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31 pages, 1516 KiB  
Systematic Review
Systematic Review of Battery Life Cycle Management: A Framework for European Regulation Compliance
by Mattia Gianvincenzi, Marco Marconi, Enrico Maria Mosconi, Claudio Favi and Francesco Tola
Sustainability 2024, 16(22), 10026; https://doi.org/10.3390/su162210026 (registering DOI) - 17 Nov 2024
Abstract
Batteries are fundamental to the sustainable energy transition, playing a key role in both powering devices and storing renewable energy. They are also essential in the shift towards greener automotive solutions. However, battery life cycles face significant environmental challenges, including the harmful impacts [...] Read more.
Batteries are fundamental to the sustainable energy transition, playing a key role in both powering devices and storing renewable energy. They are also essential in the shift towards greener automotive solutions. However, battery life cycles face significant environmental challenges, including the harmful impacts of extraction and refining processes and inefficiencies in recycling. Both researchers and policymakers are striving to improve battery technologies through a combination of bottom–up innovations and top–down regulations. This study aims to bridge the gap between scientific advancements and policy frameworks by conducting a Systematic Literature Review of 177 papers. The review identifies innovative solutions to mitigate challenges across the battery life cycle, from production to disposal. A key outcome of this work is the creation of the life cycle management framework, designed to align scientific developments with regulatory strategies, providing an integrated approach to address life cycle challenges. This framework offers a comprehensive tool to guide stakeholders in fostering a sustainable battery ecosystem, contributing to the objectives set by the European Commission’s battery regulation. Full article
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<p>PRISMA2020 Flow Diagram.</p>
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<p>Publication year of the selected papers.</p>
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<p>Flow diagram of the life cycle management framework (Superscript numbers in the manufacturing phase correspond to specific solution sets) [<a href="#B8-sustainability-16-10026" class="html-bibr">8</a>,<a href="#B12-sustainability-16-10026" class="html-bibr">12</a>,<a href="#B14-sustainability-16-10026" class="html-bibr">14</a>,<a href="#B24-sustainability-16-10026" class="html-bibr">24</a>,<a href="#B25-sustainability-16-10026" class="html-bibr">25</a>,<a href="#B30-sustainability-16-10026" class="html-bibr">30</a>,<a href="#B35-sustainability-16-10026" class="html-bibr">35</a>,<a href="#B36-sustainability-16-10026" class="html-bibr">36</a>,<a href="#B39-sustainability-16-10026" class="html-bibr">39</a>,<a href="#B43-sustainability-16-10026" class="html-bibr">43</a>,<a href="#B44-sustainability-16-10026" class="html-bibr">44</a>,<a href="#B45-sustainability-16-10026" class="html-bibr">45</a>,<a href="#B46-sustainability-16-10026" class="html-bibr">46</a>,<a href="#B47-sustainability-16-10026" class="html-bibr">47</a>,<a href="#B48-sustainability-16-10026" class="html-bibr">48</a>,<a href="#B49-sustainability-16-10026" class="html-bibr">49</a>,<a href="#B50-sustainability-16-10026" class="html-bibr">50</a>,<a href="#B51-sustainability-16-10026" class="html-bibr">51</a>,<a href="#B52-sustainability-16-10026" class="html-bibr">52</a>,<a href="#B58-sustainability-16-10026" class="html-bibr">58</a>,<a href="#B61-sustainability-16-10026" class="html-bibr">61</a>,<a href="#B62-sustainability-16-10026" class="html-bibr">62</a>,<a href="#B63-sustainability-16-10026" class="html-bibr">63</a>,<a href="#B64-sustainability-16-10026" class="html-bibr">64</a>,<a href="#B65-sustainability-16-10026" class="html-bibr">65</a>,<a href="#B66-sustainability-16-10026" class="html-bibr">66</a>,<a href="#B67-sustainability-16-10026" class="html-bibr">67</a>,<a href="#B68-sustainability-16-10026" class="html-bibr">68</a>,<a href="#B69-sustainability-16-10026" class="html-bibr">69</a>,<a href="#B75-sustainability-16-10026" class="html-bibr">75</a>,<a href="#B81-sustainability-16-10026" class="html-bibr">81</a>,<a href="#B82-sustainability-16-10026" class="html-bibr">82</a>,<a href="#B83-sustainability-16-10026" class="html-bibr">83</a>,<a href="#B84-sustainability-16-10026" class="html-bibr">84</a>,<a href="#B85-sustainability-16-10026" class="html-bibr">85</a>,<a href="#B86-sustainability-16-10026" class="html-bibr">86</a>,<a href="#B87-sustainability-16-10026" class="html-bibr">87</a>,<a href="#B88-sustainability-16-10026" class="html-bibr">88</a>,<a href="#B89-sustainability-16-10026" class="html-bibr">89</a>,<a href="#B90-sustainability-16-10026" class="html-bibr">90</a>,<a href="#B91-sustainability-16-10026" class="html-bibr">91</a>,<a href="#B92-sustainability-16-10026" class="html-bibr">92</a>,<a href="#B93-sustainability-16-10026" class="html-bibr">93</a>,<a href="#B94-sustainability-16-10026" class="html-bibr">94</a>,<a href="#B95-sustainability-16-10026" class="html-bibr">95</a>,<a href="#B96-sustainability-16-10026" class="html-bibr">96</a>,<a href="#B100-sustainability-16-10026" class="html-bibr">100</a>,<a href="#B101-sustainability-16-10026" class="html-bibr">101</a>,<a href="#B102-sustainability-16-10026" class="html-bibr">102</a>,<a href="#B103-sustainability-16-10026" class="html-bibr">103</a>,<a href="#B104-sustainability-16-10026" class="html-bibr">104</a>,<a href="#B105-sustainability-16-10026" class="html-bibr">105</a>,<a href="#B106-sustainability-16-10026" class="html-bibr">106</a>,<a href="#B107-sustainability-16-10026" class="html-bibr">107</a>,<a href="#B111-sustainability-16-10026" class="html-bibr">111</a>,<a href="#B112-sustainability-16-10026" class="html-bibr">112</a>,<a href="#B113-sustainability-16-10026" class="html-bibr">113</a>,<a href="#B114-sustainability-16-10026" class="html-bibr">114</a>,<a href="#B115-sustainability-16-10026" class="html-bibr">115</a>,<a href="#B116-sustainability-16-10026" class="html-bibr">116</a>,<a href="#B117-sustainability-16-10026" class="html-bibr">117</a>,<a href="#B118-sustainability-16-10026" class="html-bibr">118</a>,<a href="#B119-sustainability-16-10026" class="html-bibr">119</a>,<a href="#B120-sustainability-16-10026" class="html-bibr">120</a>,<a href="#B121-sustainability-16-10026" class="html-bibr">121</a>,<a href="#B125-sustainability-16-10026" class="html-bibr">125</a>,<a href="#B126-sustainability-16-10026" class="html-bibr">126</a>,<a href="#B127-sustainability-16-10026" class="html-bibr">127</a>,<a href="#B128-sustainability-16-10026" class="html-bibr">128</a>,<a href="#B129-sustainability-16-10026" class="html-bibr">129</a>,<a href="#B134-sustainability-16-10026" class="html-bibr">134</a>,<a href="#B136-sustainability-16-10026" class="html-bibr">136</a>,<a href="#B139-sustainability-16-10026" class="html-bibr">139</a>,<a href="#B140-sustainability-16-10026" class="html-bibr">140</a>,<a href="#B141-sustainability-16-10026" class="html-bibr">141</a>,<a href="#B142-sustainability-16-10026" class="html-bibr">142</a>,<a href="#B152-sustainability-16-10026" class="html-bibr">152</a>,<a href="#B155-sustainability-16-10026" class="html-bibr">155</a>,<a href="#B158-sustainability-16-10026" class="html-bibr">158</a>,<a href="#B159-sustainability-16-10026" class="html-bibr">159</a>,<a href="#B160-sustainability-16-10026" class="html-bibr">160</a>,<a href="#B161-sustainability-16-10026" class="html-bibr">161</a>,<a href="#B167-sustainability-16-10026" class="html-bibr">167</a>,<a href="#B172-sustainability-16-10026" class="html-bibr">172</a>,<a href="#B173-sustainability-16-10026" class="html-bibr">173</a>,<a href="#B174-sustainability-16-10026" class="html-bibr">174</a>,<a href="#B175-sustainability-16-10026" class="html-bibr">175</a>,<a href="#B180-sustainability-16-10026" class="html-bibr">180</a>,<a href="#B181-sustainability-16-10026" class="html-bibr">181</a>].</p>
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26 pages, 1244 KiB  
Article
Privacy-Preserving Detection of Tampered Radio-Frequency Transmissions Utilizing Federated Learning in LoRa Networks
by Nurettin Selcuk Senol, Mohamed Baza, Amar Rasheed and Maazen Alsabaan
Sensors 2024, 24(22), 7336; https://doi.org/10.3390/s24227336 (registering DOI) - 17 Nov 2024
Abstract
LoRa networks, widely adopted for low-power, long-range communication in IoT applications, face critical security concerns as radio-frequency transmissions are increasingly vulnerable to tampering. This paper addresses the dual challenges of privacy-preserving detection of tampered transmissions and the identification of unknown attacks in LoRa-based [...] Read more.
LoRa networks, widely adopted for low-power, long-range communication in IoT applications, face critical security concerns as radio-frequency transmissions are increasingly vulnerable to tampering. This paper addresses the dual challenges of privacy-preserving detection of tampered transmissions and the identification of unknown attacks in LoRa-based IoT networks. Leveraging Federated Learning (FL), our approach enables the detection of tampered RF transmissions while safeguarding sensitive IoT data, as FL allows model training on distributed devices without sharing raw data. We evaluated the performance of multiple FL-enabled anomaly-detection algorithms, including Convolutional Autoencoder Federated Learning (CAE-FL), Isolation Forest Federated Learning (IF-FL), One-Class Support Vector Machine Federated Learning (OCSVM-FL), Local Outlier Factor Federated Learning (LOF-FL), and K-Means Federated Learning (K-Means-FL). Using metrics such as accuracy, precision, recall, and F1-score, CAE-FL emerged as the top performer, achieving 97.27% accuracy and a balanced precision, recall, and F1-score of 0.97, with IF-FL close behind at 96.84% accuracy. Competitive performance from OCSVM-FL and LOF-FL, along with the comparable results of K-Means-FL, highlighted the robustness of clustering-based detection methods in this context. Visual analyses using confusion matrices and ROC curves provided further insights into each model’s effectiveness in detecting tampered signals. This research underscores the capability of federated learning to enhance privacy and security in anomaly detection for LoRa networks, even against unknown attacks, marking a significant advancement in securing IoT communications in sensitive applications. Full article
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<p>Federated learning architecture.</p>
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<p>One class SVM algorithm with FL client one results.</p>
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<p>One class SVM algorithm with FL client two results.</p>
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<p>One class SVM algorithm with FL client three results.</p>
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<p>One class SVM algorithm with FL client four results.</p>
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<p>One class SVM algorithm with FL client five results.</p>
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<p>One class SVM algorithm with FL client five results.</p>
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<p>One class SVM algorithm with FL client five results.</p>
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<p>Isolation Forest with FL data across clients.</p>
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<p>LOF client data distribution graph.</p>
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<p>K-Means algorithm with FL client results.</p>
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<p>Average time calculation between algorithms.</p>
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<p>AUC curves for the algorithms (<b>a</b>) OCSVM-FL, (<b>b</b>) CAE-FL, (<b>c</b>) IF-FL, (<b>d</b>) LOF-FL, and (<b>e</b>) K-Means-FL.</p>
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<p>The performance of five anomaly-detection methods in classifying normal and anomalous data is displayed in confusion matrices. These algorithms are (<b>a</b>) OCSVM-FL, (<b>b</b>) CAE-FL, (<b>c</b>) IF-FL, (<b>d</b>) LOF-FL, and (<b>e</b>) K-Means-FL. Lighter hues indicate misclassifications (false positives and false negatives), while darker hues indicate accurate classifications (true positives and true negatives).</p>
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16 pages, 7121 KiB  
Article
Experimental Aerodynamics of a Small Fixed-Wing Unmanned Aerial Vehicle Coated with Bio-Inspired Microfibers Under Static and Dynamic Stall
by Dioser Santos, Guilherme D. Fernandes, Ali Doosttalab and Victor Maldonado
Aerospace 2024, 11(11), 947; https://doi.org/10.3390/aerospace11110947 (registering DOI) - 17 Nov 2024
Viewed by 108
Abstract
A passive flow control technique in the form of microfiber coatings with a diverging pillar cross-section area was applied to the wing suction surface of a small tailless unmanned aerial vehicle (UAV). The coatings are inspired from ‘gecko feet’ surfaces, and their impact [...] Read more.
A passive flow control technique in the form of microfiber coatings with a diverging pillar cross-section area was applied to the wing suction surface of a small tailless unmanned aerial vehicle (UAV). The coatings are inspired from ‘gecko feet’ surfaces, and their impact on steady and unsteady aerodynamics is assessed through wind tunnel testing. Angles of attack from −2° to 17° were used for static experiments, and for some cases, the elevon control surface was deflected to study its effectiveness. In forced oscillation, various combinations of mean angle of attack, frequency and amplitude were explored. The aerodynamic coefficients were calculated from load cell measurements for experimental variables such as microfiber size, the region of the wing coated with microfibers, Reynolds number and angle of attack. Microfibers with a 140 µm pillar height reduce drag by a maximum of 24.7% in a high-lift condition and cruise regime, while 70 µm microfibers work best in the stall flow regime, reducing the drag by 24.2% for the same high-lift condition. Elevon deflection experiments showed that pitch moment authority is significantly improved near stall when microfibers cover the control surface and upstream, with an increase in CM magnitude of up to 22.4%. Dynamic experiments showed that microfibers marginally increase dynamic damping in pitch, improving load factor production in response to control surface actuation at low angles of attack, but reducing it at higher angles. In general, the microfiber pillars are within the laminar boundary layer, and they create a periodic slip condition on the top surface of the pillars, which increases the near-wall momentum over the wing surface. This mechanism is particularly effective in mitigating flow separation at high angles of attack, reducing pressure drag and restoring pitching moment authority provided by control surfaces. Full article
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Figure 1
<p>(<b>A</b>) Concept of a shark skin denticle, (<b>B</b>) close perspective of bio-inspired microfibers, scale bar ≈ 100 µm, (<b>C</b>) surface coating from top, and (<b>D</b>) flow mechanism within the fibers and outside. Adapted from [<a href="#B26-aerospace-11-00947" class="html-bibr">26</a>].</p>
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<p>Planform drawing of UAV model with microfiber coverage (dimensions in mm).</p>
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<p>(<b>a</b>) Microfiber schematic (dimensions in µm); (<b>b</b>) wing covered with microfiber coating (zoomed-in picture adapted from Doosttalab et al. [<a href="#B26-aerospace-11-00947" class="html-bibr">26</a>]).</p>
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<p>Wind tunnel model setup of the ‘high-speed, long-range’ (HSLR) variant of the Switchblade UAV.</p>
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<p>Lift coefficients, <span class="html-italic">C<sub>L</sub></span> as a function of angle of attack, <span class="html-italic">α</span>.</p>
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<p>Drag polars; lift coefficients, <span class="html-italic">C<sub>L</sub></span> as a function of drag coefficients, <span class="html-italic">C<sub>D</sub></span>.</p>
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<p>Lift-to-drag ratio, <span class="html-italic">L</span>/<span class="html-italic">D</span> as a function of angle of attack, <span class="html-italic">α</span>.</p>
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<p>High angle of attack, <span class="html-italic">α</span> lift-to-drag ratio, <span class="html-italic">L</span>/<span class="html-italic">D</span> enhancement.</p>
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<p>Time-averaged velocity over a curved APG section representative of an airfoil in turbulent flow with a freestream velocity of 30 m/s.</p>
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<p>Elevon deflection performance: pitching moment coefficient, <span class="html-italic">C<sub>M</sub></span> as a function of elevon deflection angle, <span class="html-italic">δ<sub>e</sub></span> for the baseline and micropillar cases.</p>
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<p>Dynamic pitch coefficients for different surface cases and wing coverage: (<b>a</b>) <span class="html-italic">C<sub>A</sub></span>; (<b>b</b>) <span class="html-italic">C<sub>N</sub></span>; (<b>c</b>) <span class="html-italic">C<sub>M</sub></span>. The black arrow indicates the direction of the pitch up maneuver.</p>
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<p>Dynamic derivatives in pitch: <math display="inline"><semantics> <mrow> <msub> <mi>C</mi> <mrow> <msub> <mi>A</mi> <mi>q</mi> </msub> </mrow> </msub> </mrow> </semantics></math>; <math display="inline"><semantics> <mrow> <msub> <mi>C</mi> <mrow> <msub> <mi>M</mi> <mi>q</mi> </msub> </mrow> </msub> </mrow> </semantics></math>; <math display="inline"><semantics> <mrow> <msub> <mi>C</mi> <mrow> <msub> <mi>M</mi> <mi>q</mi> </msub> </mrow> </msub> </mrow> </semantics></math> as a function of mean angle of attack.</p>
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13 pages, 2763 KiB  
Article
Numerical Simulation Study of Bearing Characteristics of Large-Diameter Flexible Piles Under Complex Loads
by Xueying Yang, Weiming Gong and Qian Yin
Buildings 2024, 14(11), 3651; https://doi.org/10.3390/buildings14113651 (registering DOI) - 17 Nov 2024
Viewed by 148
Abstract
The majority of the existing calculation methods for determining the ultimate bearing capacity of steel-pipe piles using Chinese criteria are designed for piles with diameters smaller than 2 m. To investigate the bearing capacity of flexible steel-pipe piles with diameters larger than 2 [...] Read more.
The majority of the existing calculation methods for determining the ultimate bearing capacity of steel-pipe piles using Chinese criteria are designed for piles with diameters smaller than 2 m. To investigate the bearing capacity of flexible steel-pipe piles with diameters larger than 2 m under combined loading conditions, reveal nonlinear interactions between vertical and horizontal loads, and propose bearing capacity envelopes, in this paper, a numerical method was used to study the bearing capacity of a flexible pile with a diameter of 2.8 m and an embedment length of 72 m under vertical and horizontal loading conditions. First, a numerical model was developed and calibrated using field test results. Then, the effects of vertical pressure on horizontal capacity and lateral force on vertical capacity and uplift capacity of the pile were analyzed. The results indicate that vertical pressure at the top of the pile can nonlinearly reduce its horizontal capacity, but this pressure initially has a slight positive effect on the horizontal bearing capacity before causing a rapid decrease. Conversely, horizontal force negatively impacts both the compressive and uplift bearing capacities of the pile. Finally, depending on the above results, bearing capacity envelopes for piles subjected to vertical and horizontal loads were proposed. Full article
(This article belongs to the Special Issue Trends and Prospects in Civil Engineering Structures)
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<p>Diagram of the tested pile.</p>
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<p>Diagrams of the numerical simulation: (<b>a</b>) the pile and (<b>b</b>) the soil.</p>
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<p>Comparison of results between tests and simulations: (<b>a</b>) horizontal load–displacement curves and (<b>b</b>) vertical load–displacement curves.</p>
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<p>The horizontal load–displacement curves of a pile at the mudline under different vertical pressures.</p>
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<p>The displacement of a pile along depth under different vertical pressures: (<b>a</b>) <span class="html-italic">V</span> = 1.0 MN, (<b>b</b>) <span class="html-italic">V</span> = 3.0 MN, and (<b>c</b>) <span class="html-italic">V</span> = 5.0 MN.</p>
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<p>The bending moment along depth under different vertical pressures: (<b>a</b>) <span class="html-italic">V</span> = 1.0 MN, (<b>b</b>) <span class="html-italic">V</span> = 3.0 MN, and (<b>c</b>) <span class="html-italic">V</span> = 5 MN.</p>
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<p>The vertical load–settlement curves of a pile at mudline under different horizontal loads.</p>
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<p>The horizontal displacement along with depth under different horizontal loads: (<b>a</b>) <span class="html-italic">H</span> = 0.1 MN, (<b>b</b>) <span class="html-italic">H</span> = 0.3 MN, and (<b>c</b>) <span class="html-italic">H</span> = 0.5 MN.</p>
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<p>The (<b>a</b>) uplift load–vertical displacement and (<b>b</b>) uplift load–horizontal displacement curves of a pile at mudline at different lateral loads.</p>
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<p>Bearing capacity envelopes of piles under <span class="html-italic">V</span>–<span class="html-italic">H</span> loads.</p>
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18 pages, 2525 KiB  
Article
Identifying Herbal Candidates and Active Ingredients Against Postmenopausal Osteoporosis Using Biased Random Walk on a Multiscale Network
by Boyun Jang, Youngsoo Kim, Jungbin Song, Young-Woo Kim and Won-Yung Lee
Int. J. Mol. Sci. 2024, 25(22), 12322; https://doi.org/10.3390/ijms252212322 (registering DOI) - 16 Nov 2024
Viewed by 371
Abstract
Postmenopausal osteoporosis is a major global health concern, particularly affecting aging women, and necessitates innovative treatment options. Herbal medicine, with its multi-compound, multi-target characteristics, offers a promising approach for complex diseases. In this study, we applied multiscale network and random walk-based analyses to [...] Read more.
Postmenopausal osteoporosis is a major global health concern, particularly affecting aging women, and necessitates innovative treatment options. Herbal medicine, with its multi-compound, multi-target characteristics, offers a promising approach for complex diseases. In this study, we applied multiscale network and random walk-based analyses to identify candidate herbs and their active ingredients for postmenopausal osteoporosis, focusing on their underlying mechanisms. A dataset of medicinal herbs, their active ingredients, and protein targets was compiled, and diffusion profiles were calculated to assess the propagation effects. Through correlation analysis, we prioritized herbs based on their relevance to osteoporosis, identifying the top candidates like Benincasae Semen, Glehniae Radix, Corydalis Tuber, and Houttuyniae Herba. Gene Set Enrichment Analysis (GSEA) revealed that the 49 core protein targets of these herbs were significantly associated with pathways related to inflammation, osteoclast differentiation, and estrogen metabolism. Notably, compounds such as falcarindiol from Glehniae Radix and tetrahydrocoptisine from Corydalis Tuber—previously unstudied for osteoporosis—were predicted to interact with inflammation-related proteins, including IL6, IL1B, and TNF, affecting key biological processes like apoptosis and cell proliferation. This study advances the understanding of herbal therapies for osteoporosis and offers a framework for discovering novel therapeutic agents. Full article
16 pages, 5705 KiB  
Article
Performance and Characterization of Additively Manufactured BST Varactor Enhanced by Photonic Thermal Processing
by Carlos Molina, Ugur Guneroglu, Adnan Zaman, Liguan Li and Jing Wang
Crystals 2024, 14(11), 990; https://doi.org/10.3390/cryst14110990 (registering DOI) - 16 Nov 2024
Viewed by 354
Abstract
The demand for reconfigurable devices for emerging RF and microwave applications has been growing in recent years, with additive manufacturing and photonic thermal treatment presenting new possibilities to supplement conventional fabrication processes to meet this demand. In this paper, we present the realization [...] Read more.
The demand for reconfigurable devices for emerging RF and microwave applications has been growing in recent years, with additive manufacturing and photonic thermal treatment presenting new possibilities to supplement conventional fabrication processes to meet this demand. In this paper, we present the realization and analysis of barium–strontium–titanate-(Ba0.5Sr0.5TiO3)-based ferroelectric variable capacitors (varactors), which are additively deposited on top of conventionally fabricated interdigitated capacitors and enhanced by photonic thermal processing. The ferroelectric solution with suspended BST nanoparticles is deposited on the device using an ambient spray pyrolysis method and is sintered at low temperatures using photonic thermal processing by leveraging the high surface-to-volume ratio of the BST nanoparticles. The deposited film is qualitatively characterized using SEM imaging and XRD measurements, while the varactor devices are quantitatively characterized by using high-frequency RF measurements from 300 MHz to 10 GHz under an applied DC bias voltage ranging from 0 V to 50 V. We observe a maximum tunability of 60.6% at 1 GHz under an applied electric field of 25 kV/mm (25 V/μm). These results show promise for the implementation of photonic thermal processing and additive manufacturing as a means to integrate reconfigurable ferroelectric varactors in flexible electronics or tightly packaged on-chip applications, where a limited thermal budget hinders the conventional thermal processing. Full article
(This article belongs to the Special Issue Ceramics: Processes, Microstructures, and Properties)
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Figure 1
<p>(<b>a</b>) Diagram of IDC device fabricated with key dimensions labeled; (<b>b</b>) diagram depicting how BST is deposited to only cover the finger area; (<b>c</b>) microscope image of fabricated electrode layer; (<b>d</b>) SEM image of a device after BST deposition.</p>
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<p>Diagram of ambient spray pyrolysis setup.</p>
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<p>(<b>a</b>) Magnitude of the reflection coefficient (<span class="html-italic">S</span><sub>11</sub>) of the BST IDC device under a varied bias voltage (0–50 V), and (<b>b</b>) phase of the reflection coefficient of the BST IDC device under a varied bias voltage (0–50 V).</p>
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<p>(<b>a</b>) Real part of the calculated <span class="html-italic">Z</span><sub>11</sub> (impedance) for different bias conditions, (<b>b</b>) imaginary part of the calculated <span class="html-italic">Z</span><sub>11</sub> (reactance) for different bias conditions, (<b>c</b>) calculated capacitance for the IDC device under different bias conditions, and (<b>d</b>) zoomed-in region of the calculated capacitance versus the frequency below 3 GHz.</p>
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<p>(<b>a</b>) Real part of the calculated <span class="html-italic">Z</span><sub>11</sub> (impedance) for different bias conditions, (<b>b</b>) imaginary part of the calculated <span class="html-italic">Z</span><sub>11</sub> (reactance) for different bias conditions, (<b>c</b>) calculated capacitance for the IDC device under different bias conditions, and (<b>d</b>) zoomed-in region of the calculated capacitance versus the frequency below 3 GHz.</p>
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<p>(<b>a</b>) Tunability vs. frequency of a measured IDC device at various bias voltages, and (<b>b</b>) zoomed-in tunability vs. frequency for a reduced frequency range up to 3 GHz, over which the tunability exhibits quasi-constant values.</p>
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<p>(<b>a</b>) Graph of the derived dielectric constant, and (<b>b</b>) zoomed-in dielectric constant graph.</p>
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<p>Calculated <span class="html-italic">Q</span> Factor of the IDC device as a function of frequency under various bias voltages.</p>
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<p>(<b>a</b>) Calculated loss tangent vs. frequency at a varied bias voltage (0–50 V), and (<b>b</b>) zoomed-in loss tangent vs. frequency at a reduced frequency range up to 3 GHz under a varied bias voltage (0–50 V).</p>
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<p>SEM images of the BST film deposited on the IDC device at different magnifications: (<b>a</b>) 240× magnification, (<b>b</b>) 1000× magnification, (<b>c</b>) 4000× magnification, and (<b>d</b>) 8000× magnification.</p>
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<p>SEM images of the BST film deposited on the IDC device at different magnifications: (<b>a</b>) 240× magnification, (<b>b</b>) 1000× magnification, (<b>c</b>) 4000× magnification, and (<b>d</b>) 8000× magnification.</p>
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<p>(<b>a</b>) Full span two-theta XRD scan of the BST film after the photonic thermal processing (unlabeled peaks correspond to Kβ), and (<b>b</b>) a comparison of XRD responses of as-deposited and thermally processed BST films.</p>
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<p>(<b>a</b>) Full span two-theta XRD scan of the BST film after the photonic thermal processing (unlabeled peaks correspond to Kβ), and (<b>b</b>) a comparison of XRD responses of as-deposited and thermally processed BST films.</p>
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18 pages, 4692 KiB  
Article
The Synergistic Mechanism of Chelidonium majus Alkaloids on Melanoma Treatment via a Multi-Strategy Insight
by Peng Chen, Xin-Ye Ji, Jian-Ting Feng, Xiao-Qin Wang and Bo Zhang
Molecules 2024, 29(22), 5412; https://doi.org/10.3390/molecules29225412 (registering DOI) - 16 Nov 2024
Viewed by 226
Abstract
Melanoma represents a formidable challenge in dermatological oncology due to its resistance to conventional treatments. The Celandine Alkali Injection Formula (CAIF) offers benefits on clinical internal medicine treatments, within which chelidonine and tetrandrine are recognized as potential quality markers. However, their synergistic mechanisms [...] Read more.
Melanoma represents a formidable challenge in dermatological oncology due to its resistance to conventional treatments. The Celandine Alkali Injection Formula (CAIF) offers benefits on clinical internal medicine treatments, within which chelidonine and tetrandrine are recognized as potential quality markers. However, their synergistic mechanisms facilitating their anti-melanoma action remain unveiled. This study embarked on an exploration of CAIF’s therapeutic potential through a multifaceted research design, integrating system pharmacological predictions with empirical molecular biological evaluations. The dual application of chelidonine and tetrandrine within CAIF exhibited a pronounced inhibitory effect on the proliferation of B16F10 cells, surpassing the effectiveness of individual compound administration. Computational predictions identified the top 50 targets, involved in key signaling pathways including cell cycle regulation, and melanogenesis. RNA sequencing further elucidated that the combinatory treatment modulated a broader spectrum of differentially expressed genes, implicating crucial biological processes including cell differentiation, and tyrosinase metabolism. The combination markedly enhanced melanogenesis and apoptotic indices, arrested cell cycle progression, and fostered cellular differentiation. Notably, chelidonine additionally curtailed the migratory capacity of B16F10 cells. Our findings underscore the therapeutic potential of chelidonine and tetrandrine, key components of CAIF, in effectively combating melanoma by targeting cell proliferation, migration, differentiation, and melanogenesis. Full article
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<p>Flowchart of present study <span class="html-italic">in silico</span>, <span class="html-italic">in vivo</span>, and <span class="html-italic">in vitro</span>.</p>
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<p>The number of potential targets for chelidonine and tetrandrine. (<b>A</b>) shows the structures of chelidonine and tetrandrine. (<b>B</b>) shows the number of targets predicted by CHD and TED, where the numbers inside the parentheses are the number of genes eligible for screening. (<b>C</b>) shows the potential targets of TED and CHD action. The circle represents the target protein. The darker the color, the larger the diameter of the circle, which represents a greater degree value. (<b>D</b>) indicates in the top 50 targets of the PPI network and targets–pathways network. (<b>E</b>) Top 50 targets of KEGG pathway enrichment analysis.</p>
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<p>Chelidonine and tetrandrine inhibited B16F10 cells and tumor growth. (<b>A</b>) shows that cells were treated with different concentrations of CHD and TED. Fixed 8 μmol/L of TED and different concentrations of CHD (0, 1.4, 2.8, 5.6, 11.2 μmol/L) on B16F10 cells for 24 h. (<b>B</b>) shows 8 μmol/L TED, and 5.6 μmol/L on B16F10 cells. (<b>C</b>) shows the melanin content on the B16F10 cell was detected. (<b>D</b>) shows the treatment in the mice’s body after inoculating the tumor. Experiments were divided into three groups: the model group, the individually administered group with different concentrations of CHD, and the co-treatment group. (<b>E</b>–<b>G</b>) show that the tumor was removed from the mice’s bodies with varying doses of the two compounds, and tumor volume and size were measured. ** <span class="html-italic">p</span> &lt; 0.01 vs. control group.</p>
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<p>RNA-seq analysis of CHD, TED, and co-treatment. (<b>A</b>) Venn diagram of differential genes in three experimental groups in RNA-seq. (<b>B</b>–<b>D</b>) RNA-seq gene volcano diagram in three experimental groups. (<b>E</b>) Melanoma-related gene heat map in three experimental groups. (<b>F</b>) KEGG enrichment analysis of differential genes in three experimental groups.</p>
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<p>Inhibitory roles of cell migration and cell differentiation in B16F10 cells. (<b>A</b>) shows the effect of concentrations (0, 0.5, 1, 2, 4, and 8 μmol/L) of CHD and vemurafenib after 0 h and 24 h, wounding-healing assay, and quantification of the migration distance of B16F10 cells. (<b>B</b>) shows the PCR array results about cell migration genes in CHD. (<b>C</b>) shows morphology changes in B16F10 cells treated with TED, CHD, and co-treatment for 24 h. (<b>D</b>) qRT-PCR shows the <span class="html-italic">mitf</span>, <span class="html-italic">tyr</span>, <span class="html-italic">tyrp1</span>, and <span class="html-italic">tyrp2</span> mRNA expression. * <span class="html-italic">p</span> &lt; 0.05 vs. control group, ** <span class="html-italic">p</span> &lt; 0.01 vs. control group.</p>
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<p>Apoptosis induction and cell cycle arrest on B16F10 cells. (<b>A</b>) Annexin V-PI-staining analysis was performed to evaluate apoptotic cell death in B16F10 cells after CHD, TED, and co-treatment. (<b>B</b>) PI-staining analysis was performed to evaluate the cell cycle change in B16F10 cells after CHD, TED, and co-treatment. (<b>C</b>) qPCR products showed the effects of CHE, TED, and co-treatment on mRNA expression of <span class="html-italic">p53</span>, <span class="html-italic">p21</span>, <span class="html-italic">cyclin D1</span>, <span class="html-italic">cdk2</span>, <span class="html-italic">bax</span>, and <span class="html-italic">bcl</span>−<span class="html-italic">2</span> against <span class="html-italic">gapdh</span>. (<b>D</b>) Western blot analysis of indicated proteins in CHD, TED, and co-treatment group. * <span class="html-italic">p</span> &lt; 0.05 vs. control group, ** <span class="html-italic">p</span> &lt; 0.01 vs. control group.</p>
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<p>The underlying mechanism of chelidonine and tetrandrine.</p>
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15 pages, 7236 KiB  
Article
Dry Cold Forging of High Strength AISI316 Wires by Massively Nitrogen Supersaturated CoCrMo Dies
by Tatsuhiko Aizawa, Tatsuya Fukuda and Tomomi Shiratori
Processes 2024, 12(11), 2561; https://doi.org/10.3390/pr12112561 (registering DOI) - 16 Nov 2024
Viewed by 172
Abstract
The plasma immersion nitriding system was utilized to make massive nitrogen supersaturation (MNS) to CoCrMo disc and die substrates at 723 K for 21.6 ks. The top layer thickness in the multi-layered MNSed layer was 20 μm. Its nitrogen solute content reached 5 [...] Read more.
The plasma immersion nitriding system was utilized to make massive nitrogen supersaturation (MNS) to CoCrMo disc and die substrates at 723 K for 21.6 ks. The top layer thickness in the multi-layered MNSed layer was 20 μm. Its nitrogen solute content reached 5 mass% on average after SEM-EDX analysis. The surface hardness was 1300 HV1N (HV0.1), which was much higher than the bare CoCrMo with 450 HV1N. The original polycrystalline structure was modified to be a multi-layered microstructure, which consisted of the nanograined MNSed top layer, the buffer layer with a thickness of 5 μm, and the column–granular structured layer with their textured crystallographic orientations. The BOD (ball-on-disc) testing was employed to describe the frictional sliding behavior under the applied loads of 5 N and 10 N and the sliding velocity of 0.1 m/s against the AISI316 ball. The friction coefficient was held constant by 0.68 on average. The CNC (Computer Numerical Control) stamping system was employed to upset the fine-grained 1.0 mm thick AISI316 wire up to 70% in reduction in thickness. The friction coefficient at RT was estimated to be 0.05. A round, fine-grained AISI316 wire was shaped into a thin plate with a thickness of 0.3 mm in cold and dry. Full article
28 pages, 36390 KiB  
Article
Scenic Influences on Walking Preferences in Urban Forest Parks from Top-View and Eye-Level Perspectives
by Jiahui Zou, Hongchao Jiang, Wenjia Ying and Bing Qiu
Forests 2024, 15(11), 2020; https://doi.org/10.3390/f15112020 (registering DOI) - 16 Nov 2024
Viewed by 222
Abstract
Urban forest parks offer valuable spaces for walking activities that benefit both physical and mental health. However, trails in current park designs are often underutilised, and the scene layout does not fully meet the preferences of walkers. Therefore, understanding the connection between scene [...] Read more.
Urban forest parks offer valuable spaces for walking activities that benefit both physical and mental health. However, trails in current park designs are often underutilised, and the scene layout does not fully meet the preferences of walkers. Therefore, understanding the connection between scene characteristics and walking preferences is essential. This study aimed to develop an ensemble protocol to assess the role of scene characteristics in walking preferences, using Shanghai Gongqing Forest Park as an illustrative example. A walking preference heat map was created using a combination of crowdsourced GPS data. The scene characteristics were quantified using panoramic photographs, drone orthophotos, computer vision, and deep learning techniques. Taking spatial dependence into account, the key findings include the following: (1) From an overhead view, the shortest paths, waterbody density, and recreational facility selection positively influenced walking preferences, while secondary asphalt trails had a negative effect. (2) At the eye level, aesthetically pleasing landscape elements, such as flowers and bridges, attracted more pedestrians, while closed trails were less favoured. (3) Eye-level features explained 43.5% of the variation in walking preference, with a stronger influence on walking preference compared to 22.4% for overhead features. (4) Natural elements were generally more significant than artificial ones; the feature ranking of significant impact was flowers > NACHr1000 > visual perception > water body density > bridge > SVF > retail > entertainment > asphalt. This study proposes a flexible protocol that provides urban forest park managers and planners with practical tools to create a more walker-friendly environment and more accurate trail alignment, as well as a solid empirical basis for assessing the use of urban forest parks. Full article
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<p>The extent of Gongqing Forest Park, Shanghai, China: (<b>a</b>) the orthographic projection; (<b>b</b>) the site location in Shanghai.</p>
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<p>The protocol of assessing the influence of scene characteristics on walking preference in urban forest parks.</p>
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<p>GPS locations from crowdsourced data. GPS locations of all walkers in the Gongqing Forest Park from the (<b>a</b>) 2Bulu and (<b>b</b>) Foooooot applications. Gross data from 2017 to 2024 were collected.</p>
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<p>Illustration of the process of on-site observation with the panorama camera and the positioning of photos: (<b>a</b>) the illustration of a panoramic camera by on-site observation; (<b>b</b>) the form of dichotomous scene-characteristic variables that need to be recorded manually; (<b>c</b>) an illustration of the position of panoramic photos.</p>
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<p>Semantic segmentation based on PSPNet. (<b>a</b>,<b>c</b>,<b>d</b>) The area within the red dashed line is where we extract the eye-level scene characteristics; (<b>a</b>,<b>b</b>) the area within the black dashed line is where we calculate the SVF value; (<b>e</b>) the semantic segmentation result; (<b>f</b>) the fisheye conversion process and the result of calculating the SVF.</p>
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<p>Schematic overview of subjective perception variables: (<b>a</b>) one sample of scoring for objective perception (scene encoding: 003); (<b>b</b>) a few examples of high and low scores.</p>
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<p>KDE heat map and the value of walking preference for each on-site observation point: (<b>a</b>) KDE plot for walking preference; (<b>b</b>) the raster value extracted from the KDE plot of each on-site observation point; (<b>c</b>,<b>d</b>) the walking preference data distribution trends of the KDE and points, respectively.</p>
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<p>Significant variables of scene characteristics correlated with walking preference and the ranking importance of the significant variables.</p>
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<p>Pearson correlations among the 24 significant variables, where grey parts are the retained variables that can be used for the OLS analysis. Notes: * <span class="html-italic">p</span> &lt; 0.1; ** <span class="html-italic">p</span> &lt; 0.05; *** <span class="html-italic">p</span> &lt; 0.001.</p>
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<p>The left figure shows the residual Moran’s I for OLS; the right shows the residual Moran’s I for SAC.</p>
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<p>Model performance of random forest, and the ranking importance of significant variables: (<b>a</b>) the fitting of the training and test sets in the random forest and the status of the performance evaluation metrics; (<b>b</b>) the summary plot of SHAP, showing the ranking of gross variables.</p>
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<p>The SHAP dependence of each key factor is displayed in box plots.</p>
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14 pages, 18379 KiB  
Article
A Decade of Vertebrate Palaeontology Research in the UK: Bibliometric and Topic Modelling Analysis
by Haohan Wang, Daoming Han and Zhaohui Pan
Geosciences 2024, 14(11), 314; https://doi.org/10.3390/geosciences14110314 (registering DOI) - 16 Nov 2024
Viewed by 231
Abstract
The study of vertebrate palaeontology in the United Kingdom holds a significant position in global research. This study conducts a comprehensive bibliometric analysis and topic modelling of UK vertebrate palaeontology from 2014 to 2023, utilizing data from the DeepBone database and Web of [...] Read more.
The study of vertebrate palaeontology in the United Kingdom holds a significant position in global research. This study conducts a comprehensive bibliometric analysis and topic modelling of UK vertebrate palaeontology from 2014 to 2023, utilizing data from the DeepBone database and Web of Science. A total of 2884 publications were analysed using bibliometric methods and Latent Dirichlet Allocation (LDA) to identify key research themes, institutional contributions, and international collaborations. The results reveal a significant increase in publication volume over the decade, peaking in 2021 with 374 papers. High-impact journals such as Nature and Science published approximately 6.60% of the total papers. The LDA analysis identified seven primary research themes, including morphology, palaeoanthropology, evolutionary biology, and geological periods. The Natural History Museum, University of Bristol, and University of Oxford emerged as major contributing institutions. Scientists from the United States were found to be the most frequent international collaborator. The average impact factor of the top journals in the field was 8.28 in 2024, highlighting the high quality of UK vertebrate palaeontology research. This study provides objective insights into the current state of vertebrate palaeontology in the UK, emphasizing its multidisciplinary nature, the importance of international cooperation in the field. Full article
(This article belongs to the Section Sedimentology, Stratigraphy and Palaeontology)
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<p>Annual publication trends in vertebrate palaeontology research from the United Kingdom, 2014–2023. (<b>a</b>) Total number of publications per year; (<b>b</b>) Percentage of papers published in CNS journals (Cell, Nature, Science); (<b>c</b>) Percentage of publications with UK researchers as lead authors. Black line for data points, dotted line for trend line.</p>
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<p>Global distribution of type localities for new vertebrate taxa described by UK-based researchers, 2014–2023.</p>
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<p>International collaboration network in UK vertebrate palaeontology, 2014–2023. Node size represents publication volume; line thickness represents collaboration frequency. Only top 30 contributing countries shown.</p>
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<p>Institutional collaboration network in UK vertebrate palaeontology research, 2014–2023. (<b>a</b>) International collaborators network; (<b>b</b>) Domestic collaborators network among UK institutions. Node size represents publication volume; line thickness represents collaboration frequency. Only top 30 contributing institutions shown.</p>
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<p>Topic modelling results for UK vertebrate palaeontology, 2014–2023. Intertopic distance map showing the seven main research themes identified through Latent Dirichlet Allocation (LDA) analysis.</p>
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<p>Word clouds representing the seven main research themes in UK vertebrate palaeontology, 2014–2023, as identified by Latent Dirichlet Allocation (LDA) analysis. The size of each word corresponds to its frequency and relevance within the theme.</p>
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13 pages, 1043 KiB  
Article
Quantum Channel Extreme Bandgap AlGaN HEMT
by Michael Shur, Grigory Simin, Kamal Hussain, Abdullah Mamun, M. V. S. Chandrashekhar and Asif Khan
Micromachines 2024, 15(11), 1384; https://doi.org/10.3390/mi15111384 (registering DOI) - 15 Nov 2024
Viewed by 242
Abstract
An extreme bandgap Al0.64Ga0.36N quantum channel HEMT with Al0.87Ga0.13N top and back barriers, grown by MOCVD on a bulk AlN substrate, demonstrated a critical breakdown field of 11.37 MV/cm—higher than the 9.8 MV/cm expected for [...] Read more.
An extreme bandgap Al0.64Ga0.36N quantum channel HEMT with Al0.87Ga0.13N top and back barriers, grown by MOCVD on a bulk AlN substrate, demonstrated a critical breakdown field of 11.37 MV/cm—higher than the 9.8 MV/cm expected for the channel’s Al0.64Ga0.36N material. We show that the fraction of this increase is due to the quantization of the 2D electron gas. The polarization field maintains electron quantization in the quantum channel even at low sheet densities, in contrast to conventional HEMT designs. An additional increase in the breakdown field is due to quantum-enabled real space transfer of energetic electrons into high-Al barrier layers in high electric fields. These results show the advantages of the quantum channel design for achieving record-high breakdown voltages and allowing for superior power HEMT devices. Full article
(This article belongs to the Special Issue RF and Power Electronic Devices and Applications)
22 pages, 2867 KiB  
Article
Assessment of a Top and Bottom Cooling Strategy for Prismatic Lithium-Ion Cells Intended for Automotive Use
by Said Madaoui, Bartlomiej Guzowski, Roman Gozdur, Zlatina Dimitrova, Nicolas Audiot, Jocelyn Sabatier, Jean-Michel Vinassa and Franck Guillemard
Batteries 2024, 10(11), 403; https://doi.org/10.3390/batteries10110403 (registering DOI) - 15 Nov 2024
Viewed by 243
Abstract
In contemporary vehicle applications, lithium-ion batteries have become a leading option among the diverse array of battery technologies available. This preference is attributed to their advantageous properties, which include low self-discharge rates and no memory effect. Despite these benefits, lithium-ion batteries are not [...] Read more.
In contemporary vehicle applications, lithium-ion batteries have become a leading option among the diverse array of battery technologies available. This preference is attributed to their advantageous properties, which include low self-discharge rates and no memory effect. Despite these benefits, lithium-ion batteries are not without their challenges. The key issues include a restricted driving range, concerns regarding longevity, safety risks, and prolonged charging durations. Efforts aimed at minimizing the charging duration frequently entail the introduction of elevated currents into the battery, a practice that can significantly elevate its temperature and, in turn, diminish its operational lifespan. Generally, battery packs in electric vehicles are equipped with flat cooling plates located on their side or bottom surfaces, which also serve the dual purpose of providing heating in colder conditions. Nevertheless, this cooling configuration faces difficulties during fast charging and may not efficiently heat or cool the batteries. In this work, a novel thermal management approach is proposed, in which a battery module is cooled not only with a bottom cooling plate but also using another cooling plate in contact with the busbars, located on the top of the battery module. The simulations and experimental tests show that this new configuration demonstrates significant improvements. The thermal time constant is reduced by 47%, enabling faster cooling of the module. Additionally, the maximum temperature reached by the battery during charging with dual cooling is lowered by 6 °C compared to the conventional approach. In this configuration, the top cooling plate acts as a thermal bridge. This is a key advantage that promotes temperature homogenization within the battery module. As a result, it supports an even aging process of batteries, ensuring their longevity and optimal performance. Full article
16 pages, 6481 KiB  
Article
Deposition of Diamond Coatings on Ultrathin Microdrills for PCB Board Drilling
by Shuangqing Zhou, Stephan Handschuh-Wang and Tao Wang
Materials 2024, 17(22), 5593; https://doi.org/10.3390/ma17225593 - 15 Nov 2024
Viewed by 246
Abstract
The drilling of State-of-the-Art printed circuit boards (PCBs) often leads to shortened tool lifetime and low drilling accuracy due to improved strength of the PCB composites with nanofillers and higher thickness-to-hole diameter ratio. Diamond coatings have been employed to improve the tool lifetime [...] Read more.
The drilling of State-of-the-Art printed circuit boards (PCBs) often leads to shortened tool lifetime and low drilling accuracy due to improved strength of the PCB composites with nanofillers and higher thickness-to-hole diameter ratio. Diamond coatings have been employed to improve the tool lifetime and drilling accuracy, but the coated microdrills are brittle and suffer from coating delamination. To date, it is still difficult to deposit diamonds on ultrathin microdrills with diameters lower than 0.2 mm. To avoid tool failure, the pretreatment was optimized to afford sufficient fracture strength and enough removal of cobalt. Further, the adhesion of the diamond coating was improved by employing an interlayer comprising SiC/microcrystalline diamond, which mitigates stress accumulation at the interface. By these means, microdrills with diameters of 0.8 and 0.125 mm were coated with adherent diamonds. In this context, the composite coating with the diamond/SiC interlayer and a nanodiamond top layer featured enhanced adhesion compared to single nano- or microdiamond coatings on the WC-Co microdrills. The composite diamond-coated WC-Co microdrills featured improved wear resistance, resistance to delamination of the diamond coating, and improved performance for drilling PCBs compared to micro- and nanodiamond-coated microdrills without interlayer. In addition, a higher hole quality was achieved when the diamond-coated microdrills were used. These results signify that the composite/nanodiamond coating features the highest bonding strength and best drilling performance. Full article
(This article belongs to the Special Issue Advanced Multifunctional Coatings for New Applications)
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<p>Measurement setup for determination of stress–strain curves and fracture strength of microdrills.</p>
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<p>SEM morphology of a 0.125 mm WC-Co micro drill after Murakami etching for (<b>a</b>) 3 min, followed by acid etching for 15 s. EDS spectra for the samples etched with Murakami solution for (<b>b</b>) 3 min, (<b>c</b>) 6 min, (<b>d</b>) 9 min, followed by acid etching for 15 s.</p>
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<p>Force-strain curve of micro-drills (0.125 mm) after etching with (<b>a</b>) Murakami solution for 3 to 9 min and (<b>b</b>) Murakami solution (different etching times) and Caro’s acid for 15 s.</p>
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<p>Growth of diamond on WC-Co microdrills (pretreatment 3 min Murakami, 15 s acid). (<b>a</b>) Optical image of a microdrill with a diameter of 0.8 mm. SEM micrographs of the diamond coatings along the microdrill (cutting edge, ca. 1.25 mm below the cutting edge, and ca. 4 mm below the cutting edge). SEM micrographs for (<b>b</b>) the microdiamond, (<b>c</b>) nanodiamond, and (<b>d</b>) SiC/nanodiamond coating on the WC-Co microdrill.</p>
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<p>Growth of diamond on WC-Co microdrills (pretreatment 3 min Murakami, 15 s acid). (<b>a</b>) SEM of a microdrill with a diameter of 0.125 mm. SEM micrographs of the diamond coatings along the microdrill (cutting edge, ca. 0.4 mm below the cutting edge, and ca. 0.8 mm below the cutting edge). SEM micrographs for (<b>b</b>) the microdiamond, (<b>c</b>) nanodiamond, and (<b>d</b>) SiC/nanodiamond coating on the WC-Co microdrill.</p>
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<p>Raman spectra of (<b>a</b>) the microdiamond coating, (<b>b</b>) the nanodiamond coating, and (<b>c</b>) the diamond/SiC composite interlayer + nanodiamond top layer.</p>
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<p>XRD patterns of the microcrystalline diamond coating, nanocrystalline diamond coating, and composite interlayer + nanodiamond top layer.</p>
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<p>Indentation craters of (<b>a</b>) microdiamond coating, (<b>b</b>) nanodiamond coating, and (<b>c</b>) diamond/SiC composite interlayer + nanodiamond top layer after Rockwell C indentation with a force of 1470 N. The coating is located on substrates of the flat WC-Co (pretreated with 3 min Murakami, 15 s acid).</p>
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<p>Surface morphology of the diamond-coated microdrills (diameter 0.8 mm) after drilling 50 and 500 holes in the PCB. Drilling parameters: 65 krpm, drop speed 40 mm/s, and PCB thickness 0.80 mm.</p>
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<p>Surface morphology of the diamond-coated microdrills (diameter 0.125 mm) after drilling 50 and 300 holes in the PCB. Drilling parameters: 180 krpm, drop speed 25 mm/s, and PCB thickness 0.3 mm.</p>
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<p>Appearances of the holes drilled in PCB after drilling 50 and 500 holes with the same microdrill measured by optical microscopy. The diameter of the diamond-coated microdrills were (<b>left</b>) 0.8 mm and (<b>right</b>) 0.125 mm. The red arrows highlight the formation of burrs. The microdrills were prepared with the optimized pretreatment, and the composite coating was made using the optimized TMS flow rate.</p>
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26 pages, 22159 KiB  
Article
Gas–Water–Sand Inflow Patterns and Completion Optimization in Hydrate Wells with Different Sand Control Completions
by Chenfeng Liu, Changyin Dong, Haoxian Shi, Yanjiang Yu and Bin Yin
J. Mar. Sci. Eng. 2024, 12(11), 2071; https://doi.org/10.3390/jmse12112071 - 15 Nov 2024
Viewed by 266
Abstract
Sand production poses a significant problem for marine natural gas hydrate efficient production. However, the bottom hole gas–water–sand inflow pattern remains unclear, hindering the design of standalone screen and gravel packing sand control completions. Therefore, gas–water–sand inflow patterns were studied in horizontal and [...] Read more.
Sand production poses a significant problem for marine natural gas hydrate efficient production. However, the bottom hole gas–water–sand inflow pattern remains unclear, hindering the design of standalone screen and gravel packing sand control completions. Therefore, gas–water–sand inflow patterns were studied in horizontal and vertical wells with the two completions. The experimental results showed that gas–water stratification occurred in horizontal and vertical standalone screen wells. The gas–water interface changed dynamically, leading to an uneven screen plugging, with severe plugging at the bottom and high permeability at the top. The high sand production rate and low well deviation angle exacerbated screen plugging, resulting in a faster rising rate of the gas–water interface. The screen plugging degree initially decreased and then increased as the gas–water ratio increased, resulting in the corresponding variation in the gas–water interface rising rate. Conversely, gas–water stratification did not occur in the gravel packing well because of the pore throat formed between the packing gravels. However, the impact of gas and water led to gravel rearrangement and the formation of erosion holes, causing sand control failure. A higher gas–water ratio and lower packing degree could result in more severe destabilization. Therefore, for the standalone screen completion, sand control accuracy should be designed at different levels according to the uneven plugging degree of the screen. For the gravel packing completion, increase the gravel density without destabilizing the hydrate reservoir, and use the coated gravel with a cementing effect to improve the gravel layer stability. In addition, the screen sand control accuracy inside the gravel packing layer should be designed according to the sand size to keep long-term stable hydrate production. Full article
(This article belongs to the Special Issue Advances in Marine Gas Hydrate Exploration and Discovery)
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<p>Schematic diagram of SAS and GP sand control completions.</p>
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<p>Flow chart of research idea and approach.</p>
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<p>Schematic diagram of gas–water–sand inflow during the development of hydrate.</p>
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<p>Physical and flowcharts of hydrate well bottom flow simulation device: (<b>a</b>) flowchart of device; (<b>b</b>) hydrate simulation wellbore; and (<b>c</b>) physical of device.</p>
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<p>The composition of compound formation sand: (<b>a</b>) quartz sand; (<b>b</b>) montmorillonite; (<b>c</b>) illite; and (<b>d</b>) kaolinite.</p>
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<p>Grain size distribution of experimental sand.</p>
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<p>Dynamic variation in gas–water interface at different stages: (<b>a</b>) initial stage without sand addition; (<b>b</b>) initial plugging stage; and (<b>c</b>) final plugging stage.</p>
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<p>Variation in gas–water interface in different GWR conditions.</p>
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<p>Variation rate of gas–water interface under different VCSP.</p>
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<p>The curve of screen permeability variation with the VCSP.</p>
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<p>Variation in gas-water interface in different GWR conditions.</p>
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<p>Variation in gas–water interface in different GWR conditions.</p>
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<p>Variation in gas–water interface in different well deviation angle conditions.</p>
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<p>Variation in gas–water interface in different well deviation angle conditions.</p>
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<p>Gas–water stratification phenomenon: (<b>a</b>) macro view; and (<b>b</b>) zoom-in view.</p>
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<p>Varying law of gas–water interface in a horizontal well.</p>
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<p>Varying law of screen permeability and pressure difference.</p>
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<p>Schematic diagram of the mechanism of gas–water interface transition in the vertical well: (<b>a</b>,<b>d</b>) unplugged stage; (<b>b</b>,<b>e</b>) initial plugging stage; and (<b>c</b>,<b>f</b>) final plugging stage.</p>
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<p>Schematic diagram of the mechanism of gas–water interface transition in the vertical well: (<b>a</b>,<b>d</b>) unplugged stage; (<b>b</b>,<b>e</b>) initial plugging stage; and (<b>c</b>,<b>f</b>) final plugging stage.</p>
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<p>Diagram of the mechanism of gas–water interface transition in the horizontal well.</p>
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<p>The uniform inflow of gas–water in vertical and horizontal wells with GP completion: (<b>a</b>) vertical well with GP completion; (<b>b</b>) horizontal well with GP completion.</p>
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<p>Schematic diagram of uniform inflow of gas–water–sand in GP completion: (<b>a</b>) macro view; and (<b>b</b>) zoom-in view.</p>
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<p>Formation and extension of erosion hole in the gravel layer: (<b>a</b>) formation of erosion hole; and (<b>b</b>) expansion of hole leads to screen exposure.</p>
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<p>Variation in erosion hole in the gravel layer with GWR: (<b>a</b>) GWR is 0.9 m<sup>3</sup>/m<sup>3</sup>; (<b>b</b>) GWR is 1.8 m<sup>3</sup>/m<sup>3</sup>; and (<b>c</b>) GWR is 2.7 m<sup>3</sup>/m<sup>3</sup>.</p>
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<p>The shape and depth of the erosion hole of the gravel layer with different packing degrees: (<b>a</b>) the shape of the erosion hole; (<b>b</b>) the depth of the erosion hole. Reproduced from [<a href="#B40-jmse-12-02071" class="html-bibr">40</a>], with permission from North China Petroleum Administration Bureau/2018.</p>
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<p>The curve of gravel permeability variation with the GWR.</p>
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<p>Variation in gravel layer permeability loss and recovery rates with GWR.</p>
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<p>Optimization diagram of different sand control completions.</p>
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18 pages, 980 KiB  
Article
Leveraging Six Values for Company Performance: Adaptation of Sustainable Business Model Innovation Strategies in Chinese Electric Vehicle Brand Enterprises
by Xiaohui Zang, Raja Nazim Abdullah, Long Li and Ibiwani Alisa Hussain
World Electr. Veh. J. 2024, 15(11), 526; https://doi.org/10.3390/wevj15110526 - 15 Nov 2024
Viewed by 260
Abstract
Business model innovation is crucial for enhancing company performance. This study aims to investigate the relationship between the six dimensions of sustainable business model innovation and company performance among Chinese electric vehicle brands. A structural equation model is constructed based on a comprehensive [...] Read more.
Business model innovation is crucial for enhancing company performance. This study aims to investigate the relationship between the six dimensions of sustainable business model innovation and company performance among Chinese electric vehicle brands. A structural equation model is constructed based on a comprehensive literature review and hypothesis development. Using PLS-SEM, this study empirically analyzes questionnaire data collected from the top 12 electric vehicle brands in China to explore the relationship between these six core dimensions and company performance. The results indicate that innovation in “value proposition to customers”, value creation, value delivery, and “value of residual” have a significantly positive impact on the performance of Chinese electric vehicle brands. However, value capture innovation and “value of after-sales service” innovation were not found to be statistically significant. This paper provides an in-depth analysis of the mechanism through which sustainable business model innovation impacts company performance, enriching the theoretical foundation of academic research in this field and broadening its practical applications in management. Full article
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<p>The conceptual framework of this paper.</p>
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<p>Structural model. Note: CP = Company Performance; VPCI = Value Proposition to Customer Innovation; VCrI = Value Creation Innovation; VDI = Value Delivery Innovation; VCaI = Value Capture Innovation; VSI = “Value of After-Sales Services” Innovation; VRI = “Value of Residual” Innovation.</p>
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