p>
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<p>Model performance comparisons with A-TCN and A-GRU for drive cycle LA92 at (<b>a</b>) 0 °C, (<b>b</b>) 10 °C, and (<b>c</b>) 25 °C.</p>
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<p>Model performance comparisons with A-TCN and A-GRU for drive cycle US06 at (<b>a</b>) 0 °C, (<b>b</b>) 10 °C, and (<b>c</b>) 25 °C.</p>
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<p>Model performance comparisons with A-TCN and A-GRU for drive cycle UDDS at (<b>a</b>) 0 °C, (<b>b</b>) 10 °C, and (<b>c</b>) 25 °C.</p>
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<p>Model performance comparisons with A-TCN and A-GRU for drive cycle HWFET at (<b>a</b>) 0 °C and (<b>b</b>) 10 °C.</p>
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15 pages, 2580 KiB  
Article
Self-Attention (SA)-ConvLSTM Encoder–Decoder Structure-Based Video Prediction for Dynamic Motion Estimation
by Jeongdae Kim, Hyunseung Choo and Jongpil Jeong
Appl. Sci. 2024, 14(23), 11315; https://doi.org/10.3390/app142311315 - 4 Dec 2024
Abstract
Video prediction, which is the task of predicting future video frames based on past observations, remains a challenging problem because of the complexity and high dimensionality of spatiotemporal dynamics. To address the problems associated with spatiotemporal prediction, which is an important decision-making tool [...] Read more.
Video prediction, which is the task of predicting future video frames based on past observations, remains a challenging problem because of the complexity and high dimensionality of spatiotemporal dynamics. To address the problems associated with spatiotemporal prediction, which is an important decision-making tool in various fields, several deep learning models have been proposed. Convolutional long short-term memory (ConvLSTM) can capture space and time simultaneously and has shown excellent performance in various applications, such as image and video prediction, object detection, and semantic segmentation. However, ConvLSTM has limitations in capturing long-term temporal dependencies. To solve this problem, this study proposes an encoder–decoder structure using self-attention ConvLSTM (SA-ConvLSTM), which retains the advantages of ConvLSTM and effectively captures the long-range dependencies through the self-attention mechanism. The effectiveness of the encoder–decoder structure using SA-ConvLSTM was validated through experiments on the MovingMNIST, KTH dataset. Full article
(This article belongs to the Special Issue Novel Research on Image and Video Processing Technology)
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<p>ConvLSTM cell.</p>
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<p>SA-ConvLSTM cell.</p>
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<p>Internal structure of SAM.</p>
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<p>SA-ConvLSTM-based encoder–decoder structure.</p>
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<p>Visual performance comparison by model.</p>
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<p>SSIM comparison ConvLSTM and SA-ConvLSTM with different layer configurations.</p>
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<p>MAE comparison of ConvLSTM and SA-ConvLSTM with different layer configurations.</p>
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<p>MSE comparison of ConvLSTM and SA-ConvLSTM with different layer configurations.</p>
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<p>Number of parameters in ConvLSTM and SA-ConvLSTM models with different layer configurations.</p>
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14 pages, 2267 KiB  
Article
Aero-Engine Fault Detection with an LSTM Auto-Encoder Combined with a Self-Attention Mechanism
by Wenyou Du, Jingyi Zhang, Guanglei Meng and Haoran Zhang
Machines 2024, 12(12), 879; https://doi.org/10.3390/machines12120879 - 4 Dec 2024
Abstract
The safe operation of aero-engines is crucial for ensuring flight safety, and effective fault detection methods are fundamental to achieving this objective. In this paper, we propose a novel approach that integrates an auto-encoder with long short-term memory (LSTM) networks and a self-attention [...] Read more.
The safe operation of aero-engines is crucial for ensuring flight safety, and effective fault detection methods are fundamental to achieving this objective. In this paper, we propose a novel approach that integrates an auto-encoder with long short-term memory (LSTM) networks and a self-attention mechanism for the anomaly detection of aero-engine time-series data. The dataset utilized in this study was simulated from real data and injected with fault information. A fault detection model is developed utilizing normal data samples for training and faulty data samples for testing. The LSTM auto-encoder processes the time-series data through an encoder–decoder architecture, extracting latent representations and reconstructing the original inputs. Furthermore, the self-attention mechanism captures long-range dependencies and significant features within the sequences, thereby enhancing the detection accuracy of the model. Comparative analyses with the traditional LSTM auto-encoder, as well as one-class support vector machines (OC-SVM) and isolation forests (IF), reveal that the experimental results substantiate the feasibility and effectiveness of the proposed method, highlighting its potential value in engineering applications. Full article
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<p>Auto-encoder.</p>
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<p>LSTM structure.</p>
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<p>Self-attention structure.</p>
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<p>SLAE fault detection process.</p>
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<p>Fault detection flow chart.</p>
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<p>Fault 1 raw data.</p>
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<p>Fault 2 raw data.</p>
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<p>Fault 3 raw data.</p>
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<p>Fault 1 dection. (<b>a</b>) SLAE fault dection; (<b>b</b>) LSTM fault dection; (<b>c</b>) OC-SVM fault dection; (<b>d</b>) IF fault dection.</p>
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<p>Fault 2 dection. (<b>a</b>) SLAE fault dection; (<b>b</b>) LSTM fault dection; (<b>c</b>) OC-SVM fault dection; (<b>d</b>) IF fault dection.</p>
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<p>Fault 3 dection. (<b>a</b>) SLAE fault dection; (<b>b</b>) LSTM fault dection; (<b>c</b>) OC-SVM fault dection; (<b>d</b>) IF fault dection.</p>
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23 pages, 733 KiB  
Review
“Pleiotropic” Effects of Antibiotics: New Modulators in Human Diseases
by Carlo Airola, Andrea Severino, Irene Spinelli, Antonio Gasbarrini, Giovanni Cammarota, Gianluca Ianiro and Francesca Romana Ponziani
Antibiotics 2024, 13(12), 1176; https://doi.org/10.3390/antibiotics13121176 - 4 Dec 2024
Abstract
Antibiotics, widely used medications that have significantly increased life expectancy, possess a broad range of effects beyond their primary antibacterial activity. While some are recognized as adverse events, others have demonstrated unexpected benefits. These adjunctive effects, which have been defined as “pleiotropic” in [...] Read more.
Antibiotics, widely used medications that have significantly increased life expectancy, possess a broad range of effects beyond their primary antibacterial activity. While some are recognized as adverse events, others have demonstrated unexpected benefits. These adjunctive effects, which have been defined as “pleiotropic” in the case of other pharmacological classes, include immunomodulatory properties and the modulation of the microbiota. Specifically, macrolides, tetracyclines, and fluoroquinolones have been shown to modulate the immune system in both acute and chronic conditions, including autoimmune disorders (e.g., rheumatoid arthritis, spondyloarthritis) and chronic inflammatory pulmonary diseases (e.g., asthma, chronic obstructive pulmonary disease). Azithromycin, in particular, is recommended for the long-term treatment of chronic inflammatory pulmonary diseases due to its well-established immunomodulatory effects. Furthermore, antibiotics influence the human microbiota. Rifaximin, for example, exerts a eubiotic effect that enhances the balance between the gut microbiota and the host immune cells and epithelial cells. These pleiotropic effects offer new therapeutic opportunities by interacting with human cells, signaling molecules, and bacteria involved in non-infectious diseases like spondyloarthritis and inflammatory bowel diseases. The aim of this review is to explore the pleiotropic potential of antibiotics, from molecular and cellular evidence to their clinical application, in order to optimize their use. Understanding these effects is essential to ensure careful use, particularly in consideration of the threat of antimicrobial resistance. Full article
(This article belongs to the Section Antibiotics Use and Antimicrobial Stewardship)
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<p>Overview of immunomodulatory effect of antibiotics at a molecular level. Macrolides, tetracyclines, and fluoroquinolones reduce Toll-like receptor (TLR) expression by immune cells and lead to the inhibition of pro-inflammatory cytokine production, chemokines, and matrix metalloproteinases (MMPs), which play a significant role in enhancing both acute and chronic inflammation. Furthermore, some antibiotics, such as rifaximin, tetracyclines, and fluoroquinolones, indirectly modulate immune response by modulating the gut microbiota. Nonetheless, rifaximin demonstrates a specific anti-inflammatory effect by agonizing the pregnane X receptor (PXR). CXCL: chemokine (C-X-C motif) ligand; DAMPs: damage-associated molecular patterns; IL: interleukin; NLRP: NOD-like receptor protein 3; PAMPs: pathogen-associated molecular patterns; TNF- α: tumor necrosis factor α.</p>
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30 pages, 1713 KiB  
Article
Long-Range Wide Area Network Intrusion Detection at the Edge
by Gonçalo Esteves, Filipe Fidalgo, Nuno Cruz and José Simão
IoT 2024, 5(4), 871-900; https://doi.org/10.3390/iot5040040 (registering DOI) - 4 Dec 2024
Abstract
Internet of Things (IoT) devices are ubiquitous in various applications, such as smart homes, asset and people tracking, and city management systems. However, their deployment in adverse conditions, including unstable internet connectivity and power sources, present new cybersecurity challenges through new attack vectors. [...] Read more.
Internet of Things (IoT) devices are ubiquitous in various applications, such as smart homes, asset and people tracking, and city management systems. However, their deployment in adverse conditions, including unstable internet connectivity and power sources, present new cybersecurity challenges through new attack vectors. The LoRaWAN protocol, with its open and distributed network architecture, has gained prominence as a leading LPWAN solution, presenting novel security challenges. This paper proposes the implementation of machine learning algorithms, specifically the K-Nearest Neighbours (KNN) algorithm, within an Intrusion Detection System (IDS) for LoRaWAN networks. Through behavioural analysis based on previously observed packet patterns, the system can detect potential intrusions that may disrupt critical tracking services. Initial simulated packet classification attained over 90% accuracy. By integrating the Suricata IDS and extending it through a custom toolset, sophisticated rule sets are incorporated to generate confidence metrics to classify packets as either presenting an abnormal or normal behaviour. The current work uses third-party multi-vendor sensor data obtained in the city of Lisbon for training and validating the models. The results show the efficacy of the proposed technique in evaluating received packets, logging relevant parameters in the database, and accurately identifying intrusions or expected device behaviours. We considered two use cases for evaluating our work: one with a more traditional approach where the devices and network are static, and another where we assume that both the devices and the network are mobile; for example, when we need to report data back from sensors on a rail infrastructure to a mobile LoRaWAN gateway onboard a train. Full article
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<p>Architecture for IDS in the NS.</p>
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<p>Architecture for IDS in or near each LoRaWAN gateway.</p>
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<p>Dataset characteristics.</p>
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<p>Phik correlation between different variables of the dataset.</p>
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<p>Functional architecture.</p>
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<p>Packet classification flowcharts.</p>
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<p>Schematic of LoRaWAN connection between sensors and the network using an edge computing environment.</p>
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<p>Characteristics of the packets in the test dataset for the centralized server scenario.</p>
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<p>Intrusion detection results in the centralized server environment.</p>
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<p>Locations of the gateway during the edge computing experiment.</p>
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<p>Characteristics of the packets in the test dataset for the edge computing scenario.</p>
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<p>Intrusion detection results in the edge computing environment.</p>
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15 pages, 468 KiB  
Article
Artificial Intelligence in Slow Journalism: Journalists’ Uses, Perceptions, and Attitudes
by Iban Albizu-Rivas, Sonia Parratt-Fernández and Montse Mera-Fernández
Journal. Media 2024, 5(4), 1836-1850; https://doi.org/10.3390/journalmedia5040111 (registering DOI) - 4 Dec 2024
Viewed by 122
Abstract
Through long-form, creative, high-quality stories, slow journalism seeks to counteract the effects of speed and immediacy in news production and consumption primarily driven by technological advancements. The advantages of artificial intelligence (AI) in journalism include generating and enhancing content, reducing workloads, and consequently [...] Read more.
Through long-form, creative, high-quality stories, slow journalism seeks to counteract the effects of speed and immediacy in news production and consumption primarily driven by technological advancements. The advantages of artificial intelligence (AI) in journalism include generating and enhancing content, reducing workloads, and consequently giving journalists more time for non-routine and creative tasks. This raises the question of where AI fits into slow journalism. Twenty-one semi-structured interviews were conducted with practitioners of slow journalism in Spain to explore their use, attitudes, and perceptions of AI in their work. The findings indicate that the interviewees make rudimentary use of AI tools, and their attitudes range from a slight lack of interest to a willingness to learn more about them, alongside concerns regarding ethical boundaries and the potential for job losses. They assert that they have a moral and human responsibility when producing stories that AI cannot enhance in terms of quality, creativity, and emotional depth. It can be concluded that AI offers little to ‘slow’ journalists due to the significant limitations in enhancing long-form reporting. At most, it may enable them to streamline repetitive and non-creative work, thereby allowing the depth required in slow journalism, at least in its current state of development. Full article
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<p>Tasks for which AI is being used by ‘slow’ journalists.</p>
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21 pages, 10795 KiB  
Article
COSMIC-2 RFI Prediction Model Based on CNN-BiLSTM-Attention for Interference Detection and Location
by Cheng-Long Song, Rui-Min Jin, Chao Han, Dan-Dan Wang, Ya-Ping Guo, Xiang Cui, Xiao-Ni Wang, Pei-Rui Bai and Wei-Min Zhen
Sensors 2024, 24(23), 7745; https://doi.org/10.3390/s24237745 - 4 Dec 2024
Viewed by 146
Abstract
As the application of the Global Navigation Satellite System (GNSS) continues to expand, its stability and safety issues are receiving more and more attention, especially the interference problem. Interference reduces the signal reception quality of ground terminals and may even lead to the [...] Read more.
As the application of the Global Navigation Satellite System (GNSS) continues to expand, its stability and safety issues are receiving more and more attention, especially the interference problem. Interference reduces the signal reception quality of ground terminals and may even lead to the paralysis of GNSS function in severe cases. In recent years, Low Earth Orbit (LEO) satellites have been highly emphasized for their unique advantages in GNSS interference detection, and related commercial and academic activities have increased rapidly. In this context, based on the signal-to-noise ratio (SNR) and radio-frequency interference (RFI) measurements data from COSMIC-2 satellites, this paper explores a method of predicting RFI measurements using SNR correlation variations in different GNSS signal channels for application to the detection and localization of civil terrestrial GNSS interference signals. Research shows that the SNR in different GNSS signal channels shows a correlated change under the influence of RFI. To this end, a CNN-BiLSTM-Attention model combining a convolutional neural network (CNN), bi-directional long and short-term memory network (BiLSTM), and attention mechanism is proposed in this paper, and the model takes the multi-channel SNR time series of the GNSS as the input and outputs the maximum measured value of RFI in the multi-channels. The experimental results show that compared with the traditional band-pass filtering inter-correlation method and other deep learning models, the model in this paper has a root mean square error (RMSE), mean absolute error (MAE), and correlation coefficient (R2) of 1.0185, 1.8567, and 0.9693, respectively, in RFI prediction, which demonstrates a higher RFI detection accuracy and a wide range of rough localization capabilities, showing significant competitiveness. Since the correlation changes in the SNR can be processed to decouple the signal strength, this model is also suitable for future GNSS-RO missions (such as COSMIC-1, CHAMP, GRACE, and Spire) for which no RFI measurements have yet been made. Full article
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<p>The different signal transmission paths between the RFI source, the GNSS satellites, and the GNSS RO satellites (not to scale).</p>
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<p>SNR, S4 scintillation index, elevation angle, and RFI measurements for the POD 01 antenna of C2E1 satellite near 1:35 UTC on 1 January 2023: (<b>a</b>) SNR sequence of CA code L1 band for different channels. (<b>b</b>) S4 scintillation index. (<b>c</b>) Elevation angle of the LEO-GPS link. (<b>d</b>) Maximum value of RFI measurements in multiple channels.</p>
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<p>Changes in SNR, S4 scintillation index, and RFI measurements of the C2E1 satellite POD 01 antenna when scintillation occurs on 1 January 2023 near 1:10 UTC. (<b>a</b>) SNR sequence of CA code L1 band for different channels. (<b>b</b>) S4 scintillation index. (<b>c</b>) Maximum value of RFI measurements in multiple channels.</p>
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<p>Results of the interference detection algorithm: (<b>a</b>) The result of band-pass filtering and normalization of the multi-channel SNR sequence in <a href="#sensors-24-07745-f002" class="html-fig">Figure 2</a>a. (<b>b</b>) The calculated cross-correlation sequence after moving window normalization and filtering, as well as interference, can be detected by setting a threshold (set to 0.01 in this example).</p>
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<p>Spatial distribution of the orbits of GPS and COSMIC-2 satellites during the SNR duration in <a href="#sensors-24-07745-f002" class="html-fig">Figure 2</a>a.</p>
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<p>Calculation results of the RFI measurement sequence and cross-correlation sequence output by the C2E1 satellite 01 antenna on January 1, 2023 UTC. The two sequences also show a certain degree of correlation over the day: (<b>a</b>) RFI measurement sequence; (<b>b</b>) Calculated normalized cross-correlation sequence after band-pass filtering.</p>
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<p>Basic structure of a CNN model.</p>
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<p>LSTM model schematic.</p>
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<p>Schematic diagram of the BiLSTM model.</p>
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<p>Basic structure of the CNN-BiLSTM-Attention model used in this paper.</p>
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<p>Flowchart of the algorithm.</p>
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<p>Predicted RFI measurements and dRFI for the training set on the COSMIC-2 C2E1 satellite for the CNN-BiLSTM-Attention model. The dashed line in the figure indicates the interference threshold y = ±0.001, with the time resolution downsampled to 3 h: (<b>a</b>) the blue line is the true value of the RFI measurement, and the red line is the prediction result; (<b>b</b>) dRFI.</p>
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<p>Predicted RFI measurements and dRFI for the training set on the COSMIC-2 C2E1 satellite for the BiLSTM-Attention model. The dashed line in the figure indicates the interference threshold y = ±0.001, with the time resolution downsampled to 3 h: (<b>a</b>) the blue line is the true value of the RFI measurement, and the red line is the prediction result; (<b>b</b>) dRFI.</p>
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<p>Predicted RFI measurements and dRFI for the training set on the COSMIC-2 C2E1 satellite for the LSTM model. The dashed line in the figure indicates the interference threshold y = ±0.001, with the time resolution downsampled to 3 h: (<b>a</b>) the blue line is the true value of the RFI measurement, and the red line is the prediction result; (<b>b</b>) dRFI.</p>
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<p>Predicted RFI measurements and dRFI for the test set on the COSMIC-2 C2E1 satellite for the CNN-BiLSTM-Attention model. The dashed line in the figure indicates the interference threshold y = ±0.001, with the time resolution downsampled to 3 h: (<b>a</b>) the blue line is the true value of the RFI measurement, and the red line is the prediction result; (<b>b</b>) dRFI.</p>
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<p>Predicted RFI measurements and dRFI for the test set on the COSMIC-2 C2E1 satellite for the BiLSTM-Attention model. The dashed line in the figure indicates the interference threshold y = ±0.001, with the time resolution downsampled to 3 h: (<b>a</b>) the blue line is the true value of the RFI measurement, and the red line is the prediction result; (<b>b</b>) dRFI.</p>
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<p>Predicted RFI measurements and dRFI for the test set on the COSMIC-2 C2E1 satellite for the LSTM model. The dashed line in the figure indicates the interference threshold y = ±0.001, with the time resolution downsampled to 3 h: (<b>a</b>) the blue line is the true value of the RFI measurement, and the red line is the prediction result; (<b>b</b>) dRFI.</p>
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<p>Global RFI situation map of the six COSMIC-2 satellites’ 01 and 02 antenna superposition cases using the four methods mentioned in this paper and the actual measured values: (<b>a</b>) real measured values, and the three green dotted rectangles inside the marker are the primary sources of prediction error for various algorithms (<b>b</b>) CNN-BiLSTM-Attention, (<b>c</b>) BiLSTM-Attention, (<b>d</b>) LSTM, (<b>e</b>) normalized cross-correlation method with band-pass filtering.</p>
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<p>Global RFI situation map of the six COSMIC-2 satellites’ 01 and 02 antenna superposition cases using the four methods mentioned in this paper and the actual measured values: (<b>a</b>) real measured values, and the three green dotted rectangles inside the marker are the primary sources of prediction error for various algorithms (<b>b</b>) CNN-BiLSTM-Attention, (<b>c</b>) BiLSTM-Attention, (<b>d</b>) LSTM, (<b>e</b>) normalized cross-correlation method with band-pass filtering.</p>
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27 pages, 692 KiB  
Systematic Review
Duration of Antibiotic Treatment for Foot Osteomyelitis in People with Diabetes
by Meryl Cinzía Tila Tamara Gramberg, Bart Torensma, Suzanne van Asten, Elske Sieswerda, Louise Willy Elizabeth Sabelis, Martin den Heijer, Ralph de Vries, Vincent de Groot and Edgar Josephus Gerardus Peters
Antibiotics 2024, 13(12), 1173; https://doi.org/10.3390/antibiotics13121173 - 4 Dec 2024
Viewed by 127
Abstract
Background: The optimal antimicrobial treatment duration for diabetes-related foot osteomyelitis (DFO) currently needs to be determined. We systematically reviewed the effects of short and long treatment durations on outcomes of DFO. Methods: We performed a systematic review searching Cochrane, CENTRAL, MEDLINE, Embase, and [...] Read more.
Background: The optimal antimicrobial treatment duration for diabetes-related foot osteomyelitis (DFO) currently needs to be determined. We systematically reviewed the effects of short and long treatment durations on outcomes of DFO. Methods: We performed a systematic review searching Cochrane, CENTRAL, MEDLINE, Embase, and CINAHL Plus from inception up to 19 January 2024. Two independent reviewers screened the titles and abstracts of the studies. Studies comparing short (<6 weeks) and long (>6 weeks) treatment durations for DFO were included. The primary outcome was amputation; the secondary outcomes were remission, mortality, costs, quality of life, and adverse events. Risk of bias and GRADE were assessed. Results: We identified 2708 references, of which 2173 remained after removing duplicates. Two studies were included. Differences in methodology precluded a meta-analysis. The primary outcome, major amputation, was reported in one study, with a rate of 10% in both the intervention and comparison groups (p = 1.00), regardless of treatment duration. For the secondary outcome, remission rates, the first study reported 60% in the intervention group versus 70% in the comparison group (p = 0.50). In the second study, remission rates were 84% in the intervention group versus 78% in the comparison group (p = 0.55). Data for the outcomes mortality, costs, and quality of life were not available. Short treatment duration may lead to fewer adverse events. The risk of bias was assessed as low to moderate, and the level of evidence ranged from very low to moderate. Conclusions: Our findings suggest that for DFO, there is no difference between a shorter and more prolonged duration of antimicrobial treatment regarding amputation and remission, with potentially fewer adverse events with shorter treatment durations. However, the uncertainty stems from limited, heterogeneous studies and generally low-quality evidence marred by moderate biases, imprecision, and indirectness. More high-quality studies are needed to substantiate these findings. Full article
(This article belongs to the Special Issue Feature Papers in Therapy of Diabetic Foot Infections)
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<p>PRISMA flow chart.</p>
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24 pages, 1564 KiB  
Review
Application of Mixed-Mode Ventilation to Enhance Indoor Air Quality and Energy Efficiency in School Buildings
by Christopher Otoo, Tao Lu and Xiaoshu Lü
Energies 2024, 17(23), 6097; https://doi.org/10.3390/en17236097 - 4 Dec 2024
Viewed by 245
Abstract
Indoor air quality and energy efficiency are instrumental aspects of school facility design and construction, as they directly affect the physical well-being, comfort, and academic output of both pupils and staff. The challenge of balancing the need for adequate ventilation to enhance indoor [...] Read more.
Indoor air quality and energy efficiency are instrumental aspects of school facility design and construction, as they directly affect the physical well-being, comfort, and academic output of both pupils and staff. The challenge of balancing the need for adequate ventilation to enhance indoor air quality with the goal of reducing energy consumption has long been a topic of debate. The implementation of mixed-mode ventilation systems with automated controls presents a promising solution to address this issue. However, a comprehensive literature review on this subject is still missing. To address this gap, this review examines the potential application of mixed-mode ventilation systems as a solution to attaining improved energy savings without compromising indoor air quality and thermal comfort in educational environments. Mixed-mode ventilation systems, which combine natural ventilation and mechanical ventilation, provide the versatility to alternate between or merge both methods based on real-time indoor and outdoor environmental conditions. By analyzing empirical studies, case studies, and theoretical models, this review investigates the efficacy of mixed-mode ventilation systems in minimizing energy use and enhancing indoor air quality. Essential elements such as operable windows, sensors, and sophisticated control technologies are evaluated to illustrate how mixed-mode ventilation systems dynamically optimize ventilation to sustain comfortable and healthy indoor climates. This paper further addresses the challenges linked to the design and implementation of mixed-mode ventilation systems, including complexities in control and the necessity for climate-adaptive strategies. The findings suggest that mixed-mode ventilation systems can considerably lower heating, ventilation, and air conditioning energy usage, with energy savings ranging from 20% to 60% across various climate zones, while also enhancing indoor air quality with advanced control systems and data-driven control strategies. In conclusion, mixed-mode ventilation systems offer a promising approach for school buildings to achieve energy efficiency and effective ventilation without sacrificing indoor environment quality. Full article
(This article belongs to the Special Issue Energy Consumption and Environmental Quality in Buildings)
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<p>Structure of this study.</p>
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<p>Flow chart of the study screening process.</p>
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<p>The concept of natural ventilation.</p>
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<p>An example of mechanical ventilation.</p>
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<p>Mixed-mode design configuration.</p>
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<p>Concurrent mixed-mode ventilation design.</p>
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<p>Basic mixed-mode ventilation control [<a href="#B49-energies-17-06097" class="html-bibr">49</a>].</p>
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<p>Advanced automated control architecture.</p>
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<p>Advanced control strategies for mixed-mode ventilation.</p>
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21 pages, 4740 KiB  
Article
Multi-Scale Geometric Feature Extraction and Global Transformer for Real-World Indoor Point Cloud Analysis
by Yisheng Chen, Yu Xiao, Hui Wu, Chongcheng Chen and Ding Lin
Mathematics 2024, 12(23), 3827; https://doi.org/10.3390/math12233827 - 3 Dec 2024
Viewed by 281
Abstract
Indoor point clouds often present significant challenges due to the complexity and variety of structures and high object similarity. The local geometric structure helps the model learn the shape features of objects at the detail level, while the global context provides overall scene [...] Read more.
Indoor point clouds often present significant challenges due to the complexity and variety of structures and high object similarity. The local geometric structure helps the model learn the shape features of objects at the detail level, while the global context provides overall scene semantics and spatial relationship information between objects. To address these challenges, we propose a novel network architecture, PointMSGT, which includes a multi-scale geometric feature extraction (MSGFE) module and a global Transformer (GT) module. The MSGFE module consists of a geometric feature extraction (GFE) module and a multi-scale attention (MSA) module. The GFE module reconstructs triangles through each point’s two neighbors and extracts detailed local geometric relationships by the triangle’s centroid, normal vector, and plane constant. The MSA module extracts features through multi-scale convolutions and adaptively aggregates features, focusing on both local geometric details and global semantic information at different scale levels, enhancing the understanding of complex scenes. The global Transformer employs a self-attention mechanism to capture long-range dependencies across the entire point cloud. The proposed method demonstrates competitive performance in real-world indoor scenarios, with a mIoU of 68.6% in semantic segmentation on S3DIS and OA of 86.4% in classification on ScanObjectNN. Full article
(This article belongs to the Special Issue Machine Learning Methods and Mathematical Modeling with Applications)
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<p>Architecture of the proposed network.</p>
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<p>Multi-scale geometric feature extraction.</p>
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<p>Multi-scale attention module.</p>
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<p>Global Transformer.</p>
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<p>Visualization comparison of semantic segmentation results on S3DIS. The red rectangular boxes indicate the contrasting regions.</p>
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<p>Performance of different numbers of input points.</p>
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<p>Confusion matrix on S3DIS Area 5 with the comparison of the baseline (<b>a</b>) and our PointMSGT (<b>b</b>). The confusion matrix indicates that the overall performance of our proposed method is superior to that of the baseline.</p>
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<p>Visual comparison of baseline and our method on S3DIS. The yellow rectangular boxes indicate the contrasting regions.</p>
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<p>Ablation study of convolution kernels. The red rectangular boxes indicate the contrasting regions.</p>
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16 pages, 1601 KiB  
Article
Customer Churn Prediction Approach Based on LLM Embeddings and Logistic Regression
by Meryem Chajia and El Habib Nfaoui
Future Internet 2024, 16(12), 453; https://doi.org/10.3390/fi16120453 - 3 Dec 2024
Viewed by 322
Abstract
Nowadays, predicting customer churn is essential for the success of any company. Loyal customers generate continuous revenue streams, resulting in long-term success and growth. Moreover, companies are increasingly prioritizing the retention of existing customers due to the higher costs associated with attracting new [...] Read more.
Nowadays, predicting customer churn is essential for the success of any company. Loyal customers generate continuous revenue streams, resulting in long-term success and growth. Moreover, companies are increasingly prioritizing the retention of existing customers due to the higher costs associated with attracting new ones. Consequently, there has been a growing demand for advanced methods aimed at enhancing customer loyalty and satisfaction, as well as predicting churners. In our work, we focused on building a robust churn prediction model for the telecommunications industry based on large embeddings from large language models and logistic regression to accurately identify churners. We conducted extensive experiments using a range of embedding techniques, including OpenAI Text-embedding, Google Gemini Text Embedding, bidirectional encoder representations from transformers (BERT), Sentence-Transformers, Sent2vec, and Doc2vec, to extract meaningful features. Additionally, we tested various classifiers, including logistic regression, support vector machine, random forest, K-nearest neighbors, multilayer perceptron, naive Bayes, decision tree, and zero-shot classification, to build a robust model capable of making accurate predictions. The best-performing model in our experiments is the logistic regression classifier, which we trained using the extracted feature from the OpenAI Text-embedding-ada-002 model, achieving an accuracy of 89%. The proposed model demonstrates a high discriminative ability between churning and loyal customers. Full article
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<p>Zero-Shot Classifier Methodology.</p>
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<p>Multilayer perceptron (MLP) architecture.</p>
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<p>Churn Predictive Model Building Methodology.</p>
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<p>Final Model Deployment.</p>
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14 pages, 4248 KiB  
Article
Impact of Saharan Dust Intrusions on Atmospheric Boundary Layer Height over Madrid
by Francisco Molero, Pedro Salvador and Manuel Pujadas
Atmosphere 2024, 15(12), 1451; https://doi.org/10.3390/atmos15121451 - 3 Dec 2024
Viewed by 185
Abstract
Atmospheric pollution caused by aerosols deteriorates air quality, increasing public health risks. Anthropogenic aerosols are usually located within the atmospheric boundary layer (ABL), which presents a daytime evolution that determines the air pollutants’ vertical mixing of those produced near the surface and, therefore, [...] Read more.
Atmospheric pollution caused by aerosols deteriorates air quality, increasing public health risks. Anthropogenic aerosols are usually located within the atmospheric boundary layer (ABL), which presents a daytime evolution that determines the air pollutants’ vertical mixing of those produced near the surface and, therefore, their ground-level concentration from local sources. Precise and complete characterization of the mixing layer is of crucial importance for numerical weather forecasting and climate models, but traditional methods such as radiosounding present some spatial and temporal limitations. Better resolutions have been obtained using lidar, which provides the aerosol vertical distribution. A particular type of lidar, the ceilometer, has demonstrated continuous measurement capabilities, providing vertical profiles with sub-minute time resolution and several-meter spatial resolution. Advanced methods, such as the recently developed STRATfinder algorithm, are required to estimate the ABL height in the presence of residual layers. More complex situations occur due to the advection of aerosols (e.g., due to long-range transport of desert dust, volcanic eruptions, or pyrocloud convection), producing a lofted layer in the free troposphere that may remain decoupled from the local ABL but can also be mixed. Aerosol-based methods for determination of the ABL height are challenging in those situations. The main objective of this research is the assessment of the impact of Saharan dust intrusions on the ABL using ceilometer signals, over a period of four years, 2020–2023. The ABL height database, obtained from ceilometer measurements every hour, is analyzed based on the most frequent synoptic patterns. A reduction in the ABL height was obtained from high dust load days (1576 ± 876 m) with respect to low dust load days (1857 ± 914 m), although it was still higher than clean days (1423 ± 772 m). This behavior is further studied discriminating by season and synoptic patterns. These results are relevant for health advice during Saharan dust intrusion days. Full article
(This article belongs to the Section Aerosols)
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<p>CIEMAT-Madrid site, located in the middle of the Iberian Peninsula (<b>left panel</b>), and northwest of Madrid City (<b>middle panel</b>), with the instrument (<b>right panel</b>). The satellite image at the left panel also shows a Saharan dust intrusion.</p>
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<p>Synoptic meteorological patterns (SMPs) obtained by cluster analysis of reanalysis global fields of sea level pressure at 12 UTC for the period 2001–2019. Colored areas represent atmospheric pressure measured in hPa. Cool colors are used to represent low pressures, while warm colors symbolize higher pressures. The x-axis represents longitude, while the y-axis represents latitude, both measured in degrees. The North Atlantic, Europe and North Africa are depicted on the maps.</p>
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<p>Quicklook of the range-corrected signal (raw signal multiplied by the square of range) calibrated at 1064 nm, as a color scale, and the prediction provided by the STRATfinder algorithm of the MLH (black circles) and ABLH (red crosses) at (<b>a</b>): 21 June 2022 and (<b>b</b>): 15 June 2021. The x-axis represents the time, 24 h, and the vertical axis is the height, with the color scale representing the range-corrected signal.</p>
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<p>MLH estimations (black crosses, left y-axis) and Saharan dust load (orange circles, right y-axis) for days between January 2020 and December 2023.</p>
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<p>Boxplots of MLH for all the days separated by (<b>a</b>) season and (<b>b</b>) synoptic meteorological pattern. As usual, the red line in the middle of the boxplot represents the median of the values for that group; the box comprises the interquartile range and the top and bottom lines are the maximum and minimum values, respectively. The means have also been represented as blue circles.</p>
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<p>Seasonal distribution of cases; number of cases for each season divided by the total number of cases assigned to that SMP, for the six synoptic meteorological patterns during the period 2020–2023.</p>
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<p>Boxplots of MLH for (<b>a</b>) Saharan and clean days and (<b>b</b>) high dust load, low dust load and clean days.</p>
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<p>Boxplots of Saharan and clean days separated by (<b>a</b>) season and (<b>b</b>) synoptic meteorological pattern.</p>
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<p>Distribution of clean (blue bars), low dust load (red bars) and high dust load days (orange bars) regarding the synoptic meteorological patterns for the period 2020–2023.</p>
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<p>Boxplots of high dust load, low dust load and clean days, separated (<b>a</b>) by season and (<b>b</b>) by synoptic meteorological pattern.</p>
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