Nothing Special   »   [go: up one dir, main page]

You seem to have javascript disabled. Please note that many of the page functionalities won't work as expected without javascript enabled.
 
 
Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (166)

Search Parameters:
Keywords = fouling detection

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
23 pages, 8520 KiB  
Article
Fall Detection in Q-eBall: Enhancing Gameplay Through Sensor-Based Solutions
by Zeyad T. Aklah, Hussein T. Hassan, Amean Al-Safi and Khalid Aljabery
J. Sens. Actuator Netw. 2024, 13(6), 77; https://doi.org/10.3390/jsan13060077 - 13 Nov 2024
Viewed by 296
Abstract
The field of physically interactive electronic games is rapidly evolving, driven by the fact that it combines the benefits of physical activities and the attractiveness of electronic games, as well as advancements in sensor technologies. In this paper, a new game was introduced, [...] Read more.
The field of physically interactive electronic games is rapidly evolving, driven by the fact that it combines the benefits of physical activities and the attractiveness of electronic games, as well as advancements in sensor technologies. In this paper, a new game was introduced, which is a special version of Bubble Soccer, which we named Q-eBall. It creates a dynamic and engaging experience by combining simulation and physical interactions. Q-eBall is equipped with a fall detection system, which uses an embedded electronic circuit integrated with an accelerometer, a gyroscopic, and a pressure sensor. An evaluation of the performance of the fall detection system in Q-eBall is presented, exploring its technical details and showing its performance. The system captures the data of players’ movement in real-time and transmits it to the game controller, which can accurately identify when a player falls. The automated fall detection process enables the game to take the required actions, such as transferring possession of the visual ball or applying fouls, without the need for manual intervention. Offline experiments were conducted to assess the performance of four machine learning models, which were K-Nearest Neighbors (KNNs), Support Vector Machine (SVM), Random Forest (RF), and Long Short-Term Memory (LSTM), for falls detection. The results showed that the inclusion of pressure sensor data significantly improved the performance of all models, with the SVM and LSTM models reaching 100% on all metrics (accuracy, precision, recall, and F1-score). To validate the offline results, a real-time experiment was performed using the pre-trained SVM model, which successfully recorded all 150 falls without any false positives or false negatives. These findings prove the reliability and effectiveness of the Q-eBall fall detection system in real time. Full article
Show Figures

Figure 1

Figure 1
<p>The embedded electronics within a bubble balloon.</p>
Full article ">Figure 2
<p>Player states in Q-eBall: standing, running, and various falling positions.</p>
Full article ">Figure 3
<p>Circuit diagram showing the connection of MPU-6050 accelerometer and gyroscope, along with pressure sensor for the ESP32 microcontroller.</p>
Full article ">Figure 4
<p>The labeled circuit board (<b>left</b>) and the same circuit board mounted on a bubble balloon (<b>right</b>).</p>
Full article ">Figure 5
<p>Raw data from three sensors (accelerometer, gyroscope, and pressure sensor) shown both before and after applying filters for a specific duration of 60 s to 61 s.</p>
Full article ">Figure 6
<p>Pressure signals error caused by bit sampling time.</p>
Full article ">Figure 7
<p>The organization and alignment of data from three sensors (accelerometer, gyroscope, and pressure sensor) with their corresponding labels and timestamps.</p>
Full article ">Figure 8
<p>Pressure, rotational speed, and acceleration signals, along with their corresponding labels.</p>
Full article ">Figure 9
<p>Sensor data processing and feature extraction flowchart.</p>
Full article ">Figure 10
<p>Confusion matrices illustrating the performance of four fall detection algorithms (KNNs, SVM, RF, and LSTMs) in two experimental settings. The left column (<b>a</b>,<b>c</b>,<b>e</b>,<b>g</b>) presents results using accelerometer and gyroscope data only, while the right column (<b>b</b>,<b>d</b>,<b>f</b>,<b>h</b>) shows results when pressure sensor data were additionally incorporated.</p>
Full article ">Figure 11
<p>A screenshot captures the readings from the accelerometer (in g), gyroscope (in deg/s), and pressure sensor (in kpa), along with the classifier output in real-time testing, while the player was transitioning from a seated position (36–40.7 s) to standing (41–43.7 s).</p>
Full article ">Figure 12
<p>A screenshot captures the readings from the accelerometer (in g), gyroscope (in deg/s), and pressure sensor (in kpa), along with the classifier output in real-time testing, while the player was hit without falling near the 76 s timestamp.</p>
Full article ">Figure 13
<p>A screenshot demonstrates the classifier’s response to a non-fall and fall events in real-time testing. The player was struck without falling at 76 s, as seen in <a href="#jsan-13-00077-f012" class="html-fig">Figure 12</a>. However, between 79.6 s and 82.1 s, the player was hit and fell, triggering the classifier to detect the fall and change its output from 0 to 1.</p>
Full article ">Figure 14
<p>A screenshot demonstrates the classifier’s response to three non-fall events at (163 s, 167 s, and 170 s) in real-time testing. Vertical arrangement of signals: accelerometer (g), gyroscope (deg/s), pressure (kPa), and real-time SVM classifier output.</p>
Full article ">Figure 15
<p>A screenshot demonstrates a fall detection between 178.6 s and 181.5 s. Also, a hit without falling event at 182.5 s in real-time testing is presented. Vertical arrangement of signals: accelerometer (g), gyroscope (deg/s), pressure (kPa), and real-time SVM classifier output.</p>
Full article ">
22 pages, 4437 KiB  
Article
Model-Assisted Probabilistic Neural Networks for Effective Turbofan Fault Diagnosis
by Christoforos Romesis, Nikolaos Aretakis and Konstantinos Mathioudakis
Aerospace 2024, 11(11), 913; https://doi.org/10.3390/aerospace11110913 - 6 Nov 2024
Viewed by 521
Abstract
A diagnostic method for gas-path faults of turbofan engines, relying on a Probabilistic Neural Network (PNN) coupled with a thermodynamic model of the engine, is presented. The novel aspect of the method is that its training information is generated dynamically by an accompanying [...] Read more.
A diagnostic method for gas-path faults of turbofan engines, relying on a Probabilistic Neural Network (PNN) coupled with a thermodynamic model of the engine, is presented. The novel aspect of the method is that its training information is generated dynamically by an accompanying Engine Performance Model. In the proposed approach, the PNN efficiently addresses the first step of a diagnostic process (i.e., detection of the faulty component at the current operating point), while with the aid of an adaptive engine model, the fault is then further isolated and identified. A description of the proposed method and training aspects of the PNN are presented. The method is applied to the case of a mixed-flow turbofan engine to diagnose common gas-path faults in compressors and turbines (i.e., fouling, FOD, erosion, and tip clearance). Its performance is evaluated using realistic fault data that may be acquired at various operating conditions within a flight envelope. Full article
(This article belongs to the Special Issue Machine Learning for Aeronautics (2nd Edition))
Show Figures

Figure 1

Figure 1
<p>Mapping the faults considered on the diagnostic plane and their association to ratios of health parameters deviations (Δ<math display="inline"><semantics> <mrow> <msub> <mrow> <mi>SW</mi> </mrow> <mrow> <mi mathvariant="normal">c</mi> </mrow> </msub> </mrow> </semantics></math>/Δ<math display="inline"><semantics> <mrow> <msub> <mrow> <mi mathvariant="normal">S</mi> <mi mathvariant="normal">E</mi> </mrow> <mrow> <mi mathvariant="normal">c</mi> </mrow> </msub> </mrow> </semantics></math>) of the affected component: (<b>a</b>) compressor, (<b>b</b>) turbine.</p>
Full article ">Figure 2
<p>Overview of the proposed diagnostic method scheme.</p>
Full article ">Figure 3
<p>Cross-plot of a component’s deviations of health parameters, introducing the formation of the knowledge base of the diagnostic method.</p>
Full article ">Figure 4
<p>The layout of the engine, showing measurements and parameters involved.</p>
Full article ">Figure 5
<p>Cross-plot training vs test patterns of faults in (<b>a</b>) compressors and (<b>b</b>) turbines.</p>
Full article ">Figure 5 Cont.
<p>Cross-plot training vs test patterns of faults in (<b>a</b>) compressors and (<b>b</b>) turbines.</p>
Full article ">Figure 6
<p>Success rates of the diagnostic method, under all considered operating points, at HEALTHY test cases.</p>
Full article ">Figure 7
<p>Success rates of the diagnostic method under all considered operating points for FAN and HPC test cases.</p>
Full article ">Figure 7 Cont.
<p>Success rates of the diagnostic method under all considered operating points for FAN and HPC test cases.</p>
Full article ">Figure 8
<p>Success rates of the diagnostic method, under all considered operating points, at HPT and LPT test cases.</p>
Full article ">Figure 9
<p>The confusion matrix of the diagnostic method on the test patterns at OP with ID 16.</p>
Full article ">
16 pages, 3034 KiB  
Article
An Amperometric Sensor with Anti-Fouling Properties for Indicating Xylazine Adulterant in Beverages
by Arielle Vinnikov, Charles W. Sheppard, Ann H. Wemple, Joyce E. Stern and Michael C. Leopold
Micromachines 2024, 15(11), 1340; https://doi.org/10.3390/mi15111340 - 31 Oct 2024
Viewed by 584
Abstract
Amperometric electrochemical sensing schemes, which are easily fabricated and can directly relate measured current with analyte concentrations, remain a promising strategy for the development of the portable, in situ detection of commonly employed adulterants. Xylazine (XYL) is a non-narcotic compound designed for veterinary [...] Read more.
Amperometric electrochemical sensing schemes, which are easily fabricated and can directly relate measured current with analyte concentrations, remain a promising strategy for the development of the portable, in situ detection of commonly employed adulterants. Xylazine (XYL) is a non-narcotic compound designed for veterinary use as a sedative known as Rompun®. XYL is increasingly being abused as a recreational drug, as an opioid adulterant and, because of its chemical properties, has found unfortunate prominence as a date rape drug spiked into beverages. In this study, a systematic exploration and development of fouling-resistant, amperometric XYL sensors is presented. The sensing strategy features layer-by-layer (LBL) modification of glassy carbon electrodes (GCEs) with carbon nanotubes (CNTs) for sensitivity and the engagement of cyclodextrin host–guest chemistry in conjunction with polyurethane (PU) semi-permeable membranes for selectivity. The optimization of different materials and parameters during development created a greater fundamental understanding of the interfacial electrochemistry, allowing for a more informed subsequent design of effective sensors exhibiting XYL selectivity, effective sensitivity, rapid response times (<20 s), and low estimated limits of detection (~1 ppm). Most importantly, the demonstrated XYL sensors are versatile and robust, easily fabricated from common materials, and can effectively detect XYL at <10 ppm in both common alcoholic and non-alcoholic beverages, requiring only minimal volume (20 µL) of the spiked beverage for a standard addition analysis. Full article
(This article belongs to the Special Issue Electrochemical Sensors: Design, Fabrication and Applications)
Show Figures

Figure 1

Figure 1
<p>(<b>A</b>) Representative I-t curves during successive 50 µL injections of 50 mM XYL standard (<b>↓</b>) with the step current tracked over time (inset) with each 100 µM XYL increase and showing exponential decay of current signal. (<b>B</b>) Typical cyclic voltammetry of 5 mM potassium ferricyanide (1 M KCl) or 1 mM hexamine ruthenium (III) chloride (150 mM PBS) (inset) at (a) bare GCEs and (b) GCE after exposure to XYL under potential control (+1.1 V during 50 µL injections (5) of 50 mM XYL). Note: scan rate = 100 mV/s. Note: Different color scans represent replicate electrodes.</p>
Full article ">Figure 2
<p>(<b>A</b>) Representative amperometric I-t curves during successive 50 µL XYL injections of a 50 mM XYL standard (100 µM increases) at GCE/MWCNTs/β-CD/Nafion featuring (a) COOH-MWCNTs vs. (b) MWCNTs and corresponding examples of step-current responses (inset). (<b>B</b>) I-t curves for (a) GCE/COOH-MWCNTs/β-CD/Nafion vs. (b) the same system without β-CD incorporated (expansion shows very small and diminishing stepping responses without β-CD). (<b>C</b>) I-t curves for fully-modified electrode (GCE/COOH-MWCNT/β-CD/PU (75:25) during (50 µL) injections of 50 mM XYL standard (100 µM increases) at different applied holding potentials: (a) +0.9 V, (b) +1.0 V, (c) +1.1 V, and (d) +1.2 V.</p>
Full article ">Figure 3
<p>(<b>A</b>) Representative amperometric I-t curves during successive varying volume (0.5 to 100 µL) XYL injections of a 50 mM XYL standard for a concentration range of 1 to 605 µM XYL at (a) a GCE/MWCNTs/β-CD/HPU modified electrode versus (b) an unmodified GCE electrode. (<b>B</b>) I-t curve during similar injections at a modified electrode system without the HPU capping layer.</p>
Full article ">Figure 4
<p>(<b>A</b>) Example of an amperometric I-t curve during successive varying volume (0.5 to 20 µL) XYL injections of a 50 mM XYL standard for a concentration range of 1 to 1015 µM showing stair-step responses at a modified electrode (GCE/COOH-MWCNT/β-CD/HPU), and (<b>B</b>) a calibration curve (1 to 450 µM) generated from amperometric responses from multiple (n = 16) modified electrodes. Note: a calibration curve spanning the larger concentration range is provided in <a href="#app1-micromachines-15-01340" class="html-app">Supporting Information</a>; in both cases, the standard error estimate may be smaller than the average marker.</p>
Full article ">Figure 5
<p>(<b>A</b>) Amperometric I-t curves during XYL injections (50 µL injections of 50 mM XYL standard) and potential interferent species in soda including injections resulting in 0.49 mM caffeine, 8.98 mM citric acid, 257 mM glucose, and 139 mM sucrose at (a) bare and (b) modified GCEs. (<b>B</b>) Corresponding graph of calculated selectivity coefficients for the potential interferent species at the modified GCE.</p>
Full article ">Figure 6
<p>Example amperometric I-t curves using (<b>A</b>) calibration curve (successive 10 µL injections of 50 mM XYL standard over a concentration range of 20 to 160 µM) followed by a XYL spike, and (<b>B</b>) standard addition methodology, with typical standard addition plot (inset) used to quantify XYL in spiked 150 mM PBS solutions at the fully modified electrode systems (GCE/COOH-MWCNT/β-CD/HPU). (<b>C</b>) Bar graph comparison of calculated percent recovery values at different applied potentials using the calibration curve and standard addition method targeting XYL spike concentrations of 260 and 40 µM, respectively (n = 4–6).</p>
Full article ">Scheme 1
<p>Step-wise schematic representation of the fabrication and operation (inset) of the modified GCE XYL sensor.</p>
Full article ">
15 pages, 3101 KiB  
Article
Fouling-Resistant Voltammetric Xylazine Sensors for Detection of the Street Drug “Tranq”
by Joyce E. Stern, Ann H. Wemple, Charles W. Sheppard, Arielle Vinnikov and Michael C. Leopold
Toxics 2024, 12(11), 791; https://doi.org/10.3390/toxics12110791 - 30 Oct 2024
Viewed by 506
Abstract
As the opioid crisis continues to wreak havoc on a global scale, it is increasingly critical to develop methodologies to detect the most dangerous drugs such as fentanyl and its derivatives, which have orders of magnitude higher potency than morphine. The scientific challenge [...] Read more.
As the opioid crisis continues to wreak havoc on a global scale, it is increasingly critical to develop methodologies to detect the most dangerous drugs such as fentanyl and its derivatives, which have orders of magnitude higher potency than morphine. The scientific challenge for chemical detection of fentanyl and its derivatives is complicated by both the constantly increasing synthetic variations of the drug as well as the expanded use of adulterants. One tragically consequential example is the nocuous street drug known as “Tranq”, which combines fentanyl or a fentanyl derivative with the veterinary sedative Rompun®, chemically identified as xylazine (XYL). This pervasive street cocktail is exacerbating the already staggering number of fentanyl-related deaths as its acute toxicity poses a danger to medical first-responders and complicates their initial assessment and treatment options for overdose victims. Given the widespread use of XYL as an adulterant, an electrochemical XYL sensor capable of on-site operation by non-experts as a fast-screening tool is a notable goal. This work presents a voltammetry-based sensor featuring carbon electrodes modified with carboxylic-acid functionalized multi-walled carbon nanotubes layered with cyclodextrin and polyurethane membranes for sensitivity and selectivity enhancements. The sensor has critical and robust fouling resistance while providing sensitivity at 950 μA/mM∙cm2, a low limit of detection (~5 ppm), and the ability to detect XYL in the presence of fentanyl and/or other non-fentanyl stimulants like cocaine. The demonstrated sensor can be applied to promote public health with its ability to detect and indicate XYL in the presence of opioids, serving to protect drug-users, first responders, medical examiners, and on-site forensic investigators from exposure to these dangerous mixtures. Full article
(This article belongs to the Special Issue The Identification of Narcotic and Psychotropic Drugs)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>The core structure of (<b>a</b>) fentanyl where structural changes at R<sub>1</sub>, R<sub>2</sub>, and R<sub>3</sub> create synthetic fentanyl analogs; (<b>b</b>) the structure of xylazine (XYL); and (<b>c</b>) the skin necrosis that can occur when misusing the street drug “Tranq,” fentanyl adulterated with XYL (from Ref. [<a href="#B19-toxics-12-00791" class="html-bibr">19</a>]).</p>
Full article ">Figure 2
<p>(<b>A</b>) Cyclic voltammetry (CV) of 1 mM XYL (<span class="html-italic">solid trace</span>) and corresponding background (<span class="html-italic">dashed trace</span>) of PBS without XYL (150 mM at pH = 7; 100 mV/s); (<b>B</b>) first three consecutive DPV oxidation scans of bare GCE in 1 mM XYL in PBS (150 mM PBS at pH = 7); Inset: CV of 5 mM potassium ferricyanide in 0.5 KCl at unmodified GCE (a) before and (b) after XYL exposure under applied oxidative potentials (100 mV/s).</p>
Full article ">Figure 3
<p>(<b>A</b>) CV of 2.5 mM XYL in PBS (150 mM; pH = 7) collected at various scan rates (inset) at the modified electrode system showing three major peaks including the primary XYL oxidation peak at +0.9 V, subsequent reduction of that product (+0.25V), and a second oxidation peak (+0.35) attributed to the MWCNTs; (<b>B</b>) DPV oxidative scans at GCEs modified with PU only (<span class="html-italic">top scans</span>) and fully modified GCEs (<span class="html-italic">bottom scans</span>) in PBS without XYL (a,c) vs. in 1 mM XYL solutions (b,d).</p>
Full article ">Figure 4
<p>(<b>A</b>) Consecutive DPV scans of XYL (1 mM) oxidation versus background scan (<span class="html-italic">dashed</span>) in PBS (150 mM; pH = 7) at a bare GCE (<span class="html-italic">top scans</span>) showing significant decrease in peak current (<span class="html-italic">black</span>) and shift in peak potential (<span class="html-italic">red</span>) vs. successive scans at a modified GCE (<span class="html-italic">bottom scans</span>) and comparison of each system’s peak current changes with repeated scans (inset); (<b>B</b>) DPV of bare GCE (<span class="html-italic">top, red</span>) versus modified GCE (<span class="html-italic">bottom, blue</span>) after exposure to increasing XYL concentrations (255 μM) and comparisons of peak current (I<sub>p,a</sub>) and peak potential (E<sub>p,a</sub>) after XYL exposure (insets). Note: In some cases, error bars are smaller than markers denoting average.</p>
Full article ">Figure 5
<p>(<b>A</b>) Typical DPV scans collected with a modified GCE in increasing concentrations of XYL standard (50 mM) versus PBS background (<span class="html-italic">dashed</span>); (<b>B</b>) Representative standard calibration curve plotting background-corrected signal vs. XYL concentration. Note: For clarity, not all DPV scans at every XYL concentration are displayed in (<b>A</b>). Additional XYL calibration curve results are in the <a href="#app1-toxics-12-00791" class="html-app">Supplemental Data</a>.</p>
Full article ">Figure 6
<p>DPV scans of (<b>A</b>) bare and (<b>B</b>) fully modified GCEs in (a) 150 mM buffer (<span class="html-italic">dashed trace</span>), (b) 125 µM fentanyl, (c) a mixture of 125 µM fentanyl with 125 µM XYL and (d) that same mixture spiked with an additional 125 µM XYL spike or 250 μM XYL total concentration (<span class="html-italic">dashed-dot trace</span>).</p>
Full article ">Figure 7
<p>DPV scans of (<b>A</b>) bare and (<b>B</b>) fully modified GCEs in (a) 150 mM buffer (<span class="html-italic">dashed trace</span>), (b) 165 µM cocaine, (c) a mixture of 165 µM cocaine with 165 µM XYL and (d) that same mixture spiked with an additional 165 µM XYL spike or 330 μM XYL total concentration (<span class="html-italic">dashed-dot trace</span>).</p>
Full article ">Scheme 1
<p>Depiction of layer-by-layer modification of GCE for XLY detection using COOH-MWCNT for sensitivity as well as β-CD molecules for host-guest chemistry and a polyurethane (PU) layer for selectivity.</p>
Full article ">
20 pages, 36201 KiB  
Article
CPDet: Circle-Permutation-Aware Object Detection for Heat Exchanger Cleaning
by Jinshuo Liang, Yiqiang Wu, Yu Qin, Haoyu Wang, Xiaomao Li, Yan Peng and Xie Xie
Appl. Sci. 2024, 14(19), 9115; https://doi.org/10.3390/app14199115 - 9 Oct 2024
Viewed by 587
Abstract
Shell–tube heat exchangers are commonly used equipment in large-scale industrial systems of wastewater heat exchange to reclaim the thermal energy generated during industrial processes. However, the internal surfaces of the heat exchanger tubes often accumulate fouling, which subsequently reduces their heat transfer efficiency. [...] Read more.
Shell–tube heat exchangers are commonly used equipment in large-scale industrial systems of wastewater heat exchange to reclaim the thermal energy generated during industrial processes. However, the internal surfaces of the heat exchanger tubes often accumulate fouling, which subsequently reduces their heat transfer efficiency. Therefore, regular cleaning is essential. We aim to detect circle holes on the end surface of the heat exchange tubes to further achieve automated positioning and cleaning tubes. Notably, these holes exhibit a regular distribution. To this end, we propose a circle-permutation-aware object detector for heat exchanger cleaning to sufficiently exploit prior information of the original inputs. Specifically, the interval prior to the extraction module extracts interval information among circle holes based on prior statistics, yielding prior interval context. The following interval prior fusion module slices original images into circle domain and background domain maps according to the prior interval context. For the circle domain map, prior-guided sparse attention using prior a circle–hole diameter as the step divides the circle domain map into patches and performs patch-wise self-attention. The background domain map is multiplied by a hyperparameter weak coefficient matrix. In this way, our method fully leverages prior information to selectively weigh the original inputs to achieve more effective hole detection. In addition, to adapt the hole shape, we adopt the circle representation instead of the rectangle one. Extensive experiments demonstrate that our method achieves state-of-the-art performance and significantly boosts the YOLOv8 baseline by 5.24% mAP50 and 5.25% mAP50:95. Full article
Show Figures

Figure 1

Figure 1
<p>The arrangement of circle holes is regular, using annotation files to extract the interval information of the dataset and apply the interval information to process the original image to obtain features containing a large amount of foreground information.</p>
Full article ">Figure 2
<p>Overall network architecture. This process starts by identifying intervals between circles with the IPE module, combining these data with feature extraction using the IPF module to differentiate circular and background features. The PSA module adjusts the importance of circular features based on diameter and selects key–query–value pairs for attention. A weak coefficient matrix is used to downplay background features. The features are then refined with padding and 1 × 1 convolution before producing the final detection result.</p>
Full article ">Figure 3
<p>Heat exchanger dataset.</p>
Full article ">Figure 4
<p>Evaluating whether circles align in the same row or column.</p>
Full article ">Figure 5
<p>The circle domain and background domain obtained after interval prior fusing from different input images.</p>
Full article ">Figure 6
<p>Details of the interval prior fusion module.</p>
Full article ">Figure 7
<p>Details of the prior-guided sparse attention module.</p>
Full article ">Figure 8
<p>The circle representation provides a more intuitive localization for the circle holes compared to the square representation. Additionally, the circular representation fits the circle holes more closely, leading to more accurate area calculations. Therefore, using the circular area to control the water output of the cleaning machine is more precise.</p>
Full article ">Figure 9
<p>The circle domain and background domain under varying trimming rates.</p>
Full article ">Figure 10
<p>The actual comparative gains of our method compared with the baseline method, where the red box indicates successful reduction of the False Positive results, and the blue box indicates successful reduction of the False Negative results; moreover, the gray box indicates a failed reduction of the False Negative results.</p>
Full article ">Figure 11
<p>The comparative detection results of different detection models on the heat exchanger dataset: the blue boxes highlight the parts that were incorrectly detected, and the red boxes indicate the sections that were missed during detection.</p>
Full article ">
35 pages, 17147 KiB  
Article
Utilizing Wastewater Tunnels as Thermal Reservoirs for Heat Pumps in Smart Cities
by Fredrik Skaug Fadnes and Mohsen Assadi
Energies 2024, 17(19), 4832; https://doi.org/10.3390/en17194832 - 26 Sep 2024
Viewed by 559
Abstract
The performance of heat pump systems for heating and cooling heavily relies on the thermal conditions of their reservoirs. This study introduces a novel thermal reservoir, detailing a 2017 project where the Municipality of Stavanger installed a heat exchanger system on the wall [...] Read more.
The performance of heat pump systems for heating and cooling heavily relies on the thermal conditions of their reservoirs. This study introduces a novel thermal reservoir, detailing a 2017 project where the Municipality of Stavanger installed a heat exchanger system on the wall of a main wastewater tunnel beneath the city center. It provides a comprehensive account of the system’s design, installation, and performance, and presents an Artificial Neural Network (ANN) model that predicts heat pump capacity, electricity consumption, and outlet temperature across seasonal variations in wastewater temperatures. By integrating domain knowledge with the ANN, this study demonstrates the model’s capability to detect anomalies in heat pump operations effectively. The network also confirms the consistent performance of the heat exchangers from 2020 to 2024, indicating minimal fouling impacts. This study establishes wastewater heat exchangers as a safe, effective, and virtually maintenance-free solution for heat extraction and rejection. Full article
Show Figures

Figure 1

Figure 1
<p>Key figures for the 114 systems installed by UHRIG from 2007 to 2023.</p>
Full article ">Figure 2
<p>Daily averages of flow, rainfall, and water height in the tunnel (2015). Based on data provided by the municipality of Stavanger.</p>
Full article ">Figure 3
<p>(<b>Top left</b>) design sketch of the heat exchanger system showing a cross-sectional view. (<b>Top center</b> and <b>right</b>) photographs taken during the system installation. (<b>Bottom</b>) overhead design sketch of the system layout above the tunnel floor. Photos by Uhrig/Municipality of Stavanger.</p>
Full article ">Figure 4
<p>Thermal energy plant and surrounding buildings in relation to the wastewater tunnel.</p>
Full article ">Figure 5
<p>Schematic of the energy plant system with relevant sensors and meters.</p>
Full article ">Figure 6
<p>Model configuration of wastewater heat pump ANN.</p>
Full article ">Figure 7
<p>Examples of data smoothing using the Savitzky-Golay filter for Heat Production (<b>top</b>), Electricity Consumption (<b>middle</b>) and Wastewater Temperature (<b>bottom</b>).</p>
Full article ">Figure 8
<p>Duration curve heat production 2022.</p>
Full article ">Figure 9
<p>Duration curve heat production 2023.</p>
Full article ">Figure 10
<p>Input values used during visual validation.</p>
Full article ">Figure 11
<p>Results from visual validation, heat production both heat pumps.</p>
Full article ">Figure 12
<p>Results from visual validation, outlet temperature from IK001.</p>
Full article ">Figure 13
<p>Input data for the ANN applied on 2024 test data.</p>
Full article ">Figure 14
<p>Predicted vs. actual heat production for 2024 test data.</p>
Full article ">Figure 15
<p>Predicted vs. actual electricity consumption for 2024 test data.</p>
Full article ">Figure 16
<p>Predicted vs. actual outlet temperature for 2024 test data.</p>
Full article ">Figure 17
<p>Correlation Matrices for IK001 (<b>top</b>) and IK002 (<b>bottom</b>).</p>
Full article ">Figure 18
<p>Comprehensive visualization of heat pump performance metrics for IK001, based on 21,800 rows of data. (<b>Top Left</b>) heat production vs. electricity consumption, depicted with a color index representing SEI. (<b>Top Right</b>) COP vs. electrical load factor, with SEI as the color index. (<b>Middle Left</b>) SEI plotted against COP, with heat production serving as the color index. (<b>Middle Right</b>) COP in relation to wastewater temperature, colored by heat production. (<b>Bottom Left</b>) heat production vs. temperature lift with SEI as the color index. (<b>Bottom Right</b>) heat production vs. temperature lift with COP as the color index.</p>
Full article ">Figure 19
<p>Comprehensive visualization of heat pump performance metrics for IK002, based on 6566 rows of data. Visualizations: same as <a href="#energies-17-04832-f018" class="html-fig">Figure 18</a>, with datasets corresponding to IK002.</p>
Full article ">Figure 20
<p>Historical data for the wastewater temperature for the years 2021, 2022, and 2024. Comparison of wastewater temperature and ambient temperature—2021–2023.</p>
Full article ">Figure 21
<p>Sorted duration curve for ambient temperature with corresponding wastewater temperatures for the years 2021, 2022, and 2023.</p>
Full article ">Figure 22
<p>Evaluation of heat pump operation during test interval 2024.</p>
Full article ">Figure 23
<p>A sign mounted on the door entry to the wastewater tunnel by Uhrig, reading “Careful! Heat Exchangers” in Danish.</p>
Full article ">
17 pages, 2852 KiB  
Article
Flourishing in Darkness: Protist Communities of Water Sites in Shulgan-Tash Cave (Southern Urals, Russia)
by Natalia E. Gogoleva, Marina A. Nasyrova, Alexander S. Balkin, Olga Ya. Chervyatsova, Lyudmila Yu. Kuzmina, Elena I. Shagimardanova, Yuri V. Gogolev and Andrey O. Plotnikov
Diversity 2024, 16(9), 526; https://doi.org/10.3390/d16090526 - 1 Sep 2024
Viewed by 1028
Abstract
Karst caves, formed by the erosion of soluble carbonate rocks, provide unique ecosystems characterized by stable temperatures and high humidity. These conditions support diverse microbial communities, including wall microbial fouling, aquatic biofilms, and planktonic communities. This study discloses the taxonomic diversity of protists [...] Read more.
Karst caves, formed by the erosion of soluble carbonate rocks, provide unique ecosystems characterized by stable temperatures and high humidity. These conditions support diverse microbial communities, including wall microbial fouling, aquatic biofilms, and planktonic communities. This study discloses the taxonomic diversity of protists in aquatic biotopes of Shulgan-Tash Cave, a culturally significant site and popular tourist destination, by 18S rRNA gene metabarcoding. Our findings reveal the rich protist communities in the cave’s aquatic biotopes, with the highest diversity observed in Blue Lake at the cave entrance. In contrast, Distant Lake in the depth of the cave was inhabited by specific communities of plankton, mats, and pool fingers, which exhibited lower richness and evenness, and were adapted to extreme conditions (cold, darkness, and limited nutrients). High-rank taxa including Opisthokonta, Stramenopiles, and Rhizaria dominated all biotopes, aligning with observations from other subterranean environments. Specific communities of biotopes inside the cave featured distinct dominant taxa: amoeboid stramenopile (Synchromophyceae) and flagellates (Choanoflagellatea and Sandona) in mats; flagellates (Choanoflagellatea, Bicoecaceae, Ancyromonadida) and amoeboid protists (Filasterea) in pool fingers; flagellates (Ochromonadales, Glissomonadida, Synchromophyceae), fungi-like protists (Peronosporomycetes), and fungi (Ustilaginomycotina) in plankton. The specificity of the communities was supported by LEfSe analysis, which revealed enriched or differentially abundant protist taxa in each type of biotope. The predominance of Choanoflagellatea in the communities of cave mats and pool fingers, as well as the predominance of Synchromophyceae in the cave mats, appears to be a unique feature of Shulgan-Tash Cave. The cold-tolerant yeast Malassezia recorded in other caves was present in both plankton and biofilm communities, suggesting its resilience to low temperatures. However, no potentially harmful fungi were detected, positioning this research as a baseline for future monitoring. Our results emphasize the need for ongoing surveillance and conservation efforts to protect the fragile ecosystems of Shulgan-Tash Cave from human-induced disturbances and microbial invasions. Full article
(This article belongs to the Special Issue Diversity in 2024)
Show Figures

Figure 1

Figure 1
<p>Map of the research area and Shulgan-Tash Cave sampling sites: (<b>A</b>) Overview map showing the global position of the research area. (<b>B</b>) The position of the cave in relation to the Southern Urals. (<b>C</b>) Digital model of the cave combined with the relief of the Tirmentau massif. Visualization was created using Cloud Compare 2020 software with laser scanning point clouds [<a href="#B32-diversity-16-00526" class="html-bibr">32</a>]. The cavities of the phreatic zone are shown schematically (by Snetkov E., unpublished data). (<b>D</b>) Sampling scheme of Distant Lake and its watercourses. PF—pool finger biofilm; CEW—lake water at the point of inflow into Distant Lake; WPF—water surrounding pool fingers; WDL—water in the middle of Distant Lake; MDL—mats of Distant Lake; BL—water from Blue Lake.</p>
Full article ">Figure 2
<p>Distant Lake sampling sites: (<b>a</b>) Distant Lake; (<b>b</b>) the outflowing creek with filamentous microbial mats; (<b>c</b>) microbial mats; (<b>d</b>) pool fingers.</p>
Full article ">Figure 3
<p>Alpha diversity indices of the protist communities in the sites of Shulgan-Tash Cave and the outer Blue Lake: Chao 1, Shannon, Gini-Simpson, and Pielou’s evenness. The points on the plot correspond to the individual samples and are colored according to the different sites: PF—pool finger biofilm; CEW—lake water at the point of inflow into Distant Lake; WPF—water surrounding pool fingers; WDL—water in the middle of Distant Lake; MDL—mats of Distant Lake; BL—water from Blue Lake.</p>
Full article ">Figure 4
<p>2D plots based on the results of principal coordinate analysis (PCoA) of the protist communities using Bray–Curtis (left) and the weighted UniFrac (right) distances. PCo1 (Axis 1) and PCo2 (Axis 2) explained 33.65% and 25.8% of the protist community variance at the ASV level, respectively. PF—pool finger biofilms; CEW—lake water at the point of inflow into Distant Lake; WPF—water surrounding pool fingers; WDL—water in the middle of Distant Lake; MDL—mats of Distant Lake; BL—water from Blue Lake.</p>
Full article ">Figure 5
<p>The most abundant protist taxa in the communities of water sites in Shulgan-Tash Cave. Circle size indicates the inferred relative abundance based on amplicon numbers (in %). PF—pool finger biofilm; CEW—lake water at the point of inflow into Distant Lake; WPF—water surrounding pool fingers; WDL—water in the middle of Distant Lake; MDL—mats of Distant Lake; BL—water from Blue Lake.</p>
Full article ">Figure 6
<p>The relative abundances of the protist functional groups in communities of Blue Lake and Distant Lake (Shulgan-Tash Cave). The colors correspond to the supergroup names.</p>
Full article ">
11 pages, 2036 KiB  
Article
Application of Online Flow Cytometry for Early Biofouling Detection in Reverse Osmosis Membrane Systems
by Laura Pulido Beltran, Johannes S. Vrouwenvelder and Nadia Farhat
Membranes 2024, 14(9), 185; https://doi.org/10.3390/membranes14090185 - 27 Aug 2024
Viewed by 1095
Abstract
Biofouling poses a significant challenge to reverse osmosis (RO) membrane systems, necessitating timely detection for effective control. This study evaluated the efficacy of flow cytometry (FCM) for early biofilm detection in comparison to conventional system performance indicators. Feed channel pressure drop and total [...] Read more.
Biofouling poses a significant challenge to reverse osmosis (RO) membrane systems, necessitating timely detection for effective control. This study evaluated the efficacy of flow cytometry (FCM) for early biofilm detection in comparison to conventional system performance indicators. Feed channel pressure drop and total cell concentration in the Membrane Fouling Simulator (MFS) flowcell cross-flow outlet water were monitored over time as early biofouling indicators. The results demonstrated the potential of increased bacterial cell concentration in cross-flow outlet water as a reliable indicator of biofouling development on the membrane. Water outlet monitoring enabled faster biofouling detection compared to feed channel pressure drop. Membrane autopsy confirmed biofilm presence prior to the pressure drop increase, highlighting the advantage of early detection in implementing corrective measures. Timely intervention reduces operational costs and energy consumption in membrane-based processes. Full article
(This article belongs to the Section Membrane Applications for Water Treatment)
Show Figures

Figure 1

Figure 1
<p>Experimental setup showing the sampling point for the online flow cytometry measurements.</p>
Full article ">Figure 2
<p>Feed channel pressure drop (mbar) and total cell concentration (TCC) (cells/mL) over time in the MFS+S inlet and outlet.</p>
Full article ">Figure 3
<p>Biofilms: (<b>A</b>) total cell concentration (cells.cm<sup>−2</sup>) and (<b>B</b>) Adenosine Triphosphate (pg.cm<sup>−2</sup>) of the MFS+S membrane and control membrane obtained from the autopsy (after 3 days of substrate dosing).</p>
Full article ">Figure 4
<p>Feed channel pressure drop (mbar) and total cell concentration (cells.mL<sup>−1</sup>) over time in the MFS+S inlet and outlet water.</p>
Full article ">Figure 5
<p>Biofilms: (<b>A</b>) total cell concentration (cells.cm<sup>−2</sup>) and (<b>B</b>) Adenosine Triphosphate (pg.cm<sup>−2</sup>) of the MFS+S membrane and control membrane obtained from the autopsy (after 1 day of substrate dosing).</p>
Full article ">
20 pages, 4099 KiB  
Article
Treatment of Synthetic Wastewater Containing Polystyrene (PS) Nanoplastics by Membrane Bioreactor (MBR): Study of the Effects on Microbial Community and Membrane Fouling
by Anamary Pompa-Pernía, Serena Molina, Laura Cherta, Lorena Martínez-García and Junkal Landaburu-Aguirre
Membranes 2024, 14(8), 174; https://doi.org/10.3390/membranes14080174 - 9 Aug 2024
Viewed by 1194
Abstract
The persistent presence of micro- and nanoplastics (MNPs) in aquatic environments, particularly via effluents from wastewater treatment plants (WWTPs), poses significant ecological risks. This study investigated the removal efficiency of polystyrene nanoplastics (PS-NPs) using a lab-scale aerobic membrane bioreactor (aMBR) equipped with different [...] Read more.
The persistent presence of micro- and nanoplastics (MNPs) in aquatic environments, particularly via effluents from wastewater treatment plants (WWTPs), poses significant ecological risks. This study investigated the removal efficiency of polystyrene nanoplastics (PS-NPs) using a lab-scale aerobic membrane bioreactor (aMBR) equipped with different membrane types: microfiltration (MF), commercial ultrafiltration (c-UF), and recycled ultrafiltration (r-UF) membranes. Performance was assessed using synthetic urban wastewater spiked with PS-NPs, focusing on membrane efficiency, fouling behavior, and microbial community shifts. All aMBR systems achieved high organic matter removal, exceeding a 97% COD reduction in both the control and PS-exposed reactors. While low concentrations of PS-NPs did not significantly impact the sludge settleability or soluble microbial products initially, a higher accumulation increased the carbohydrate concentrations, indicating a protective bacterial response. The microbial community composition also adapted over time under polystyrene stress. All membrane types exhibited substantial NP removal; however, the presence of nano-sized PS particles negatively affected the membrane performance, enhancing the fouling phenomena and increasing transmembrane pressure. Despite this, the r-UF membrane demonstrated comparable efficiency to c-UF, suggesting its potential for sustainable applications. Advanced characterization techniques including pyrolysis gas chromatography/mass spectrometry (Py-GC/MS) were employed for NP detection and quantification. Full article
(This article belongs to the Special Issue Membrane Technologies for Water Purification)
Show Figures

Figure 1

Figure 1
<p>Representation of the experimental setup.</p>
Full article ">Figure 2
<p>Bacterial community composition at the phylum level (<b>a</b>) and genera level (<b>b</b>) in both reactors (i.e., MBR-Control and MBR-PS) sampled on the initial day (day 1st), on day 15, and day 39.</p>
Full article ">Figure 3
<p>Heat-map of the bacterial community composition at the phylum level with cluster analysis. The color intensity in each panel shows the percentage in a sample, referring to the color key at the left.</p>
Full article ">Figure 4
<p>Variation of the transmembrane pressure (TMP) over the experimental time of the (<b>a</b>) microfiltration membrane (the highlighted TMP values on the 32nd day relate to chemical cleaning of the membranes) and (<b>b</b>) ultrafiltration membranes (comparison between r-UF and c-UF).</p>
Full article ">Figure 5
<p>Resistances of the MF, commercial UF (c-UF), and recycled UF (r-UF) membranes in the control (MBR-Control) and the experimental (MBR-PS) reactors. <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>R</mi> </mrow> <mrow> <mi>t</mi> </mrow> </msub> </mrow> </semantics></math>: total resistance; <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>R</mi> </mrow> <mrow> <mi>f</mi> </mrow> </msub> </mrow> </semantics></math>: fouling resistance; <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>R</mi> </mrow> <mrow> <mi>m</mi> </mrow> </msub> </mrow> </semantics></math>: membrane resistance; <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>R</mi> </mrow> <mrow> <mi>c</mi> </mrow> </msub> </mrow> </semantics></math>: cake layer resistance; <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>R</mi> </mrow> <mrow> <mi>p</mi> <mi>b</mi> </mrow> </msub> </mrow> </semantics></math>: pore blocking resistance.</p>
Full article ">Figure 6
<p>(<b>A</b>) Membrane surface micrographs of the membranes at the end of the experiment after the physical clean: membranes from the MBR-Control (second row) and membranes from MBR-PS (third row). (<b>B</b>) 3D projection from confocal laser scanning microscopy of the MBR-PS membranes. Green dots in the 3D projection of the membranes represent the PS nanoparticles.</p>
Full article ">
17 pages, 3796 KiB  
Article
Evaluation of In Vitro Serotonin-Induced Electrochemical Fouling Performance of Boron Doped Diamond Microelectrode Using Fast-Scan Cyclic Voltammetry
by Mason L. Perillo, Bhavna Gupta, James R. Siegenthaler, Isabelle E. Christensen, Brandon Kepros, Abu Mitul, Ming Han, Robert Rechenberg, Michael F. Becker, Wen Li and Erin K. Purcell
Biosensors 2024, 14(7), 352; https://doi.org/10.3390/bios14070352 - 19 Jul 2024
Viewed by 1207
Abstract
Fast-scan cyclic voltammetry (FSCV) is an electrochemical sensing technique that can be used for neurochemical sensing with high spatiotemporal resolution. Carbon fiber microelectrodes (CFMEs) are traditionally used as FSCV sensors. However, CFMEs are prone to electrochemical fouling caused by oxidative byproducts of repeated [...] Read more.
Fast-scan cyclic voltammetry (FSCV) is an electrochemical sensing technique that can be used for neurochemical sensing with high spatiotemporal resolution. Carbon fiber microelectrodes (CFMEs) are traditionally used as FSCV sensors. However, CFMEs are prone to electrochemical fouling caused by oxidative byproducts of repeated serotonin (5-HT) exposure, which makes them less suitable as chronic 5-HT sensors. Our team is developing a boron-doped diamond microelectrode (BDDME) that has previously been shown to be relatively resistant to fouling caused by protein adsorption (biofouling). We sought to determine if this BDDME exhibits resistance to electrochemical fouling, which we explored on electrodes fabricated with either femtosecond laser cutting or physical cleaving. We recorded the oxidation current response after 25 repeated injections of 5-HT in a flow-injection cell and compared the current drop from the first with the last injection. The 5-HT responses were compared with dopamine (DA), a neurochemical that is known to produce minimal fouling oxidative byproducts and has a stable repeated response. Physical cleaving of the BDDME yielded a reduction in fouling due to 5-HT compared with the CFME and the femtosecond laser cut BDDME. However, the femtosecond laser cut BDDME exhibited a large increase in sensitivity over the cleaved BDDME. An extended stability analysis was conducted for all device types following 5-HT fouling tests. This analysis demonstrated an improvement in the long-term stability of boron-doped diamond over CFMEs, as well as a diminishing sensitivity of the laser-cut BDDME over time. This work reports the electrochemical fouling performance of the BDDME when it is repeatedly exposed to DA or 5-HT, which informs the development of a chronic, diamond-based electrochemical sensor for long-term neurotransmitter measurements in vivo. Full article
(This article belongs to the Special Issue Diamond Technology for Biosensing and Quantum Sensing)
Show Figures

Figure 1

Figure 1
<p>BDDME fabrication and representative devices. (<b>A</b>) Material and geometry pattern for silicon (Si) wafer-based chemical vapor deposition. Boron-doped diamond (BDD) is grown on a Si wafer, and then reactive ion etching (RIE) is used to pattern the BDD. The BDD probes are released from the Si wafer, and the insulating polycrystalline diamond (PCD) grows around the BDD shanks. (<b>B</b>) Representative CFME tip at 900× magnification. (<b>C</b>) Scanning electron microscope (SEM) image of the BDDME shank, integrated connection pad, and the sensing tip. (<b>D</b>) C-BDDME tip at 1500× magnification. (<b>E</b>) SEM image of the sensing tip of a C-BDDME. The conductive BDD core is exposed from the PCD during fabrication by cleaving the end of the shank with a knife or by laser-cutting the shank with a femtosecond laser. (<b>F</b>) FS-BDDME tip at 1500× magnification. The left column of this figure is adapted from [<a href="#B21-biosensors-14-00352" class="html-bibr">21</a>].</p>
Full article ">Figure 2
<p>Representative current versus time ((<b>I</b>) vs. t) traces and 3D color plots for the CMFE, CBDDME, and FS-BDDME with 5-HT. (<b>A</b>–<b>C</b>) show the I vs. t plot for a representative 1st and 25th 5-HT injection of 5-HT. (<b>D</b>–<b>F</b>) depict color plots for the 1st 5-HT response, and (<b>G</b>–<b>I</b>) show color plots for the 25th.</p>
Full article ">Figure 3
<p>Calibration curves. All plots include the linear regressions for the entire calibrated ranges and their corresponding line equations. (<b>A</b>) CFME calibration curve with a slope of 47.5 nAµM<sup>−1</sup> with a concentration range of 25–1000 nM 5-HT (<span class="html-italic">n</span> = 6). (<b>B</b>) C-BDDME calibration curve with a slope of 0.0914 nAµM<sup>−1</sup> with the concentration range of 1–100 µM 5-HT (<span class="html-italic">n</span> = 4–5). (<b>C</b>) FS-BDDME calibration curve with a slope of 0.0914 nAµM<sup>−1</sup> with the concentration range of 1–100 µM 5-HT (<span class="html-italic">n</span> = 4). (<b>D</b>) Calculations performed using the four calibrated data points with the highest linearity (CFME and FS-BDDME: 0.025–0.2 µM 5-HT, C-BDDME: 2–20 µM 5-HT).</p>
Full article ">Figure 4
<p>Electrochemical fouling results for 5 µM 5-HT and DA. Current is represented as a percentage of the oxidation peak of the first injection. (<b>A</b>,<b>D</b>,<b>G</b>) Representative (<span class="html-italic">n</span> = 1) changes in FSCV voltammograms from the 1st (black) to the 25th (pink) 5-HT bolus injection. (<b>B</b>,<b>E</b>,<b>H</b>) 25 consecutive oxidation peak currents from 5 µM DA (black) and 5 µM 5-HT (pink) (<span class="html-italic">n</span> = 6, 4, and 5 from top to bottom). The 5-HT fouling trajectories were significantly different between all three electrode types (<span class="html-italic">p</span> &lt; 0.001, linear mixed model ANOVA with a Bonferroni post hoc test, *). (<b>C</b>,<b>F</b>,<b>I</b>) Percent changes from the 1st to the 25th injection for DA (black) and 5-HT (pink). The change in 5-HT peak current from the 1st to 25th injection was also significant for each device type using two-tailed, paired <span class="html-italic">t</span>-tests (CFME, <span class="html-italic">p</span> &lt; 0.001, **), (C-BDDME, <span class="html-italic">p</span> &lt; 0.05, *), and (FS-BDDME, <span class="html-italic">p</span> &lt; 0.001, **). The CFME also showed a significant decrease in DA response, although it had the lowest percentage drop of 4.9 ± 1.5% (<span class="html-italic">t</span>-test, two-tailed, paired, <span class="html-italic">p</span> &lt; 0.05, *).</p>
Full article ">Figure 5
<p>Electrochemical fouling results for 50 µM DA and 5-HT. (<b>A</b>,<b>D</b>,<b>G</b>) Representative (<span class="html-italic">n</span> = 1) changes in FSCV voltammograms from the 1st (black) to the 25th (pink) 5-HT bolus injection. (<b>B</b>,<b>E</b>,<b>H</b>) 25 consecutive oxidation peak currents from 50 µM DA (black) and 50 µM 5-HT (pink) (<span class="html-italic">n</span> = 4, 4, and 2 from top to bottom). The 5-HT fouling trajectories were significantly different between all three electrode types (<span class="html-italic">p</span> &lt; 0.001, linear mixed model ANOVA with a Bonferroni post hoc test, *). (<b>C</b>,<b>F</b>,<b>I</b>) Percent changes from the 1st to the 25th injection for DA (black) and 5-HT (pink). The change in serotonin peak current from the 1st to 25th injection was also significant for each device type using two-tailed, paired <span class="html-italic">t</span>-tests (CFME, <span class="html-italic">p</span> &lt; 0.001, **), (C-BDDME, <span class="html-italic">p</span> &lt; 0.001, **), and (FS-BDDME, <span class="html-italic">p</span> &lt; 0.05, *).</p>
Full article ">Figure 6
<p>Electrochemical stability analysis with response repeatability and etching stability. Oxidation peak currents are normalized to the 0-min values. (<b>A</b>–<b>C</b>) show 5-HT response repeatability over a two-hour recording period with 5 µM 5-HT injections every 10 min. Both the CFME ((<b>A</b>), +0.35 ± 0.98%, <span class="html-italic">n</span> = 3) and the C-BDDME ((<b>B</b>), −3.69 ± 8.41%, <span class="html-italic">n</span> = 3) exhibited stable repeatability with no significant difference between the 0-min and 120-min data points (paired, two-tailed <span class="html-italic">t</span>-test <span class="html-italic">p</span> &gt; 0.05, ns). However, the FS-BDDME ((<b>C</b>), −20.63 ± 5.5%, <span class="html-italic">n</span> = 2) showed a near-significant reduction in current between the 0-min and 120-min 5-HT exposures (paired, two-tailed <span class="html-italic">t</span>-test <span class="html-italic">p</span> ≈ 0.06). (<b>D</b>–<b>F</b>) Changes in FSCV backgrounds in Tris Buffer before and after exposure to the DA waveform at 60 Hz for 24 h to simulate 6 days of constant recording. CFMEs (<b>D</b>) exhibit growth in the background, C-BDDMEs (<b>E</b>) have a very stable background with almost no change in size, and FS-BDDME (<b>F</b>) backgrounds are reduced.</p>
Full article ">
13 pages, 1783 KiB  
Article
Development and Succession of Non-Indigenous and Cryptogenic Species over Two Different Substrates in the Port of Alicante (Western Mediterranean)
by Alejandro Carmona-Rodríguez, Carlos Antón, Miguel-Ángel Climent, Pedro Garcés, Vicente Montiel, Elisa Arroyo-Martínez and Alfonso A. Ramos-Esplá
J. Mar. Sci. Eng. 2024, 12(7), 1188; https://doi.org/10.3390/jmse12071188 - 15 Jul 2024
Viewed by 1027
Abstract
Artificial structures act as points of entry for non-indigenous species (NIS) in port areas and may support higher abundance and richness of them. The studies about NIS are increasing, but studies focusing on the variations in temporal recruitment and ecological mechanisms are still [...] Read more.
Artificial structures act as points of entry for non-indigenous species (NIS) in port areas and may support higher abundance and richness of them. The studies about NIS are increasing, but studies focusing on the variations in temporal recruitment and ecological mechanisms are still scarce. Thus, the aim of this work was to determine the colonization and development of non-indigenous sessile fouling species over two types of substrates (electrolytic carbonated and steel) during 12 months of immersion in the Alicante harbor. The biofouling communities of both substrates were analyzed in terms of abundance and species richness by status (native, cryptogenic, and NIS), and NIS assemblages of both substrates were studied by means of multivariate analyses. In total, 53 different species were identified, 38 in steel (six NIS and six cryptogenic) and 50 in the carbonated substrate (six NIS and 10 cryptogenic). Most NIS were more abundant and diverse after 9 months of immersion and had a preference for carbonated substrates. Furthermore, most of them were positively correlated in both substrates (mainly in steel) and it is noted that the number of NIS in the port of Alicante is increasing as new records have been detected. Full article
(This article belongs to the Section Marine Ecology)
Show Figures

Figure 1

Figure 1
<p>Alicante’s harbor location and ninth dock position (white circle). Images adapted from Google Earth via QGIS 3.16.7.</p>
Full article ">Figure 2
<p>Bar graph for abundance (<b>a</b>) and species richness (<b>b</b>) of each status of introduction type among substrates and immersion time.</p>
Full article ">Figure 3
<p>A non-metric multidimensional scaling based on Bray–Curtis similarity of NIS biofouling assemblages for each immersion time and substrate type. The vectors represent the NIS with a correlation over 0.5.</p>
Full article ">
23 pages, 30532 KiB  
Article
Performance and Impact of Crosslinking Level of Hierarchical Anion-Exchange Membranes on Demineralization of a Complex Food Solution by Electrodialysis
by Elodie Khetsomphou, Francesco Deboli, Mateusz L. Donten and Laurent Bazinet
Membranes 2024, 14(7), 155; https://doi.org/10.3390/membranes14070155 - 12 Jul 2024
Viewed by 1156
Abstract
Promising results were recently reported for hierarchical ion-exchange membranes, fabricated by the UV crosslinking of a thin functional coating on a porous substrate, on model NaCl solution demineralization by electrodialysis (ED). Hierarchical anion-exchange membranes (hAEMs) have never been tested with complex solutions to [...] Read more.
Promising results were recently reported for hierarchical ion-exchange membranes, fabricated by the UV crosslinking of a thin functional coating on a porous substrate, on model NaCl solution demineralization by electrodialysis (ED). Hierarchical anion-exchange membranes (hAEMs) have never been tested with complex solutions to demonstrate their potential use in the biofood industry. The impact of three different crosslinking densities of the ion-exchange coating (EbN-1, EbN-2 and EbN-3) on the performances of whey demineralization by ED was investigated and compared with commercial AMX. The results showed that by increasing the coating crosslinking density, the membrane conductivity decreased, leading to an increase in the global system resistance during whey demineralization (from +28% to +64%). However, 18% sweet whey solutions were successfully treated until 70% demineralization for all membranes. The energy consumption (averaged EbN value of 14.8 vs. 15.1 Wh for AMX) and current efficiency (26.0 vs. 27.4%) were similar to the control. Potential fouling by non-protein nitrogen was detected by ATR-FTIR for hAEMs impacting some membranes properties and ED performances. Overall, EbN-1 obtained results were comparable with the benchmark and can be considered as an alternative membrane for whey demineralization by ED and other applications in the demineralization of complex products from the food industry. Full article
(This article belongs to the Section Membrane Analysis and Characterization)
Show Figures

Figure 1

Figure 1
<p>Fabrication process of the hierarchical anion-exchange membranes.</p>
Full article ">Figure 2
<p>Electrodialysis cell configuration employed for whey demineralization. A<sup>−</sup>: anion; C<sup>+</sup>: cation; CEM: cation-exchange membrane and AEM: anion-exchange membrane.</p>
Full article ">Figure 3
<p>Cross-section micrographs for (<b>a</b>) EbN-1, (<b>b</b>) EbN-2 and (<b>c</b>) EbN-3.</p>
Full article ">Figure 4
<p>Whey demineralization evolution during ED with AMX or hAEMs.</p>
Full article ">Figure 5
<p>Ion concentration evolution in the KCl solution (concentrate) during ED according to the demineralization rate: (<b>a</b>) calcium; (<b>b</b>) potassium; (<b>c</b>) magnesium; (<b>d</b>) sodium; (<b>e</b>) phosphorous and (<b>f</b>) chloride.</p>
Full article ">Figure 6
<p>Evolution of pH in whey and KCl compartments during ED according to the demineralization with hAEMs or AMX.</p>
Full article ">Figure 7
<p>Global system resistance evolution during ED with hAEMs or AMX.</p>
Full article ">Figure 8
<p>Thickness (<b>a</b>), conductivity (<b>b</b>), contact angle (<b>c</b>) and IEC (<b>d</b>) of hAEMs and AMX reported before and after three consecutive ED runs. * Values with different letters for the same membrane (A, B) before and after were significantly different at <span class="html-italic">p</span> &lt; 0.05 (<span class="html-italic">t</span>-test).</p>
Full article ">Figure 8 Cont.
<p>Thickness (<b>a</b>), conductivity (<b>b</b>), contact angle (<b>c</b>) and IEC (<b>d</b>) of hAEMs and AMX reported before and after three consecutive ED runs. * Values with different letters for the same membrane (A, B) before and after were significantly different at <span class="html-italic">p</span> &lt; 0.05 (<span class="html-italic">t</span>-test).</p>
Full article ">Figure 9
<p>SEM images of the surface in contact with the whey solution of hAEMs and AMX before and after three consecutive ED runs: (<b>a</b>) AMX before, (<b>b</b>) AMX after, (<b>c</b>) EbN-1 before, (<b>d</b>) EbN-1 after, (<b>e</b>) EbN-2 before, (<b>f</b>) EbN-2 after, (<b>g</b>) EbN-3 before and (<b>h</b>) EbN-3 after.</p>
Full article ">Figure 9 Cont.
<p>SEM images of the surface in contact with the whey solution of hAEMs and AMX before and after three consecutive ED runs: (<b>a</b>) AMX before, (<b>b</b>) AMX after, (<b>c</b>) EbN-1 before, (<b>d</b>) EbN-1 after, (<b>e</b>) EbN-2 before, (<b>f</b>) EbN-2 after, (<b>g</b>) EbN-3 before and (<b>h</b>) EbN-3 after.</p>
Full article ">Figure 10
<p>ATR-FTIR graphs of (<b>a</b>) AMX, (<b>b</b>) EbN-1, (<b>c</b>) EbN-2 and (<b>d</b>) EbN-3 before and after ED.</p>
Full article ">Figure 11
<p>Evaluation of electrodialysis treatment performances using a radar graph.</p>
Full article ">
19 pages, 8829 KiB  
Article
Detection and Analysis of Corrosion on Coated Metal Surfaces Using Enhanced YOLO v5 Algorithm for Anti-Corrosion Performance Evaluation
by Qifeng Yu, Yudong Han, Wuguang Lin and Xinjia Gao
J. Mar. Sci. Eng. 2024, 12(7), 1090; https://doi.org/10.3390/jmse12071090 - 27 Jun 2024
Cited by 4 | Viewed by 1156
Abstract
This study addresses the severe corrosion issues in the coastal regions of southern China by proposing an improved YOLO v5-GOLD-NWD model. Utilizing corrosion data from the National Center for Materials Corrosion and Protection Science of China, a dataset was constructed for metal-surface corrosion [...] Read more.
This study addresses the severe corrosion issues in the coastal regions of southern China by proposing an improved YOLO v5-GOLD-NWD model. Utilizing corrosion data from the National Center for Materials Corrosion and Protection Science of China, a dataset was constructed for metal-surface corrosion under different protective coatings. This dataset was used for model training, testing, and comparison. Model accuracy was validated using precision, recall, F1 score, and prediction probability. The results demonstrate that the proposed improved model exhibits better identification precision in metal corrosion detection, achieving 78%, a 4% improvement compared to traditional YOLO v5 models. Additionally, through identification and statistical analysis of corrosion image datasets from five types of coated metal specimens, it was found that powder epoxy coating, fluorocarbon coating, epoxy coating, and chlorinated rubber coating showed good corrosion resistance after 24 months of exposure. Conversely, Wuxi anti-fouling coating exhibited poor corrosion resistance. After 60 months of natural exposure, the powder epoxy coating specimens had the highest corrosion occurrence probability, followed by chlorinated rubber coating and epoxy coating, with fluorocarbon coating showing relatively lower probability. The fluorocarbon coating demonstrated relatively good corrosion resistance at both 24 and 60 months of exposure. The findings of this study provide a theoretical basis for enhancing the corrosion protection effectiveness of steel structures in coastal areas. Full article
Show Figures

Figure 1

Figure 1
<p>Research framework.</p>
Full article ">Figure 2
<p>Sample images in dataset.</p>
Full article ">Figure 3
<p>Data augmentation.</p>
Full article ">Figure 4
<p>Framework structure of traditional YOLO v5.</p>
Full article ">Figure 5
<p>Corrosion recognition results based on traditional neck structure (<b>left</b>) and modified neck structure (<b>right</b>).</p>
Full article ">Figure 6
<p>GOLD-YOLO Model Framework.</p>
Full article ">Figure 7
<p>Principle of loss function improvement: small object detection (<b>left</b>) and normal object detection (<b>right</b>).</p>
Full article ">Figure 8
<p>Comparison of precision among three algorithms.</p>
Full article ">Figure 9
<p>Confusion matrix results for the three models: (<b>a</b>) YOLO v5, (<b>b</b>) YOLO v5-NWD, and (<b>c</b>) YOLO v5-GOLD-NWD.</p>
Full article ">Figure 10
<p>Corrosion distribution of different coated specimens during experimental periods.</p>
Full article ">Figure 10 Cont.
<p>Corrosion distribution of different coated specimens during experimental periods.</p>
Full article ">
23 pages, 5442 KiB  
Article
Species Composition and Distribution of Hull-Fouling Macroinvertebrates Differ According to the Areas of Research Vessel Operation
by Hyung-Gon Lee, Ok-Hwan Yu, Sang-Lyeol Kim, Jung-Hoon Kang and Kyoung-Soon Shin
J. Mar. Sci. Eng. 2024, 12(4), 613; https://doi.org/10.3390/jmse12040613 - 1 Apr 2024
Viewed by 1313
Abstract
Global ecological concern regarding the transfer of fouling organisms to ship hulls is increasing. This study investigated the species composition, dominant species, distribution patterns, community structure, and life-cycle differences of hull-fouling macroinvertebrates on five research vessels (R/Vs: Isabu, Onnuri, Eardo, Jangmok 1, and [...] Read more.
Global ecological concern regarding the transfer of fouling organisms to ship hulls is increasing. This study investigated the species composition, dominant species, distribution patterns, community structure, and life-cycle differences of hull-fouling macroinvertebrates on five research vessels (R/Vs: Isabu, Onnuri, Eardo, Jangmok 1, and Jangmok 2) operated by the Korea Institute of Ocean Science and Technology (KIOST). Hull-fouling macroinvertebrates were collected three to five times on quadrats from the upper and middle sectors of the hull sides, bottom, and niche areas (the propellers, shafts, and thrusters). A total of 47 macroinvertebrate species were identified, represented by 8519 individuals (ind.)/m2 and a biomass of 1967 gWWt/m2 on the five vessels. The number of species, density, and biomass were greater on the coastal vessels Eardo, Jangmok 1, and Jangmok 2 than on the ocean-going vessels the Isabu and Onnuri. Among the coastal vessels, barnacles were the most abundant and had the greatest density, while mollusks had the highest biomass. Differences between hull sectors showed that the highest species abundance and density appeared on all hulls in ports and bays where the Jangmok 1 operated, while the highest species abundance, density, and biomass were identified in the niche areas of the Eardo, which operated farther from the coast. The hull-fouling macroinvertebrates that exceeded 1% of all organisms were the barnacles Amphibalanus amphitrite, Balanus trigonus, and Amphibalanus improvisus; the polychaete Hydroides ezoensis; the bivalves Magallana gigas and Mytilus galloprovincialis; and the amphipod Jassa slatteryi. The dominant species were cosmopolitan and globally distributed, and many of them were cryptogenic. Six native species were identified: M. gigas, H. ezoensis, the amphipod Melita koreana, the isopod Cirolana koreana, and the barnacles B. trigonus and F. kondakovi. Eight non-indigenous species (NIS) were detected: the barnacles A. amphitrite and A. improvisus, the bivalve M. galloprovincialis, the polychaete Perinereis nuntia, the amphipods J. slatteryi and Caprella californica, and the bryozoans Bugulina californica and Bugula neritina. Of the fouling macroinvertebrates found on the vessel hulls, 13% were native, and 17% were NIS. More diverse communities developed on the hulls of vessels that operated locally rather than globally or in deep oceans. The species diversity index correlated positively with the total number of anchoring days and coastal operation days and negatively with the total number of operation days and ocean operation days. The macroinvertebrates differed by the area of operation, the port of anchorage, the number of days in operation and at anchor, and the hull sectors. There is no previous research data on hull-fouling macroinvertebrates in the Republic of Korea, and this study provides a basis for future studies to identify introduced species and their differences based on operation area. Full article
Show Figures

Figure 1

Figure 1
<p>Sampling locations for attached hull-fouling macroinvertebrates. Samples were collected 3–5 times repeatedly using quadrats (15 × 15 cm) in each sector: upper, middle, bottom, and niche areas (propeller shaft or thruster).</p>
Full article ">Figure 2
<p>Attached hull-fouling macroinvertebrates on the five research vessels ((<b>A</b>): Isabu, (<b>B</b>): Onnuri, (<b>C</b>): Eardo, (<b>D</b>): Jangmok 1, (<b>E</b>): Jangmok 2; <b>upper</b>: waterline on the hull side, <b>middle</b>: between the waterline and bottom line, <b>bottom</b>: including the seawater inlet, <b>niche areas</b>: propeller, shaft, and thruster; quadrats: 15 × 15 cm).</p>
Full article ">Figure 3
<p>Map showing the navigation areas of the Korea Institute of Ocean Science and Technology (KIOST) research vessels during 2016–2017 (green line: ocean worldwide class the Isabu, yellow line: ocean class the Onnuri, blue line: coastal class the Eardo, magenta line: local class the Jangmok 1, ocher line: coastal-local class the Jangmok 2; <a href="http://oceandata.kiost.ac.kr/realtime" target="_blank">http://oceandata.kiost.ac.kr/realtime</a> (accessed on 11 February 2023)).</p>
Full article ">Figure 4
<p>The number of species by taxa of attached macroinvertebrates on the vessels.</p>
Full article ">Figure 5
<p>The number of individuals by taxa of attached macroinvertebrates on the vessels.</p>
Full article ">Figure 6
<p>The biomass by taxa of attached macroinvertebrates on the vessels.</p>
Full article ">Figure 7
<p>The number of species by hull sector of attached macroinvertebrates on the vessels.</p>
Full article ">Figure 8
<p>The number of individuals by hull sector of attached macroinvertebrates on the vessels.</p>
Full article ">Figure 9
<p>The biomass by hull sector of attached macroinvertebrates on the vessels.</p>
Full article ">Figure 10
<p>Distribution of dominant species of hull-fouling macroinvertebrates by vessel.</p>
Full article ">Figure 11
<p>Distribution of dominant species of hull-fouling macroinvertebrates in each ship hull sector. The Isabu and Onnuri have a different scale than the other three vessels. Vertical lines are standard errors.</p>
Full article ">Figure 12
<p>Diversity and evenness indices of hull-fouling macroinvertebrate communities on the vessels. Vertical lines are standard errors.</p>
Full article ">Figure 13
<p>Eight NIS of hull-fouling macroinvertebrates introduced by five research vessels among the species introduced into Korea: bryozoans <span class="html-italic">B. californica and B. neritina</span>; bivalve <span class="html-italic">M. galloprovincialis</span>; polychaete <span class="html-italic">P. nuntia</span>; amphipods <span class="html-italic">C. californica and J. slatteryi</span>; barnacles <span class="html-italic">A. amphitrite</span> and <span class="html-italic">A. improvisus</span>.</p>
Full article ">Figure 14
<p>Nonmetric multidimensional scaling (nMDS) ordination of Bray–Curtis similarities of fourth-root transformed species abundance data from the five KIOST research vessels (SIMPROF test: the groups are separated by red lines; ANOSIM results: Global test R = 0.90, <span class="html-italic">p</span> &lt; 0.001). The stress value is a representation of the spatial dispersion based on resemblances among 69 samples. Vector and species overlays were produced using Pearson correlations between the species variables and the ordination MDS 1 and MDS 2 axes (blue lines). This is offered purely as an exploratory tool to visualize potential linear or monotonic relationships between a given set of variables and ordination axes.</p>
Full article ">
17 pages, 4488 KiB  
Article
Highly Sensitive Electrochemical Determination of Butylated Hydroxyanisole in Food Samples Using Electrochemical-Pretreated Three-Dimensional Graphene Electrode Modified with Silica Nanochannel Film
by Chengqing Huang, Shiyue Zhang, Xinying Ma, Fei Yan and Weizhong Tang
Nanomaterials 2024, 14(7), 569; https://doi.org/10.3390/nano14070569 - 25 Mar 2024
Cited by 3 | Viewed by 1230
Abstract
The sensitive detection of antioxidants in food is essential for the rational control of their usage and reducing potential health risks. A simple three-dimensional (3D) electrode integrated with an anti-fouling/anti-interference layer possesses great potential for the direct and sensitive electrochemical detection of antioxidants [...] Read more.
The sensitive detection of antioxidants in food is essential for the rational control of their usage and reducing potential health risks. A simple three-dimensional (3D) electrode integrated with an anti-fouling/anti-interference layer possesses great potential for the direct and sensitive electrochemical detection of antioxidants in food samples. In this work, a 3D electrochemical sensor was developed by integrating a 3D graphene electrode (3DG) with vertically ordered mesoporous silica film (VMSF), enabling highly sensitive detection of the common antioxidant, butylated hydroxyanisole (BHA), in food samples. A simple electrochemical polarization was employed to pre-activate the 3DG electrode (p3DG), enhancing its hydrophilicity. Using the p3DG as the supporting electrode, stable modification of VMSF was achieved using the electrochemical assisted self-assembly (EASA) method, without the need for any adhesive agents (VMSF/p3DG). Taking BHA in food as a model analyte, the VMSF/p3DG sensor demonstrated high sensitivity, due to the enrichment by nanochannels, towards BHA. Electrochemical detection of BHA was achieved with a linear range of 0.1 μM to 5 μM and from 5 μM to 150 μM with a low limit of detection (12 nM). Owing to the fouling resistance and anti-interference capabilities of VMSF, the constructed 3D electrochemical sensor can be directly applied for the electrochemical detection of BHA in complex food samples. Full article
Show Figures

Figure 1

Figure 1
<p>Schematic illustration for (<b>I</b>) the fabrication of the VMSF/p3DG sensor and (<b>II</b>) the corresponding anti-fouling (the dashed-line box on the left) and signal amplification (the solid-line box on the right) for BHA detection (the illustration in the middle).</p>
Full article ">Figure 2
<p>SEM images of (<b>a</b>) 3DG and (<b>b</b>) p3DG. Contact angle image of (<b>c</b>) 3DG and (<b>d</b>) p3DG.</p>
Full article ">Figure 3
<p>High-resolution C1s spectra of (<b>a</b>) 3DG, (<b>b</b>) p3DG, and (<b>c</b>) VMSF/p3DG. High-resolution Si2p spectrum of (<b>d</b>) VMSF/p3DG.</p>
Full article ">Figure 4
<p>Cyclic voltametric curves obtained on 3DG, p3DG, SM@VMSF/p3DG, and VMSF/p3DG electrodes in (<b>a</b>) Fe(CN)<sub>6</sub><sup>3−</sup> (0.5 mM) or (<b>b</b>) Ru(NH<sub>3</sub>)<sub>6</sub><sup>3+</sup> (0.5 mM) solution (in 0.05 M KHP). Insets are illustrated structure of the redox probe (left) and the amplified curve obtained on 3DG.</p>
Full article ">Figure 5
<p>(<b>a</b>) Cyclic voltametric curves and (<b>b</b>) linear sweep voltametric curves obtained on different electrodes, including 3DG, p3DG, and VMSF/p3DG as well as 2D GCE, pGCE, and VMSF/pGCE in 0.1 M PBS (pH = 5.0) containing 20 μM BHA. Sweep speed was 0.1 V/s. The curves were obtained using the adsorption/enrichment time of 2 min. The adsorption enrichment process was carried out at the zero point. Oxidation peak current of BHA obtained using linear sweep voltammetry at different pH values of electrolyte (<b>c</b>) or different enrichment time (<b>d</b>).</p>
Full article ">Figure 6
<p>(<b>a</b>) Linear sweep voltametric curves obtained on VMSF/p3DG electrode in PBS (0.1 M, pH = 5) containing different concentrations of BHA. (<b>b</b>) Relationship of anodic peak current in linear sweep voltametric curves with BHA concentration. (<b>c</b>) Anodic peak current obtained on linear sweep voltametric curves using VMSF/p3DG electrode in the absence (<span class="html-italic">I</span><sub>0</sub>) or presence (<span class="html-italic">I</span>) of different interferents. The concentration of BHA is 5 μM. The concentration of the other substance is 10 μM. (<b>d</b>) Anodic peak current obtained on linear sweep voltametric curves using regenerated VMSF/p3DG electrode in BHA (5 μM) or PBS.</p>
Full article ">
Back to TopTop