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9 pages, 2876 KiB  
Proceeding Paper
Fatigue Strength Determination of AISI 316L Steel and Welded Specimens Using Energy Methods
by Danilo D’Andrea, Giacomo Risitano, Pasqualino Corigliano and Davide D’Andrea
Eng. Proc. 2025, 85(1), 31; https://doi.org/10.3390/engproc2025085031 - 1 Mar 2025
Viewed by 92
Abstract
AISI 316 is a stainless steel known for its exceptional corrosion resistance and excellent mechanical properties. It is used in the chemical and pharmaceutical industries, food processing equipment, and medical devices. This alloy’s wide range of applications underscores its importance in industries requiring [...] Read more.
AISI 316 is a stainless steel known for its exceptional corrosion resistance and excellent mechanical properties. It is used in the chemical and pharmaceutical industries, food processing equipment, and medical devices. This alloy’s wide range of applications underscores its importance in industries requiring materials that can withstand extreme conditions while maintaining structural integrity and performance. Additionally, the excellent weldability and formability of AISI 316 allow for versatile design and production processes, ensuring durable and reliable performance in marine environments. This work aims to examine the behavior of AISI 316L and its welded joints under high-cycle fatigue loadings using infrared thermography (IR). Two kinds of experimental tests are performed on specimens with the same geometry: static tests and stepwise succession tests. The results of the static tests are in accordance with the stepwise succession test results in predicting the fatigue properties. Full article
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<p>Temperature evolution during (<b>a</b>) constant amplitude and (<b>b</b>) stepwise fatigue tests [<a href="#B25-engproc-85-00031" class="html-bibr">25</a>].</p>
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<p>Temperature trend during a static tensile test [<a href="#B26-engproc-85-00031" class="html-bibr">26</a>].</p>
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<p>AISI 316L specimens (3 mm thickness).</p>
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<p>Static Thermography Method (STM) applied on AISI 316L specimens: (<b>a</b>) “as-received”; (<b>b</b>) “welded”.</p>
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<p>Temperature evolution during a stepwise fatigue test of “as-received” AISI 316L at R = 0.1.</p>
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<p>Stabilization temperature vs. applied stress level for “as-received” AISI 316L at stress ratio R 0.1.</p>
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16 pages, 8053 KiB  
Article
A Novel Hydrogen Leak Detection Method for PEM Fuel Cells Using Active Thermography
by Martina Totaro, Dario Santonocito, Giacomo Risitano, Orazio Barbera and Giosuè Giacoppo
Energies 2025, 18(5), 1185; https://doi.org/10.3390/en18051185 - 28 Feb 2025
Viewed by 326
Abstract
Hydrogen leakage in Proton Exchange Membrane (PEM) fuel cells poses critical safety, efficiency, and operational reliability risks. This study introduces an innovative infrared (IR) thermography-based methodology for detecting and quantifying hydrogen leaks towards the outside of PEM fuel cells. The proposed method leverages [...] Read more.
Hydrogen leakage in Proton Exchange Membrane (PEM) fuel cells poses critical safety, efficiency, and operational reliability risks. This study introduces an innovative infrared (IR) thermography-based methodology for detecting and quantifying hydrogen leaks towards the outside of PEM fuel cells. The proposed method leverages the catalytic properties of a membrane electrode assembly (MEA) as an active thermal tracer, facilitating real-time visualisation and assessment of hydrogen leaks. Experimental tests were conducted on a single-cell PEM fuel cell equipped with intact and defective gaskets to evaluate the method’s effectiveness. Results indicate that the active tracer generates distinct thermal signatures proportional to the leakage rate, overcoming the limitations of hydrogen’s low IR emissivity. Comparative analysis with passive tracers and baseline configurations highlights the active tracer-based approach’s superior positional accuracy and sensitivity. Additionally, the method aligns detected thermal anomalies with defect locations, validated through pressure distribution maps. This novel, non-invasive technique offers precise, reliable, and scalable solutions for hydrogen leak detection, making it suitable for dynamic operational environments and industrial applications. The findings significantly advance hydrogen’s safety diagnostics, supporting the broader adoption of hydrogen-based energy systems. Full article
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<p>(<b>a</b>) PEM fuel cell (<b>b</b>) test station.</p>
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<p>The experimental setup: in the foreground, on the tripod, the thermal IR camera, and in the background, the testing station with the single cell mounted on the bench.</p>
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<p>Two pictures of the gasket: (<b>a</b>) intact, (<b>b</b>) with intentional defect.</p>
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<p>Pictures of the used fuel cell (in the centre) with defective gasket: (<b>a</b>) as it is, (<b>b</b>) with passive tracer, (<b>c</b>) with active tracer.</p>
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<p>IR image of the fuel cell with intact gasket: (<b>a</b>) without tracer and (<b>b</b>) with active tracer. Labels (“Environment”, ”Plate”, “Gas mixture”) indicate where the temperature was measured for the graph of <a href="#energies-18-01185-f006" class="html-fig">Figure 6</a>).</p>
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<p>Heating rates of the plate (green) and the environment (red) as the gas mixture temperature increases (blue). The vertical dashed line indicates the insertion of the active tracer in contact with the single cell.</p>
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<p>IR Image with the defective gasket in baseline conditions. No leaks are visible.</p>
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<p>IR image of the thermal gas plume escaping near the defect visible on the passive tracer surface. The label “Leakage” indicates the point where the temperature was measured: (<b>a</b>) with a lower nitrogen flow rate; and (<b>b</b>) with a high nitrogen flow rate.</p>
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<p>Temperature profile of the passive tracer by increasing the nitrogen’s flow rate escaping from the PEM cell. Frame A and Frame B are depicted in <a href="#energies-18-01185-f008" class="html-fig">Figure 8</a>.</p>
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<p>(<b>a</b>) The thermal plume of gas escaping near the defect, displayed on the active tracer, yellow colour corresponds to the highest temperatures, purple colour to the lowest; (<b>b</b>) temperature along the height; (<b>c</b>) temperature along the width of the tracer.</p>
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<p>Correlation between temperature and mass flow increasing, (<b>a</b>) without H<sub>2</sub>–N<sub>2</sub> mixture, (<b>b</b>) with 50 mL/min of H<sub>2</sub> in H<sub>2</sub>–N<sub>2</sub> mixture, (<b>c</b>) with 75 mL/min of H<sub>2</sub> in of H<sub>2</sub>–N<sub>2</sub> mixture.</p>
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<p>Contact pressure distribution of the cell with gasket (<b>a</b>) intact and (<b>b</b>) defective.</p>
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<p>Correlation between (<b>a</b>) the actual position of the leakage evaluated with the sensor arrays and (<b>b</b>) the leakage position revealed from the thermographic image.</p>
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32 pages, 3991 KiB  
Review
Artificial Intelligence in IR Thermal Imaging and Sensing for Medical Applications
by Antoni Z. Nowakowski and Mariusz Kaczmarek
Sensors 2025, 25(3), 891; https://doi.org/10.3390/s25030891 - 1 Feb 2025
Viewed by 913
Abstract
The state of the art in IR thermal imaging methods for applications in medical diagnostics is discussed. A review of advances in IR thermal imaging technology in the years 1960–2024 is presented. Recently used artificial intelligence (AI) methods in the analysis of thermal [...] Read more.
The state of the art in IR thermal imaging methods for applications in medical diagnostics is discussed. A review of advances in IR thermal imaging technology in the years 1960–2024 is presented. Recently used artificial intelligence (AI) methods in the analysis of thermal images are the main interest. IR thermography is discussed in view of novel applications of machine learning methods for improved diagnostic analysis and medical treatment. The AI approach aims to improve image quality by denoising thermal images, using applications of AI super-resolution algorithms, removing artifacts, object detection, face and characteristic features localization, complex matching of diagnostic symptoms, etc. Full article
(This article belongs to the Collection Medical Applications of Sensor Systems and Devices)
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<p>(<b>a</b>) Anatomy of the skin (from [<a href="#B10-sensors-25-00891" class="html-bibr">10</a>])—depth of burn; (<b>b</b>) three-layer structural model; (<b>c</b>) equivalent thermoelectric model [<a href="#B22-sensors-25-00891" class="html-bibr">22</a>].</p>
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<p>Electric equivalent circuit simulating thermal processes at the ROI surface, where U(x,y,t) is the voltage of a temperature value at a pixel x, y at time t; U—voltage sources representing ambient A, stimulation ST, and body B temperature (boundary conditions); Ri—thermal resistances; Ci—thermal capacitances [<a href="#B22-sensors-25-00891" class="html-bibr">22</a>].</p>
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<p>Block diagram of basic ADT/TSR/TT measurement procedure [<a href="#B22-sensors-25-00891" class="html-bibr">22</a>].</p>
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<p>Thermal Tomography procedure for reconstruction of a tested structure’s properties [<a href="#B22-sensors-25-00891" class="html-bibr">22</a>].</p>
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<p>Block diagram of the stand for research with the ADT, TSR, and TT methods [<a href="#B22-sensors-25-00891" class="html-bibr">22</a>].</p>
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<p>(<b>a</b>) Postoperative wound evaluation in cardiac surgery on the 3rd day after cardiac surgery; parametric images—according to Equation (2); photograph of the patient. (<b>b</b>) Postoperative wound evaluation in cardiac surgery patient on the 3rd day after cardiac surgery; TSR parametric images: first 6 parametric images of logarithmic coefficients a<sub>i</sub>—according to Equation (5); first row from left: a<sub>0</sub>, a<sub>1</sub>, a<sub>2</sub>; second row from the left: a<sub>3</sub>, a<sub>4</sub>, a<sub>5</sub>.</p>
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<p>(<b>a</b>) Postoperative wound evaluation in cardiac surgery on the 3rd day after cardiac surgery; parametric images—according to Equation (2); photograph of the patient. (<b>b</b>) Postoperative wound evaluation in cardiac surgery patient on the 3rd day after cardiac surgery; TSR parametric images: first 6 parametric images of logarithmic coefficients a<sub>i</sub>—according to Equation (5); first row from left: a<sub>0</sub>, a<sub>1</sub>, a<sub>2</sub>; second row from the left: a<sub>3</sub>, a<sub>4</sub>, a<sub>5</sub>.</p>
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<p>Visualization of artificial intelligence concept relationships.</p>
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<p>Major steps in preparing a deep learning model for thermographic diagnostics.</p>
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<p>Steps in preparing a federated deep learning context for thermographic diagnostics.</p>
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18 pages, 18717 KiB  
Article
Processing of Eddy Current Infrared Thermography and Magneto-Optical Imaging for Detecting Laser Welding Defects
by Pengyu Gao, Xin Yan, Jinpeng He, Haojun Yang, Xindu Chen and Xiangdong Gao
Metals 2025, 15(2), 119; https://doi.org/10.3390/met15020119 - 25 Jan 2025
Viewed by 556
Abstract
Infrared (IR) magneto-optical (MO) bi-imaging is an innovative method for detecting weld defects, and it is important to process both IR thermography and MO imaging characteristics of weld defects. IR thermography and MO imaging can not only run simultaneously but can also run [...] Read more.
Infrared (IR) magneto-optical (MO) bi-imaging is an innovative method for detecting weld defects, and it is important to process both IR thermography and MO imaging characteristics of weld defects. IR thermography and MO imaging can not only run simultaneously but can also run separately in special welding processes. This paper studies the sensing processing of eddy current IR thermography and MO imaging for detecting weld defects of laser spot welding and butt joint laser welding, respectively. To address the issues of high-level noise and low contrast in eddy current IR detection thermal images interfering with defect detection and recognition, a method based on least squares and Gaussian-adaptive bilateral filtering is proposed for denoising eddy current IR detection thermal images of laser spot welding cracks and improving the quality of eddy current IR detection thermal images. Meanwhile, the image gradient is processed by Gaussian-adaptive bilateral filtering, and then the filter is embedded in the least squares model to smooth and denoise the image while preserving defect information. Additionally, MO imaging for butt joint laser welding defects is researched. For the acquired MO images of welding cracks, pits, incomplete fusions, burn-outs, and weld bumps, the MO image processing method that includes median filtering, histogram equalization, and Wiener filtering was used, which could eliminate the noise in an image, enhance its contrast, and highlight the weld defect features. The experimental results show that the proposed image processing method can eliminate most of the noise while retaining the weld defect features, and the contrast between the welding defect area and the normal area is greatly improved. The denoising effect using the Natural Image Quality Evaluator (NIQE) and the Blind Image Quality Index (BIQI) has been evaluated, further demonstrating the effectiveness of the proposed method. The differences among weld defects could be obtained by analyzing the gray values of the weld defect MO images, which reflect the weld defect information. The MO imaging method can be used to investigate the magnetic distribution characteristics of welding defects, and its effectiveness has been verified by detecting various butt joint laser welding weldments. Full article
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<p>MO and eddy current IR thermography system for detecting laser welding defects.</p>
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<p>Weld defect detection simulation. (<b>a</b>) Three-dimensional model for defect detection. (<b>b</b>) Magnetic flux density map projected onto the surface of the MO film in the defect detection process. The blue box, green box, and red line in (<b>c</b>,<b>d</b>) carry the same significance, all representing the top view of the surface of the workpiece under examination. The blue box delineates the outer contour of a defect with a depth of 1 mm, while the green box indicates a defect with a depth of 0.5 mm. The red line maps the magnetic flux density magnitude values to the corresponding position in (<b>e</b>), implying that the horizontal coordinate in (<b>e</b>) corresponds to the position of the red line along the <span class="html-italic">x</span>-axis of the global coordinate system, with the vertical coordinate representing the magnetic flux density magnitude at that specific location.</p>
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<p>Typical sample image and its processing method. (<b>a</b>) Defect-free sample, (<b>b</b>) burn-out sample, (<b>c</b>) crack sample, (<b>d</b>) incomplete fusion sample, (<b>e</b>) weld bump sample, (<b>f</b>) pit sample.</p>
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<p>The process of weld bump edge extraction by Prewitt operator, which corresponds to <a href="#metals-15-00119-f003" class="html-fig">Figure 3</a>e. Symbol * denotes the convolution operation.</p>
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<p>Experimental system of weld defect ECT detection. (<b>a</b>) Diagram of experimental device, (<b>b</b>) defect detection principle schematic diagram in ECT, (<b>c</b>) welding spot cross-sectional image.</p>
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<p>Laser spot weldment. (<b>a</b>) Laser spot welding specimen image, (<b>b</b>) Welding spot image (red box) collected on microscope, (<b>c</b>) Welding spot image (red box) collected on infrared thermal imager.</p>
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<p>Grayscale curves of the middle column from the magneto-optical image of the crack.</p>
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<p>Comparison of the grayscale curves from the middle column of the crack and defect-free images.</p>
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<p>Visual comparison of samples A1, A2, A3, and A4 before and after denoising.</p>
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<p>Bar graph of BIQI values for each sample before and after denoising of IR thermogram.</p>
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<p>Bar graph of NIQE values for each sample before and after denoising of IR thermogram.</p>
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<p>Bar graph of PSNR values for each sample of IR thermogram.</p>
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10 pages, 2539 KiB  
Article
Heat Transmission Coefficient of Wooden House—Comparison of Infrared Thermography Measurements and Calculation
by Yoon-Seong Chang
Buildings 2025, 15(1), 105; https://doi.org/10.3390/buildings15010105 - 31 Dec 2024
Viewed by 445
Abstract
In this paper, the thermal insulation performance of a wooden house was evaluated with infrared thermographies which were captured by a non-contact and non-destructive method. Heat transmissions were determined by the difference between surface temperature of outdoor and indoor sides of the walls, [...] Read more.
In this paper, the thermal insulation performance of a wooden house was evaluated with infrared thermographies which were captured by a non-contact and non-destructive method. Heat transmissions were determined by the difference between surface temperature of outdoor and indoor sides of the walls, which were measured with an IR ray signal, and indoor and outdoor air temperatures. The heat transmission coefficient, which was determined by IR thermography, was compared to the coefficient calculated with thermal conductivities of wall component materials. The heat transmission coefficient calculated through wall components was 0.24 W/m2·K, while the coefficients determined with IR thermography ranged from 0.27 to 4.61 W/m2·K. The invisible thermal insulation defects in the wall, such as heat losses from the premature deterioration of thermal insulation material and air leakage through windows, were observed by IR thermography. It is expected that the results of this study could be used effectively not only for improving thermal insulation performance but also for suppressing decay occurrence in wooden building materials. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
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<p>Test house at the Korea Forest Research Institute.</p>
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<p>Sectional view of the studied wooden wall.</p>
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<p>Theoretical background of the temperature difference ratio (TDR).</p>
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<p>IR images of the indoor wall of wooden house. The numbers in the pictures are the surface temperatures of the wall.</p>
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<p>IR images of the outdoor wall of wooden house. The numbers in the pictures are the surface temperatures of the wall.</p>
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31 pages, 6912 KiB  
Article
Enhancing Early Breast Cancer Detection with Infrared Thermography: A Comparative Evaluation of Deep Learning and Machine Learning Models
by Reem Jalloul, Chethan Hasigala Krishnappa, Victor Ikechukwu Agughasi and Ramez Alkhatib
Technologies 2025, 13(1), 7; https://doi.org/10.3390/technologies13010007 - 26 Dec 2024
Viewed by 1677
Abstract
Breast cancer remains one of the most prevalent and deadly cancers affecting women worldwide. Early detection is crucial, particularly for younger women, as traditional screening methods like mammography often struggle with accuracy in cases of dense breast tissue. Infrared thermography offers a non-invasive [...] Read more.
Breast cancer remains one of the most prevalent and deadly cancers affecting women worldwide. Early detection is crucial, particularly for younger women, as traditional screening methods like mammography often struggle with accuracy in cases of dense breast tissue. Infrared thermography offers a non-invasive imaging alternative that enhances early detection by capturing subtle thermal variations indicative of breast abnormalities. This study investigates and compares the performance of various deep learning and machine learning models in analyzing thermographic data to classify breast tissue as healthy, benign, or malignant. To maximize detection accuracy, data preprocessing, feature extraction, and dimensionality reduction were implemented to isolate distinguishing characteristics across tissue types. Leveraging advanced feature extraction and visualization techniques inspired by geospatial data methodologies, we evaluated several deep learning architectures and classical classifiers using the DRM-IR and Breast Thermography Mendeley thermal datasets. Among the tested models, the ResNet152 architecture combined with a Support Vector Machine (SVM) classifier delivered the highest performance, achieving 97.62% accuracy, 95.79% precision, 98.53% recall, 94.52% specificity, an F1 score of 97.16%, an area under the curve (AUC) of 99%, a latency of 0.06 s, and CPU utilization of 88.66%. These findings underscore the potential of integrating infrared thermography with advanced deep learning and machine learning approaches to significantly improve the accuracy and efficiency of breast cancer detection, supporting its role as a valuable tool for early diagnosis. Full article
(This article belongs to the Section Information and Communication Technologies)
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<p>Proposed Framework for Feature Extraction and Classification from Thermal Breast Images.</p>
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<p>Sample of Thermal Images from Dataset.</p>
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<p>Example of a Full-Body Thermal Image Capturing the Breast Area.</p>
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<p>Effects of the preprocessing filters applied to infrared images.</p>
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<p>Distribution of pixel intensities on the real-world vs. augmented data.</p>
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<p>Workflow of 10-fold cross-validation implementation.</p>
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<p>PCA Visualization of Thermal Image Features for Breast Cancer Detection.</p>
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<p>Feature Correlation Heatmap for Thermal Image Dataset.</p>
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<p>Top 10 Most Important Features from the Thermal Images for Breast Cancer Detection.</p>
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<p>Confusion Matrix for SVM with ResNet-152 Features.</p>
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<p>Precision–Recall Curve of the Model.</p>
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<p>The ROC curve of the Model.</p>
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<p>Accuracy Comparison of Classifiers across Feature Models.</p>
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<p>AUC Comparison of Classifiers across Feature Models for Breast Cancer Classification.</p>
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<p>Grad-CAM Overlay for Normal Class (the original thermal image (<b>left</b>) alongside the Grad-CAM overlay (<b>right</b>) highlights the regions contributing to the model’s prediction of the “Normal” class with a confidence score of 0.80).</p>
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<p>Grad-CAM Overlay for Sick Class (the original thermal image (<b>left</b>) alongside the Grad-CAM overlay (<b>right</b>) demonstrates the model’s focus on specific regions, leading to the prediction of the “Sick” class with a confidence score of 0.85).</p>
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<p>Grad-CAM Overlay for Malignant Class (the original thermal image (<b>left</b>) and its corresponding Grad-CAM overlay (<b>right</b>) show the model’s focus on abnormal heat regions, supporting the “malignant” classification with a confidence score of 0.89).</p>
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<p>Grad-CAM Overlay for Benign Class (the original thermal image (<b>left</b>) and its Grad-CAM overlay (<b>right</b>) depict the regions contributing to the model’s prediction of the “benign” class with a confidence score of 0.88).</p>
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<p>(<b>Left</b>) Original thermal image highlighting the temperature distribution across the chest area, with warmer regions indicated by red/yellow hues and cooler regions by blue/green hues. (<b>Right</b>) Grad-CAM overlay demonstrating the areas of highest model attention during classification, with cooler colours indicating less attention and warmer colours indicating regions of interest.</p>
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18 pages, 7180 KiB  
Article
A New Sensorized Approach Based on a DeepLabCut Model and IR Thermography for Characterizing the Thermal Profile in Knees During Exercise
by Davide Crisafulli, Marta Spataro, Cristiano De Marchis, Giacomo Risitano and Dario Milone
Sensors 2024, 24(23), 7862; https://doi.org/10.3390/s24237862 - 9 Dec 2024
Viewed by 943
Abstract
The knee is one of the joints most vulnerable to disease and injury, particularly in athletes and older adults. Surface temperature monitoring provides insights into the health of the analysed area, supporting early diagnosis and monitoring of conditions such as osteoarthritis and tendon [...] Read more.
The knee is one of the joints most vulnerable to disease and injury, particularly in athletes and older adults. Surface temperature monitoring provides insights into the health of the analysed area, supporting early diagnosis and monitoring of conditions such as osteoarthritis and tendon injuries. This study presents an innovative approach that combines infrared thermography techniques with a Resnet 152 (DeepLabCut based) to detect and monitor temperature variations across specific knee regions during repeated sit-to-stand exercises. Thermal profiles are then analysed in relation to weight distribution data collected using a Wii Balance Board during the exercise. DeepLabCut was used to automate the selection of the region of interest (ROI) for temperature assessments, improving data accuracy compared to traditional time-consuming semi-automatic methods. This integrative approach enables precise and marker-free measurements, offering clinically relevant data that can aid in the diagnosis of knee pathologies, evaluation of the rehabilitation progress, and assessment of treatment effectiveness. The results emphasize the potential of combining thermography with DeepLabCut-driven data analysis to develop accessible, non-invasive tools for joint health monitoring or preventive diagnostics of pathologies. Full article
(This article belongs to the Special Issue IMU and Innovative Sensors for Healthcare)
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<p>Schematic representation of the procedural setup, equipment (WBB, infrared camera and metronome) and sit-to-stand phases: (<b>I</b>) sitting phase; (<b>II</b>) standing phase.</p>
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<p>Thermograms during a sit to stand exercise phase: (<b>a</b>) Standing position without ROI; (<b>b</b>) Sitting position with ROI; (<b>c</b>) Standing with ROI.</p>
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<p>Named knee zones and boundaries: SL, superior lateral; SM superior medial; P, patella; LJLA lateral joint line area; MJLA, medial joint line area; PT, patella tendon. Initial letters: R, right leg; L, left leg.</p>
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<p>Temperature map of the knee region: (<b>a</b>) pre-exercise; (<b>b</b>) post-exercise.</p>
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<p>Temperature variation during exercise for the right (red) and left (blue) legs is shown for: (<b>a</b>) maximum temperature trend and (<b>b</b>) minimum temperature trend.</p>
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<p>Temperature variation during exercise for the right (red) and left (blue) legs is shown for: (<b>a</b>) maximum temperature trend and (<b>b</b>) minimum temperature trend.</p>
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<p>Thermograms during a sitting phase, green circles represent the different regions detected by the DeepLabCut model on the knee area on the standing phase (<b>a</b>), during sitting phase (<b>b</b>) and sitting (<b>c</b>).</p>
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<p>Temperature evolution on knee areas showed in <a href="#sensors-24-07862-f003" class="html-fig">Figure 3</a>.</p>
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<p>Wii Balance Board acquisition from 20 to 36 s of the sit-to stand activity: (<b>a</b>) Weight distribution (kg); (<b>b</b>) Force distribution on right (blue) and left (red) leg; (<b>c</b>) Force distribution on left (red) and right (blue) rearfoot, left (yellow) and right (cyan) forefoot.</p>
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<p>Centre of pressure position and body weight distribution on the feet for each of the four loadcells (in %) during the exercise.</p>
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<p>Correlation between the leg bearing the greater load and the leg with the most significant thermal variation classified by gender (men = blue, women = green) (AGREE (AG) true for both methods, DISAGREE (DAG) false for both methods, PARTIAL AGREEMENT (PAG) true for one of the two methods): (<b>a</b>) Leg with the greatest cooling; (<b>b</b>) Leg with the greatest heating.</p>
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<p>Regression analysis between the semi-automatic method and the automatic one. A strong correlation was found for 67% of the measurements with R<sup>2</sup> of 0.71 ± 0.17, both for the ligament (<b>a</b>) and the patellar zone (<b>b</b>).</p>
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<p>Thermal trend in the automatic (<b>a</b>) and semi-automatic (<b>b</b>) methods shows distinct differences. The automatic shows a clear decreasing trend, with an RMSE of 0.01, indicating a near-perfect linear trend. In contrast, the semi-automatic method lacks a significant correlation, reflected by a much higher RMSE of 0.15.</p>
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<p>Bland–Altman plots of Left and Right Ligament (<b>a</b>,<b>b</b>), Right Patella, and Left Patella (<b>c</b>,<b>d</b>). The green diamonds represent the individual data points, plotting the difference between the two methods on the y-axis against the average of the two measurements on the x-axis. The blue line indicates the mean difference between the two methods. The red dashed lines represent the 95% confidence range, within which most of the data points are expected to fall.</p>
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<p>Bland–Altman plots of Left and Right Ligament (<b>a</b>,<b>b</b>), Right Patella, and Left Patella (<b>c</b>,<b>d</b>). The green diamonds represent the individual data points, plotting the difference between the two methods on the y-axis against the average of the two measurements on the x-axis. The blue line indicates the mean difference between the two methods. The red dashed lines represent the 95% confidence range, within which most of the data points are expected to fall.</p>
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20 pages, 9659 KiB  
Article
Nondestructive Detection of Osmotic Damage in GFRP Boat Hulls Using Active Infrared Thermography Methods
by Endri Garafulić, Petra Bagavac and Lovre Krstulović-Opara
J. Mar. Sci. Eng. 2024, 12(12), 2247; https://doi.org/10.3390/jmse12122247 - 6 Dec 2024
Viewed by 533
Abstract
This article presents the application of infrared thermography as a nondestructive testing method (NDT) for detecting osmotic damage in glass-fiber-reinforced polymer (GFRP) and glass-reinforced polymer (GRP) boat hull structures. The aim of the conducted experiments is to explore the possibilities of applying active [...] Read more.
This article presents the application of infrared thermography as a nondestructive testing method (NDT) for detecting osmotic damage in glass-fiber-reinforced polymer (GFRP) and glass-reinforced polymer (GRP) boat hull structures. The aim of the conducted experiments is to explore the possibilities of applying active infrared thermography to real structures and to establish a procedure capable of filtering out anomalies caused by various thermal influences, such as thermal reflections from surrounding objects, geometry effects, and heat flow variations on the observed object. The methods used for post-processing IR signals include lock-in thermography (LT), pulse thermography (PT), pulse phase thermography (PPT), and gradient pulse phase thermography (GT). The practical application and advantages and disadvantages of infrared thermography in identifying osmotic damage in GFRP and GRP boat hulls will be illustrated through three case studies. Each case study is based on specific conditions and characteristics of different types of osmotic damage, enabling a thorough analysis of the effectiveness of the method in detecting and assessing the severity of the damage. The post-processed thermal images enable a clearer distinction between damaged and undamaged zones, improving the robustness of detection under realistic field conditions. Full article
(This article belongs to the Section Ocean Engineering)
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<p>Formation of osmotic bubbles.</p>
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<p>(<b>a</b>) Visible blisters and (<b>b</b>) the standard method of detecting the osmotic process.</p>
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<p>The transition from the (<b>a</b>) time domain to the (<b>b</b>) frequency domain using the FFT algorithm [<a href="#B14-jmse-12-02247" class="html-bibr">14</a>].</p>
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<p>Signal processing in PPT: (<b>a</b>) thermogram sequence, 3D matrix, and thermal profiles for a defective pixel, red line (Td), a nondefective pixel, blue line (TSa), and the difference between them, green line (TdTSa); (<b>b</b>) amplitudegram sequence and amplitude profiles; (<b>c</b>) phasegram sequence and phase profiles for a defective pixel, red line (Fd), a non-defective pixel, blue line (Fsa), and the difference between them, green line (Fd-Fsa).</p>
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<p>(<b>a</b>) Setup for nondestructive testing with lock-in thermography, (<b>b</b>) region of interest (ROI) where osmotic damage is circled and marked with labels A, B, C, and D.</p>
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<p>Sinusoidal response of relay-controlled halogen floodlights.</p>
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<p>Raw thermal image.</p>
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<p>Phase delay, P = 24 s, the osmotic damage is circled and marked with labels A, B, C, and D.</p>
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<p>Phase delay, P = 72 s, the osmotic damage is circled and marked with labels A, B, C, and D.</p>
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<p>Phase delay, P = 120 s, the osmotic damage is circled and marked with labels A, B, C, and D.</p>
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<p>Osmotic damage on the boat hull: (<b>a</b>) photo of the boat hull, (<b>b</b>) osmotic blisters A and B.</p>
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<p>A-scan of the back wall on calibration steel block K1: (<b>a</b>) 4 MHz frequency probe, (<b>b</b>) 1 MHz frequency probe.</p>
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<p>(<b>a</b>) USM GO device; (<b>b</b>) K1S-C 1 MHz frequency probe with a plexiglass attachment for beam focusing.</p>
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<p>A-scan: (<b>a</b>) osmotic damage, (<b>b</b>) undamaged material.</p>
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<p>Phase shift at different excitation frequencies: (<b>a</b>) f = 0.04167 Hz, (<b>b</b>) f = 0.0208 Hz, (<b>c</b>) f = 0.0139 Hz, and (<b>d</b>) f = 0.0083 Hz.</p>
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<p>Phase shift at different excitation frequencies: (<b>a</b>) f = 0.04167 Hz, (<b>b</b>) f = 0.0208 Hz, (<b>c</b>) f = 0.0139 Hz, and (<b>d</b>) f = 0.0083 Hz.</p>
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<p>Osmotic damage on the hull of the vessel after grinding the anti-fouling paint and protective epoxy coating.</p>
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<p>The undamaged hull of the vessel: (<b>a</b>) during UT testing, (<b>b</b>) after grinding the anti-fouling paint and protective epoxy coating.</p>
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<p>Phase shift at different excitation frequencies: (<b>a</b>) f = 0.04167 Hz, (<b>b</b>) f = 0.0208 Hz, (<b>c</b>) f = 0.0139 Hz, and (<b>d</b>) f = 0.0083 Hz.</p>
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<p>(<b>a</b>) PT applied on a boat’s hull, (<b>b</b>) photography of zones where blisters are detected, and (<b>c</b>) thermogram with location of osmotic blisters.</p>
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<p>PPT results of blister osmosis detection: (<b>a</b>) selected amplitudegrams—even symmetry; (<b>b</b>) selected phasegrams—odd symmetry, for the following frequencies: ±0.01, 0.02, 0.03, 0.04, 0.05 Hz.</p>
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<p>Boat’s hull phasegrams, image detail of osmosis damage—2D review for (<b>a</b>) f = 0.01 Hz and (<b>c</b>) f = 0.075 Hz, and 3D review for (<b>b</b>) f = 0.01 Hz and (<b>d</b>) f = 0.075 Hz.</p>
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<p>(<b>a</b>) Thermogram with the location of the osmotic blisters, (<b>b</b>) and thermal gradient image processing.</p>
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<p>Gradient of phasegram image shown in <a href="#jmse-12-02247-f022" class="html-fig">Figure 22</a>a.</p>
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<p>Wet fiberglass and delamination from the acids in zone A.</p>
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13 pages, 2817 KiB  
Article
Flammability and Thermoregulation Performance of Multilayer Protective Clothing Incorporated with Phase Change Materials
by Muhammad Shoaib, Hafsa Jamshaid, Rajesh Kumar Mishra, Kashif Iqbal, Miroslav Müller, Vijay Chandan and Tatiana Alexiou Ivanova
Materials 2024, 17(23), 5826; https://doi.org/10.3390/ma17235826 - 27 Nov 2024
Viewed by 1516
Abstract
Firefighters need personal protection equipment and protective clothing to be safe and protected when responding to fire incidents. At present, firefighters’ suits are developed by using inherently thermal-resistant fibers but pose serious problems related to comfort. In the present research, multilayered fire-fighting fabrics [...] Read more.
Firefighters need personal protection equipment and protective clothing to be safe and protected when responding to fire incidents. At present, firefighters’ suits are developed by using inherently thermal-resistant fibers but pose serious problems related to comfort. In the present research, multilayered fire-fighting fabrics were developed with different fiber blends. Multilayer fire retardant (FR) fabrics with phase change materials (PCMs) inserts were developed and compared with reference multilayer fabrics without PCM. In this context, four fabric samples were chosen to fabricate the multilayer FR fabrics. Properties of multilayer fabrics were investigated, which include physical, thermo–physiological comfort, and flame-resistant performance. The heating process of the clothing was examined using infrared (IR) thermography, differential scanning calorimetry (DSC), thermal protective testing (TPP), and steady-state (Convective and Radiant) heat resistance tests. Areal density and thickness were measured as physical parameters, and air permeability (AP), overall moisture management capacity (OMMC), and thermal conductivity were measured as thermo–physiological comfort characteristics. The inclusion of PCM improved the thermal protection as well as flame resistance significantly. Sample S1 (Nomex + PTFE + Nomex with PCM) demonstrated superior fire resistance, air permeability, and thermal protection, with a 37.3% increase in air permeability as compared to the control sample (SC) by maintaining comfort while offering high thermal resilience. The inclusion of PCM enhanced its thermal regulation, moderating heat transfer. Flame resistance tests confirmed its excellent performance, while thermo–physiological assessments highlighted a well-balanced combination of thermal conductivity and air permeability. This study will help to improve the performance of firefighter protective fabrics and provide guidelines in terms of balancing comfort and performance while designing firefighter protective clothing for different climatic conditions. Full article
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<p>Schematic and assembly for the fabrication of multilayer firefighter suit.</p>
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<p>Instruments used for thermal testing of multilayer fabrics: (<b>a</b>) thermal protective tester, (<b>b</b>) Kawabata thermal conductivity tester, and (<b>c</b>) auto/horizontal flame tester.</p>
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<p>Multilayer fabrics after flame tests.</p>
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<p>PCM’s performance: (<b>a</b>) thermal images of multilayer fabrics at different residence times. (<b>b</b>) Enthalpy of PCMs.</p>
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<p>Comparison of thermal protective performance of the multilayer fabrics, S1, S2, S3, S4, SC, and barchart showing their thermal performance. The bars in <a href="#materials-17-05826-f005" class="html-fig">Figure 5</a> show mean values with standard deviation (SD). As can be seen, the trend of the protective performance of the prepared samples was S1 &gt; S3 &gt; S2 &gt; S4, respectively. As S1 and S3 samples consist of Nomex, which has inherently good char ability and creates a protective layer on the surface of the fabric, its thermal protective performance was better than other types of fibers used. Sample S4 showed the lowest thermal performance, which was also evident from the minimum char produced.</p>
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19 pages, 6251 KiB  
Article
Cooling Effectiveness of the Sustainable Cooling Solution for Cattle: Case Study in Poland
by Jagoda Błotny, Anna Szczepanowska-Białek, Robert Kupczyński, Anna Budny-Walczak and Sabina Rosiek
Appl. Sci. 2024, 14(21), 9678; https://doi.org/10.3390/app14219678 - 23 Oct 2024
Viewed by 890
Abstract
Recently, the dairy sector has been ever more affected by global warming. This study aimed to test a novel conductive cooling system for cattle that was successfully implemented and evaluated under summer thermally challenging weather conditions in Poland. The system consists mainly of [...] Read more.
Recently, the dairy sector has been ever more affected by global warming. This study aimed to test a novel conductive cooling system for cattle that was successfully implemented and evaluated under summer thermally challenging weather conditions in Poland. The system consists mainly of the chiller, tank, and chilled water-driven mattress, designed to prioritize animal well-being. The experimental evaluation was carried out on three Friesian dry cows, housed on different types of bedding—commercial water mattress, straw, and cooling water mattress—and supplied with water at 10 °C (day) and 16 °C (night). The cooling water mattress’ surface temperature was twice as low as that of the commercial water mattress. The animal’s thermal comfort was assessed with physiological and behavioral reactions. The cooling effect on animals’ bodies was demonstrated with a lower reticulorumen temperature of the cooled cow (p < 0.05) than the reference ones. The local effect of cooling was proved with an 8 °C-lower skin temperature after the cow’s resting period. The presented study opens a new research direction toward dairy cattle’s welfare, sustainability, and the food–energy–water nexus, based on potential energy and water savings. Full article
(This article belongs to the Special Issue Breakthroughs in Real-Time Bioprocess Monitoring)
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<p>Geometry of the innovative cooling water mattress [<a href="#B24-applsci-14-09678" class="html-bibr">24</a>].</p>
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<p>Innovative cooling water mattress and its supplying cooling system.</p>
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<p>Hydraulic scheme of the cooling water production and distribution system (RadMAT system) and its connection with an innovative cooling water mattress.</p>
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<p>Three types of beddings that were used during the experiment: the innovative cooling water mattress (CM), the commercial water mattress (M), and the conventional straw bedding (S). The last two are the referenced ones.</p>
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<p>Outdoor temperature measured from 6:00 at 14.08.2022 to 6:00 at 21.08.2022 in the experimental period by the meteorological station located near the selected barn.</p>
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<p>Experimental barn’s air temperature, humidity, and Temperature Humidity Index (THI) for the experimental period.</p>
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<p>Hourly average Temperature Humidity Index (THI) level distribution for each experimental day.</p>
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<p>Water temperature measured at the inlet and outlet to the cooling water mattress and the temperature increment between them.</p>
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<p>The surface temperature of the cooling water mattress and the commercial mattress for all experimental days.</p>
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<p>Thermograms taken 1 min after the animals got up from their bedding areas (temperature scale in °C).</p>
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<p>Cows’ skin temperature in the thigh area within 7 min after animals got up.</p>
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<p>Cows’ skin temperature in the abdomen area within 7 min after animals got up.</p>
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<p>Changes in rumen temperature of each cow during the experimental days.</p>
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17 pages, 8968 KiB  
Article
Improvement of Optical-Induced Thermography Defect Detectability by Equivalent Heating and Non-Uniformity Compensation in Polyetheretherketone
by Yoonjae Chung, Chunyoung Kim, Seungju Lee, Hyunkyu Suh and Wontae Kim
Appl. Sci. 2024, 14(19), 8720; https://doi.org/10.3390/app14198720 - 27 Sep 2024
Cited by 1 | Viewed by 851
Abstract
This paper deals with the experimental procedures of lock-in thermography (LIT) for polyetheretherketone (PEEK), which is used as a lightweight material in various industrial fields. The LIT has limitations due to non-uniform heating by external optic sources and the non-uniformity correction (NUC) of [...] Read more.
This paper deals with the experimental procedures of lock-in thermography (LIT) for polyetheretherketone (PEEK), which is used as a lightweight material in various industrial fields. The LIT has limitations due to non-uniform heating by external optic sources and the non-uniformity correction (NUC) of the infrared (IR) camera. It is generating unintended contrast in the IR image in thermal imaging inspection, reducing detection performance. In this study, the non-uniformity effect was primarily improved by producing an equivalent array halogen lamp. Then, we presented absolute temperature compensation (ATC) and temperature ratio compensation (TRC) techniques, which can equalize the thermal contrast of the test samples by compensating for them using reference samples. By applying compensation techniques to data acquired from the test samples, defect detectability improvement was quantitatively presented. In addition, binarization was performed and detection performance was verified by evaluating the roundness of the detected defects. As a result, the contrast of the IR image was greatly improved by applying the compensation technique. In particular, raw data were enhanced by up to 54% using the ATC compensation technique. Additionally, due to improved contrast, the signal-to-noise ratio (SNR) was improved by 7.93%, and the R2 value of the linear trend equation exceeded 0.99, demonstrating improved proportionality between the defect condition and SNR. Full article
(This article belongs to the Section Optics and Lasers)
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<p>Principle of radiation emission from surrounding environment and heat source in thermographic testing.</p>
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<p>The principle of the four-point phase shifting method for thermal waves demodulated on the object surface.</p>
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<p>Geometric information of PEEK test sample.</p>
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<p>The experimental configuration for LIT testing with reflection mode.</p>
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<p>Information on HA lamp and parabolic lamp: (<b>a</b>) geometric details of HA lamp, (<b>b</b>) HA lamp picture, and (<b>c</b>) conventional parabolic lamp picture.</p>
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<p>The LIT testing and analysis flow chart of study.</p>
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<p>IR Images at 50 s of modulation frequency 0.01 Hz along each lamp type: (<b>a</b>) parabolic type, (<b>b</b>) HA type.</p>
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<p>Sample surface temperature distribution according to lamp type: (<b>a</b>) horizontal direction, (<b>b</b>) vertical direction.</p>
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<p>Images along the data type at modulation frequency 0.01 Hz: (<b>a</b>) raw (temperature), (<b>b</b>) amplitude, and (<b>c</b>) phase.</p>
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<p>Images along the data type at modulation frequency 0.01 Hz with the ATC compensation method applied: (<b>a</b>) raw (temperature), (<b>b</b>) amplitude, and (<b>c</b>) phase.</p>
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<p>Images along the data type at modulation frequency 0.01 Hz with the TRC compensation method applied: (<b>a</b>) raw (temperature), (<b>b</b>) amplitude, and (<b>c</b>) phase.</p>
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<p>Amplitude binarization image by Otsu algorithm: (<b>a</b>) not ATC applied, (<b>b</b>) ATC applied.</p>
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<p>Phase binarization image by Otsu algorithm: (<b>a</b>) not ATC applied, (<b>b</b>) ATC applied.</p>
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<p>SNR trend along the compensation method applied: (<b>a</b>) according to defect depth, (<b>b</b>) according to defect diameter.</p>
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12 pages, 1611 KiB  
Article
Application of High-Resolution Infrared Thermography to Study the Effects of Technologically Processed Antibodies on the Near-Surface Layer of Aqueous Solutions
by Elena Don, Evgenii Zubkov, Ekaterina Moroshkina, Irina Molodtsova, Anastasia Petrova and Sergey Tarasov
Molecules 2024, 29(18), 4309; https://doi.org/10.3390/molecules29184309 - 11 Sep 2024
Viewed by 691
Abstract
A new class of biologics is obtained using the technologically processed of antibodies (TPA), which are used as the initial substance, and their dilution at each stage is accompanied by a controlled external vibrational (mechanical) treatment. This article focuses on the development and [...] Read more.
A new class of biologics is obtained using the technologically processed of antibodies (TPA), which are used as the initial substance, and their dilution at each stage is accompanied by a controlled external vibrational (mechanical) treatment. This article focuses on the development and validation of a novel technique that can be applied for assessing the identity of TPA-based drugs. It has previously been found that after such treatment, the resulting solution either acquired new properties that were not present in the initial substance or a quantitative change in properties compared to the initial substance was observed. The use of mechanical treatment during the manufacture of the TPA-based drugs can cause the formation of new bonds between the solvent and antibody molecules. These changes manifest themselves in altered adsorption at the surface of the test solutions, which results in the formation of a near-surface film. One of the indicators of such events is the change in the surface temperature of the solution, which can be analyzed using high-resolution thermography. Unlike other methods, the high-resolution thermography allows the near-surface layer of a heterogeneous aqueous solution to be clearly visualized and quantified. A number of experiments were performed: seven replicates of sample preparations were tested; the influence of factors “day” or “operator” was investigated during 12 days of testing by two operators. The method also allowed us to distinguish between technologically processed antibodies and samples containing technologically processed buffer. The thermographic analysis has proven to be a simple, specific, and reproducible technique that can be used to analyze the identity of TPA-based drugs, regardless of the dosage form tested. Full article
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<p>The mean surface area free of film for samples of one batch of the test sample and placebo. (*—<span class="html-italic">p</span> &lt; 0.1 vs. placebo, all q &gt; 17.8, qcrit = 3.98, Tukey test).</p>
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<p>An example of a scatter plot with straight line approximation and its confidence interval.</p>
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<p>Confidence intervals which show the difference in the mean surface areas free of film for the compared groups of samples.</p>
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<p>Mean surface area free of film (in relative units) for samples of TPAs to various molecules, and control (*—<span class="html-italic">p</span> &lt; 0.1 vs. placebo sample, q1 = 36.5, q2 = −25.5, qcrit = 2.95, Tukey test).</p>
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<p>A representative image of a Petri dish with a surface film formed during cooling. The film is the dark part of the image. The lighter part of the image shows the area free of film.</p>
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13 pages, 3715 KiB  
Article
Thermal Reading of Texts Buried in Historical Bookbindings
by Stefano Paoloni, Giovanni Caruso, Noemi Orazi, Ugo Zammit and Fulvio Mercuri
Sensors 2024, 24(17), 5493; https://doi.org/10.3390/s24175493 - 24 Aug 2024
Viewed by 743
Abstract
In the manufacture of ancient books, it was quite common to insert written scraps belonging to earlier library material into bookbindings. For scholars like codicologists and paleographers, it is extremely important to have the possibility of reading the text lying on such scraps [...] Read more.
In the manufacture of ancient books, it was quite common to insert written scraps belonging to earlier library material into bookbindings. For scholars like codicologists and paleographers, it is extremely important to have the possibility of reading the text lying on such scraps without dismantling the book. In this regard, in this paper, we report on the detection of these texts by means of infrared (IR) pulsed thermography (PT), which, in recent years, has been specifically proven to be an effective tool for the investigation of Cultural Heritage. In particular, we present a quantitative analysis based, for the first time, on PT images obtained from books of historical relevance preserved at the Biblioteca Angelica in Rome. The analysis has been carried out by means of a theoretical model for the PT signal, which makes use of two image parameters, namely, the distortion and the contrast, related to the IR readability of the buried texts. As shown in this paper, the good agreement between the experimental data obtained in the historical books and the theoretical analysis proved that the capability of the adopted PT method could be fruitfully applied, in real case studies, to the detection of buried texts and to the quantitative characterization of the parameters affecting their thermal readability. Full article
(This article belongs to the Section Remote Sensors)
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<p>A book printed in 1758 (ʘ.2.16) from the Biblioteca Angelica of Rome: (<b>a</b>) a picture of the back endleaf; (<b>b</b>) a thermogram recorded 0.02 s after the light pulse, showing the text buried at a depth of 95 μm; (<b>c</b>) a thermogram recorded 0.30 s after the light pulse, also showing the text buried at a depth of 155 μm.</p>
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<p>A book printed in 1592 (f.9.31) from the Biblioteca Angelica of Rome: (<b>a</b>) a picture of the back endleaf; thermograms of the black framed part (area III) recorded 0.02 s (<b>b</b>), 0.05 s (<b>c</b>) and 0.30 s (<b>d</b>) after the light pulse, showing the text buried at a depth of 110 μm.</p>
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<p>A sketch of the specimen considered in the model.</p>
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<p>A sketch of the PT signal profiles over the edge at <math display="inline"><semantics> <mrow> <mover accent="true"> <mrow> <mi>x</mi> </mrow> <mo>¯</mo> </mover> </mrow> </semantics></math> = 0 of a subsurface ink feature, where 1D (black dotted line) and 3D (continuous gray line) heat diffusion regimes are considered. Also represented is the distortion index ∆ (see text).</p>
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<p>The theoretical delay-time dependence of the contrast <span class="html-italic">C</span>(<span class="html-italic">t</span>) (<b>a</b>) and the distortion index ∆(<span class="html-italic">t</span>) (<b>b</b>) over the edge of graphical features buried at different depths in a paper layer.</p>
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<p>Sketches of the bookbinding cross-sections of (<b>a</b>) book ʘ.2.16 and (<b>b</b>) book f.9.31.</p>
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<p>Thermograms of text I buried just beneath the endpaper in the area framed in blue previously shown in <a href="#sensors-24-05493-f001" class="html-fig">Figure 1</a>b, obtained for increasing delay times of 0.02 s (<b>a</b>), 0.05 s (<b>b</b>) and 0.30 s (<b>c</b>) after the heating light pulse. (<b>d</b>) The PT signal profiles obtained over one of the letters.</p>
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<p>Thermograms of text II buried just beneath the endpaper in the area framed in red (previously shown in <a href="#sensors-24-05493-f001" class="html-fig">Figure 1</a>c) obtained for increasing delay times of 0.02 s (<b>a</b>), 0.05 s (<b>b</b>) and 0.30 s (<b>c</b>) after the heating light pulse. (<b>d</b>) The PT signal profiles obtained over one of the letters.</p>
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<p>Thermograms of text III buried just beneath the area framed in black of the endpaper previously shown in <a href="#sensors-24-05493-f002" class="html-fig">Figure 2</a>a, obtained for increasing delay times of 0.02 s (<b>a</b>), 0.05 s (<b>b</b>) and 0.30 s (<b>c</b>) after the heating light pulse. (<b>d</b>) The PT signal profiles obtained over one of the letters.</p>
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<p>The time dependence of (<b>a</b>) the contrast <span class="html-italic">C</span>(<span class="html-italic">t</span>) and (<b>b</b>) distortion ∆ of the texts buried at different depths. The continuous lines represent the theoretical prediction, while the symbols correspond to the experimental data obtained according to the procedure described in the text.</p>
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23 pages, 9322 KiB  
Article
Defect Detection of GFRP Composites through Long Pulse Thermography Using an Uncooled Microbolometer Infrared Camera
by Murniwati Anwar, Faizal Mustapha, Mohd Na’im Abdullah, Mazli Mustapha, Nabihah Sallih, Azlan Ahmad and Siti Zubaidah Mat Daud
Sensors 2024, 24(16), 5225; https://doi.org/10.3390/s24165225 - 12 Aug 2024
Viewed by 1216
Abstract
The detection of impact and depth defects in Glass Fiber Reinforced Polymer (GFRP) composites has been extensively studied to develop effective, reliable, and cost-efficient assessment methods through various Non-Destructive Testing (NDT) techniques. Challenges in detecting these defects arise from varying responses based on [...] Read more.
The detection of impact and depth defects in Glass Fiber Reinforced Polymer (GFRP) composites has been extensively studied to develop effective, reliable, and cost-efficient assessment methods through various Non-Destructive Testing (NDT) techniques. Challenges in detecting these defects arise from varying responses based on the geometrical shape, thickness, and defect types. Long Pulse Thermography (LPT), utilizing an uncooled microbolometer and a low-resolution infrared (IR) camera, presents a promising solution for detecting both depth and impact defects in GFRP materials with a single setup and minimal tools at an economical cost. Despite its potential, the application of LPT has been limited due to susceptibility to noise from environmental radiation and reflections, leading to blurry images. This study focuses on optimizing LPT parameters to achieve accurate defect detection. Specifically, we investigated 11 flat-bottom hole (FBH) depth defects and impact defects ranging from 8 J to 15 J in GFRP materials. The key parameters examined include the environmental temperature, background reflection, background color reflection, and surface emissivity. Additionally, we employed image processing techniques to classify composite defects and automatically highlight defective areas. The Tanimoto Criterion (TC) was used to evaluate the accuracy of LPT both for raw images and post-processed images. The results demonstrate that through parameter optimization, the depth defects in GFRP materials were successfully detected. The TC success rate reached 0.91 for detecting FBH depth defects in raw images, which improved significantly after post-processing using Canny edge detection and Hough circle detection algorithms. This study underscores the potential of optimized LPT as a cost-effective and reliable method for detecting defects in GFRP composites. Full article
(This article belongs to the Section Sensor Materials)
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<p>Radiation captured during data measurement using an IR camera [<a href="#B33-sensors-24-05225" class="html-bibr">33</a>].</p>
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<p>Front rear of the eleven flat bottom holes (FBH) of the GFRP sample.</p>
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<p>Impact defect of the GFRP sample: (<b>a</b>) sample IM1 and (<b>b</b>) sample IM2.</p>
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<p>LPT setup using (<b>a</b>) reflex configurations and (<b>b</b>) an enclosure.</p>
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<p>Example of black-colored paper used in the experiment.</p>
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<p>Close setup of the enclosure using hard cardboard.</p>
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<p>Surface material covered with color tape.</p>
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<p>Image-segmentation method for automatic defect detection.</p>
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<p>Edge detection flowchart.</p>
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<p>Circle detection algorithm flowchart.</p>
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<p>Outdoor output image at temperatures above 35 °C for 10–40 s of heating duration.</p>
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<p>Indoor output image at room temperature (23–25 °C) for 10–40 s of heating duration.</p>
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<p>Indoor output image at low temperatures (16–18 °C) for 10–40 s of heating duration.</p>
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<p>Temperature bar for one of the images captured outdoors at temperatures above 35 °C.</p>
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<p>Output image for the black-colored background of the internal wall for 20–40 s of heating.</p>
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<p>Output image for the white-colored background of the internal wall for 20–40 s of heating.</p>
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<p>Output image for the yellow-colored background of the internal wall for 20–40 s of heating.</p>
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<p>Result for indoors, without an enclosure at temperatures from 16 °C to 18 °C from 20 s (first row) to 40 s (last row) of heating.</p>
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<p>Result for indoors, using an enclosure at temperatures from 16 °C to 18 °C from 20 s (first row) to 40 s (last row) of heating.</p>
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<p>Without tape covered on the surface material at low temperatures (16° C to 18 °C) from 10 s (first row) to 40 s (last row) of heating.</p>
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<p>Yellow tape covered on top of the surface sample at low temperatures (16 °C to 18 °C) from 10 s (first row) to 40 s (last row) of heating.</p>
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<p>With black tape on the surface material at low temperatures (16 °C to 18 °C) from 10 s (first row) to 40 s (last row) of heating.</p>
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<p>Optimized FBH defect of the GFRP detected.</p>
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<p>Impact defect detection results using optimized parameters for samples (<b>a</b>) B1 and (<b>b</b>) B2.</p>
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<p>FBH depth defect detection process using Canny edge detection segmentation.</p>
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<p>FBH depth defect detection process using Sobel edge detection segmentation.</p>
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<p>Edge image segmentation for GFRP impact defect detection using the Canny edge detection method for (<b>a</b>) defect IM1 and (<b>b</b>) defect IM2.</p>
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<p>FBH depth defect detection using histogram threshold.</p>
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<p>Histogram threshold segmentation method result for (<b>a</b>) defect IM1 and (<b>b</b>) defect IM2.</p>
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<p>FBH defect detection using the circle segmentation method.</p>
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24 pages, 9047 KiB  
Article
Integrated Investigations to Study the Materials and Degradation Issues of the Urban Mural Painting Ama Il Tuo Sogno by Jorit Agoch
by Giulia Germinario, Andrea Luigia Logiodice, Paola Mezzadri, Giorgia Di Fusco, Roberto Ciabattoni, Davide Melica and Angela Calia
Sustainability 2024, 16(12), 5069; https://doi.org/10.3390/su16125069 - 14 Jun 2024
Viewed by 1410
Abstract
This paper focuses on an integrated approach to study the materials and the degradation issues in the urban mural painting Ama Il Tuo Sogno, painted by the famous street artist Jorit Agoch in Matera (Italy). The study was conducted in the framework of [...] Read more.
This paper focuses on an integrated approach to study the materials and the degradation issues in the urban mural painting Ama Il Tuo Sogno, painted by the famous street artist Jorit Agoch in Matera (Italy). The study was conducted in the framework of a conservation project, aiming to contrast a progressive decay affecting the artifact that started a few months after its creation. Multi-analytical techniques were used to investigate the stratigraphy and chemical composition of the pictorial film within a low-impact analytical protocol for sustainable diagnostics. They included polarized light microscopy in UV and VIS reflected light, FTIR spectroscopy, Py-GC-HRAMS, and SEM-EDS. The mineralogical–petrographic composition of the mortar employed in the pictorial support was also studied with optical microscopy of thin sections and X-ray diffractometry. To know the mechanism underlying the degradation, IR thermography was performed in situ to establish the waterways and the distribution of the humidity in the mural painting. In addition, ion chromatography and X-ray diffractometry were used to identify and quantify the soluble salts and to understand their sources. The overall results allowed us to determine the chemical composition of the binder and pigments within the pictorial layers, the mineralogical–petrographic characteristics of the mortar of the support, and the execution technique of the painting. They also highlighted a correlation between the presence of humidity in the painted mural and the salt damage. The mineralogical phases were detected in the mural materials by XRD, and the results of ion chromatographic analyses suggested a supply of soluble salts mainly from the mortar of the support. Finally, the study provided basic knowledge for planning appropriate sustainable conservation measures. Full article
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Figure 1

Figure 1
<p>The mural painting <span class="html-italic">Ama Il Tuo Sogno</span> (6.45 × 2.10 m<sup>2</sup>) by Jorit Agoch and the sampling points.</p>
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<p>Decay affecting the mural painting: (<b>a</b>) lack of adhesion and lifting of pictorial film; (<b>b</b>) lacuna on painting layers; (<b>c</b>) white veils due to efflorescence; (<b>d</b>) crystal salt aggregates on the surface, as observed with a Dino Lite video microscope (50× magnification).</p>
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<p>Cross-section stratigraphy under reflected VIS light: (<b>a</b>) JA1 and (<b>b</b>) JA2 samples, where layer a is the mortar support; (<b>c</b>) JA9 sample, where layer a is the stone support.</p>
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<p>Cross-section stratigraphy under reflected VIS (on the <b>right</b>) and UV light (on the <b>left</b>) in the JA4 sample.</p>
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<p>JA4 sample: backscattered image of the pink pictorial layer (b) and the dark red/orange layer (a), EDS spectra (Sp.) and maps of titanium, silicon, calcium, and iron.</p>
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<p>ATR-FTIR spectrum of the JA1 (in bleu), brown JA4 (in brown), and black JA9 (in orange) samples.</p>
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<p>Comparison of two FTIR-ATR spectra relative to the JA4 mural painting sample (in purple) and RV205 spray paint sample (in orange).</p>
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<p>THM-GC-HRAMS chromatograms for RV136 (<b>top</b>), RV97 (<b>middle</b>) and JA4 (<b>bottom</b>) at a pyrolysis temperature of 550 °C. (Key: 1: benzaldehyde; 2: octanoic acid, ME; 3: benzoic acid, ME; 4: decanoic acid; 5: phthalic anhydride; 6: 1(3H)-isobenzofuranone; 7: octanedioic acid, DME; 8:dimethyl phthalate; 9: N-propyl benzamide; 10: nonanedioic acid, DME; 11: decenedioic acid, diethyl ester; 12: decanedioic acid, DME; 13: 1,4-benzene dicarboxylic acid; 14: dimethyl phthalate; 15: hexanoic acid, ME; 16: isopropyl phthalate; 17: dibutyl phthalate; 18: oleic acid, ME; 19: octadecanoic acid, ME; 20: docosanoic acid, ME; 21: linoleic acid, ME; 22: oxiraneoctanoic acid, 3-octyl, ME; 23: phthalic acid, methyl phenyl ester; 24: phthalic acid, methyl 2-pentyl ester).</p>
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<p>Thin-section micrographs (transmitted light, cross-nicols) of (<b>a</b>) top mortar layer; (<b>b</b>) bottom mortar layer.</p>
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<p>XRD spectra: (<b>a</b>) IG21 mortar used for the top plaster layer; (<b>b</b>) KD2 mortar used in the bottom plaster layer. (Key: A: albite; M: calcite magnesian; P: portlandite; Q: quartz; C<sub>2</sub>S: belite; C<sub>3</sub>S: alite; C<sub>3</sub>A: celite).</p>
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<p>Thermographic images of the mural painting: (<b>a</b>) spring season; (<b>b</b>) autumn season; (<b>c</b>) overlapping of the thermographic image in spring season with the graphic map of the decay.</p>
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<p>Weight percentages of anions (<b>a</b>) and cations (<b>b</b>) in the samples from the mural paintings, in the raw mortar materials of the preparatory layers, and in the samples from the masonry wall. (Sample key: IG21, raw mortar used for the top layer in the paint support; KD2, raw mortar used for the bottom layer in the paint support; JA3, efflorescence on the painting; JA5, mortar from the top layer under the painting; JA6, efflorescence on the mortar joint of the wall; JA7, joint mortar powder; JA8, white veil on the painting; JA10, white veil on the stone ashlar of the wall; JA11, stone ashlar of the wall).</p>
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<p>XRD spectra: (<b>a</b>) efflorescence on the painted surface (JA3); (<b>b</b>) white veil on the painted surface (JA8); (<b>c</b>) efflorescence on the wall mortar joint (JA6). (Key: E: epsomite; G: gypsum; M: calcite magnesian; MPh: magnesium phosphate; Q: quartz; Th: thenardite).</p>
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