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13 pages, 630 KiB  
Article
Impact of the Sloping Land Conversion Program on Rural Household Income in China
by Lingchao Li, Yue Lu, Can Liu and Hao Liu
Forests 2024, 15(12), 2071; https://doi.org/10.3390/f15122071 (registering DOI) - 24 Nov 2024
Abstract
As the largest Payment for Environmental Services (PESs) program in China, the Sloping Land Conversion Program (SLCP) has exerted a profound impact on both the ecosystems and rural households’ livelihoods. However, the direct impact and indirect impact mechanism of the SLCP on income [...] Read more.
As the largest Payment for Environmental Services (PESs) program in China, the Sloping Land Conversion Program (SLCP) has exerted a profound impact on both the ecosystems and rural households’ livelihoods. However, the direct impact and indirect impact mechanism of the SLCP on income remain poorly understood. To bridge this research gap, a unique dataset was used in this study, comprising more than 1200 sampled rural households from 1995 to 2016. An estimation was conducted regarding the direct impact of the SLCP and its subsidy changes in different implementation stages on rural household income, as well as the indirect impact mechanism of the SLCP on income. Our results provided twofold findings. First, participation in the first round of the SLCP increased rural household’s income by 4.63% compared with non-participation. However, in the transition period, the SLCP had no significant effect on the total income of rural households. In the subsidy extension and subsidy expiration stages, participation in the SLCP increased rural household total income by 12.53% and 11.77%, respectively. Second, the variables, including farmland area, forestland area, land-based production expenditure, land-based labor input, and off-farm labor input, had significant mediation effects on the impact of the SLCP on rural household income. To improve the implementation of the SLCP, policymakers could pay attention to more integrative approaches, such as forestland transfer, reduction in forestland fragmentation, and promotion of off-farm job opportunities. Full article
(This article belongs to the Section Forest Economics, Policy, and Social Science)
18 pages, 6329 KiB  
Article
The Influence of Sand Pore Structure on Air Migration During Air-Injected Desaturation Process
by Yumin Chen, Chengzhao Qin, Saeed Sarajpoor, Runze Chen, Yi Han and Zijun Wang
Buildings 2024, 14(12), 3730; https://doi.org/10.3390/buildings14123730 (registering DOI) - 23 Nov 2024
Abstract
The air injection method serves as a liquefaction mitigation technique to improve the liquefaction resistance of the foundations by decreasing the degree of saturation. To investigate the desaturation effect of this technique in various soil strata of the foundation, thin plate model tests [...] Read more.
The air injection method serves as a liquefaction mitigation technique to improve the liquefaction resistance of the foundations by decreasing the degree of saturation. To investigate the desaturation effect of this technique in various soil strata of the foundation, thin plate model tests were conducted, considering the impacts of gradation and relative density, to visualize the air migration process and distribution. The findings reveal the following: (1) The air migration process, delineated by air injection parameters, comprises four distinct phases, with stages II and III notably influenced by the pore structure; (2) air migration is governed by the pore throat dimensions, particle arrangement, and connectivity within the pore structure, exhibiting two predominant patterns: channel flow, primarily driven by inertial forces, and chamber flow, predominantly influenced by viscous and capillary forces; (3) referring to the air injection port, the gas phase distribution within the sand samples is consistent in the horizontal direction but not in the vertical direction. The concentration area and uniformity of the gas phase distribution are controlled by the pore structure. These results suggest potential enhancements in the positioning of air injection ports within complex soil layers, as well as improvements in the construction process, both aimed at optimizing the desaturation effect. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
28 pages, 30892 KiB  
Article
Study on Changes in Comprehensive Land Prices for Expropriation Zones Based on Land Use Changes
by Xu Dong, Xinming Dong, Fang Wang, Meichen Fu, Guanzhi Deng, Sijia Li, Haoyang Kang and Yuqing Xiong
Sustainability 2024, 16(23), 10267; https://doi.org/10.3390/su162310267 (registering DOI) - 23 Nov 2024
Abstract
Comprehensive land prices for expropriation zones can effectively alleviate many conflicts in China’s land expropriation practices. This contributes to achieving sustainable development goals such as “SDG-10: Reduced Inequalities” and “ SDG-11: Sustainable Cities and Communities”. The reasonable delineation of expropriation zones and scientific [...] Read more.
Comprehensive land prices for expropriation zones can effectively alleviate many conflicts in China’s land expropriation practices. This contributes to achieving sustainable development goals such as “SDG-10: Reduced Inequalities” and “ SDG-11: Sustainable Cities and Communities”. The reasonable delineation of expropriation zones and scientific calculation of zone prices have become crucial. This study used the Cangzhou urban area in Hebei Province, China, as a case study. By integrating the CA–Markov model, multiple linear regression model, coupling coordination degree model, relative development degree model, and GIS spatial analysis techniques, the study deeply analyzed the spatiotemporal coupling relationship between land use and comprehensive land prices for expropriation zones from 2009 to 2021. Furthermore, it simulated and forecasted the changes in land use, expropriation zones, and zone prices in 2027. The study yielded the following conclusions: (1) The changes in land use reflected land economic value, land resource condition and land location condition shifts, which formed an interactive feedback mechanism with the comprehensive land price for land expropriation zones. (2) Land use impacted zone distribution through the spatial distribution characteristics of construction land, with recent development zones in the central urban area primarily extending east and southeast due to planning and policies related to land use for construction. (3) The coupling coordination and relative developmental degree between land use degree and zone price gradually develop in a good direction. A linear relationship is observed among land economic value, land resource condition, and land location condition concerning the zone price. Based on this, the predicted adjustment ranges for zone prices from high to low in 2027 will be 2.6400 to 2.7210, 2.1900 to 2.2537, and 1.8300 to 1.9306 million CNY/hectare. This study provides a new method for studying comprehensive land prices for expropriation zones, supporting decision making. Full article
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<p>Interaction mechanism between land use and land expropriation.</p>
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<p>Location map of the Cangzhou urban area. (<b>a</b>) The location of the Cangzhou urban area in China. (<b>b</b>) The location of the Cangzhou urban area in Cangzhou City. (<b>c</b>) Remote sensing image map of the Cangzhou urban area. (<b>d</b>) Zone distribution conditions in the Cangzhou urban area, from left to right, during the following years: 2009, 2012, 2015, 2018, and 2021.</p>
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<p>Land use map of the Cangzhou urban area from 2009 to 2021.</p>
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<p>Methodological framework diagram.</p>
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<p>Framework for calculating coupling coordination degree and relative development model.</p>
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<p>Simulated land use map of the Cangzhou urban area for 2027.</p>
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<p>The spatial characteristics of construction land and the zone distribution map. (<b>a</b>) Concentration of construction land. (<b>b</b>) Distance from construction land (unit: m). (<b>c</b>) Distance from Zones I and II (unit: m).</p>
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<p>Histograms of factor frequency distributions of Zone III that was upgraded to Zone II. (<b>a</b>) Core density of construction land. (<b>b</b>) Distance from construction land. (<b>c</b>) Distance from Zones I and II.</p>
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<p>The migration of the construction land centroid in the Cangzhou urban area from 2009 to 2027.</p>
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<p>Scatter plots of land use degrees and zone prices. Zone price unit: million CNY/hectare.</p>
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<p>The land category proportions and land use degrees in various zones of the Cangzhou urban area from 2009 to 2021.</p>
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<p>Coupling coordination and relative development degree diagram of zone prices and land use degree in the Cangzhou urban area from 2009 to 2021.</p>
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<p>Zone III conversion rules. (<b>a</b>) Urban planning area. (<b>b</b>) Urban development boundary. (<b>c</b>) Zones III-2 and III-3 were more prone to conversion in 2021. (<b>d</b>) Agglomeration degree of construction land in 2027 (unit: m). (<b>e</b>) Distance from construction land in 2027 (unit: m). (<b>f</b>) Distance from 2021 Zones I and II (unit: m).</p>
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<p>Simulation map of zone distribution in the Cangzhou urban area in 2027.</p>
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26 pages, 1789 KiB  
Article
How Do Algorithmic Management Practices Affect Workforce Well-Being? A Parallel Moderated Mediation Model
by Husam Zayid, Ahmad Alzubi, Ayşen Berberoğlu and Amir Khadem
Behav. Sci. 2024, 14(12), 1123; https://doi.org/10.3390/bs14121123 (registering DOI) - 23 Nov 2024
Abstract
Modern workplaces increasingly use algorithmic management practices (AMPs), which shape task assignment, monitoring, and evaluation. Despite the potential benefits these practices offer, like increased efficiency and objectivity, their impact on workforce well-being (WFW) has raised concerns. Drawing on self-determination theory (SDT) and conservation [...] Read more.
Modern workplaces increasingly use algorithmic management practices (AMPs), which shape task assignment, monitoring, and evaluation. Despite the potential benefits these practices offer, like increased efficiency and objectivity, their impact on workforce well-being (WFW) has raised concerns. Drawing on self-determination theory (SDT) and conservation of resources theory (COR), this study examines the relationship between algorithmic management practices and workforce well-being, incorporating job burnout (JBO) and perceived threat (PT) as parallel mediators and person–job fit (PJF) as a moderator. The research employed a cross-sectional survey design targeting 2450 KOSGEB-registered manufacturing SMEs in Istanbul, Turkey. A sample of 666 respondents participated, and the data were analyzed using Smart PLS 4, employing structural equation modeling to test the proposed model. The results indicated that algorithmic management practices significantly increased job burnout and perceived threat, both of which negatively impacted workforce well-being. However, the direct effect of algorithmic management practices on workforce well-being was non-significant. Person–job fit moderated the relationships between algorithmic management practices and both job burnout and perceived threat, further influencing workforce well-being. The findings underscore the critical need for organizations to balance algorithmic efficiency with human-centric practices. Prioritizing person–job fit and fostering transparency in algorithmic processes can mitigate negative impacts, enhance employee well-being, and drive sustainable organizational success in the digital age. Full article
(This article belongs to the Special Issue Leadership in the New Era of Technology)
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<p>Research model.</p>
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<p>Evaluation of the measurement model. Note: Dashed arrows represent moderating effect, sold arrows represent direct relationships.</p>
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<p>Estimation of the structural model. Note(s): Absolute values are applied to <span class="html-italic">p</span>-values. Note: Dashed arrows represent moderating effect, sold arrows represent direct relationships.</p>
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<p>The moderation effect of PJF in the relationship between AMPs and job burnout.</p>
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<p>The moderation effect of PJF in the relationship between AMPs and perceived threat.</p>
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<p>The moderation effect of PJF in the relationship between AMPs and workforce well-being.</p>
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20 pages, 300 KiB  
Article
Impact of Energy Intensity and CO2 Emissions on Economic Growth in Gulf Cooperation Council Countries
by Ihsen Abid, Soumaya Hechmi and Ines Chaabouni
Sustainability 2024, 16(23), 10266; https://doi.org/10.3390/su162310266 (registering DOI) - 23 Nov 2024
Abstract
This study investigates the impact of energy intensity and CO2 emissions on economic growth in Gulf Cooperation Council (GCC) countries, aiming to understand the interplay between energy consumption, environmental sustainability, and economic performance. We analyze data from 1990 to 2023 across six [...] Read more.
This study investigates the impact of energy intensity and CO2 emissions on economic growth in Gulf Cooperation Council (GCC) countries, aiming to understand the interplay between energy consumption, environmental sustainability, and economic performance. We analyze data from 1990 to 2023 across six GCC countries. The study employs the fixed effects model, random effects model, and pooled regression model to examine the relationships between energy intensity, CO2 emissions, and GDP growth, controlling for factors such as foreign direct investment, trade openness, population, unemployment, and urbanization. Our findings reveal a significant negative impact of energy intensity on economic growth, and an increase in energy intensity is associated with a decrease of approximately 0.2969 units in GDP, indicating that higher energy consumption per unit of output hinders economic performance. While CO2 emissions positively affect growth in GCC countries, a one-unit increase in CO2 emissions is associated with an increase of approximately 0.3961 units in GDP. The study emphasizes the necessity for GCC countries to adopt sustainable energy practices to reduce energy intensity and boost economic growth. By aligning economic strategies with environmental sustainability goals, these nations can achieve long-term growth while effectively addressing the challenges of climate change. This research contributes to the ongoing discourse on sustainable development in the region and underscores the importance of harmonizing economic growth strategies with environmental objectives. Full article
19 pages, 6256 KiB  
Article
Major and Trace Airborne Elements and Ecological Risk Assessment: Georgia Moss Survey 2019–2023
by Omari Chaligava, Inga Zinicovscaia, Alexandra Peshkova, Nikita Yushin, Marina Frontasyeva, Konstantin Vergel, Makhabbat Nurkassimova and Liliana Cepoi
Plants 2024, 13(23), 3298; https://doi.org/10.3390/plants13233298 (registering DOI) - 23 Nov 2024
Abstract
The study, carried out as part of the International Cooperative Program on Effects of Air Pollution on Natural Vegetation and Crops, involved collecting 95 moss samples across the territory of Georgia during the period from 2019 to 2023. Primarily samples of Hypnum cupressiforme [...] Read more.
The study, carried out as part of the International Cooperative Program on Effects of Air Pollution on Natural Vegetation and Crops, involved collecting 95 moss samples across the territory of Georgia during the period from 2019 to 2023. Primarily samples of Hypnum cupressiforme were selected, with supplementary samples of Abietinella abietina, Pleurozium schreberi, and Hylocomium splendens in cases of the former’s absence. The content of 14 elements (Al, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, S, Sr, V, and Zn) was detected using Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES), while the Hg content was determined using a Direct Mercury Analyzer. To identify any relationships between chemical elements and to depict their sources, multivariate statistics was applied. Principal component analysis identified three main components: PC1 (geogenic, 43.4%), PC2 (anthropogenic, 13.3%), and PC3 (local anomalies, 8.5%). The results were compared with the first moss survey conducted in Georgia in the period from 2014 to 2017, offering insights into temporal trends of air quality. Utilizing GIS, a spatial map illustrating pollution levels across Georgia, based on the Pollution Load Index, was generated. The Potential Environmental Risk Index emphasized significant risks associated with mercury and cadmium at several locations. The study highlights the utility of moss biomonitoring in assessing air pollution and identifying hotspots of contamination. The findings from this study could be beneficial for future biomonitoring research in areas with varying physical and geographical conditions. Full article
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<p>Correlation matrix between the elements of the entire initial data set. X stands for not significant.</p>
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<p>(<b>a</b>) Biplot of PC1 and PC2 denote the first two principal components explaining 56.7% of the variance in the data. (<b>b</b>) Biplot of PC2 and PC3 represent the second and third principal components explaining 21.8% of the variance in the data. Each point, distinguished by a unique combination of color and symbol, represents a sample of one of the four species. Arrows emanate from the origin, representing the variables.</p>
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<p>(<b>a</b>) Biplot of PC1 and PC2 denote the first two principal components explaining 56.7% of the variance in the data. (<b>b</b>) Biplot of PC2 and PC3 represent the second and third principal components explaining 21.8% of the variance in the data. Each point, distinguished by a unique combination of color and symbol, represents a sample of one of the four species. Arrows emanate from the origin, representing the variables.</p>
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<p>PMF analysis factor fingerprint showing the percentage contribution of three identified factors (Factor 1, Factor 2, Factor 3) across various elements measured in the moss samples.</p>
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<p>Comparison of Contamination Factors (CF) between current (95 Samples) and previous (120 Samples) moss surveys in Georgia.</p>
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<p>Spatial distribution of the Pollution Load Index (PLI) across all sampling locations. The PLI is represented by colored dots on the map, with different colors indicating varying levels of pollution. Each dot corresponds to a specific sampling site, numbered for reference purposes.</p>
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<p>Boxplots of the Potential Ecological Risk Index (PERI) for selected elements accumulated by the mosses.</p>
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<p>Map of sampling locations with color-coded markers to indicate moss species collected. Red dots indicate <span class="html-italic">Abietinella abietina</span>, green—<span class="html-italic">Hylocomium splendens</span>, yellow—<span class="html-italic">Hypnum cupressiforme</span>, and blue—<span class="html-italic">Pleurozium schreberi</span>.</p>
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21 pages, 14871 KiB  
Article
Electrochemical Co-Degradation of Acetaminophen and Bisphenol A in Aqueous Solutions: Degradation Competition and Pathways
by Kuo-Lin Huang, Jui-Chiung Hung and Yi-Ming Kuo
Processes 2024, 12(12), 2641; https://doi.org/10.3390/pr12122641 (registering DOI) - 23 Nov 2024
Abstract
This study investigated the degradation competition and pathways of electrochemical co-degradation of two emerging environmental contaminants, polar acetaminophen (AP) and (moderately) non-polar bisphenol A (BPA), on a boron-doped diamond (BDD) electrode in aqueous solutions. The results showed that both compounds mainly relied on [...] Read more.
This study investigated the degradation competition and pathways of electrochemical co-degradation of two emerging environmental contaminants, polar acetaminophen (AP) and (moderately) non-polar bisphenol A (BPA), on a boron-doped diamond (BDD) electrode in aqueous solutions. The results showed that both compounds mainly relied on hydroxyl radicals (•OH) to trigger indirect oxidation for their electrochemical degradation, although AP also underwent direct oxidation during electrolysis. The effect of increasing current density on the increases in degradation performance was almost the same for AP and BPA. However, BPA exhibited a better performance in mono-degradation than AP, while the opposite tendency was observed for their co-degradation. Their degradation efficiencies were better in 1 M Na2SO4 solution than in a real water matrix. Both UV-vis and excitation–emission matrix (EEM) fluorescence analyses demonstrated that all the aromatic rings of AP and BPA were opened after 30 min of electrolysis at 0.5 A cm−2 in 1 M Na2SO4 solution. Regardless of the small difference in intermediate species, the pathways of electrochemical AP+BPA co-degradation were similar to those of their mono-degradation combination. A double exponential decay model is proposed to simulate the formation and degradation rate constants of benzoquinone (an intermediate). Full article
(This article belongs to the Topic Wastewater Treatment Based on AOPs, ARPs, and AORPs)
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<p>The experimental device for target compound degradation (A: BDD anode, B: Nafion 212 separator, C: Ti cathode, D: magnetic stirrer, E: DC power supply, and F: temperature controller).</p>
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<p>(<b>a</b>) CVs of acetaminophen (AP) with increasing concentrations (100–800 ppm) in 1 M Na<sub>2</sub>SO<sub>4</sub> solutions; (<b>b</b>) CVs of AP, biphenyl A (BPA), and AP+BPA in 1 M Na<sub>2</sub>SO<sub>4</sub> solutions (O1: oxygen evolution potential; O2: sulfate oxidation peak; O3: AP oxidation peak; R: corresponding reduction peak of O3; and ↑: direction of curve change for increasing AP concentration).</p>
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<p>Plots of normalized AP (<b>a</b>) (inset: ln(C<sub>0</sub>/C<sub>t</sub>) vs. time), BPA (<b>b</b>) (inset: ln(C<sub>0</sub>/C<sub>t</sub>) vs. time), TOC (<b>c</b>), and MCE (<b>d</b>) with time for electrochemical co-degradation of AP+BPA at different current densities in 1 M Na<sub>2</sub>SO<sub>4</sub> solution; DMPO-OH signal in ESR analysis (<b>e</b>); and Lnk vs. LnI linear plots for AP and BPA (<b>f</b>).</p>
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<p>Comparison of electrochemical mono- and co-degradation of target compounds (<b>a</b>) and TOC (<b>b</b>) (inset: MCE) at 0.5 A cm<sup>−2</sup> in 1 M Na<sub>2</sub>SO<sub>4</sub> solutions.</p>
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<p>Comparison of electrochemical co-degradation of (<b>a</b>) target compounds (in 1 M Na<sub>2</sub>SO<sub>4</sub> spiked with AP+BPA) and (<b>b</b>) TOC (in 1 M Na<sub>2</sub>SO<sub>4</sub> spiked with AP+BPA vs. in RW spiked with AP+BPA and 1 M Na<sub>2</sub>SO<sub>4</sub>) at 0.5 A cm<sup>−2</sup>.</p>
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<p>Plots of normalized pBQ with time for electrochemical co-degradation of target compounds at different current densities (<b>a</b>), and at 0.5 A cm<sup>−2</sup> in different solutions (<b>b</b>) (DF: data-fitting curve in pink), and data fitting (BPA degradation at 0.05 A cm<sup>−2</sup> on Ti/BDD in 0.1 M Na<sub>2</sub>SO<sub>4</sub>) taken from [<a href="#B9-processes-12-02641" class="html-bibr">9</a>] (<b>c</b>).</p>
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<p>UV-Vis spectra for co-electrolysis of AP+BPA (100 mg/L each) in 1.0 M Na<sub>2</sub>SO<sub>4</sub>.</p>
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<p>Fluorescence excitation–emission matrix (EEM) spectra for (<b>a</b>) blank 1.0 M Na<sub>2</sub>SO<sub>4</sub>, (<b>b</b>) blank river water, and (<b>c</b>) electrochemical degradation of AP+BPA (100 ppm each) in river water spiked with 1.0 M Na<sub>2</sub>SO<sub>4</sub>.</p>
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<p>Pathways of electrochemical degradation of acetaminophen (AP).</p>
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<p>Pathways of electrochemical degradation of biphenyl A (BPA).</p>
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<p>Pathways of electrochemical co-degradation of AP+BPA.</p>
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23 pages, 4517 KiB  
Article
Rhamnolipid-Enriched PA3 Fraction from Pseudomonas aeruginosa SWUC02 Primes Chili Plant Defense Against Anthracnose
by Natthida Sudyoung, Siritron Samosorn, Kulvadee Dolsophon, Kwannan Nantavisai, Onanong Pringsulaka, Supaart Sirikantaramas, Akira Oikawa and Siriruk Sarawaneeyaruk
Int. J. Mol. Sci. 2024, 25(23), 12593; https://doi.org/10.3390/ijms252312593 (registering DOI) - 23 Nov 2024
Viewed by 47
Abstract
Chili anthracnose, caused by Colletotrichum truncatum, causes significant yield loss in chili production. In this study, we investigated the elicitor properties of a rhamnolipid (RL)-enriched PA3 fraction derived from Pseudomonas aeruginosa SWUC02 in inducing systemic resistance in yellow chili seedlings and antifungal [...] Read more.
Chili anthracnose, caused by Colletotrichum truncatum, causes significant yield loss in chili production. In this study, we investigated the elicitor properties of a rhamnolipid (RL)-enriched PA3 fraction derived from Pseudomonas aeruginosa SWUC02 in inducing systemic resistance in yellow chili seedlings and antifungal activity against C. truncatum CFPL01 (Col). Fractionation of the ethyl acetate extract yielded 12 fractions, with PA3 demonstrating the most effective disease suppression, reducing the disease severity index to 4 ± 7.35% at 7 days post-inoculation compared with Col inoculation alone (83 ± 23.57%). PA3 also exhibited direct antifungal activity, inhibiting Col mycelial growth by 41 ± 0.96% at 200 µg/mL. Subfractionation revealed PA3 as a mixture of mono- and di-RLs, confirmed by 1H nuclear magnetic resonance and electrospray ionization mass spectrometry data. Additionally, PA3 enhanced seed germination and promoted plant growth without causing phytotoxicity. Transcriptomics revealed that PA3 pre-treatment prior to Col infection primed the defense response, upregulating defense-related genes involved in the phenylpropanoid, flavonoid, and jasmonic acid biosynthesis pathways, as well as those associated with cell wall reinforcement. Our findings highlight the potential of RL-enriched PA3 as both an antifungal agent and a plant defense elicitor, with transcriptome data providing new insights into defense priming and resistance pathways in chili, offering an eco-friendly solution for sustainable anthracnose management. Full article
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<p>Induced systemic resistance assay of the fractions (PA1 to PA12) isolated from the ethyl acetate extract of CF-SWUC02 in yellow chili seedlings. (<b>A</b>) % DSI represented as box plots (<span class="html-italic">n</span> ≥ 6). Different letters (a, b, c, d) indicate significant differences (<span class="html-italic">p</span> &lt; 0.05). (<b>B</b>) Disease symptoms observed on seedlings at seven dpi. Col = <span class="html-italic">C. truncatum</span> CFPL01.</p>
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<p>Percentage of mycelial growth inhibition (% MGI) and abnormalities in Col germination under PA3 treatment. (<b>A</b>) % MGI by PA3, carbendazim 50% WP, and mancozeb 80% WP at 200, 20, and 2 µg/mL. The negative control was potato dextrose agar without any supplements. Bars represent mean ± SD. Difference letters (a, b, c) indicate significant differences (<span class="html-italic">p</span> &lt; 0.05) between treatments within each concentration. (<b>B</b>) Microscopic observations (1000×) of germinated hyphae from conidia treated with PA3 at 0 (control), 15.6, and 4000 µg/mL. Red arrows highlight abnormalities.</p>
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<p>PA3 characteristic by <sup>1</sup>H NMR and ES-MS spectroscopic data. (<b>A</b>) <sup>1</sup>H NMR spectrum of PA3 in CD<sub>3</sub>OD, showing characteristic proton signals with the chemical structure of mono- and di-RLs displayed. (<b>B</b>) Negative-ion electrospray mass spectrum of PA3, with red circles highlighting the main detected peaks corresponding to molecular ions of mono- and di-RLs. The blue arrow indicates the detection limit, while the asterisks indicate the calculated monoisotopic masses of the detected ions.</p>
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<p>Characterization of PA3 subfractions (PA3-1 and PA3-2) and their effects on disease symptoms in yellow chili seedlings. (<b>A</b>) Thin-layer chromatography (TLC) plate analysis of PA3 (<b>left</b>), PA3-1 (<b>middle</b>), and PA3-2 (<b>right</b>), visualized with <span class="html-italic">p</span>-anisaldehyde staining. (<b>B</b>) Percentage disease severity index (% DSI) of seedlings in mock, PA3-1, PA3-2, and Col treatments. Bars represent mean ± SD. Different letters (a, b) indicate significant differences (<span class="html-italic">p</span> &lt; 0.05). (<b>C</b>) Disease severity symptoms observed on seedlings across different treatments.</p>
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<p>Effects of PA3 application on seed germination and plant growth of yellow chili. (<b>A</b>) Germination speed index (GSI). (<b>B</b>) Percentage of seed germination (% SG). (<b>C</b>) Vigor index (VI). (<b>D</b>) Number of leaves per plant. (<b>E</b>) Number of flower buds per plant. (<b>F</b>) Plant height (cm). (<b>G</b>) Stem diameter (cm). Each dot represents an individual sample. Different letters (a, b, c) indicate statistically significant differences between treatments (<span class="html-italic">p</span> &lt; 0.05).</p>
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<p>Venn diagrams and heatmap of DEGs related to defense response. (<b>A</b>) Venn diagram showing the number of upregulated DEGs. (<b>B</b>) Venn diagram showing the number of downregulated DEGs. (<b>C</b>) Heatmap of 70 defense-related DEGs identified by GO terms, displaying Z-scores of gene expression levels. Genes highlighted in red indicate upregulated genes, while those in green indicate downregulated genes. Superscripts indicate the following: C = significant DEGs in Col treatment alone, PC = significant DEGs in PA3+Col treatment, and C + PC = significant DEGs in both treatments.</p>
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<p>Top 10 enriched GO terms across three categories—biological process (yellow), cellular component (purple), and molecular function (blue)—related to DEGs. (<b>A</b>) Enriched GO terms in the Col treatment alone. (<b>B</b>) Enriched GO terms in the PA3+Col treatment. Unique defense-related GO terms are indicated in green, while shared defense-related GO terms between treatments are highlighted in pink.</p>
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<p>Differential expression of DEGs involved in the phenylpropanoid and flavonoid biosynthesis pathways across different treatments. (<b>A</b>) The heatmap shows DEGs with their respective enzyme codes and gene IDs, with gene expression levels represented as Z-scores, indicating relative expression changes compared to the mean expression across treatments. (<b>B</b>) The schematic diagram illustrates the phenylpropanoid and flavonoid biosynthesis pathways. The colors within the boxes correspond to the Z-scores in the heatmap. Treatments are abbreviated as M = mock, P = PA3, PC = PA3+Col, and C = Col. DEGs encoding enzymes involved in the phenylpropanoid pathway are shown in red text, while those involved in the flavonoid pathway are shown in blue text.</p>
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<p>Differential expression of DEGs involved in the α-linolenic acid biosynthesis pathway across different treatments. (<b>A</b>) The heatmap shows DEGs with their respective enzyme codes and gene IDs, with gene expression levels represented as Z-scores, indicating relative expression changes compared to the mean expression across treatments. (<b>B</b>) The schematic diagram illustrates the α-linolenic acid biosynthesis pathway, with enzyme codes and DEGs mapped to specific reactions. Treatments are abbreviated as M = mock, P = PA3, PC = PA3+Col, and C = Col.</p>
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<p>Validation of gene expression levels by RNA-seq and RT-qPCR for six DEGs: <span class="html-italic">PAL</span>, <span class="html-italic">C4H</span>, <span class="html-italic">CHI</span>, <span class="html-italic">AOC</span>, <span class="html-italic">ECHB</span>, and <span class="html-italic">BPR1</span>. (<b>A</b>) Fold change comparison in the Col treatment alone relative to the mock treatment; and (<b>B</b>) fold change comparison in the PA3+Col treatment relative to the mock treatment. Yellow bars represent RNA-seq results, while purple bars represent RT-qPCR results, shown as log<sub>2</sub> fold change.</p>
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21 pages, 15517 KiB  
Article
3D Reconstruction of Building Blocks Based on Extraction of Exterior Wall Lines Using Point Cloud Density Generated from Spherical Camera Images
by Qazale Askari, Hossein Arefi and Mehdi Maboudi
Remote Sens. 2024, 16(23), 4377; https://doi.org/10.3390/rs16234377 (registering DOI) - 23 Nov 2024
Viewed by 69
Abstract
The 3D modeling of urban buildings has become a common research area in various disciplines such as photogrammetry and computer vision, with different applications such as intelligent city management, navigation of self-driving cars and architecture, just to name a few. The objective of [...] Read more.
The 3D modeling of urban buildings has become a common research area in various disciplines such as photogrammetry and computer vision, with different applications such as intelligent city management, navigation of self-driving cars and architecture, just to name a few. The objective of this study is to produce a 3D model of the external facade of the buildings with the required precision, accuracy and level of detail according to the user’s requirements, while minimizing time and cost. This research focuses on the production of 3D models for blocks of residential buildings in Tehran, Iran. The Insta 360 One X2 spherical camera is selected to capture the data due to its low cost and 360 × 180° field of view. The camera specifications have facilitated more efficient data collection in terms of both time and cost. The proposed modeling method is based on extracting lines of external walls through the utilization of the point cloud density concept. Initially, photogrammetric point clouds are generated in with a reconstruction precision of 0.24 m from spherical camera images. In the next step, the 3D point cloud is projected into a 2D point cloud by setting the height component to zero. The 2D point cloud is then rotated based on the direction angle determined by the Hough transform so that the perpendicular walls are parallel to the axes of the coordinate system. Next, a 2D point cloud density analysis is performed by voxelizing the point cloud and counting the number of points in each voxel in both the horizontal and vertical directions. By determining the peaks in the density plot, the lines of the external vertical and horizontal walls are extracted. To extract the diagonal external walls, the density analysis is performed in the direction of the first principal component. Finally, by determining the height of each wall in the point cloud, a 3D model is created at the level of detail one. The resulting model has a precision of 0.32 m compared to real sizes, and the 2D plan has a precision of 0.31 m compared to the ground truth map. The use of the spherical camera and point cloud density analysis makes this method efficient and cost-effective, making it a promising approach for future urban modeling projects. Full article
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<p>The Insta 360 One X2 camera, as presented on the website <a href="https://www.insta360.com/product/insta360-onex2" target="_blank">https://www.insta360.com/product/insta360-onex2</a>, (accessed on 30 August 2023).</p>
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<p>This figure illustrates the geometric process for creating an equirectangular image from two circular images of the front and rear fisheye lenses of the Insta 360 One X2 camera; (<b>a</b>) equirectangular image of Insta360 OneX2; (<b>b</b>) equirectangular geometric projection format.</p>
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<p>The data acquisition route comprises two red and blue closed loops, measuring 740 m in length, situated in Tehran, Iran on Google Map.</p>
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<p>Flowchart of the proposed methods in 3D street mapping using spherical camera.</p>
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<p>Point cloud generated from four building blocks in the Agisoft Metashape software.</p>
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<p>Classified point cloud generated from four building blocks in the Agisoft Metashape software.</p>
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<p>Building point cloud class generated from four building blocks in the Agisoft Metashape software.</p>
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<p>Depth image and binary image generated from the point cloud of a building block (<b>a</b>). raster with average height; (<b>b</b>) binary raster.</p>
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<p>Display of the pixels of the edge of the binary image of the building block in Hough space.</p>
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<p>The variance graph (the variance in the columns of the accumulator matrix) and the largest peak.</p>
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<p>The 2D point cloud representation of a building block before and after the rotation (<b>a</b>) the point cloud before rotation; (<b>b</b>) the point cloud after rotation.</p>
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<p>Steps of implementing the density analysis on the point cloud of the building block in order to extract the lines of the vertical walls: (<b>a</b>) a point cloud of the building block mapped on the X-Z plane; (<b>b</b>) a histogram of point cloud voxelization along the x-axis; (<b>c</b>) show the peaks of the point cloud density graph along the x-axis.</p>
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<p>Steps of implementing the density analysis on the point cloud of the building block in order to extract the lines of the horizontal walls: (<b>a</b>) a point cloud of the building block mapped on the Y-Z plane; (<b>b</b>) a histogram of point cloud voxelization along the Y-axis; (<b>c</b>) show the peaks of the point cloud density graph along the Y-axis.</p>
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<p>Showing the steps of density analysis on the diagonal wall in the X-axis direction: (<b>a</b>) a point cloud of the diagonal wall mapped on the X-Z plane; (<b>b</b>) a histogram of point cloud voxelization along the x-axis; (<b>c</b>) show the peaks of the point cloud density graph along the x-axis.</p>
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<p>Showing the steps of density analysis on the diagonal wall in the Y-axis direction: (<b>a</b>) a point cloud of the diagonal wall mapped on the Y-Z plane; (<b>b</b>) a histogram of point cloud voxelization along the Y-axis; (<b>c</b>) show the peaks of the point cloud density graph along the x-axis.</p>
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<p>Lines of horizontal and vertical walls, as well as the coordinates of the intersection of these lines: (<b>a</b>) the lines passing through the peaks of the density graph in the direction of the y-axis indicate the position of the horizontal walls; (<b>b</b>) the lines passing through the peaks of the density graph in the direction of the x-axis represent the lines of the vertical walls.</p>
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<p>The process of extracting the diagonal wall line after applying the first principal component analysis: (<b>a</b>) a diagonal wall density analysis was conducted in accordance with the fist principal component and the diagonal wall line is displayed in the new coordinate system; (<b>b</b>) display of the diagonal wall line in the original coordinate system after applying the inverse of the principal component analysis.</p>
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<p>Extracted wall lines of a building block using density analysis.</p>
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<p>Visual comparison of the produced 2D plan and Tehran municipality map in Arc GIS software.</p>
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<p>Displays of the 2D plan and 3D model along with walls between buildings in each block: (<b>a</b>) Drawing the lines separating the buildings in each block on the map; (<b>b</b>) the 3D model of 4 building blocks in SketchUp.</p>
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20 pages, 10906 KiB  
Article
Experimental and LES Study of H2/CH4 Premixed Gas Deflagration Under Different Obstacle Conditions
by Yanan Han, Jianfeng Gao, Yang Wu, Xiaojun Shao and Shuxuan Peng
Appl. Sci. 2024, 14(23), 10843; https://doi.org/10.3390/app142310843 (registering DOI) - 23 Nov 2024
Viewed by 90
Abstract
To study the influence of obstacles on the premixed gas explosion process and provide a theoretical basis for the safe use of fuel and the space configuration within weakly constrained structures, experimental and numerical simulation studies were conducted to investigate the explosion behavior [...] Read more.
To study the influence of obstacles on the premixed gas explosion process and provide a theoretical basis for the safe use of fuel and the space configuration within weakly constrained structures, experimental and numerical simulation studies were conducted to investigate the explosion behavior of H2/CH4 premixed gas under different obstacle conditions. According to the angle and position of obstacles, 12 explosion working conditions were set up, and the flame kinetic behavior under the combined influence was obtained. The results show that increasing the direct contact area between the obstacle and the flame near the ignition source can effectively reduce the explosion effect. The explosion consequence is most serious when the obstacle is located in the middle position of the weakly constrained structure. When the obstacle is close to the vent, the later the flame reaches the vent, the more the explosion pressure peaks, and the explosion impact decreases as the angle of the obstacle decreases. In the numerical simulation, it was also found that when the flame passes through the obstacle near the ignition source, it takes on a special “jellyfish” shape toward the vent. In conclusion, the results of the study are useful for making reasonable assumptions about the location of the ignition source and the presence of obstacles based on the degree of damage to the weakly confined structure caused by the premixed gas explosion. Full article
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<p>Experimental setup diagram.</p>
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<p>Obstacle.</p>
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<p>Arrangement of obstacles in the pipeline.</p>
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<p>Mesh and physical model.</p>
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<p>Mesh-independent verification.</p>
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<p>Comparison of experimental and simulated pressures.</p>
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<p>Flame evolution at 200 mm for obstacles of different angles.</p>
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<p>Flame evolution at 500 mm for obstacles with different angles.</p>
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<p>Flame evolution at 800 mm for obstacles of different angles.</p>
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<p>Pressure changes at the same position for obstacles with different angles.</p>
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<p>Change in flame area over time.</p>
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<p>Flame conditions at peak area for each operating condition.</p>
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<p>Flame velocity–frontal surface position over time.</p>
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<p>Flow field at 200 mm for obstacles of different angles.</p>
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<p>Flow field at 500 mm for obstacles of different angles.</p>
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<p>Flow field at 800 mm for obstacles of different angles.</p>
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16 pages, 974 KiB  
Article
Relations Between Executive Functions and Reading Comprehension: A Study of Fourth-Grade Students with and Without Reading Comprehension Difficulties
by José-Pablo Escobar, Victoria Espinoza and Sofia Balboa
Brain Sci. 2024, 14(12), 1174; https://doi.org/10.3390/brainsci14121174 (registering DOI) - 23 Nov 2024
Viewed by 145
Abstract
Background: The role of non-linguistic factors, such as executive functions, in the reading comprehension process has been analyzed. The present research sought to investigate the relationship between executive functions and reading comprehension. Methods: In an exploratory cross-sectional study, a group of 89 fourth-grade [...] Read more.
Background: The role of non-linguistic factors, such as executive functions, in the reading comprehension process has been analyzed. The present research sought to investigate the relationship between executive functions and reading comprehension. Methods: In an exploratory cross-sectional study, a group of 89 fourth-grade students were evaluated, considering a balanced number of children with and without reading comprehension difficulties. Results: The results indicate that students with reading comprehension difficulties present a lowered profile with respect to both executive functions and reading variables. The path analysis indicates the presence of differences in the variables that explain reading comprehension for both groups. While in the case of students without reading comprehension difficulties, working memory has both a direct and an indirect effect, i.e., through vocabulary, on reading comprehension; in the case of children with reading comprehension difficulties, only cognitive flexibility has a direct impact. In both cases, inhibition has an indirect impact through vocabulary. Conclusions: We reflect on the differentiated role of executive functions according to the level of development of reading skills, highlighting the possibility that some skills may act in a compensatory manner in the presence of general difficulties. The role of vocabulary in the relationship between executive skills and reading is highlighted. Full article
(This article belongs to the Section Developmental Neuroscience)
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<p>Proposed path analysis models: (<b>a</b>) students without reading comprehension difficulties; (<b>b</b>) students with RCD.</p>
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<p>Final model for: (<b>a</b>) students without reading comprehension difficulties; (<b>b</b>) students with RCD.</p>
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21 pages, 19993 KiB  
Article
UAV Visual Object Tracking Based on Spatio-Temporal Context
by Yongxiang He, Chuang Chao, Zhao Zhang, Hongwu Guo and Jianjun Ma
Drones 2024, 8(12), 700; https://doi.org/10.3390/drones8120700 - 22 Nov 2024
Viewed by 262
Abstract
To balance the real-time and robustness of UAV visual tracking on a single CPU, this paper proposes an object tracker based on spatio-temporal context (STCT). STCT integrates the correlation filter and Siamese network into a unified framework and introduces the target’s motion model, [...] Read more.
To balance the real-time and robustness of UAV visual tracking on a single CPU, this paper proposes an object tracker based on spatio-temporal context (STCT). STCT integrates the correlation filter and Siamese network into a unified framework and introduces the target’s motion model, enabling the tracker to adapt to target scale variations and effectively address challenges posed by rapid target motion, etc. Furthermore, a spatio-temporal regularization term based on the dynamic attention mechanism is proposed, and it is introduced into the correlation filter to suppress the aberrance of the response map. The filter solution is provided through the alternating direction method of multipliers (ADMM). In addition, to ensure efficiency, this paper proposes the average maximum response value-related energy (AMRE) for adaptive tracking state evaluation, which considers the time context of the tracking process in STCT. Experimental results show that the proposed STCT tracker can achieve a favorable balance between tracking robustness and real-time performance for UAV object tracking while running at ∼38 frames/s on a low-cost CPU. Full article
23 pages, 1715 KiB  
Article
Research on Particle Swarm Optimization-Based UAV Path Planning Technology in Urban Airspace
by Qing Cheng, Zhengyuan Zhang, Yunfei Du and Yandong Li
Drones 2024, 8(12), 701; https://doi.org/10.3390/drones8120701 - 22 Nov 2024
Viewed by 332
Abstract
Urban airspace, characterized by densely packed high-rise buildings, presents complex and dynamically changing environmental conditions. It brings potential risks to UAV flights, such as the risk of collision and accidental entry into no-fly zones. Currently, mainstream path planning algorithms, including the PSO algorithm, [...] Read more.
Urban airspace, characterized by densely packed high-rise buildings, presents complex and dynamically changing environmental conditions. It brings potential risks to UAV flights, such as the risk of collision and accidental entry into no-fly zones. Currently, mainstream path planning algorithms, including the PSO algorithm, have issues such as a tendency to converge to local optimal solutions and poor stability. In this study, an improved particle swarm optimization algorithm (LGPSO) is proposed to address these problems. This algorithm redefines path planning as an optimization problem, constructing a cost function that incorporates safety requirements and operational constraints for UAVs. Stochastic inertia weights are added to balance the global and local search capabilities. In addition, asymmetric learning factors are introduced to direct the particles more precisely towards the optimal position. An enhanced Lévy flight strategy is used to improve the exploration ability, and a greedy algorithm evaluation strategy is designed to evaluate the path more quickly. The configuration space is efficiently searched using the corresponding particle positions and UAV parameters. The experiments, which involved mapping complex urban environments with 3D modeling tools, were carried out by simulations in MATLAB R2023b to assess their algorithmic performance. The results show that the LGPSO algorithm improves by 23% over the classical PSO algorithm and 18% over the GAPSO algorithm in the optimal path distance under guaranteed security. The LGPSO algorithm shows significant improvements in stability and route planning, providing an effective solution for UAV path planning in complex environments. Full article
13 pages, 5108 KiB  
Article
Investigating Antibacterial Activity of Copper-Silver-Cerium Alloys
by Chen-Ying Su, Satoshi Kameoka, Yu-Cheng Tsai, Qiao-Ping Cheng, Shu-Hsuan Wu, Yi-Xin Liu and Hsu-Wei Fang
Metals 2024, 14(12), 1323; https://doi.org/10.3390/met14121323 - 22 Nov 2024
Viewed by 250
Abstract
Antibacterial alloys are widely applied to reduce the incidence of medical-implant-associated infection. Copper (Cu) and silver (Ag) are commonly used in antibacterial alloys; however, rare earth elements, such as Cerium (Ce), are now gaining attention because their low trace is sufficient for killing [...] Read more.
Antibacterial alloys are widely applied to reduce the incidence of medical-implant-associated infection. Copper (Cu) and silver (Ag) are commonly used in antibacterial alloys; however, rare earth elements, such as Cerium (Ce), are now gaining attention because their low trace is sufficient for killing bacteria. Accordingly, the antibacterial activity of Copper48-Silver48-Cerium4 (CuAgCe4) alloys with different crystalline structures was investigated. The immersion approach was employed for alloys cultured with Escherichia coli, and a direct contact method was used for alloys cultured with Staphylococcus aureus. Surface morphology was observed when alloys were made, and the crystalline structures of alloys were examined before and after being cultured with bacteria. The immersion method revealed that all the CuAgCe4 alloy samples could inhibit the growth of Escherichia coli, and the crystallized structures were distorted after the alloys were cultured with bacteria. Conversely, the direct contact approach showed the crystalline structures of CuAgCe4 alloys remained unchanged after the culture with Staphylococcus aureus, thereby indicating that the antibacterial activity did not correspond to the crystalline structures. Despite the lack of clarity surrounding the possible antibacterial mechanisms of CuAgCe4 alloy, the current findings demonstrate the potential antibacterial effects of CuAgCe4 alloy in medical implants. Full article
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<p>SEM micrographs representing the dark and light sides of amorphous and various crystallized CuAgCe<sub>4</sub> ribbons. The scale bar shows 50 μm with 1000× magnification.</p>
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<p>XRD results of (<b>a</b>) amorphous, (<b>b</b>) semi-crystallization, and crystallization of CuAgCe<sub>4</sub> alloy ribbons at (<b>c</b>) 250 °C and (<b>d</b>) 450 °C.</p>
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<p>XRD results of CuAgCe<sub>4</sub> ribbons before and after culture with <span class="html-italic">E. coli</span>. (<b>a</b>) amorphous, (<b>b</b>) semi-crystallization, and crystallization at (<b>c</b>) 250 °C, and (<b>d</b>) 450 °C.</p>
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<p>Plots showing the concentrations of Cu and Ce ions in the mixture.</p>
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<p>XRD results for CuAgCe<sub>4</sub> alloy ribbons before and after culture with <span class="html-italic">S. aureus</span> (<b>a</b>) amorphous, (<b>b</b>) semi-crystallization, and crystallization at (<b>c</b>) 250 °C and (<b>d</b>) 450 °C.</p>
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17 pages, 1215 KiB  
Article
Spinal Cord Stimulation for Spinal Cord Injury-Related Pain: A Pilot Study
by Alexander Alamri, Meredith MacDonald, Alaa Al-Mohammad, Lucia Ricciardi, Michael G. Hart and Erlick A. Pereira
Brain Sci. 2024, 14(12), 1173; https://doi.org/10.3390/brainsci14121173 - 22 Nov 2024
Viewed by 235
Abstract
Background: Spinal cord stimulation (SCS) has emerged as an effective treatment for managing chronic pain that is unresponsive to traditional therapies. While SCS is well documented for conditions like failed back surgery syndrome (FBSS) and complex regional pain syndrome (CRPS), its effectiveness in [...] Read more.
Background: Spinal cord stimulation (SCS) has emerged as an effective treatment for managing chronic pain that is unresponsive to traditional therapies. While SCS is well documented for conditions like failed back surgery syndrome (FBSS) and complex regional pain syndrome (CRPS), its effectiveness in managing pain related to spinal cord injuries (SCI) is less studied. This study aims to assess the efficacy of SCS in alleviating SCI-related pain and improving patients’ quality of life, filling a gap in the existing literature. Methods: This cohort study included 15 adult patients with traumatic and non-traumatic SCIs, treated between 2016 and 2022. Patients received SCS implants after either a trial or direct implantation. Pain levels were assessed using visual analog scale (VAS) scores, while quality of life was evaluated using the EuroQol five-dimensional (EQ-5D) scale. The SCS devices were implanted at different spinal levels, with various stimulation protocols applied, including high-frequency stimulation (10 kHz). Results: In patients with traumatic SCI, the mean VAS score decreased from 8.6 to 4.5, with 71% reporting more than 50% pain relief. Non-traumatic SCI patients experienced a reduction from 8.5 to 2.5, with all showing more than 50% pain relief. EQ-5D scores improved in both groups. A 49% reduction in pain medication usage was also observed, though one patient required revision surgery due to an adverse event. Conclusions: SCS significantly reduces pain and improves quality of life for SCI patients, particularly with high-frequency protocols. While promising, further research is needed to optimize patient selection and stimulation parameters for better long-term outcomes. Full article
(This article belongs to the Section Neuroscience of Pain)
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