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Search Results (4,165)

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Keywords = friction coefficient

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20 pages, 3012 KiB  
Article
Experimental Investigation and Prediction of Mechanical Properties of Carbonate Rocks Under Uniaxial and Triaxial Compressions
by Esraa Alomari, Kam Ng and Lokendra Khatri
Materials 2025, 18(6), 1211; https://doi.org/10.3390/ma18061211 (registering DOI) - 8 Mar 2025
Abstract
Compressive strength and Young’s modulus are key design parameters in rock engineering, essential for understanding the mechanical behavior of carbonate rocks. Understanding the mechanical behavior of carbonate rocks under varying load conditions is crucial for geotechnical stability analysis. In this paper, empirical relationships [...] Read more.
Compressive strength and Young’s modulus are key design parameters in rock engineering, essential for understanding the mechanical behavior of carbonate rocks. Understanding the mechanical behavior of carbonate rocks under varying load conditions is crucial for geotechnical stability analysis. In this paper, empirical relationships are developed to predict the mechanical properties of carbonate rocks. A series of uniaxial and triaxial compression experiments were conducted on carbonate rocks including limestone, dolostone, and granite from Wyoming. In addition, experimental data on different carbonate rocks from the literature are compiled and integrated into this study to evaluate the goodness of fit of our proposed empirical relationships in the prediction of compressive strength and Young’s modulus of carbonate rocks. Regression analysis was used to develop predictive models for the uniaxial compressive strength (UCS), Young’s modulus (E), and triaxial compressive strength (σ1) incorporating parameters such as the porosity (n) and confining pressure (σ3). The results indicated that the UCS and Young’s modulus showed a power relationship with porosity (n), whereas the σ1 showed a linear relationship with n and σ3. Furthermore, an analytical model expanded from the wing crack model was applied to predict the σ1 of limestone based on the coefficient of friction, the initial level of damage, the initial flaw size, and the fracture toughness of the rock. The model showed a good predictability of the σ1 with a mean bias (i.e., the ratio of the measured to the predicted strength) of 1.07, indicating its reliability in accurately predicting the rock strength. This predictability is crucial for making informed engineering decisions, design optimization, and improving safety protocols in practical applications such as structural analysis and manufacturing processes. Full article
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<p>Testing equipment GCTS Rapid Triaxial Rock (RTR-1500) for triaxial compression testing.</p>
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<p>Three deviatoric stress–strain curves of Sherman granite specimens under confining pressures of 0, 4, and 10 MPa.</p>
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<p>The negative relationship between the rock <span class="html-italic">UCS</span> and porosity, indicating how increased rock porosity can lead to strength reduction.</p>
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<p>The linear relationship between peak compressive strength, porosity, and confining pressure, highlighting a positive correlation with confining pressure and a negative correlation with porosity.</p>
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<p>Power relationship showing the decrease in mean Young’s modulus (<span class="html-italic">E</span>) as porosity (<span class="html-italic">n</span>) increases.</p>
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<p>Wing crack growth from an inclined crack under compression (adapted from Ashby and Hallam [<a href="#B17-materials-18-01211" class="html-bibr">17</a>]).</p>
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<p>Comparison of measured and predicted compressive strengths for carbonate rocks, showing a good accuracy in predicting the compressive strength.</p>
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15 pages, 5089 KiB  
Article
Base Oils and Formulated Transmission Oils for Electrical Vehicles: Thermophysical and Tribological Properties
by José M. Liñeira del Río, Alonso Alba, Martín Gómez Martínez, Alfredo Amigo and Josefa Fernández
Materials 2025, 18(6), 1207; https://doi.org/10.3390/ma18061207 (registering DOI) - 8 Mar 2025
Viewed by 9
Abstract
The aim of this research is to analyze the thermophysical, wettability, and tribological properties of some base oils of different nature (synthetic and mineral), as well as of formulated oils, to find potential transmission oils for electrical vehicles. Regarding the thermophysical properties, viscosity, [...] Read more.
The aim of this research is to analyze the thermophysical, wettability, and tribological properties of some base oils of different nature (synthetic and mineral), as well as of formulated oils, to find potential transmission oils for electrical vehicles. Regarding the thermophysical properties, viscosity, density, and viscosity index were analyzed. Surface tension and contact angle were also measured to obtain the wettability performance of tested lubricants. The highest viscosities were found for the PAO8 oil and the lowest for the G-III 3 base oil, while the highest densities were found for the formulated oils. Concerning wettability performance, the surface tensions of PAOs and G-IIIs rise gradually with an increase in viscosity, the surface tension being the greatest for G-III 6 and the lowest for G-III 3. Finally, in the tribological characterization, the lowest coefficients of friction and produced wear were found with the formulated lubricants, due to the presence of an additive package. Full article
(This article belongs to the Special Issue Advances in Wear Behaviour and Tribological Properties of Materials)
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<p>Dynamic viscosities found for all the tested lubricant oils.</p>
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<p>Density values achieved for all the tested lubricant oils.</p>
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<p>Viscosity index values obtained for all the studied lubricant oils.</p>
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<p>Surface tension values obtained for the different tested oils at 298.15 and 313.15 K.</p>
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<p>Linear relationship between ln (γ) and ln (<math display="inline"><semantics> <mrow> <mi mathvariant="sans-serif">ρ</mi> </mrow> </semantics></math>) for the studied lubricant oils.</p>
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<p>Contact angle values achieved for the tested lubricants at 298.15 and 313.15 K.</p>
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<p>Contact angle photographs for all the studied lubricants at t = 1 s and t = 25 s for the temperatures 298.15 and 313.15 K.</p>
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<p>Contact angle photographs for all the studied lubricants at t = 1 s and t = 25 s for the temperatures 298.15 and 313.15 K.</p>
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<p>Average coefficients of friction (μ) attained with the different lubricant oils at 393.15 K.</p>
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<p>Wear 3D profiles found for the steel pins tested with lubricant bases, PAOs (<b>a</b>), formulated oils (<b>b</b>), and GIII oils (<b>c</b>).</p>
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21 pages, 36846 KiB  
Article
The Effective Depth of Skid Resistance (EDSR): A Novel Approach to Detecting Skid Resistance in Asphalt Pavements
by Yi Luo, Yongli Xu, Yiming Li, Liming Wang and Hongguang Wang
Materials 2025, 18(6), 1204; https://doi.org/10.3390/ma18061204 - 7 Mar 2025
Viewed by 65
Abstract
Asphalt pavement skid resistance, governed by surface texture, is critical for traffic safety. Most research has focused on full-depth textural characteristics, often overlooking the depth of tire–pavement contact under real traffic conditions. This study introduces the concept of the Effective Depth of Skid [...] Read more.
Asphalt pavement skid resistance, governed by surface texture, is critical for traffic safety. Most research has focused on full-depth textural characteristics, often overlooking the depth of tire–pavement contact under real traffic conditions. This study introduces the concept of the Effective Depth of Skid Resistance (EDSR) to describe the effective depth of tire–asphalt contact, improving skid resistance assessment accuracy. Using blue linear laser scanning, surface textures of three common asphalt pavements with wearing courses—AC-13, AC-16, and SMA-13—were analyzed, and friction coefficients were measured using a British pendulum. After pre-processing three-dimensional texture data, fractal dimensions at various depths were calculated using the box-counting method and correlated with the friction coefficients. Previous studies show an insignificant correlation between full-depth asphalt pavement textures and skid resistance. However, this study found a significant positive correlation between skid resistance and pavement textures at specific depths or the EDSR. A depth with a correlation exceeding 0.9 was defined as the EDSR. Linear formulas were established for each pavement type within these EDSR ranges. A theoretical model was developed for predicting skid resistance, showing an over 80% accuracy against real-world data, indicating its potential for improving road surface performance detection. Full article
23 pages, 5483 KiB  
Article
A Study on Tantalum Alloying Layer and Its Performance on the Surface of 316LSS in Harsh Environments
by Qinghua Li, Zhehang Fan, Xiaohu Chen, Xiaoyong Tao, Ruian Ni, Kai Zhang, Aqib Mashood Khan, Syed Muhammad Raza, Yiming Wen and Hongyan Wu
Coatings 2025, 15(3), 313; https://doi.org/10.3390/coatings15030313 - 7 Mar 2025
Viewed by 70
Abstract
Tantalum diffusion layers were fabricated on 316L stainless steel substrates using the double glow plasma surface alloying technology (DGPSAT). The optimization rules of the Fe-Ta diffusion layer under varying alloying times were investigated, focusing on the effects of processing parameters on the phase [...] Read more.
Tantalum diffusion layers were fabricated on 316L stainless steel substrates using the double glow plasma surface alloying technology (DGPSAT). The optimization rules of the Fe-Ta diffusion layer under varying alloying times were investigated, focusing on the effects of processing parameters on the phase structure and microstructure. The results indicate that, as the alloying time increases, the surface wrinkled structure in the Fe-Ta alloy layer gradually transforms into a nanoscale acicular α-Ta structure, improving surface roughness and water contact angle. The surface microstructure influenced by the alloying time enhanced mechanical properties significantly, increasing Vickers hardness from 152 HV0.2 to 970 HV0.2, improving bonding strength, and reducing the friction coefficient to 0.5. Electrochemical testing showed that the corrosion rate of the tantalum diffusion layer was significantly reduced from 1.04 × 10−2 mm/a to 2.83 × 10−4 mm/a, demonstrating the excellent corrosion resistance. The island growth pattern during the formation of alloy layers was simulated by molecular dynamics. Replacing bulk materials with tantalum diffusion layers can economize rare metals, reduce costs, and be of great significant for the special equipment applications in harsh environments. Full article
16 pages, 5820 KiB  
Article
Optimization of Plating Parameters and Properties of Ultrasonic-Assisted Jet-Electrodeposited Ni-W-Al2O3 Nanocomposite Coatings
by Mengyu Cao, Dehao Tian, Xue Guo and Wei Li
Int. J. Mol. Sci. 2025, 26(6), 2404; https://doi.org/10.3390/ijms26062404 - 7 Mar 2025
Viewed by 65
Abstract
Ni-W-Al2O3 nanocomposite coatings were fabricated using ultrasonic-assisted jet electrodeposition (UAJED) to improve the wear resistance of agricultural machinery parts. To find the best combination of process parameters, the response surface plotter, contour plotter, and pre-set plotter in the JMP (version [...] Read more.
Ni-W-Al2O3 nanocomposite coatings were fabricated using ultrasonic-assisted jet electrodeposition (UAJED) to improve the wear resistance of agricultural machinery parts. To find the best combination of process parameters, the response surface plotter, contour plotter, and pre-set plotter in the JMP (version Pro 14.3.0) software were employed to investigate the effects of various process parameters (jet rate, Al2O3 content, and ultrasonic power) on the microhardness of the nanocomposite coatings. The surface morphology, microstructure, and properties of the coatings, which were prepared under various combinations of process parameters, were studied through scanning electron microscopy (SEM), an X-ray diffractometer (XRD), transmission electron microscopy (TEM), a microhardness tester, and tribemates to determine the optimal process parameters for creating Ni-W-Al2O3 nanocomposite coatings. The results indicated that the jet rate, Al2O3 content, ultrasonic power, interaction terms, and quadratic terms significantly influenced the microhardness of the coatings. The optimized process parameters using the JMP software were a jet rate of 3.71 m/s, Al2O3 content of 15.38 g/L, and ultrasonic power of 210 W. Furthermore, the coatings produced under these optimal conditions showed low wear rates and friction coefficients, a refined grain size, a dense surface topology, and a high microhardness (724.9 HV). Full article
(This article belongs to the Section Materials Science)
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<p>The deposition principle of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings obtained by UAJED.</p>
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<p>Predicted and actual microhardness values of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings.</p>
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<p>Influence of the interaction between jet rate and Al<sub>2</sub>O<sub>3</sub> content on the microhardness of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings.</p>
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<p>Influence of the interaction of jet rate and Al<sub>2</sub>O<sub>3</sub> content on the microhardness of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings.</p>
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<p>Influence of jet rate and ultrasonic power interaction on microhardness of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings.</p>
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<p>Influence of the interaction of jet rate and ultrasonic power on the microhardness of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings.</p>
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<p>Influence of ultrasonic power and Al<sub>2</sub>O<sub>3</sub> content on the microhardness of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings.</p>
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<p>Influence of the interaction of ultrasonic power and Al<sub>2</sub>O<sub>3</sub> content on the microhardness of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings.</p>
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<p>Prediction of maximum microhardness and technological parameters of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings.</p>
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<p>SEM images of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings prepared via different combinations: (<b>a</b>) G1, (<b>b</b>) G2, and (<b>c</b>) G3.</p>
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<p>XRD spectrums of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings.</p>
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<p>TEM images of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings prepared with different parameter combinations: (<b>a</b>) G1, (<b>b</b>) G2, and (<b>c</b>) G3.</p>
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<p>The obtained TEM images for the Ni-W-Al<sub>2</sub>O<sub>3</sub> coatings prepared with G2 process parameters combination: (<b>a</b>) low magnification, (<b>b</b>) higher magnification, (<b>c</b>) lattice fringes of Al<sub>2</sub>O<sub>3</sub> nanoparticles, (<b>d</b>) selected area electron diffraction (SAED) pattern, and (<b>e</b>) noise-filtered image of Al<sub>2</sub>O<sub>3</sub> nanoparticles.</p>
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<p>Microhardness values of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings prepared with different plating combinations.</p>
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<p>Wear coefficients of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings prepared with different parameter combinations.</p>
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<p>Wear extents of Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings prepared with different parameter combinations.</p>
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<p>Physical device for Ni-W-Al<sub>2</sub>O<sub>3</sub> composite coatings fabricated by UAJED.</p>
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15 pages, 3028 KiB  
Article
Theoretical Study on Critical Liquid-Carrying Capacity of Gas Wells in Fuling Shale Gas Field
by Yang Cheng, Dajiang Wang, Jun Luo and Ruiquan Liao
Processes 2025, 13(3), 776; https://doi.org/10.3390/pr13030776 - 7 Mar 2025
Viewed by 68
Abstract
The most common type of well in the Fuling shale gas field is the long horizontal section well. Once the energy attenuates, it is difficult to discharge the accumulated liquid. So, it is particularly important to determine the time of accumulation. Through indoor [...] Read more.
The most common type of well in the Fuling shale gas field is the long horizontal section well. Once the energy attenuates, it is difficult to discharge the accumulated liquid. So, it is particularly important to determine the time of accumulation. Through indoor experiments, it was observed that droplets in the gas core flowing under critical conditions and the liquid film adhering to the tube wall cannot be ignored. It was also discovered that the liquid phase on the tube wall can form fluctuations due to the shear effect of the gas phase. Based on the observed distribution of gas–liquid phases in experiments, a critical liquid-carrying velocity calculation method considering the coexistence of droplets and liquid films, as well as the frictional resistance coefficient at the gas–liquid interface under wave morphology, was established. Integrating production data from 106 wells at home and abroad, as well as testing data from the Fuling example well, the new model was validated. The results showed that the new model can accurately diagnose fluid accumulation in different gas fields, with an accuracy rate of 86.8%, and it can provide an accurate diagnosis for fluid accumulation in gas wells in different water-producing gas fields. Full article
(This article belongs to the Section Chemical Processes and Systems)
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<p>Laboratory device diagram.</p>
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<p>Distribution of gas–liquid phases during critical liquid-carrying under different liquid flow rates.</p>
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<p>Comparison of critical liquid-carrying velocity and rolling wave threshold.</p>
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<p>Physical model of critical liquid-carrying state of inclined tube.</p>
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<p>Variation in critical liquid-carrying velocity under different inclination angles of the pipeline.</p>
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<p>Physical model of gas–liquid interface distribution.</p>
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<p>Comparison of model application status.</p>
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<p>Test results of flow pressure gradient of Well A.</p>
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<p>Comparison of fluid accumulation diagnosis throughout the entire life cycle of a gas well.</p>
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23 pages, 16312 KiB  
Article
Comparative Study of Friction Models in High-Speed Machining of Titanium Alloys
by Fan Yi, Ruoxi Zhong, Wenjie Zhu, Run Zhou, Li Guo and Ying Wang
Lubricants 2025, 13(3), 113; https://doi.org/10.3390/lubricants13030113 - 6 Mar 2025
Viewed by 116
Abstract
Friction has a significant impact on chip formation, so modeling it accurately is crucial in numerical cutting simulations. However, there is still controversy regarding the application scope and effectiveness of various friction models. A two-dimensional orthogonal cutting thermomechanical coupled finite element model is [...] Read more.
Friction has a significant impact on chip formation, so modeling it accurately is crucial in numerical cutting simulations. However, there is still controversy regarding the application scope and effectiveness of various friction models. A two-dimensional orthogonal cutting thermomechanical coupled finite element model is established. Critical strain values, recrystallization temperature, and recrystallization flow stress are introduced, and a power-law-modified softening coefficient is used to modify the standard Johnson–Cook constitutive model to simulate material mechanical properties. Zorev’s friction model, velocity-dependent friction model, and temperature-dependent friction model are separately employed to describe the friction behavior between the tool and workpiece. The contact and friction characteristics between the workpiece and tool, material damage, and temperature field are evaluated. Predicted cutting forces are compared and analyzed with experimental values. The friction coefficient can adjust the contact length between the tool and chip, the high-temperature range on the tool surface, and the fluctuation of temperature throughout the entire cutting process. The friction coefficient is more sensitive to sliding velocity, and the temperature distribution is more sensitive to the friction model than to different working conditions. Whether by modifying the friction coefficient or maximum friction shear stress, and regardless of whether adding parameters affected by velocity or temperature changes the fluctuation range, period, and local peaks of the cutting force prediction curve, improving the accuracy of predictions within certain working condition ranges to some extent. However, the overall trend of error fluctuations obtained from these friction models is similar, and the accuracy of predictions from these friction models tends to become more inaccurate with increasing cutting thickness. Full article
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<p>Flowchart of calculation.</p>
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<p>Orthogonal cutting model.</p>
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<p>Friction−related results of temperature–dependent friction model with varied machining conditions. (<b>a</b>–<b>d</b>): Contact pressure under various operating conditions, (<b>e</b>–<b>h</b>): Contact shear stress under various operating conditions, (<b>i</b>–<b>l</b>): Frictional slip equivalent force under various operating conditions, (<b>m</b>–<b>p</b>): Frictional slip ratio under various operating conditions.</p>
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<p>Simulation results of temperature–dependent friction model with varied machining conditions. (<b>a</b>–<b>d</b>): Equivalent plastic strain under various operating conditions, (<b>e</b>–<b>h</b>): Scalar damage evolution under various operating conditions, (<b>i</b>–<b>l</b>): Node temperature under various operating conditions.</p>
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<p>Friction–related results of velocity–dependent friction model with varied machining conditions. (<b>a</b>–<b>d</b>): Contact pressure under various operating conditions, (<b>e</b>–<b>h</b>): Contact shear stress under various operating conditions, (<b>i</b>–<b>l</b>): Frictional slip equivalent force under various operating conditions, (<b>m</b>–<b>p</b>): Frictional slip ratio under various operating conditions.</p>
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<p>Simulation results of velocity–dependent friction model with varied machining conditions. (<b>a</b>–<b>d</b>): Equivalent plastic strain under various operating conditions, (<b>e</b>–<b>h</b>): Scalar damage evolution under various operating conditions, (<b>i</b>–<b>l</b>): Node temperature under various operating conditions.</p>
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<p>Friction−related results of Zorev’s friction model with varied machining conditions. (<b>a</b>–<b>d</b>): Contact pressure under various operating conditions, (<b>e</b>–<b>h</b>): Contact shear stress under various operating conditions, (<b>i</b>–<b>l</b>): Frictional slip equivalent force under various operating conditions, (<b>m</b>–<b>p</b>): Frictional slip ratio under various operating conditions.</p>
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<p>Simulation results of Zorev’s friction model with varied machining conditions. (<b>a</b>–<b>d</b>): Equivalent plastic strain under various operating conditions, (<b>e</b>–<b>h</b>): Scalar damage evolution under various operating conditions, (<b>i</b>–<b>l</b>): Node temperature under various operating conditions.</p>
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<p>Temperature on tool face of temperature-dependent friction model with varied machining conditions.</p>
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<p>Temperature on tool face of velocity-dependent friction model with varied machining conditions.</p>
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<p>Temperature on tool face of Zorev’s friction model with varied machining conditions.</p>
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<p>Cutting force when cutting depth is 0.1 mm and cutting speed is 280 m/min.</p>
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<p>Cutting force when cutting depth is 0.1 mm and cutting speed is 360 m/min.</p>
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<p>Cutting force when cutting depth is 0.15 mm and cutting speed is 280 m/min.</p>
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<p>Cutting force when cutting depth is 0.15 mm and cutting speed is 360 m/min.</p>
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<p>Deviation of cutting force from experimental data with temperature−dependent friction model.</p>
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<p>Deviation of cutting force from experimental data with velocity−dependent friction model.</p>
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<p>Deviation of cutting force from experimental data with Zorev’s friction model.</p>
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19 pages, 8848 KiB  
Article
Tribological Behavior and Mechanism of Silane-Bridged h-BN/MoS2 Hybrid Filling Epoxy Solid Lubricant Coatings
by Xiaoxiao Peng, Haiyan Jing, Lan Yu, Zongdeng Wu, Can Su, Ziyu Ji, Junjie Shu, Hua Tang, Mingzhu Xia, Xifeng Xia, Wu Lei and Qingli Hao
Nanomaterials 2025, 15(5), 401; https://doi.org/10.3390/nano15050401 - 6 Mar 2025
Viewed by 136
Abstract
To significantly improve the tribological performance of epoxy resin (EP), a novel h-BN/MoS2 composite was successfully synthesized using spherical MoS2 particles with lamellar self-assembly generated through the calcination method, followed by utilizing the “bridging effect” of a silane coupling agent to [...] Read more.
To significantly improve the tribological performance of epoxy resin (EP), a novel h-BN/MoS2 composite was successfully synthesized using spherical MoS2 particles with lamellar self-assembly generated through the calcination method, followed by utilizing the “bridging effect” of a silane coupling agent to achieve a uniform and vertically oriented decoration of hexagonal boron nitride (h-BN) nanosheets on the MoS2 surface. The chemical composition and microstructure of the h-BN/MoS2 composite were systematically investigated. Furthermore, the enhancement effect of composites with various contents on the frictional properties of epoxy coatings was studied, and the mechanism was elucidated. The results demonstrate that the uniform decoration of h-BN enhances the chemical stability of MoS2 in friction tests, and the MoS2 prevents oxidation and maintains its self-lubricating properties. Consequently, due to the protective effect of h-BN and the synergistic interaction between h-BN and MoS2, the 5 wt % h-BN/MoS2 composite exhibited the best friction and wear resistance when incorporated into EP. Compared to pure EP coatings, its average friction coefficient and specific wear rate (0.026 and 1.5 × 10−6 mm3 N−1 m−1, respectively) were significantly reduced. Specifically, the average friction coefficient decreased by 88% and the specific wear rate decreased by 99%, highlighting the superior performance of the h-BN/MoS2-enhanced epoxy composite coating. Full article
(This article belongs to the Section 2D and Carbon Nanomaterials)
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<p>The schematic diagrams of the preparation processes for (<b>a</b>) KH560-MoS<sub>2</sub>, (<b>b</b>) KH550-BN, and (<b>c</b>) h-BN/MoS<sub>2</sub>.</p>
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<p>(<b>a</b>) XRD patterns of BN, KH550-BN, MoS<sub>2</sub>, KH560-MoS<sub>2</sub>, and h-BN/MoS<sub>2</sub> hybrids, FT-IR spectra of (<b>b</b>) BN, BN-OH, KH550-BN, and (<b>c</b>) MoS<sub>2</sub>, KH560-MoS<sub>2</sub>, and h-BN/MoS<sub>2</sub> hybrids, and (<b>d</b>) Raman spectroscopy of MoS<sub>2</sub> and KH560-MoS<sub>2</sub>.</p>
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<p>(<b>a</b>) Full-range XPS spectra and high-resolution spectra of h-BN/MoS<sub>2</sub> hybrids including (<b>b</b>) B 1s, (<b>c</b>) Mo 3d, (<b>d</b>) C 1s, (<b>e</b>) N 1s, and (<b>f</b>) S 2p.</p>
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<p>(<b>a</b>) TEM images of h-BN/MoS<sub>2</sub> hybrids, (<b>b</b>–<b>e</b>) HRTEM image, and the corresponding SAED patterns of h-BN/MoS<sub>2</sub> hybrids. (<b>f</b>) Elemental mapping of h-BN/MoS<sub>2</sub> hybrids.</p>
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<p>(<b>a</b>,<b>c</b>) The friction coefficients of the samples as a function of sliding time. (<b>b</b>,<b>d</b>) The friction coefficients’ error bar for different samples.</p>
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<p>(<b>a</b>) Wear rates and wear track width of the coatings for different samples. (<b>b</b>) Vickers hardnesses of the coatings with different samples. (<b>c</b>) The long-cycle tribological performance of 5 wt % h-BN/MoS<sub>2</sub>.</p>
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<p>(<b>a</b>,<b>b</b>) TGA and (<b>c</b>,<b>d</b>) DTG curves of pure EP, 5 wt % MoS<sub>2</sub>/EP, and 5 wt % h-BN/MoS<sub>2</sub> /EP under N<sub>2</sub> and air atmospheres.</p>
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<p>Fracture sections for different coatings: (<b>a</b>) EP, (<b>b</b>) 5 wt % MoS<sub>2</sub>/EP, (<b>c</b>) 1 wt % h-BN/MoS<sub>2</sub>/EP, (<b>d</b>) 2 wt % h-BN/MoS<sub>2</sub>/EP, (<b>e</b>) 5 wt % h-BN/MoS<sub>2</sub>/EP, and (<b>f</b>) 10 wt % h-BN/MoS<sub>2</sub>/EP.</p>
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<p>SEM morphology of worn surfaces of the composites with different contents of h-BN/MoS<sub>2</sub> (<b>a</b>) 1 wt %, (<b>b</b>) 2 wt %, (<b>c</b>) 5 wt %, (<b>d</b>) 10 wt %), (<b>e</b>) the pure EP coating, and (<b>f</b>) the single MoS<sub>2</sub> coating.</p>
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<p>XPS spectra of 5 wt % h-BN/MoS<sub>2</sub> composite coating after friction: (<b>a</b>) C 1s, (<b>b</b>) Mo 3d, (<b>c</b>) S 2p, (<b>d</b>) Si 2p, and (<b>e</b>) Fe 2p.</p>
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<p>Schematic of wear mechanism of EP composite coatings enhanced via h-BN/MoS<sub>2</sub> hybrids.</p>
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17 pages, 9632 KiB  
Article
Wear and Corrosion Behavior of Diamond-like Carbon Coatings in Artificial Saliva
by Monika Madej, Katarzyna Piotrowska, Martin Vicen and Viera Zatkaliková
Coatings 2025, 15(3), 305; https://doi.org/10.3390/coatings15030305 - 5 Mar 2025
Viewed by 297
Abstract
This study investigates the properties of diamond-like carbon (DLC) coatings deposited onto a Ti6Al4V titanium alloy using plasma-assisted chemical vapor deposition (PACVD). The research encompasses adhesion tests, hardness, surface characterization, as well as corrosion and tribological evaluations. Artificial saliva was employed as both [...] Read more.
This study investigates the properties of diamond-like carbon (DLC) coatings deposited onto a Ti6Al4V titanium alloy using plasma-assisted chemical vapor deposition (PACVD). The research encompasses adhesion tests, hardness, surface characterization, as well as corrosion and tribological evaluations. Artificial saliva was employed as both the lubricating and corrosive medium. Microscopic examination revealed a uniform coating with a thickness of about 3.2 µm. Scratch test results indicated that the deposited DLC coating exhibited superior adhesion, lower frictional resistance, and reduced wear compared to the titanium alloy. The coating deposition increased the hardness of the Ti6Al4V alloy by about 75%. Friction coefficients, measured under dry and lubricated conditions, were approximately 80% lower for the DLC-coated samples. Corrosion studies revealed that both the coated and uncoated surfaces demonstrated typical passive behavior and high corrosion resistance in artificial saliva. For DLC coatings, the corrosion current density and the corrosion rate were reduced by 85%. Microscopic observations of wear tracks following tribological and scratch tests confirmed the inferior wear and scratch resistance of the titanium alloy relative to the DLC coating. Under both dry and lubricated conditions (with artificial saliva), the volumetric wear rate of the titanium alloy was over 90% higher than for the DLC coating. Full article
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<p>Three-electrode corrosion cell: 1—heating circuit, 2—auxiliary Pt electrode, 3—SCE reference electrode, 4—sample.</p>
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<p>Friction pair: view (<b>a</b>), diagram (<b>b</b>), 1—load, 2—temperature sensor, 3—ball, 4—coating, 5—sample.</p>
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<p>Linear distribution of elements and coating thickness on the cross-section.</p>
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<p>Ti6Al4V axonometric image 3D (<b>a</b>), primary surface profile (<b>b</b>).</p>
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<p>DLC axonometric image 3D (<b>a</b>), primary surface profile (<b>b</b>).</p>
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<p>Scratch test DLC: optical images (<b>a</b>), graph (<b>b</b>).</p>
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<p>Scratch test Ti6Al4V: optical images (<b>a</b>), graph (<b>b</b>).</p>
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<p>Two-dimensional axonometric image of a scratch: Ti6Al4V (<b>a</b>), DLC (<b>b</b>).</p>
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<p>Potentiodynamic polarization curves.</p>
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<p>Details of potentiodynamic polarization curves in linear axes for comparison of the passive current densities in the passivity regions above 0.15 V vs. SCE. Passivity is sustained when the current density remains below a critical threshold of 0.05 mA/cm<sup>2</sup>. Exceeding this threshold can result in the loss of passivity [<a href="#B47-coatings-15-00305" class="html-bibr">47</a>].</p>
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<p>Example waveforms: coefficients of friction (<b>a</b>), linear wear (<b>b</b>).</p>
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<p>Average values: coefficients of friction (<b>a</b>) and linear wear (<b>b</b>).</p>
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<p>Three-dimensional axonometric images, Ti6Al4V: dry friction (<b>a</b>), artificial saliva (<b>b</b>); DLC: dry friction (<b>c</b>), artificial saliva (<b>d</b>).</p>
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12 pages, 2510 KiB  
Article
Selection of Optimal Process Parameters for Arc Metallization
by Bauyrzhan Rakhadilov, Dastan Buitkenov, Akbota Apsezhanova, Dauir Kakimzhanov, Aiym Nabioldina and Nurtoleu Magazov
Coatings 2025, 15(3), 300; https://doi.org/10.3390/coatings15030300 - 4 Mar 2025
Viewed by 174
Abstract
This paper studies the coatings deposited on a 65G steel substrate by electric arc metallization using a 30KhGSA wire. The properties of the coatings obtained at 30 V, 40 V and 45 V are discussed, including their microstructure, porosity, microhardness, coefficient of friction [...] Read more.
This paper studies the coatings deposited on a 65G steel substrate by electric arc metallization using a 30KhGSA wire. The properties of the coatings obtained at 30 V, 40 V and 45 V are discussed, including their microstructure, porosity, microhardness, coefficient of friction and corrosion resistance. The experiments showed that the coatings possess a layered structure formed by sequential deposition of metal microdroplets. It was found that the increase in voltage favors the decrease in porosity, increase in layer density, increase in microhardness and improvement in wear resistance and corrosion resistance. At maximum voltage (45 V), there are optimum performance characteristics, such as minimal porosity (1.36%), high microhardness (305 HV) and improved corrosion resistance. The main defects of the coatings, including pores and oxide inclusions, which are formed during the sputtering process and depend on the kinetic energy of the microdroplets, were identified. These defects affect the mechanical and protective properties of the coatings. Full article
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<p>General view of the complex for high-speed electric arc metallization SX-600: 1—welding rectifier, 2—piston compressor, 3—spray gun, 4—remote control panel, 5—power cables, 6—air hose, 7—manipulator, 8—wire spools (electrodes).</p>
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<p>Microstructure of coatings obtained using scanning electron microscope: (<b>a</b>,<b>a’</b>) V1; (<b>b</b>,<b>b’</b>) V2; (<b>c</b>,<b>c’</b>) V3.</p>
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<p>Results of X-ray phase analysis.</p>
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<p>Microhardness of the coating.</p>
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<p>Results of tribological tests of coatings: friction coefficient.</p>
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17 pages, 10957 KiB  
Article
Effect of Loads on Tribological Performance of Rubber Seals at Floating Wind Power in Deep Sea
by Guibin Tan, Cheng Zhou, Jiantao Liang, Guangjing Huang, Zhixing Wang and Xing Huang
Lubricants 2025, 13(3), 111; https://doi.org/10.3390/lubricants13030111 - 3 Mar 2025
Viewed by 269
Abstract
The main shaft seal of offshore wind power equipment is one of the key components of wind power systems. However, wear issues between the seals and the main shaft caused by the intrusion of particulate matter in the environment have become a key [...] Read more.
The main shaft seal of offshore wind power equipment is one of the key components of wind power systems. However, wear issues between the seals and the main shaft caused by the intrusion of particulate matter in the environment have become a key factor affecting the service life of the equipment. To improve the surface performance of the main shaft, this study used laser cladding technology to prepare an Fe55 coating on the surface of QT-500 components. Through the wear experiments on HNBR seal pairs with the main shaft under different load conditions, this study thoroughly investigated the impact of the coating on frictional coefficients, wear mechanisms, and the wear morphology of metal surfaces. The experimental results show that the average hardness of the Fe55 coating is 533 HV, which is about 2.3 times the hardness of the substrate, and as the loading force increases, the wear form of the QT-500 metal changes from being dominated by pits to being dominated by furrows. In contrast, the wear form of the Fe55 coating is more inclined to furrows, and no pit formation is observed, indicating that the coating has improved the wear resistance of the surface. The frictional coefficient of the HNBR pair with the metal decreases with increasing load, and the frictional coefficient of the coating is lower than that of the substrate. As the loading increases, the wear morphology of the rubber surface transitions from furrows to pits, and the wear mechanism becomes abrasive wear. Full article
(This article belongs to the Special Issue Marine Tribology)
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<p>Common problems of rubber seals at floating wind power. (<b>a</b>) The floating system of wind power. (<b>b</b>) The main construction at deep sea. (<b>c</b>) The rubber seals and the shafting rotor.</p>
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<p>(<b>a</b>) Schematic diagram of the rubber seals (HNBR) at the main shaft for the wind turbine. (<b>b</b>) The rough soft-contact model of the seal pair.</p>
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<p>Schematic diagram of the tribological testing rig. (<b>a</b>) CFT-I. (<b>b</b>) The HNBR samples. (<b>c</b>) Steel samples. (<b>d</b>) The testing data of the HNBR stress–strain curve.</p>
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<p>(<b>a</b>) The cross-section of Fe55 cladding coating. (<b>b</b>,<b>c</b>) The cross-sectional morphology of Fe55 cladding coating. (<b>d</b>) Microstructure of the Fe55 laser cladding coating. (<b>e</b>) The hardness distribution of Fe55 cladding coating. (<b>f</b>) The XRD pattern of Fe55 cladding coating.</p>
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<p>The numerical simulation results of rubber seals at wind power. (<b>a</b>) Mises stress cloud diagram of lip seal friction pair. (<b>b</b>) The contact stress cloud diagram of seals. (<b>c</b>) Diagram of radial force variation with eccentricity. (<b>d</b>) Leakage rate and friction force of each section.</p>
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<p>Average frictional coefficient under different contact loads under oil lubrication.</p>
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<p>Surface wear phenomenon of rubber seals at oil lubrication: (<b>a</b>) 60 N, (<b>b</b>) 70 N, (<b>c</b>) 80 N, (<b>d</b>) 90 N.</p>
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<p>The variation curve of frictional coefficient over time under different axial loads.</p>
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<p>Average coefficient of friction between the QT-500 and Fe55 coatings under different loading conditions.</p>
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<p>The worn morphology of rubber surface of HNBR/QT-500 pairs and HNBR/Fe55 pairs under the different loads.</p>
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<p>The microscope images and 3D profiles. (<b>A</b>) Fe55 coating surface wear morphology. (<b>B</b>) QT-500 surface wear morphology.</p>
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<p>The wear characteristic dimensions of the QT-500 and Fe55 coating. (<b>a</b>) The morphological height profile of the QT-500. (<b>b</b>) The morphological height profile of Fe55 coating.</p>
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<p>(<b>a</b>) Surface wear phenomenon of QT-500 under 140 N. (<b>b</b>) Surface wear phenomenon of Fe55 under 140 N.</p>
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<p>The diagram of soft lubrication mechanism in rubber seals. (<b>a</b>) Lip seal and soft contact. (<b>b</b>) Surface contact state. (<b>c</b>) Oil lubrication friction. (<b>d</b>) Hydrodynamic pressure effect.</p>
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<p>(<b>a</b>) Schematic diagram of the friction mechanism under the axial load 80 N. (<b>b</b>) Schematic diagram of soft contact under the axial load of 100 N, 120 N. (<b>c</b>) Schematic diagram of soft contact under the axial load of 140 N. (<b>d</b>) The force analysis of particles at lubricating surface.</p>
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27 pages, 12001 KiB  
Article
Numerical Simulation of Convective Heat Transfer in Gyroid, Diamond, and Primitive Microstructures Using Water as the Working Fluid
by Jie Zhang and Xiaoqing Yang
Energies 2025, 18(5), 1230; https://doi.org/10.3390/en18051230 - 3 Mar 2025
Viewed by 202
Abstract
With the continuous increase in the thermal power of electronic devices, air cooling is becoming increasingly challenging in terms of meeting heat dissipation requirements. Liquid cooling media have a higher specific heat capacity and better heat dissipation effect, making it a more efficient [...] Read more.
With the continuous increase in the thermal power of electronic devices, air cooling is becoming increasingly challenging in terms of meeting heat dissipation requirements. Liquid cooling media have a higher specific heat capacity and better heat dissipation effect, making it a more efficient cooling method. In order to improve the heat dissipation effect of liquid cooling, a TPMS structure with a larger specific surface area, which implicit function parameters can control, can be arranged in a shape manner and it is easy to expand the structural design. It has excellent potential for application in the field of heat dissipation. At present, research is still in its initial stage and lacks comparative studies on liquid cooled convective heat transfer of TPMS structures G (Gyroid), D (Diamond), and P (Primitive). This paper investigates the heat transfer performance and pressure drop characteristics of a sheet-like microstructure composed of classic TPMS structures, G (Gyroid), D (Diamond), and P (Primitive), with a single crystal cell length of 2π (mm), a cell number of 1 × 1 × 5, and a microstructure size of 2π (mm) × 2π (mm) × 22π (mm) using a constant temperature surface model. By analyzing the outlet temperature tout, structural pressure p, average convective heat transfer coefficient h0, Nusselt number Nu, and average wall friction factor f of the microstructure within the speed range of 0.01–0.11 m/s and constant temperature surface temperature is 100 °C, the heat transfer capacity D > G > P and pressure drop D > G > P were obtained (the difference in pressure drop between G and P is very small, less than 20 Pa, which can be considered consistent). When flow velocity is 0.01 m/s, the maximum temperature difference at the outlet of the four structures reached 17.14 °C, and the maximum difference in wall friction factor f reached 103.264, with a relative change of 646%. When flow velocity is 0.11 m/s, the maximum pressure difference among the four structures reached 8461.84 Pa, and the maximum difference in h0 reached 7513 W/(m2·K), with a relative change of 63.36%; the maximum difference between Nu reached 76.32, with a relative change of 62.09%. This paper explains the reasons for the above conclusions by analyzing the proportion of solid area on the constant temperature surface of the structure, the porosity of the structure, and the characteristics of streamlines in the microstructure. Full article
(This article belongs to the Section J1: Heat and Mass Transfer)
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<p>TPMS-G structure with cycles of (2, 2, 7).</p>
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<p>TPMS to be repaired in SpaceClaim.</p>
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<p>TPMS initially presented in COMSOL.</p>
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<p>Imported TPMS Defects.</p>
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<p>Embedded rectangular prism in TPMS.</p>
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<p>TPMS-G structure with Boolean post cycle numbers of (1, 1, 5).</p>
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<p>Physical Model of TPMS-G Microstructure.</p>
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<p>Single cells of four TPMS structures.</p>
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<p>Four types of TPMS imported into COMSOL.</p>
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<p>Microstructure physical models of four types of TPMS.</p>
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<p>Mesh division of different refinement levels on the entrance surface of the microstructure TPMS.</p>
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<p>Outlet temperature under different grids.</p>
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<p>Structural pressure under different grids.</p>
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<p>Relative outlet temperature under different grids.</p>
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<p>Relative pressure under different grids.</p>
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<p>Flow velocity in the yz section of four TPMS microstructures.</p>
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<p>Velocity cloud map through the yz plane of microstructure geometry center.</p>
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<p>Velocity cloud map of microstructure TPMS inlet surface.</p>
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<p>Flow velocity in the yz section of TPMS in four microstructures.</p>
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<p>Structure of TPMS along the mainstream direction.</p>
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<p>Partial streamline of TPMS.</p>
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<p>Partial streamline of TPMS and outlet section of microstructure.</p>
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<p>Streamline of TPMS-G, D1, P, D2 outlet.</p>
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<p>Velocity cloud map through microstructure geometric center xy plane.</p>
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<p>Temperature cloud map of xy plane through microstructure geometry center.</p>
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<p>Temperature cloud map through the yz plane of microstructure geometry center.</p>
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<p>Outlet temperatures of four microstructures at different flow velocities.</p>
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<p>Four microstructure pressures at different flow velocities.</p>
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<p>Average convective heat transfer coefficients <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>h</mi> </mrow> <mrow> <mn>0</mn> </mrow> </msub> </mrow> </semantics></math> of four microstructures at different flow velocities.</p>
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<p>Nusselt numbers <math display="inline"><semantics> <mrow> <mi>N</mi> <mi>u</mi> </mrow> </semantics></math> of four microstructures at different flow velocities.</p>
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<p>Average wall friction factors <math display="inline"><semantics> <mrow> <mi>f</mi> </mrow> </semantics></math> of four microstructures at different flow velocities.</p>
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21 pages, 10268 KiB  
Article
Tribological Performance Comparison of Lubricating Greases for Electric Vehicle Bearings
by Deepika Shekhawat, Ayush Jain, Nitesh Vashishtha, Arendra Pal Singh and Rahul Kumar
Lubricants 2025, 13(3), 108; https://doi.org/10.3390/lubricants13030108 - 1 Mar 2025
Viewed by 471
Abstract
EV motors and machine elements operate at higher speeds, generate significant heat and noise (vibration), and subject lubricants (bearings) to multiple degrading factors, requiring thermal stability, wear protection, mitigating wear mechanisms like pitting and scuffing, and low electrical conductivity to prevent arcing damage [...] Read more.
EV motors and machine elements operate at higher speeds, generate significant heat and noise (vibration), and subject lubricants (bearings) to multiple degrading factors, requiring thermal stability, wear protection, mitigating wear mechanisms like pitting and scuffing, and low electrical conductivity to prevent arcing damage to bearings. This study evaluates the tribological performance of four types of greases—PUEs, PUPao, PUEth (polyurea-based), and LiPAO (lithium–calcium complex-based)—to determine their suitability for electric motor bearings. Key performance metrics include tribological properties, electrical resistivity, leakage, bearing noise, and wear behavior. A four-ball wear test ranks the greases by scar diameter as PUPao < PUEs < PUEth < LiPAO, while the coefficient of friction is observed in the range of 0.15–0.18, with LiPAO exhibiting the lowest friction. Electrical resistivity tests reveal that PUEs grease has the lowest resistivity. Electrical leakage tests, conducted with a voltage differential across bearings, assess pitting damage, with PUEth and LiPAO showing evidence of surface pitting. Optical microscopy and scanning electron microscopy analysis is carried out to examine the pitting. In bearing noise tests, PUEs demonstrates the lowest noise levels, whereas LiPAO produces the highest. Visual and microscopic examination of the greases further characterizes their lubricating properties. Based on overall performance, the greases are ranked in suitability for electric motor applications as PUEs > PUPao > PUEth > LiPAO. The findings highlight the critical need for selecting appropriate grease formulations to ensure optimal bearing performance under varying operational conditions. Full article
(This article belongs to the Special Issue Tribology of Electric Vehicles)
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<p>Schematic illustration of the oil bleeding test.</p>
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<p>METRAVI DIT 914 digital insulation tester.</p>
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<p>UMT tribometer (four-ball assembly).</p>
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<p>Electrically induced bearing damage test rig.</p>
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<p>Photographic illustration of ball bearing 6203LLU filled with PUEs, LiPAO, PUPao, and PUEth greases for testing.</p>
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<p>Electric circuit.</p>
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<p>FTIR analysis of PUEs, PUPao, LiPAO, and PUEth grease.</p>
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<p>Microscopy images of four-ball wear scar of (<b>a</b>) LiPAO, (<b>b</b>) PUPao, (<b>c</b>) PUEs, and (<b>d</b>) PUEth grease (at 50×).</p>
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<p>(<b>a</b>) acoustic emission, (<b>b</b>) electrical contact resistance, (<b>c</b>) average coefficient of friction, and (<b>d</b>) wear scar diameter for PUEs, PUEth, PUPao, and LiPAO grease.</p>
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<p>Ball bearing 6203 LLU: cross-section.</p>
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<p>Optical microscopy images of the inner raceway of bearings after the electrically induced bearing damage test: (<b>a</b>) PUEs, (<b>b</b>) PUEth, (<b>c</b>) PUPao, and (<b>d</b>) LiPAO (at 100×).</p>
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<p>SEM images of craters formed on the inner raceway of PUEs.</p>
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<p>The high band (HG) and low band (LB) noise measurement values for all four greases in bearing 6203 LLU before and after the electrically induced bearing damage test.</p>
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<p>Rating of greases based on the eight different influencing factors for selecting EV bearing greases (a higher rating indicates a better performance).</p>
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12 pages, 5789 KiB  
Article
Effect of SiC Concentration on the Microstructure and Anti-Wear Performance of Electrodeposited Ni-SiC Composite Coatings Constructed for Piston Ring Application
by Fengwu Zhang, Qiuhua Wang, Huajie Shen, Caixia Bai, Chaoyu Li, Dehao Tian and Baojin Wang
Materials 2025, 18(5), 1117; https://doi.org/10.3390/ma18051117 - 1 Mar 2025
Viewed by 350
Abstract
At present, the improvement of anti-wear performance of piston rings remains a challenge. In this article, Ni-SiC composite coatings fabricated at 3, 9, and 15 g/L SiC were denoted as NSc-3, NSc-9, and NSc-15 coatings. Meanwhile, the influence of SiC concentration on the [...] Read more.
At present, the improvement of anti-wear performance of piston rings remains a challenge. In this article, Ni-SiC composite coatings fabricated at 3, 9, and 15 g/L SiC were denoted as NSc-3, NSc-9, and NSc-15 coatings. Meanwhile, the influence of SiC concentration on the surface morphology, phase structure, microhardness, and anti-wear performance of electrodeposited Ni-SiC composite coatings were investigated utilizing scanning electron microscopy, X-ray diffraction, a microhardness tester, and a friction–wear tester, respectively. The SEM images presented NSc-9 coatings with a compact, flat, or cauliflower-like surface morphology. The cross-sectional morphology and EDS results showed that the Si and Ni elements were uniformly distributed in the NSc-9 coatings with dense and flat microstructures. Moreover, the average grain size of the NSc-9 coatings was only 429 nm. Furthermore, the microhardness and indentation path of the NSc-9 coatings were 672 Hv and 13.7 μm, respectively. Also, the average friction coefficient and worn weight loss of the NSc-9 coatings were 0.46 and 29.5 mg, respectively, which were lower than those of the NSc-3 and NSc-15 coatings. In addition, a few shallow scratches emerged on the worn surfaces of the NSc-9 coatings, demonstrating their outstanding anti-wear performance when compared to the NSc-3 and NSc-15 coatings. Full article
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<p>TEM image of SiC nanoparticles.</p>
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<p>Schematic graph of electrodeposited Ni-SiC composite coatings.</p>
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<p>Schematic facility for measuring the anti-wear performance of Ni-SiC composite coatings.</p>
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<p>SEM images of Ni-SiC composite coatings manufactured at various SiC concentrations: (<b>a</b>) NSc-3, (<b>b</b>) NSc-9, and (<b>c</b>) NSc-15 coatings.</p>
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<p>Cross-sectional SEM image and element distribution of NSc-9 coatings.</p>
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<p>XRD spectra of Ni-SiC composite coatings prepared at different SiC concentrations: (a) NSc-3, (b) NSc-9, and (c) NSc-15 coatings.</p>
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<p>Microhardness value of Ni-SiC composite coatings prepared at different SiC concentrations: (a) NSc-3, (b) NSc-9, and (c) NSc-15 coatings.</p>
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<p>Indentation depths of Ni-SiC composite coatings prepared at different SiC concentrations: (a) NSc-3, (b) NSc-9, and (c) NSc-15 coatings.</p>
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<p>Friction coefficients of Ni-SiC composite coatings prepared at different SiC concentrations: (a) NSc-3, (b) NSc-9, and (c) NSc-15 coatings.</p>
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<p>Worn surface morphology of Ni-SiC composite coatings prepared at different SiC concentrations: (<b>a</b>) NSc-3, (<b>b</b>) NSc-9, and (<b>c</b>) NSc-15 coatings.</p>
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<p>Worn weight losses of Ni-SiC composite coatings prepared at different SiC concentrations: (a) NSc-3, (b) NSc-9, and (c) NSc-15 coatings.</p>
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12 pages, 3484 KiB  
Article
Influence of La/Al Doping via Magnetron Sputtering on the Mechanical and Tribological Properties of TiN Coatings
by Weihang Chang, Hongfeng Zhang, Changling Tian, Yujun Xue and Gang Liu
Coatings 2025, 15(3), 284; https://doi.org/10.3390/coatings15030284 - 28 Feb 2025
Viewed by 209
Abstract
Adding alloying elements to binary nitrides enables the design of hard and tough coatings. To improve the mechanical and tribological performances of TiN-based coatings, La atoms were added to TiAlN coatings to form TiAlLaN coatings. Magnetron sputtering was conducted to prepare the TiAlLaN [...] Read more.
Adding alloying elements to binary nitrides enables the design of hard and tough coatings. To improve the mechanical and tribological performances of TiN-based coatings, La atoms were added to TiAlN coatings to form TiAlLaN coatings. Magnetron sputtering was conducted to prepare the TiAlLaN coatings. Thereafter, scanning electron microscopy (SEM), x-ray diffraction (XRD), nano-indentation, and a tribometer were utilized to test their microstructure, phases, and mechanical and tribological performances. Next, this study analyzed how lanthanum affected the microstructure and tribological performances of the TiAlLaN coatings. Incorporating La atoms in TiAlN coatings reduced the crystallite size and enhanced the coating toughness and hardness. The hardness H and elastic modulus E of the TiAlLaN coatings first increased and then decreased with the increase in La. Meanwhile, the coatings had improved wear and friction properties. The increased H/E and H3/E2 levels, which have been considered to reflect the hard coating’s toughness, were acquired based on the TiAlLaN coating, possessing enhanced hardness (19.8 GPa). The coefficient of friction and the wear rates of the coatings reduced and then increased with the increase in La. The TiAlLaN coating with 1.4 % of lanthanum had the lowest friction coefficient and wear rate of around 0.383 and 1.59 × 10−8 mm3/N·m, respectively, corresponding to a higher H/E (~0.086) and H3/E2 (~0.147 GPa). Adding an appropriate amount of La can substantially enhance the TiAlN coating’s tribological and mechanical properties. The TiAlLaN coating with remarkable characteristics may be applied to a steel substrate. Full article
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<p>Schematic of the magnetron sputtering process.</p>
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<p>Surface morphologies of the TiN, TiAlN, and TiAlLaN coatings: (<b>a</b>) TiN1, (<b>b</b>) TiN2, (<b>c</b>) TiN3, (<b>d</b>) TiAlN1, (<b>e</b>) TiAlN2, (<b>f</b>) TiAlN3, (<b>g</b>) TiALaN1, (<b>h</b>) TiALaN2, and (<b>i</b>) TiALaN3.</p>
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<p>XRD patterns and grain sizes for the TiN, TiAlN, and TiAlLaN coatings: (<b>a</b>) TiN; (<b>b</b>) TiAlN; (<b>c</b>) TiAlLaN; (<b>d</b>) grain sizes of coatings.</p>
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<p>(<b>a</b>) Hardness and elastic modulus and (<b>b</b>) H/E and H<sup>3</sup>/E<sup>2</sup> ratios of the TiN, TiAlN, and TiAlLaN coatings.</p>
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<p>Friction coefficients of the TiAlN and TiAlLaN coatings. (<b>a</b>)TiAlN; (<b>b</b>)TiAlLaN.</p>
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<p>Worn surface morphologies for the TiAlN and TiAlLaN coatings: (<b>a</b>) TiAlN1, (<b>b</b>) TiAlN2, (<b>c</b>) TiAlN3, (<b>d</b>) TiALaN1, (<b>e</b>) TiALaN2, and (<b>f</b>) TiALaN3.</p>
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