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Search Results (100,290)

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13 pages, 1978 KiB  
Article
Influence of Composition on the Patterns of Electrokinetic Potential of Thermosensitive N-(Isopropyl)Acrylamide Derivatives with Poly(Ethylene Glycol) Dimethacrylate and N-(2-Hydroxyethyl)Acrylamide
by Monika Gasztych, Aleksandra Malamis-Stanowska, Mateusz Trafalski and Witold Musiał
Int. J. Mol. Sci. 2024, 25(24), 13554; https://doi.org/10.3390/ijms252413554 (registering DOI) - 18 Dec 2024
Abstract
The synthesis of poly(N-isopropyl acrylamide) (pNIPA)-based polymers via the surfactant-free precipitation polymerization (SFPP) method produced thermosensitive nanospheres with a range of distinctive physicochemical properties. Nano- and microparticles were generated using various initiators, significantly influencing particle characteristics, including the hydrodynamic diameter (DH), [...] Read more.
The synthesis of poly(N-isopropyl acrylamide) (pNIPA)-based polymers via the surfactant-free precipitation polymerization (SFPP) method produced thermosensitive nanospheres with a range of distinctive physicochemical properties. Nano- and microparticles were generated using various initiators, significantly influencing particle characteristics, including the hydrodynamic diameter (DH), which varied from 87.7 nm to 1618.1 nm. Initiators, such as potassium persulfate and 2,2′-azobis(2-methylpropionamidine) dihydrochloride, conferred anionic and cationic functionalities, respectively, impacting the electrokinetic potential (EP) of the particles. Notably, certain particles with cationic initiators exhibited negative EP values at 18 °C, attributed to residual initiator components that affected the surface charge distribution. The presence of hydrophilic N-(2-hydroxyethyl)acrylamide (HEAA) segments also influenced solubility and phase transition behaviors, with critical dependencies on the HEAA/NIPA (N-isopropyl acrylamide) molar ratios. EP measurements taken at 18 °C and 42 °C revealed substantial differences, primarily governed by the initiator type and polymer composition. Observed variations in particle stability and size were associated with the choice of crosslinking agents and comonomer content, which affected both DH and EP in distinct ways. This study provides insights into key factors influencing colloidal stability and electrostatic interactions within thermosensitive polymer systems, underscoring their potential applications in biomedical and industrial fields. Full article
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<p>Chemical structure of a NIPA N-isopropyl acrylamide monomer. The central amide group enhances water solubility through hydrogen bonding, counteracting the hydrophobic characteristics of the chain backbone and side group [<a href="#B18-ijms-25-13554" class="html-bibr">18</a>].</p>
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<p>The effect of the temperature on the polydispersity index (PDI)—<span style="color:#ED7D31">●</span> and hydrodynamic diameter (D<sub>H</sub>)—<span style="color:#4472C4">●</span> of the synthesized particles N1–N6 obtained from dynamic light scattering.</p>
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<p>Schematic diagram of the methods and abbreviated results used in the present work—measurement of particle size, zeta potential, and phase transition temperature.</p>
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<p>The variability of the pH values of particles N1–N6, polymers synthesized with the anionic initiator (black columns, left side), and polymers synthesized with the cationic initiator (blue col-umns). Full columns are the pH values before purification, and gradient columns are the pH values after purification.</p>
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<p>The electrokinetic potential, pH, and size of assessed polymeric particles. The red dotted arrows represent the increase in temperature from 18 to 42 °C. Type of particle: at 18 °C: (1)-N2 (blue) and N5 (grey); (2)-N3 (blue) and N6 (grey); (3)-N1 (blue) and N4 (grey); at 42 °C: (1)-N2 (orange) and N5 (yellow); (2)-N3 (orange) and N6 (yellow); (3)-N1 (orange) and N4 (yellow).</p>
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<p>Schematic diagram showing composition and smallest and largest molecule sizes at 18 and 42 °C.</p>
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28 pages, 19250 KiB  
Article
Application of Powder-Bed Fusion of Metals Using a Laser for Manufacturing of M300 Maraging Steel Tools Intended for Sheet Metal Bending
by Krzysztof Żaba, Maciej Balcerzak, Łukasz Kuczek, Marcel Wiewióra, Ilona Różycka, Tomasz Trzepieciński and Jarosław Mizera
Materials 2024, 17(24), 6185; https://doi.org/10.3390/ma17246185 (registering DOI) - 18 Dec 2024
Abstract
This paper presents the results of a pilot application of Powder-Bed Fusion of Metals Using a Laser (PBF-LB/M) for the fabrication of M300 (1.2709) maraging steel sheet metal bending tools. S235 steel was used as a substrate for the fabrication of bending punches. [...] Read more.
This paper presents the results of a pilot application of Powder-Bed Fusion of Metals Using a Laser (PBF-LB/M) for the fabrication of M300 (1.2709) maraging steel sheet metal bending tools. S235 steel was used as a substrate for the fabrication of bending punches. The main goal of the research was to determine the usability of such tools without heat treatment, which would contribute to the increase in the cost of tool production. Industrial tests of tools were conducted during the forming of Inconel 625 and AW-6061 T0 aluminium alloy sheets. The punches were subjected to tests of surface roughness, hardness, microstructure, porosity, and geometric quality in order to verify the quality and accuracy of tools made by the PBF-LB/M technique before and after experimental investigations in industrial conditions in a selected manufacturing company. It was found that tools with an M300 steel working layer after the PBF-LB/M process without heat treatment show suitability for bending sheet metal in a certain range of force parameters, ensuring obtaining elements after bending from Inconel 625 and AW-6061 T0 aluminium alloy sheets of the required geometric quality. Full article
(This article belongs to the Special Issue Design and Application of Additive Manufacturing: Volume III)
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<p>Geometry and dimensions (in mm) of the bending tool (<b>a</b>) and model of a tool part manufactured using AM (<b>b</b>).</p>
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<p>SEM image of M300 steel powder.</p>
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<p>The 3D-printed M300 steel working layers of tools on a 235 steel plate (<b>a</b>), bending tool in as-received state (<b>b</b>), and bending tool after polishing (<b>c</b>).</p>
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<p>Bending tool (inside the red circle) mounted in the holder (<b>a</b>); test stand during industrial tests (<b>b</b>).</p>
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<p>Bending process diagram (<b>a</b>); tool mounting diagram in the press (<b>b</b>).</p>
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<p>A punch with a M300 steel working part made using 3D printing technology (<b>a</b>), drawpieces made of Inconel 625 alloy sheet (<b>b</b>), and AW-6061 T0 aluminium alloy sheet (<b>c</b>).</p>
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<p>Principle of operations of T-05 roller-block tester: 1—block, 2—roller, 3—insert, and 4—sample holder (<b>a</b>) [<a href="#B59-materials-17-06185" class="html-bibr">59</a>]; example of 3D-printed M300 steel countersample (<b>b</b>).</p>
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<p>Schematic representation of Vickers hardness measurement for 3D-printed tools.</p>
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<p>Measurement points for the hardness of drawpieces.</p>
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<p>(<b>a</b>) Surface view, (<b>b</b>) surface topography, and (<b>c</b>) roughness profiles of as-received tool.</p>
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<p>(<b>a</b>) Surface view, (<b>b</b>) surface topography, and (<b>c</b>) roughness profiles of tool after polishing.</p>
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<p>Dependence of friction force on time of tested sheet metal samples of AW-6061 T0 (<b>a</b>) and Inconel 625 (<b>b</b>).</p>
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<p>Hardness distribution on the cross-section of the PBF-LB/M printed punch—before forming.</p>
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<p>Microstructure of M300 steel after PBF-LB/M process: the cross-section of 3D-printed M300Steel and base S325 steel material (<b>a</b>) and point chemical composition of cross-section (<b>b</b>).</p>
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<p>Sample with a working layer after 3D printing without surface treatment: 3D view of reconstructed data (<b>a</b>), visualization of porosity (<b>b</b>) and sample with a working layer after 3D printing and polishing 3D view of reconstructed data (<b>c</b>), and visualization of porosity (<b>d</b>).</p>
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<p>Hardness distribution on the cross-section of the PBF-LB/M printed punch (without finishing) after forming the Inconel 625 alloy sheet.</p>
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<p>Hardness distribution on the cross-section of the PBF-LB/M printed punch (polished surface) after forming the Inconel 625 alloy sheet.</p>
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<p>Deformation of a 3D-printed tool (without finishing) after industrial tests.</p>
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<p>Deformation of a 3D-printed tool (polished surface) after industrial tests.</p>
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<p>(<b>a</b>) Surface view of surface of drawpiece made of Inconel 625 material, (<b>b</b>) surface topography, and (<b>c</b>) roughness profiles.</p>
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<p>(<b>a</b>) Surface view of surface of drawpiece made of AW-6061 T0 material, (<b>b</b>) surface topography, and (<b>c</b>) roughness profiles.</p>
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<p>Microstructure of the Inconel 625 alloy after the stamping process: (<b>a</b>) sheet surface after forming with a PBF-LB/M printed punch, (<b>b</b>) sheet surface after forming with a polished punch, (<b>c</b>) microstructure inside the tested material after forming with a PBF-LB/M printed punch, and (<b>d</b>) microstructure inside the tested material after forming with a polished punch.</p>
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<p>Microstructure of the AW-6061 T0 aluminium alloy after the stamping process: (<b>a</b>) sheet surface after forming with a LPBF PBF-LB/M printed punch and (<b>b</b>) sheet surface after forming with a polished punch, (<b>c</b>) microstructure inside the tested material after forming with a PBF-LB/M printed punch, and (<b>d</b>) microstructure inside the tested material after forming with a polished punch.</p>
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<p>Deviation of geometry of the Inconel 625 alloy drawpieces formed under the load of: (<b>a</b>) 3 Mg (29.43 kN), (<b>b</b>) 5 Mg (49.05 kN), (<b>c</b>) 10 Mg (98.10 kN), and (<b>d</b>) 15 Mg (147.15 kN).</p>
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<p>Deviation of geometry of the AW-6061 T0 aluminium alloy drawpieces formed under the load of: (<b>a</b>) 3 Mg (29.43 kN), (<b>b</b>) 5 Mg (49.05 kN), (<b>c</b>) 10 Mg (98.10 kN), and (<b>d</b>) 15 Mg (147.15 kN).</p>
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28 pages, 2956 KiB  
Article
A Study on the Exploration of the Development Process of Regenerative Applications of Energy Technologies in Industrial Warehouse Buildings: Bibliometric Research from 2004 to 2024
by Hongyu Chen, Difei Zhao, Jiayi Li, Lanxi Zhang, Ting Shen and Yinghao Yin
Buildings 2024, 14(12), 4019; https://doi.org/10.3390/buildings14124019 (registering DOI) - 18 Dec 2024
Abstract
Due to the high energy consumption characteristics of industrial warehouse buildings, the demand for energy regeneration technology is increasingly urgent. In recent years, with the rapid development of building energy technology, warehouse building energy regeneration technology has made remarkable progress in energy conservation [...] Read more.
Due to the high energy consumption characteristics of industrial warehouse buildings, the demand for energy regeneration technology is increasingly urgent. In recent years, with the rapid development of building energy technology, warehouse building energy regeneration technology has made remarkable progress in energy conservation and sustainable development. A deep understanding of the previous research progress and trends can provide the scientific basis for guiding subsequent in-depth research. Through the bibliometric analysis of 145 journal articles collected from the Web of Science (WoS) database between 2004 and 2024, this research has studied the research trends and progress on the application of energy regeneration in industrial warehouse buildings. This study first revealed the overall development trend of energy regeneration technology in warehouse buildings through quantitative analysis, indicating that related research is growing rapidly. Core scholars in the field such as Lund H. and Mathiesen B.V., as well as major journals such as Energy and Sustainability, have been identified through the analysis of the literature. Five core research themes, including energy efficiency improvement and regeneration technology, renewable energy system design, life cycle sustainable technology, renewable energy utility assessment, and policy support and energy consumption simulation, were identified through cluster analysis. Through evolutionary analysis, this study demonstrates the development process of energy regeneration in warehouse buildings and the critical role played by advances in new energy technologies in the field of warehouse construction. On this basis, this study proposes current key research directions, including energy life cycle assessment, energy regeneration environment optimization, and energy system management. The research on the energy regeneration of warehouse buildings has gradually become an important cross-subject of architecture and energy technology, providing technical support for the transformation of low-carbon storage buildings. The analysis of the current research status, evolutionary logic, and research trends can provide scientific references for further in-depth research and technological applications in this field. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
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<p>Number of Publications in Warehouse Building Energy Technology.</p>
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<p>Data retrieval, filtering, and standardization process.</p>
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<p>Time trend of the publications on warehouse building energy technology.</p>
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<p>Country and its cooperative relations and string diagram.</p>
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<p>Co-occurrence of keywords.</p>
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<p>Keyword evolution based on CiteSpace.</p>
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<p>Explosive words in the field of warehouse building energy regeneration research from 2004 to 2024.</p>
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18 pages, 1899 KiB  
Article
A Bibliometric Analysis of Generation Z and Tourism Research: Insights from VOSviewer Mapping
by Ioana-Simona Ivasciuc, Adina Nicoleta Candrea, Ana Ispas and Brenda-Andreea Piuaru
Adm. Sci. 2024, 14(12), 337; https://doi.org/10.3390/admsci14120337 (registering DOI) - 18 Dec 2024
Abstract
In recent years, Generation Z has had a pivotal influence across global industries, with tourism being significantly impacted. As the first generation fully immersed in digital technology, Generation Z members have travel preferences, behaviours, and values which differ markedly from previous generations, presenting [...] Read more.
In recent years, Generation Z has had a pivotal influence across global industries, with tourism being significantly impacted. As the first generation fully immersed in digital technology, Generation Z members have travel preferences, behaviours, and values which differ markedly from previous generations, presenting both challenges and opportunities for the tourism sector. This study explores studies on Generation Z in the context of the tourism industry through key research questions, including the primary trends and thematic clusters in the existing literature, the most influential journals and authors, and the temporal evolution of research in this area. To address these questions, this article presents a comprehensive bibliometric analysis of 217 publications on Generation Z and tourism, spanning from 2018 to 2024, sourced from the Web of Science. Using VOSviewer, the analysis maps the main trends, the most influential publications, and the emerging themes, providing insights into how Generation Z is reshaping the tourism landscape. The bibliometric analysis and VOSviewer mapping add a rigorous methodological approach, offering a structured overview of existing research while identifying gaps for further exploration, especially in this emerging field. The study highlights the most published and cited journals, providing a broad contextual view, followed by an in-depth exploration of thematic clusters within Generation Z tourism research. The results indicate that although research on this topic gained attention in 2018, it is still in its early stages, with significant room for expansion. Current studies primarily focus on social media marketing communications for Generation Z, as well as Generation Z tourism experiences and their attitudes and preferences towards tourism, suggesting areas for future exploration. Full article
(This article belongs to the Special Issue Tourism and Hospitality Marketing: Trends and Best Practices)
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<p>Research stages Source: authors’ processing.</p>
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<p>Studies on Generation Z and tourism, by journal. Source: authors’ processing in Excel, using Web of Science indexed articles. Source: authors’ processing.</p>
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<p>A map of the occurrence of studies on Generation Z and tourism experiences, by country. Source: authors’ processing in VOSviewer, using Web of Science indexed articles. Source: authors’ processing.</p>
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<p>Trends of publications and citations on Generation Z and tourism. Source: authors’ processing in Excel, using Web of Science indexed articles.</p>
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<p>A map of the occurrences and links for terms related to Generation Z and tourism. Source: authors’ processing in VOSviewer, using Web of Sciences indexed articles.</p>
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<p>Interconnections between clusters. Source: authors’ processing.</p>
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20 pages, 1454 KiB  
Review
Understanding the Causes of Keel Bone Damage and Its Effects on the Welfare of Laying Hens
by Xin Li, Xia Cai, Xiaoliang Wang, Lihui Zhu, Huaxiang Yan, Junfeng Yao and Changsuo Yang
Animals 2024, 14(24), 3655; https://doi.org/10.3390/ani14243655 (registering DOI) - 18 Dec 2024
Abstract
Keel bone damage (KBD) is a prominent concern within the realm of the egg-laying industry, exerting substantial impacts on the welfare and productivity of laying hens. This comprehensive review undertakes a detailed exploration of the diverse factors contributing to KBD, such as inadequate [...] Read more.
Keel bone damage (KBD) is a prominent concern within the realm of the egg-laying industry, exerting substantial impacts on the welfare and productivity of laying hens. This comprehensive review undertakes a detailed exploration of the diverse factors contributing to KBD, such as inadequate calcium sources in the medullary bone, genetic factors, nutritional deficiencies, and physical stressors. The consequences of KBD on production performance, stress and inflammation levels, and the physical and chemical properties of the keel are meticulously examined. Additionally, the review evaluates the existing methods for assessing KBD, including keel curvature scoring, imaging techniques, palpation, biomechanical testing, behavioral observations, and biochemical markers. Finally, management strategies, including nutritional adjustments, genetic selection, and environmental modifications, are proposed to potentially mitigate the prevalence and severity of KBD, thereby aiming to enhance the welfare and productivity of laying hens. Full article
(This article belongs to the Section Poultry)
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<p>Types and functions of bones. The chart uses different colors to distinguish and emphasize different content.</p>
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<p>Timeline of keel bone maturation [<a href="#B1-animals-14-03655" class="html-bibr">1</a>,<a href="#B7-animals-14-03655" class="html-bibr">7</a>,<a href="#B49-animals-14-03655" class="html-bibr">49</a>,<a href="#B50-animals-14-03655" class="html-bibr">50</a>]. In the figure, different colors are used to distinguish various stages and events in the development of laying hens and keels.</p>
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<p>Characteristics and possible causes of keel bone damage in laying hens.</p>
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34 pages, 3107 KiB  
Review
Nanotechnology for Healthcare: Plant-Derived Nanoparticles in Disease Treatment and Regenerative Medicine
by Arun Karnwal, Amar Yasser Jassim, Ameer Abbas Mohammed, Vikas Sharma, Abdel Rahman Mohammad Said Al-Tawaha and Iyyakkannu Sivanesan
Pharmaceuticals 2024, 17(12), 1711; https://doi.org/10.3390/ph17121711 (registering DOI) - 18 Dec 2024
Abstract
Nanotechnology has revolutionised biomedical research, offering innovative healthcare solutions. Plant-based nanotechnology is emerging as a sustainable alternative, minimising environmental impacts and enhancing therapeutic effectiveness. This paper explores the potential of plant-derived nanoparticles (PNPs) in medicine, highlighting their biocompatibility, multifunctionality, and eco-friendliness. PNPs, synthesised [...] Read more.
Nanotechnology has revolutionised biomedical research, offering innovative healthcare solutions. Plant-based nanotechnology is emerging as a sustainable alternative, minimising environmental impacts and enhancing therapeutic effectiveness. This paper explores the potential of plant-derived nanoparticles (PNPs) in medicine, highlighting their biocompatibility, multifunctionality, and eco-friendliness. PNPs, synthesised through green methods, have demonstrated promising applications in drug delivery, cancer therapy, antimicrobial treatments, and tissue regeneration. Their unique properties, such as a high surface area and bioactive components, enable improved drug delivery, targeting, and controlled release, reducing side effects and enhancing treatment efficacy. Additionally, plant-derived compounds’ inherent antimicrobial and antioxidant properties, retained within platinum nanoparticles (PNPs), present innovative opportunities for combating antimicrobial resistance and promoting wound healing. Despite their potential, challenges remain in standardising PNP synthesis, ensuring consistency, and scaling up production for industrial applications. This review emphasises the need for further research on PNP toxicity, biocompatibility, and regulatory frameworks to fully harness their capabilities in clinical and commercial applications. Plant-based nanotechnology represents a promising, greener alternative for advancing healthcare solutions, aligning with global sustainability goals. Full article
(This article belongs to the Special Issue Recent Advances in Natural Product Based Nanostructured Systems)
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<p>Methods commonly used for nanoparticle synthesis: (<b>a</b>) Physical, chemical, and physicochemical techniques employed in the production of nanomaterials; (<b>b</b>) nanoparticle fabrication through bottom-up and top-down approaches, which are widely recognised methods for creating nanoparticles.</p>
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<p>Different applications of nanoparticles (NPs) in the medical and healthcare industries. Nanoparticles are used in various ways, including in drug delivery systems for targeted and controlled release, improving the effectiveness of cancer treatments, enhancing diagnostic imaging techniques, and facilitating wound healing and tissue regeneration. They also play a role in antimicrobial therapies, helping combat infections and developing advanced medical devices. These diverse applications highlight the potential of NPs to revolutionise healthcare by improving patient outcomes and treatment precision.</p>
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<p>Eco-friendly synthesis of nanoparticles using plant and microbial resources, emphasising sustainable methods. This process utilises natural materials such as plant extracts and microorganisms to create nanoparticles, offering an environmentally friendly alternative to traditional chemical synthesis. These biological resources reduce the environmental impact and enhance the biocompatibility and functionality of the nanoparticles, making them ideal for applications in medicine and other industries.</p>
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<p>The antimicrobial effects of silver nanoparticles (AgNPs) involve several mechanisms: (1) Disruption of the cell wall and cytoplasmic membrane: silver ions (Ag<sup>+</sup>) released from silver nanoparticles adhere to or penetrate the cell wall and cytoplasmic membrane. (2) Ribosome denaturation: silver ions disrupt ribosomes, hindering protein synthesis. (3) Membrane disruption by reactive oxygen species: reactive oxygen species, generated from the disrupted electron transport chain, can lead to membrane damage. (4) Interference with DNA replication: silver ions and reactive oxygen species bind to DNA, preventing its replication and cell division. (5) Membrane denaturation: silver nanoparticles accumulate in cell wall recesses, leading to membrane denaturation. (6) Membrane perforation: silver nanoparticles traverse the cytoplasmic membrane, potentially releasing cellular organelles.</p>
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<p>Application of gold nanoparticles in various areas for human welfare. From biomedical fields such as diagnostics, therapeutics, and drug delivery to environmental remediation and catalysis, AuNPs showcase remarkable versatility. Their unique physicochemical properties enable precise imaging in medical diagnostics, targeted drug delivery for enhanced therapeutic efficacy, and efficient pollutant removal from water and air. As a result, AuNPs stand as critical players in advancing technologies to improve human health and environmental sustainability.</p>
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<p>Illustration depicting common applications of metal oxide nanoparticles in various fields, showcasing their versatility and impact.</p>
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<p>Revitalising wounds with eco-friendly nanoparticles: A sustainable approach to accelerated healing using green-derived nanoparticles. This figure illustrates the application of biologically synthesised nanoparticles, emphasising their biocompatibility, enhanced wound repair properties, and reduced environmental footprint.</p>
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<p>Treatment of defective bone using green nanomaterial: a schematic representation showcasing the application of nanostructured scaffolds in bone repair. These greener nanomaterials are designed to enhance biocompatibility, promote cellular regeneration, and provide structural support, paving the way for sustainable and efficient bone tissue engineering solutions.</p>
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27 pages, 16290 KiB  
Article
Unveiling the Potential of Civil Briquette Furnace Slag as a Silico–Aluminon Additive in Alkali-Activated Materials
by Suoying Ren, Liang Li, Xianhui Zhao, Haoyu Wang and Renlong Zhao
Materials 2024, 17(24), 6188; https://doi.org/10.3390/ma17246188 (registering DOI) - 18 Dec 2024
Abstract
Civil briquette furnace slag (FS), as a type of industrial solid waste, is not currently being recycled as a resource by the building materials industry. This study focuses on the potential of FS in the formulation of alkali-activated materials (AAMs) compared with calcium [...] Read more.
Civil briquette furnace slag (FS), as a type of industrial solid waste, is not currently being recycled as a resource by the building materials industry. This study focuses on the potential of FS in the formulation of alkali-activated materials (AAMs) compared with calcium carbide slag (CS). This study encompasses three distinct AAM systems: alkali-activated fly ash alone (AAFA), fly ash–slag powder blends (AAFB), and slag powder alone (AABS). Electrical conductivity, fluidity, drying shrinkage, and flexural and compressive strengths were also assessed. Advanced characterization techniques, including SEM-EDS, XRD, FTIR, and TG-DSC, were utilized to examine the morphology, mineralogy, and reaction products. Despite the chemical similarity between FS and CS, FS exhibits limited active chemical components (SiO2, Al2O3, CaO, and MgO) and primarily functions as a physical filler, and thus lacks the chemical binding properties of CS. FS has a positive effect on the long-term compressive strength of the AABS system but not on the AAFA and AAFB systems. The NaOH-activated SP mortar sample with 20% FS reaches a compressive strength of 29.8 MPa at 360 days. The binding strength in AAMs incorporating FS is predominantly attributed to the gel formation within the alkali-activated matrix. This research offers valuable insights into the strategic use and substitution of CS, FS, and other silico–aluminon additives within the context of AAMs development. Full article
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<p>SEM images of silica–alumina precursors and additives: (<b>a</b>) fly ash, (<b>b</b>) slag powder, (<b>c</b>) calcium carbide slag, and (<b>d</b>) furnace slag.</p>
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<p>(<b>a</b>) XRD pattern and (<b>b</b>) FTIR spectrum of river sand as fine aggregate.</p>
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<p>Schematic diagram of alkali-activated samples with FS and controls about the preparation process and experiment measurements.</p>
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<p>(<b>a</b>) Fluidity and (<b>b</b>) electrical conductivity of fresh alkali-activated mixtures incorporating FS or CS.</p>
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<p>Drying shrinkage of alkali-activated mortars incorporating FS or CS with curing ages.</p>
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<p>(<b>a</b>) The 28-d flexural strengths, (<b>b</b>) 28-d compressive strengths, (<b>c</b>) 360-d flexural strengths, and (<b>d</b>) 360-d compressive strengths of alkali-activated mortars incorporating FS or CS.</p>
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<p>SEM images and EDS spectra of 360 d samples from the AAFA system. (<b>a</b>) FA1, (<b>b</b>) FA2, and (<b>c</b>) FA3.</p>
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<p>SEM images and EDS spectra of 360 d samples from the AAFA system. (<b>a</b>) FA1, (<b>b</b>) FA2, and (<b>c</b>) FA3.</p>
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<p>SEM images and EDS spectra of 360 d samples from the AAFB system. (<b>a</b>) FB1, (<b>b</b>) FB2, and (<b>c</b>) FB3.</p>
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<p>SEM images and EDS spectra of 360 d samples from the AABS system. (<b>a</b>) BS1, (<b>b</b>) BS2, and (<b>c</b>) BS3.</p>
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<p>XRD patterns of (<b>a</b>) raw materials; 360 d samples from (<b>b</b>) AAFA, (<b>c</b>) AAFB, and (<b>d</b>) AABS systems.</p>
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<p>FTIR spectra of (<b>a</b>) binder materials and 360 d samples from (<b>b</b>) AAFA, (<b>c</b>) AAFB, and (<b>d</b>) AABS systems.</p>
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<p>TG, DSC, and DTG curves of alkali-activated samples with FS or CS at 360 days. (<b>a</b>) FB1, (<b>b</b>) FB2, (<b>c</b>) FB3, (<b>d</b>) FA3, and (<b>e</b>) BS3.</p>
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<p>TG, DSC, and DTG curves of alkali-activated samples with FS or CS at 360 days. (<b>a</b>) FB1, (<b>b</b>) FB2, (<b>c</b>) FB3, (<b>d</b>) FA3, and (<b>e</b>) BS3.</p>
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<p>Synthesized diagram for aluminosilicate products involving the major elements of silico–aluminon precursors and additives (FS, CS, etc.).</p>
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<p>Surface fluorescence of alkali-activated samples at room temperature. (<b>a</b>) AAFA, (<b>b</b>) AAFB, and (<b>c</b>) AABS systems.</p>
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<p>Surface fluorescence of alkali-activated samples at room temperature. (<b>a</b>) AAFA, (<b>b</b>) AAFB, and (<b>c</b>) AABS systems.</p>
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27 pages, 20405 KiB  
Article
Implementation and Experimental Application of Industrial IoT Architecture Using Automation and IoT Hardware/Software
by David Calderón, Francisco Javier Folgado, Isaías González and Antonio José Calderón
Sensors 2024, 24(24), 8074; https://doi.org/10.3390/s24248074 (registering DOI) - 18 Dec 2024
Abstract
The paradigms of Industry 4.0 and Industrial Internet of Things (IIoT) require functional architectures to deploy and organize hardware and software taking advantage of modern digital technologies in industrial systems. In this sense, a lot of the literature proposes and describes this type [...] Read more.
The paradigms of Industry 4.0 and Industrial Internet of Things (IIoT) require functional architectures to deploy and organize hardware and software taking advantage of modern digital technologies in industrial systems. In this sense, a lot of the literature proposes and describes this type of architecture with a conceptual angle, without providing experimental validation or with scarce details about the involved equipment under real operation. Aiming at overcoming these limitations, this paper presents the experimental application of an IIoT architecture divided into four functional layers, namely, Sensing, Network, Middleware and Application layers. Automation and IoT hardware and software are used to implement and apply the architecture. Special attention is put on the software Grafana, chosen in the top layer to deploy graphical user interfaces that are remotely accessible via web. A pilot microgrid integrating photovoltaic energy and hydrogen served as scenario to test and prove the suitability of the architecture in four application cases. Full article
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<p>Block diagram of access to Grafana dashboards.</p>
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<p>Publications dealing with Grafana over time according to the Scopus database.</p>
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<p>Block diagram of the IIoT architecture.</p>
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<p>Schematic diagram of the microgrid used as the experimental application scenario.</p>
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<p>Physical aspect of the PV modules that compose the generator.</p>
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<p>Block diagram of the IIoT architecture applied to monitor the PV generator.</p>
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<p>Monitor interface for the PV generator.</p>
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<p>PV-generated power and solar irradiance.</p>
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<p>Physical aspect of the battery modules.</p>
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<p>Block diagram of the IIoT architecture applied to monitor the battery.</p>
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<p>Monitor interface for battery.</p>
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<p>Total battery and modules current.</p>
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<p>Physical aspect of the hydrogen generator.</p>
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<p>Block diagram of the IIoT architecture applied to monitor the hydrogen generator.</p>
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<p>Monitor interface for the hydrogen generator.</p>
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<p>Stack 2 voltage and current.</p>
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<p>Physical aspect of the hydrogen fuel cell.</p>
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<p>Block diagram of the IIoT architecture applied to monitor the fuel cell.</p>
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<p>Monitor interface for fuel cell.</p>
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<p>Fuel cell current and voltage.</p>
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19 pages, 1229 KiB  
Article
How Rural Digitization Promote Coordinated Urban–Rural Development: Evidence from a Quasi-Natural Experiment in China
by Zhongchao Wang, Xinchen Liu, Yaping Qin and Yang Zhang
Agriculture 2024, 14(12), 2323; https://doi.org/10.3390/agriculture14122323 (registering DOI) - 18 Dec 2024
Abstract
Rural digitalization not only constitutes the strategic orientation of rural revitalization but also serves as a potent means for augmenting farmers’ income. This study regards the implementation of China’s digital village pilot policy as a quasi-natural experiment. Based on the panel data of [...] Read more.
Rural digitalization not only constitutes the strategic orientation of rural revitalization but also serves as a potent means for augmenting farmers’ income. This study regards the implementation of China’s digital village pilot policy as a quasi-natural experiment. Based on the panel data of Chinese counties spanning from 2017 to 2022, it employs a multi-period difference-in-differences model to investigate the influence of rural digitalization on the coordinated development of urban and rural areas from the perspective of the income gap. The findings indicate that the policy has significantly reduced the urban–rural income gap. Mechanism analysis reveals that this reduction is achieved through enhancing county innovation capacity, accelerating agricultural digitization, promoting advanced industrial structure, and expanding non-farm employment. Heterogeneity analyses reveal that the policy has a greater impact in regions with less robust digital infrastructure, higher levels of community service, and stronger financial development. Consequently, it is indispensable to enhance the digital literacy of farmers, accelerate the digitalization of agriculture and the upgrading of industrial institutions, promote the balanced development of digital villages in various regions, and fully exert the guiding and facilitating role of community service levels. Full article
(This article belongs to the Section Agricultural Economics, Policies and Rural Management)
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<p>The influence of the Digital Village Policy on the urban–rural income gap.</p>
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<p>Parallel trend test.</p>
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<p>Placebo test.</p>
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19 pages, 536 KiB  
Article
The Supplier Selection of Prefabricated Component Production Line: A Lean-Based AHP–Improved VIKOR Framework
by Pei Dang, Hui Gao, Zhanwen Niu, Linna Geng, Felix Kin Peng Hui and Chao Sun
Buildings 2024, 14(12), 4018; https://doi.org/10.3390/buildings14124018 (registering DOI) - 18 Dec 2024
Abstract
Prefabrication is increasingly recognized as a sustainable construction practice, with the efficiency of prefabricated component (PC) production lines playing a critical role in its success. However, supplier selection for PC production lines has become more complex due to evolving industrial demands, uncertain supply [...] Read more.
Prefabrication is increasingly recognized as a sustainable construction practice, with the efficiency of prefabricated component (PC) production lines playing a critical role in its success. However, supplier selection for PC production lines has become more complex due to evolving industrial demands, uncertain supply chain conditions, and operational complexities. This study addresses this gap by developing a lean-based AHP–improved VIKOR decision-making framework to enhance the supplier selection for PC production lines. The framework integrates advanced lean principles with universal and specific evaluation criteria, identified through a comprehensive literature review and expert interviews. Its validity was tested via a real-world case study with Yizhong Construction Co., Ltd., Tianjin, China. The results show that the three suppliers are ranked as Zhongjian > Tianyi > Xindadi, where Zhongjian is the best supplier in this case study, with a VIKOR index of 0.156. The findings show that the developed framework can improve the supplier selection efficiency by aligning with lean principles and enhancing the performance of PC production lines. By addressing the challenges of PC supplier selection, this study provides a practical tool to advance the adoption of prefabrication in construction. Furthermore, it contributes to the development of the PC industry by offering a robust method for the selection of suitable suppliers, which can help to optimize the production efficiency and support sustainable practices in construction. Full article
(This article belongs to the Special Issue Strategic Planning and Control in Complex Project Management)
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<p>Lean-based AHP–improved VIKOR framework.</p>
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36 pages, 3115 KiB  
Article
The Role of Artificial Intelligence and Big Data Analytics in Shaping the Future of Professions in Industry 6.0: Perspectives from an Emerging Market
by Delia Deliu and Andrei Olariu
Electronics 2024, 13(24), 4983; https://doi.org/10.3390/electronics13244983 (registering DOI) - 18 Dec 2024
Abstract
Digital technologies are fundamentally transforming professions by altering roles and redefining competencies across all sectors. The progression from computerization to digitization, digitalization, and now digital transformation has been driven by the widespread integration of artificial intelligence (AI) and big data analytics (BDA). Industry [...] Read more.
Digital technologies are fundamentally transforming professions by altering roles and redefining competencies across all sectors. The progression from computerization to digitization, digitalization, and now digital transformation has been driven by the widespread integration of artificial intelligence (AI) and big data analytics (BDA). Industry 4.0 introduced smart automation and connectivity, Industry 5.0 emphasized human–machine collaboration and personalization, and Industry 6.0 now integrates advanced technologies with sustainability and ethical considerations, exerting a profound influence on many professions. This transformation is especially significant in emerging markets, where AI and BDA are overhauling traditional practices and enhancing efficiency but also introducing new challenges. Focusing on the accounting profession, this paper examines AI’s and BDA’s dual impact on the roles and skill sets of professional accountants (PAs). Specifically, it addresses how these technologies shape the activities, interactions, roles, and competencies of PAs in an Industry 6.0 context, as well as the opportunities and challenges that arise. Given the public interest role of PAs in ensuring accuracy and transparency in financial reporting, understanding their perceptions and experiences of digital transformation is essential. The findings reveal that while AI and BDA drive efficiency gains and open strategic pathways, they also risk eroding core traditional accounting competencies, reducing client engagement, and raising ethical concerns such as data security and privacy—all of which can undermine service quality and, ultimately, public trust. These insights underscore the need for responsible AI and BDA integration, particularly in emerging markets, where digital literacy gaps and regulatory limitations may slow adoption. This study offers actionable recommendations for policymakers, educators, and organizations, highlighting the importance of ethical standards, targeted training, and sustainable practices to preserve the relevance and integrity of the accounting profession in an increasingly technology-driven era. Full article
(This article belongs to the Special Issue Future Trends of Artificial Intelligence (AI) and Big Data)
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<p>Theoretical framework.</p>
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<p>Research workflow.</p>
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<p>Linear regression graph: experiences regarding the support provided by AI and BDA in performing the profession.</p>
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<p>The level of involvement of the Chamber of Financial Auditors of Romania in providing support for understanding and using AI and BDA in auditing.</p>
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<p>Respondents’ perception of the current level of professional preparedness of auditors.</p>
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<p>The most important tasks in the future considering the impact of AI and BDA.</p>
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<p>The most important skills in the context of the accelerated digitalization of the profession through AI and BDA.</p>
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<p>The extent to which the modification of International Auditing Standards is considered necessary.</p>
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33 pages, 1534 KiB  
Article
A Transdisciplinary Overlay for Nature-Based Design of Sustainable Buildings
by Anosh Nadeem Butt and Branka Dimitrijević
Architecture 2024, 4(4), 1157-1189; https://doi.org/10.3390/architecture4040060 (registering DOI) - 18 Dec 2024
Abstract
The article presents the development and validation of transdisciplinary collaboration (TDC) guidelines for nature-based design (NBD) of sustainable buildings that were used to develop and validate a proposed NBD Overlay of the Royal Institute of British Architects (RIBA) Plan of Work (PoW) 2020. [...] Read more.
The article presents the development and validation of transdisciplinary collaboration (TDC) guidelines for nature-based design (NBD) of sustainable buildings that were used to develop and validate a proposed NBD Overlay of the Royal Institute of British Architects (RIBA) Plan of Work (PoW) 2020. The study first presents the results of consultations with architects on the application of NBD in all stages the RIBA PoW. The development of the proposed NBD Overlay of the RIBA PoW is described, followed by the results of a survey of architects on its contents. Over 80% of the architects in the consultation group confirmed the significance of the proposed NBD Overlay and its relevance in advancing sustainable building practices. The potential of the proposed NBD Overlay to foster tansdisciplinary collaboration and promote NBD approaches, principles, and solutions bodes well for the future of sustainable architecture, driving the industry towards a more resilient and environmentally conscious built environment. Full article
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<p>Functions of the BREEAM Outstanding buildings that were part of the survey results.</p>
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<p>Percentage of application of NBD within the stages of the RIBA PoW.</p>
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<p>Percentage of application of NBD in the BREEAM categories.</p>
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<p>Professions involved in design teams that incorporated NBD in the surveyed BREEAM Outstanding projects.</p>
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<p>A general framework for conducting transdisciplinary research (TDR) adapted from Butt and Dimitrijević [<a href="#B35-architecture-04-00060" class="html-bibr">35</a>].</p>
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23 pages, 1994 KiB  
Article
Pursuing Cleaner Skies: A Study on the Impact of China’s Environmental Protection Tax Law on Haze Pollution
by Wuxin Zhang and Haiying Pan
Sustainability 2024, 16(24), 11095; https://doi.org/10.3390/su162411095 (registering DOI) - 18 Dec 2024
Abstract
Haze pollution control is integral to green development, and fiscal and taxation policies are fundamental mechanisms supporting this effort. This study leverages the implementation of China’s Environmental Protection Tax (EPT) Law as a quasi-natural experiment to assess the impact and mechanisms of the [...] Read more.
Haze pollution control is integral to green development, and fiscal and taxation policies are fundamental mechanisms supporting this effort. This study leverages the implementation of China’s Environmental Protection Tax (EPT) Law as a quasi-natural experiment to assess the impact and mechanisms of the greening of the tax system on haze pollution based on panel data from 281 prefecture-level cities in China from 2012 to 2021. The findings indicate that (1) the implementation of the EPT Law significantly reduces haze pollution, with results confirmed after a series of robustness tests; (2) the EPT Law controls haze pollution through promoting cleaner industrial structure, fostering green technological innovation, and strengthening the rigidity of environmental law enforcement; (3) fiscal decentralization enhances the inhibitory effect of the implementation of the EPT Law on haze pollution; (4) the haze-reduction effect of the EPT Law is especially notable in non-old industrial bases, areas with less pressure on officials’ promotions, and areas with higher public environmental awareness. This study not only enriches research on the policy effects of the EPT Law but also contributes to the environmental sustainable development goal of greening the tax system and continuously fighting for blue skies. Full article
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<p>Research framework.</p>
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<p>Influence mechanism.</p>
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<p>Parallel trend test.</p>
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<p>Placebo test.</p>
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<p>The mechanism of the moderating effect.</p>
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15 pages, 6548 KiB  
Article
Formation of Coatings Containing Cr2AlC MAX Phase During Plasma Spraying of Mixture of Cr3C2+Al Powders
by Natalia Vigilianska, Carolina Iantsevitch, Tania Tsymbalista, Oleksii Burlachenko, Oleksandr Grishchenko, Oleksandr Gudymenko, Szymon Zawadzki and Cezary Senderowski
Coatings 2024, 14(12), 1584; https://doi.org/10.3390/coatings14121584 (registering DOI) - 18 Dec 2024
Abstract
In this article, the structure formation and phase composition of coatings containing Cr2AlC MAX phase under the conditions of plasma spraying were studied. Mechanical mixtures of commercially available Cr3C2 and Al powders were used as a material for [...] Read more.
In this article, the structure formation and phase composition of coatings containing Cr2AlC MAX phase under the conditions of plasma spraying were studied. Mechanical mixtures of commercially available Cr3C2 and Al powders were used as a material for spraying. The amount of aluminium in the mixtures was 9 and 18 wt.%. As a result of studying physicochemical processes occurring during plasma spraying of mechanical mixtures of selected compositions, the formation of coatings containing Cr2AlC MAX phase was established, the synthesis of which occurs both at the stage of the particles flight of initial components in the plasma jet as a result of the collision and coagulation, and at the stage of a coating layer formation as a result of layering particles deformed during the collision–splats. It is shown that for the formation of a denser coating with a higher MAX phase content for spraying, it is rational to use a mixture of chromium carbide powders with 9 wt.% of aluminium. A coating with the composition 91Cr3C2-9Al (wt.%) has high corrosion resistance in operation conditions in a chloride-acetate solution, and by its indicators of corrosion resistance, is not inferior to the Cr3C2-NiCr coating, which is widely used in industry to protect parts from corrosion and wear. The obtained results show the possibility and feasibility of using mechanical mixtures of commercially available powders for the formation of coatings containing Cr2AlC MAX phase instead of expensive synthesized MAX-Cr2AlC powders. Full article
(This article belongs to the Special Issue Advances in Experimental Testing of Thermal Barrier Coatings)
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<p>Probable Cr<sub>3</sub>C<sub>2</sub> transformations in thermal spraying.</p>
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<p>Temperature dependence of a change in Gibbs energy in the Cr-Al-C system. Numbers on the curves correspond to reaction numbers.</p>
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<p>Microstructure of (<b>a</b>) Cr<sub>3</sub>C<sub>2</sub> and (<b>b</b>) Al powder particles.</p>
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<p>Histograms of particles sizes distribution of (<b>a</b>) Cr<sub>3</sub>C<sub>2</sub> and (<b>b</b>) Al.</p>
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<p>X-ray diffraction patterns of (<b>a</b>) Cr<sub>3</sub>C<sub>2</sub> and (<b>b</b>) Al powders.</p>
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<p>Computer simulation of the velocity and temperature of the plasma jet (<b>a</b>) and sprayed particles of Cr<sub>3</sub>C<sub>2</sub> (<b>b</b>) and Al (<b>c</b>).</p>
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<p>Microstructure of (<b>a</b>) Cr<sub>3</sub>C<sub>2</sub> and (<b>b</b>) Al powder particles after passing through the plasma jet.</p>
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<p>Histograms of particles size distribution of (<b>a</b>) Cr<sub>3</sub>C<sub>2</sub> and (<b>b</b>) Al powders after passing through the plasma jet.</p>
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<p>Microstructure of particles of (<b>a</b>) 91Cr<sub>3</sub>C<sub>2</sub>-9Al and (<b>b</b>) 82Cr<sub>3</sub>C<sub>2</sub>-18Al powders after passing through the plasma jet.</p>
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<p>Histograms of particles size distribution of (<b>a</b>) 91Cr<sub>3</sub>C<sub>2</sub>-9Al and (<b>b</b>) 82Cr<sub>3</sub>C<sub>2</sub>-18Al powders after passing through the plasma jet.</p>
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<p>X-ray diffraction patterns of powder particles after passing through the plasma jet.</p>
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<p>X-ray diffraction patterns of plasma-sprayed coatings.</p>
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<p>Microstructure of (<b>a</b>) 91Cr<sub>3</sub>C<sub>2</sub>-9Al and (<b>b</b>) 82Cr<sub>3</sub>C<sub>2</sub>-18Al plasma-sprayed coatings.</p>
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<p>Variation curves of the distribution of microhardness values of (<b>a</b>) 91Cr<sub>3</sub>C<sub>2</sub>-9Al and (<b>b</b>) 82Cr<sub>3</sub>C<sub>2</sub>-18Al plasma-sprayed coatings.</p>
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<p>Polarization curves of plasma-sprayed coatings and steel without coating in a chloride-acetate solution: 1—82Cr<sub>3</sub>C<sub>2</sub>-18Al coating; 2—91Cr<sub>3</sub>C<sub>2</sub>-9Al coating; 3—Cr<sub>3</sub>C<sub>2</sub>-NiCr coating; 4—steel AISI 1017.</p>
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22 pages, 2251 KiB  
Article
Humanoid Robots in Tourism and Hospitality—Exploring Managerial, Ethical, and Societal Challenges
by Ida Skubis, Agata Mesjasz-Lech and Joanna Nowakowska-Grunt
Appl. Sci. 2024, 14(24), 11823; https://doi.org/10.3390/app142411823 (registering DOI) - 18 Dec 2024
Abstract
The paper evaluates the benefits and challenges of employing humanoid robots in tourism and hospitality, examining their roles, decision-making processes, human-centric approaches, and oversight mechanisms. Data will be collected from a variety of sources, including academic journals, websites of the companies where the [...] Read more.
The paper evaluates the benefits and challenges of employing humanoid robots in tourism and hospitality, examining their roles, decision-making processes, human-centric approaches, and oversight mechanisms. Data will be collected from a variety of sources, including academic journals, websites of the companies where the robots operate, case studies, and news articles. Specific attention will be given to concrete examples of humanoid robots deployed in the tourism and hospitality sector, such as Connie, Spencer, and Henn-na Hotel’s robots. Robots highlight the potential to assume roles traditionally occupied by humans. The presence of humanoid robots also influences cultural practices and social interactions within the hospitality context. Humanoid robots also have the potential to improve equity and accessibility in the tourism and hospitality industry. The interaction between humans and humanoid robots can have psychological and emotional effects on both guests and employees. Finally, the usage of humanoid robots intersects with broader sustainability operational efficiency and customer satisfaction across various sectors within the tourism and hospitality industry. Introducing humanoid robots represents a challenge in innovation that holds promise for revolutionizing service delivery and guest experiences. Full article
(This article belongs to the Special Issue AI from Industry 4.0 to Industry 5.0: Engineering for Social Change)
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<p>Technological Framework of Intelligent Automation in Tourism by Tussyadiah. The photo taken from [<a href="#B12-applsci-14-11823" class="html-bibr">12</a>].</p>
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<p>Connie. The photo taken from [<a href="#B63-applsci-14-11823" class="html-bibr">63</a>].</p>
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<p>Spencer. The photo taken from [<a href="#B64-applsci-14-11823" class="html-bibr">64</a>].</p>
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<p>Henn-na Hotel’s humanoid robots. The photo taken from [<a href="#B66-applsci-14-11823" class="html-bibr">66</a>].</p>
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