Search Results (3,917)

To improve the collaborative design of laser cladding Ni-based self-fluxing alloy (SFA) wear-resistant coatings, machine learning methods were applied. A comprehensive database was constructed from the literature, linking alloy composition, processing parameters, testing conditions, and the wear properties of Ni-based SFA coatings. Feature correlation analysis using Pearson’s correlation coefficient and feature importance assessment via the random forest (RF) model highlighted the significant impact of C and B elements. The predictive performance of five classical machine learning algorithms was evaluated using metrics such as the squared correlation coefficient (R²) and mean absolute error (MAE). The RF model, which exhibited the best overall performance, was further combined with a genetic algorithm (GA) to optimize both composition and processing parameters collaboratively. This integrated RF-GA optimization system significantly enhanced efficiency and successfully designed multiple composition and process plans. The optimized alloy demonstrated superior wear resistance with an average friction coefficient of only 0.34, attributed to an enhanced solid solution strengthening effect (110 MPa) and increased hard phase content (52%), such as Ni₃Si, CrB, and NbC. These results provide valuable methodological insights and theoretical support for the preparation of laser cladding coatings and enable efficient process optimization for other laser processing applications. Full article

In recent years, Golden Hard Anodizing (G.H.A.^®) has been developed as a variant of the traditional hard anodizing process with the addition of Ag⁺ ions in the nanoporous structure. The tribological properties of this innovative surface treatment are still not well understood. In this study, ball-on-disk tests were conducted in dry sliding conditions using 100Cr6 (AISI 52100) bearing steel balls as a counterbody and GHA^®-anodized EN AW-6082 aluminum alloy disks. The novelty of this work lies in the mapping of the wear properties of the tribocouple under different test conditions for a better comparison of the results. Three different normal loads (equal to 5, 10, and 15 N) and three different reciprocating frequencies (equal to 2, 3, and 4 Hz) were selected to investigate a spectrum of operating conditions for polished and unpolished G.H.A.^®-anodized EN AW-6082 aluminum alloy. Quantitative wear maps were built based on the resulting wear rate values to define the critical operating limits of the considered tribocouple. The results suggest that the coefficient of friction (COF) was independent of test conditions, while different wear maps were found for polished and non-polished surfaces. Polishing before anodizing permitted the acquisition of lower wear for the anodized disks and the steel balls. Full article

The working conditions of tools during plastic working operations are determined by, among other things, temperature, loads, loading method, and processing speed. In sheet metal forming processes, additionally, lubricant and tool surface roughness play a key role in changing the surface topography of the drawpieces. This article presents the results of friction analysis on the edge of the punch in a deep drawing process using the bending under tension test. A DC04 steel sheet was used as the test material. The influence of various types of titanium nitride and titanium coatings applied on the surface of countersamples made of 145Cr6 cold-work tool steel was tested by means of high-intensity plasma pulses, magnetron sputtering, and electron pulse irradiation. The influence of the type of tool coating on the evolution of the coefficient of friction, the change in the sheet surface topography, and the temperature in the contact zone is presented in this paper. An increase in the coefficient of friction with sample elongation was observed. Countersamples modified with protective coatings provided a more stable coefficient value during the entire friction test compared to dry friction conditions. The electron pulse irradiated countersample provided the highest stability of the coefficient of friction in the entire range of sample elongation until fracture. The skewness Ssk of the sheet metal tested against the coated countersamples was characterized by negative value, which indicates a plateau-like shape of their surface. The highest temperature in the contact zone during friction with all types of countersamples was observed for the uncoated countersample. Full article

The well-known “click chemistry” reaction copper(I)-catalyzed azide-alkyne 1,3-dipolar cycloaddition (CuAAC) was used to transform under very mild conditions hyaluronan-based graft copolymers HA(270)-FA-Pg into the crosslinked derivatives HA(270)-FA-TEGERA-CL and HA(270)-FA-HEGERA-CL. In particular, medium molecular weight (i.e., 270 kDa) hyaluronic acid (HA) grafted at various extents (i.e., 10, 20, and 40%) with fluorogenic ferulic acid (FA) residue bonding propargyl groups were used in the CuAAC reaction with novel azido-terminated crosslinking agents Tri(Ethylene Glycol) Ethyl Resorcinol Acrylate (TEGERA) and Hexa(Ethylene Glycol) Ethyl Resorcinol Acrylate (HEGERA). The resulting HA(270)-FA-TEGERA-CL and HA(270)-FA-HEGERA-CL materials were characterized from the point of view of their structure by performing NMR studies. Moreover, the swelling behavior and rheological features were assessed employing TGA and DSC analysis to evaluate the potential gel-like properties of the resulting crosslinked materials. Despite the 3D crosslinked structure, HA(270)-FA-TEGERA-CL and HA(270)-FA-HEGERA-CL frameworks showed adequate swelling performance, the required shear thinning behavior, and coefficient of friction values close to those of the main commercial HA solutions used as viscosupplements (i.e., 0.20 at 10 mm/s). Furthermore, the presence of a crosslinked structure guaranteed a longer residence time. Indeed, HA(270)-FA-TEGERA-CL-40 and HA(270)-FA-HEGERA-CL-40 after 48 h showed a four times greater enzymatic resistance than the commercial viscosupplements. Based on the promising obtained results, the crosslinked materials are proposed for their potential applicability as novel viscosupplements. Full article

Aloe vera is well known for its biological properties as a bioflavonoid anti-inflammatory and antibacterial agent. It has been used frequently in the food sector as a food coating due to its hygroscopic properties and as an ingredient in the lucrative cosmetic industry. Studies have also included aloe vera as an eco-friendly green solution based on these properties. The current research focuses on the use of aloe vera gel in printing pastes as an alternative sustainable solution to synthetic thickeners, evaluating its wet performance and ease of fabric stitching, and has been inspired by studies that similarly used this substance and measured its effect on the fabric’s coefficient of friction and antimicrobial action. In the current study, printing pastes with natural colourants, such as saffron, curcumin, and annatto, and aloe vera gel thickener derived from natural leaves from Crete increased the fabric’s mechanical resistance to abrasion compared to the untreated pastes. The measured performance did not differ substantially from prints with traditional synthetic pastes, hence tolerating the substitution with the non-contaminant variant. The enhanced resistance to abrasion and wear extends the fabric’s serviceable life and resulting garments, decreasing the need for high industry processing volumes and, as a result, reducing pollution. The resistance to wear was evaluated using the dominant method in textile testing of the Martindale apparatus, which measured the cycles to failure, weight loss, and general appearance deterioration using the official photographic standards. Full article

Rapid developments in aerospace and nuclear industries pushed forward the search for high-performance self-lubricating materials with low friction and wear characteristics under severe environment. In this paper, we investigated the influence of the Mo element on the tribological performance of nickel alloy matrix composites from room temperature to 800 °C under atmospheric conditions. The results demonstrated that composites exhibited excellent lubricating (with low friction coefficients of 0.19–0.37) and wear resistance properties (with low wear rates of 2.5–28.1 × 10⁻⁵ mm³/Nm), especially at a content of elemental Mo of 8 wt. % and 12 wt. %. The presence of soft metal Ag on the sliding surface as solid lubricant resulted in low friction and wear rate in a temperature range from 25 to 400 °C, while at elevated temperatures (600 and 800 °C), the effective lubricant contributed to the formation of a glazed layer rich in NiCr₂O₄, BaF₂/CaF₂, and Ag₂MoO₄. SEM, EDS, and the Raman spectrum indicated that abrasive and fatigue wear were the main wear mechanisms for the studied composites during sliding against the Si₃N₄ ceramic ball. The obtained results provide an insightful suggestion for future designing and fabricating solid lubricant composites with low friction and wear properties. Full article

Friction and wear characteristics play a critical role in the functionality and durability of prosthetic sockets, which are essential components in lower-limb prostheses. Traditionally, these sockets are manufactured from bulk polymers or composite materials reinforced with advanced carbon, glass, and Kevlar fibres. However, issues of accessibility, affordability, and sustainability remain, particularly in less-resourced regions. This study investigates the potential of self-reinforced polymer composites (SRPCs), including poly-lactic acid (PLA), polyethylene terephthalate (PET), glass fibre (GF), and carbon fibre (CF), as sustainable alternatives for socket manufacturing. The tribological behaviour of these self-reinforced polymers (SrPs) was evaluated through experimental friction tests, comparing their performance to commonly used materials like high-density polyethylene (HDPE) and polypropylene (PP). Under varying loads and rotational speeds, HDPE and PP exhibited lower coefficients of friction (COF) compared to SrPLA, SrPET, SrGF, and SrCF. SrPLA recorded the highest average COF of 0.45 at 5 N and 240 rpm, while SrPET demonstrated the lowest COF of 0.15 under the same conditions. Microscopic analysis revealed significant variations in wear depth, with SrPLA showing the most profound wear, followed by SrCF, SrGF, and SrPET. In all cases, debris from the reinforcement adhered to the steel ball surface, influencing the COF. While these findings are based on friction tests against steel, they provide valuable insights into the durability and wear resistance of SRPCs, a crucial consideration for socket applications. This study highlights the importance of tribological analysis for optimising prosthetic socket design, contributing to enhanced functionality and comfort for amputees. Further research, including friction testing with skin-contact scenarios, is necessary to fully understand the implications of these materials in real-world prosthetic applications. Full article

This study investigates the effects of aluminum and nitrogen content on the microstructure, mechanical properties, and tribological performance of high-entropy coatings based on (TiCrAl_xNbY)N_y systems. Using a hybrid magnetron sputtering technique, both metallic and nitride coatings were synthesized and evaluated. Increasing the aluminum concentration led to a transition from a crystalline to a nanocrystalline and nearly amorphous (NC/A) structure, with the TiAl_0.5CrNbY sample (11.8% Al) exhibiting the best balance of hardness (6.8 GPa), elastic modulus (87.1 GPa), and coefficient of friction (0.64). The addition of nitrogen further enhanced these properties, transitioning the coatings to a denser fine-grained FCC structure. The HN2 sample (45.8% nitrogen) displayed the highest hardness (21.8 GPa) but increased brittleness, while the HN1 sample (32.9% nitrogen) provided an optimal balance of hardness (14.3 GPa), elastic modulus (127.5 GPa), coefficient of friction (0.60), and wear resistance (21.2 × 10⁻⁶ mm³/Nm). Electrochemical impedance spectroscopy revealed improved corrosion resistance for the HN1 sample due to its dense microstructure. Overall, the (TiAl_0.5CrNbY)N_0.5 coating achieved the best performance for friction applications, such as break and clutch systems, requiring high coefficients of friction, high wear resistance, and durability. Full article

The plasma immersion nitriding system was utilized to make massive nitrogen supersaturation (MNS) to CoCrMo disc and die substrates at 723 K for 21.6 ks. The top layer thickness in the multi-layered MNSed layer was 20 μm. Its nitrogen solute content reached 5 mass% on average after SEM-EDX analysis. The surface hardness was 1300 HV_1N (HV_0.1), which was much higher than the bare CoCrMo with 450 HV_1N. The original polycrystalline structure was modified to be a multi-layered microstructure, which consisted of the nanograined MNSed top layer, the buffer layer with a thickness of 5 μm, and the column–granular structured layer with their textured crystallographic orientations. The BOD (ball-on-disc) testing was employed to describe the frictional sliding behavior under the applied loads of 5 N and 10 N and the sliding velocity of 0.1 m/s against the AISI316 ball. The friction coefficient was held constant by 0.68 on average. The CNC (Computer Numerical Control) stamping system was employed to upset the fine-grained 1.0 mm thick AISI316 wire up to 70% in reduction in thickness. The friction coefficient at RT was estimated to be 0.05. A round, fine-grained AISI316 wire was shaped into a thin plate with a thickness of 0.3 mm in cold and dry. Full article

The low viscosity of water-lubricated films compromises their load-bearing capacity, posing challenges for practical application. Enhancing the lubrication stability of these films under load is critical for the successful use of seawater-lubricated bearings in engineering. Polydopamine (PDA) shows great potential to address this issue due to its strong bio-inspired adhesion and hydration lubrication properties. Thus, PDA nanoparticles and seawater suspensions were synthesized to promote adhesive lubricating film formation under dynamic friction. The lubrication properties of PDA suspensions were evaluated on Cu ball and ultra-high molecular weight polyethylene (UHMWPE) tribo-pairs, with a detailed comparison to seawater. The results show PDA nanoparticles provide excellent adhesion and lubrication, enhancing the formation of lubricating films during friction with seawater. Under identical conditions, PDA suspensions demonstrated the lowest friction coefficient and minimal wear. At 3 N, friction decreased by 56% and wear by 47% compared to distilled water. These findings suggest a novel strategy for using PDA as a lubricant in seawater for engineering applications. Full article

(AlCrNbSiTiMo)N high-entropy alloy films with different nitrogen contents were deposited on tungsten carbide substrates using a radio-frequency magnetron sputtering system. Two different types of targets were used in the sputtering process: a hot-pressing sintered AlCrNbSiTi target fabricated using a single powder containing multiple elements and a vacuum arc melting Mo target. The deposited films were denoted as R_N0, R_N33, R_N43, R_N50, and R_N56, where R_N indicates the nitrogen flow ratio relative to the total nitrogen and argon flow rate (R_N = (N₂/(N₂ + Ar)) × 100%). The as-sputtered films were vacuum annealed, with the resulting films denoted as HR_N0, HR_N33, HR_N43, HR_N50, and HR_N56, respectively. The effects of the nitrogen content on the composition, microstructure, mechanical properties, and tribological properties of the films, in both as-sputtered and annealed states, underwent thorough analysis. The R_N0 and R_N33 films displayed non-crystalline structures. However, with an increase in nitrogen content, the R_N43, R_N50, and R_N56 films transitioned to FCC structures. Among the as-deposited films, the R_N43 film exhibited the best mechanical and tribological properties. All of the annealed films, except for the HR_N0 film, displayed an FCC structure. In addition, they all formed an MoO₃ solid lubricating phase, which reduced the coefficient of friction and improved the anti-wear performance. The heat treatment HR_N43 film displayed the supreme hardness, H/E ratio, and adhesion strength. It also demonstrated excellent thermal stability and the best wear resistance. As a result, in milling tests on Inconel 718, the R_N43-coated tool demonstrated a significantly lower flank wear and notch wear, indicating an improved machining performance and extended tool life. Thus, the application of the R_N43 film in aerospace manufacturing can effectively reduce the tool replacement cost. Full article

The positive effect of plasma electrolytic treatment on CrWMn tool steel to increase the wear resistance of its surface is shown. The effect of plasma electrolytic nitriding and subsequent polishing on the structure, phase and elemental composition, microhardness of the surface layer, and surface morphology is established. Steel nitriding leads to the formation of a modified surface layer including Fe_2–3N iron nitride and nitrogen martensite, below which hardening martensite is formed, reaching a microhardness value of 1200 HV. Subsequent polishing leads to a decrease in surface roughness by 42–68%. Tribological tests were carried out according to the shaft-bushing scheme. A decrease in the friction coefficient and weight wear of up to 2.6 and 30.1 times, respectively, is shown. The formed structure of the surface layer compensates for the effect of the counter body and determines the destruction of friction bonds by plastic displacement. The wear mechanism has been established and is defined as fatigue wear under dry friction and plastic contact. Full article

Impregnated graphite is a common material for friction pairs in aeroengine seals, especially at high temperatures. For the convenience of the application of graphite materials in aeroengines, an SRV-4 tribometer and a synchronous thermal analyzer are employed to study the tribological properties and thermal stability of pure, resin-impregnated, metal-impregnated, and phosphate-impregnated graphite against stainless steel from room temperature to 500 °C. The results indicate that impregnations can improve the wear resistance and thermal stability of graphite at high temperatures. Compared with other impregnated graphite materials, the resin-impregnated graphite shows a good friction coefficient and poor wear rate and thermal stability over 300 °C, due to the degradation and oxidation of the resin-and-graphite matrix. The metal- and phosphate-impregnated graphite materials exhibit excellent wear resistance and thermal stability under 500 °C as a result of the protection of the impregnations, while the average friction coefficient of the metal-impregnated graphite is much greater than the phosphate-impregnated graphite, and even reaches 2.14-fold at 300 °C. The wear rates for the graphite impregnated with resin, metal, and phosphate are 235 × 10⁻⁷, 7 × 10⁻⁷, and 16 × 10⁻⁷ mm³N⁻¹m⁻¹ at 500 °C, respectively. Considering all aspects, the phosphate-impregnated graphite exhibits excellent tribological properties and thermal stability. Full article

We investigate the effect of three different harmonically varying loads as a function of the friction coefficient on energy loss in a three-dimensional discrete uncoupled frictional contact problem. Three loading cases include (1) a normal force is constant and a tangential force varies, (2) normal and tangential forces both vary, but the loading and unloading curves are identical, and (3) normal and tangential forces both vary, but the loading and unloading curves are different. For a higher coefficient of friction, three loading cases show different characteristics. If a normal force is constant and a tangential force varies, there is always some slip, but dissipation tends asymptotically to zero at large coefficient of friction. If normal and tangential forces both vary, but the loading and unloading curves are identical, there is no slip and no dissipation above a critical coefficient of friction. If the loading and unloading curves are different, dissipation occurs for all values of the coefficient of friction, and we expect that the dissipation is asymptotic to the relaxation damping value as the coefficient of friction approaches infinity. For lowering coefficient of friction, the three loading cases show similar behavior. Dissipation increases and reaches a maximum just before a state where gross slip is possible. Full article

This study investigates the impact of tightening torque (preload) and the friction coefficient on stress generation and fatigue resistance of a Ti-6Al-4V abutment screw with an internal hexagonal connection under dynamic multi-axial masticatory loads in high-cycle fatigue (HCF) conditions. A three-dimensional model of the implant–abutment assembly was simulated using ANSYS Workbench 16.2 computer aided engineering software with chewing forces ranging from 300 N to 1000 N, evaluated over 1.35 × 10⁷ cycles, simulating 15 years of service. Results indicate that the healthy range of normal to maximal mastication forces (300–550 N) preserved the screw’s structural integrity, while higher loads (≥800 N) exceeded the Ti-6Al-4V alloy’s yield strength, indicating a risk of plastic deformation under extreme conditions. Stress peaked near the end of the occluding phase (206.5 ms), marking a critical temporal point for fatigue accumulation. Optimizing the friction coefficient (0.5 µ) and preload management improved stress distribution, minimized fatigue damage, and ensured joint stability. Masticatory forces up to 550 N were well within the abutment screw’s capacity to sustain extended service life and maintain its elastic behavior. Full article