In cognitive radio (CR), superposition cooperative spectrum sensing (SPCSS) is able to offer a much improved sensing reliability compared to individual sensing. Because of the differences in sensing channel condition, the reporting order for each cognitive radio user (CU) will highly affect the sensing performance of the network. In this paper, we propose an algorithm to assign the best reporting order to each CU in order to maximize sensing performance under SPCSS. The numerical results show that the proposed scheme can obtain the same performance as the optimal scheme.