A surface plasmon polaritons (SPPs) refractive index sensor which consists of two metal-insulator-metal (MIM) waveguides coupled to each other by a ring resonator is proposed. The transmission properties are numerically simulated by finite element method. The sensing characteristics of such structure are systematically analyzed by investigating the transmission spectrum. The results indicate that there exist three resonance peaks in the transmission spectrum, and all of which have a linear relationship with the refractive index of the material under sensing. Through the optimization of structural parameters, we achieve a theoretical value of the refractive index sensitivity as high as 3460nmRIU(-1). Furthermore, this structure can also be used as a temperature sensor with temperature sensitivity of 1.36nm/°C. This work paves the way toward sensitive nanometer scale refractive index sensor and temperature sensor for design and application.